RU2588568C2 - Композиция полипропилена, армированного волокнами с высокой текучестью - Google Patents
Композиция полипропилена, армированного волокнами с высокой текучестью Download PDFInfo
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- RU2588568C2 RU2588568C2 RU2014143382/04A RU2014143382A RU2588568C2 RU 2588568 C2 RU2588568 C2 RU 2588568C2 RU 2014143382/04 A RU2014143382/04 A RU 2014143382/04A RU 2014143382 A RU2014143382 A RU 2014143382A RU 2588568 C2 RU2588568 C2 RU 2588568C2
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- Prior art keywords
- propylene
- propylene copolymer
- mass
- composition
- copolymer
- Prior art date
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- -1 Polypropylene Polymers 0.000 title claims abstract description 99
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- 239000004743 Polypropylene Substances 0.000 title claims abstract description 79
- 239000000203 mixture Substances 0.000 title claims abstract description 74
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 128
- 229920001577 copolymer Polymers 0.000 claims abstract description 102
- 239000011159 matrix material Substances 0.000 claims abstract description 55
- 229920001384 propylene homopolymer Polymers 0.000 claims abstract description 49
- 238000000034 method Methods 0.000 claims abstract description 41
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- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 31
- 229920001198 elastomeric copolymer Polymers 0.000 claims abstract description 30
- 239000005977 Ethylene Substances 0.000 claims abstract description 28
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- 239000000155 melt Substances 0.000 claims description 17
- 239000011152 fibreglass Substances 0.000 claims description 10
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- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000013001 point bending Methods 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 229920005653 propylene-ethylene copolymer Polymers 0.000 description 1
- 238000004445 quantitative analysis Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/02—Heterophasic composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Ethene-propene or ethene-propene-diene copolymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
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| EP12163221 | 2012-04-04 | ||
| PCT/EP2013/056578 WO2013149915A1 (en) | 2012-04-04 | 2013-03-27 | High-flow fiber reinforced polypropylene composition |
Publications (2)
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| RU2014143382A RU2014143382A (ru) | 2016-05-27 |
| RU2588568C2 true RU2588568C2 (ru) | 2016-07-10 |
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| RU2014143382/04A RU2588568C2 (ru) | 2012-04-04 | 2013-03-27 | Композиция полипропилена, армированного волокнами с высокой текучестью |
Country Status (11)
| Country | Link |
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| US (1) | US9650504B2 (enExample) |
| EP (1) | EP2834301B1 (enExample) |
| KR (1) | KR101495488B1 (enExample) |
| CN (1) | CN104204070A (enExample) |
| BR (1) | BR112014024333B1 (enExample) |
| ES (1) | ES2604902T3 (enExample) |
| IN (1) | IN2014DN07937A (enExample) |
| MX (1) | MX349998B (enExample) |
| PL (1) | PL2834301T3 (enExample) |
| RU (1) | RU2588568C2 (enExample) |
| WO (1) | WO2013149915A1 (enExample) |
Cited By (4)
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| RU2699810C1 (ru) * | 2016-07-25 | 2019-09-11 | Бореалис Аг | Вязкая композиция пропилена с хорошей стабильностью размеров и отличным внешним видом поверхности |
| RU2721714C1 (ru) * | 2016-07-25 | 2020-05-21 | Бореалис Аг | Соединения для наружных элементов автомобиля с высокой текучестью и отличным внешним видом поверхности |
| RU2733961C1 (ru) * | 2017-02-21 | 2020-10-08 | Милликен Энд Компани | Способ получения гетерофазных полимерных композиций |
| RU2754224C1 (ru) * | 2018-07-13 | 2021-08-30 | Бореалис Аг | Композиция гетерофазного полипропилена с улучшенным балансом свойств |
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| DE102013110036A1 (de) * | 2013-09-12 | 2015-03-12 | Benecke-Kaliko Ag | Folie und Verfahren zu deren Herstellung |
| CN105745269B (zh) * | 2013-11-29 | 2018-03-13 | 博禄塑料（上海）有限公司 | 具有低收缩率和平衡的机械性能的聚丙烯组合物 |
| CN105829437B (zh) * | 2013-12-20 | 2018-09-18 | 博禄塑料（上海）有限公司 | 具有低线性热膨胀系数和高尺寸稳定性的聚丙烯组合物 |
| WO2016101139A1 (en) * | 2014-12-23 | 2016-06-30 | Borouge Compounding Shanghai Co., Ltd. | Fiber reinforced polypropylene composite |
| ES2837860T3 (es) * | 2015-04-27 | 2021-07-01 | Borealis Ag | Material compuesto de polipropileno |
| PL3095818T3 (pl) * | 2015-05-22 | 2019-09-30 | Borealis Ag | Kompozyt polipropylen-włókno węglowe |
| ES2733836T3 (es) | 2015-05-22 | 2019-12-03 | Borealis Ag | Composición polimérica reforzada con fibra |
| ES2676310T3 (es) | 2015-07-01 | 2018-07-18 | Borealis Ag | Composición de polipropileno reforzado con fibras con alta deformación de rotura |
| WO2017041296A1 (en) * | 2015-09-11 | 2017-03-16 | Borouge Compounding Shanghai Co., Ltd. | Polypropylene composition |
| KR101958609B1 (ko) * | 2015-09-13 | 2019-07-04 | 밀리켄 앤드 캄파니 | 헤테로상 중합체 조성물의 제조 방법 |
| CN105348647B (zh) * | 2015-12-14 | 2018-02-16 | 上海金发科技发展有限公司 | 一种玻纤增强聚丙烯复合物及其制备方法 |
| EP3184586B1 (en) * | 2015-12-23 | 2019-04-10 | Borealis AG | Light weight fiber reinforced polypropylene composition |
| CN106905604B (zh) * | 2015-12-23 | 2019-05-24 | 余姚市菲特塑料有限公司 | 一种聚丙烯组合物的制备方法 |
| EP3199586B1 (en) * | 2016-01-29 | 2020-04-29 | Borealis AG | Polyolefin composition with improved thoughness |
| US10519306B2 (en) * | 2016-05-18 | 2019-12-31 | Borealis Ag | Soft polypropylene composition |
| WO2018017551A1 (en) * | 2016-07-20 | 2018-01-25 | Sabic Global Technologies B.V. | Glass-filled polypropylene compositions |
| EP3494175B1 (en) * | 2016-08-03 | 2020-06-10 | Borealis AG | Fiber reinforced polypropylene composite |
| PL3309212T3 (pl) * | 2016-10-17 | 2019-05-31 | Borealis Ag | Kompozyt polipropylenowy wzmocniony włóknem |
| EP3330315B1 (en) | 2016-12-01 | 2021-10-20 | Borealis AG | Foamed polypropylene composition |
| ES2873506T3 (es) * | 2016-12-09 | 2021-11-03 | Borealis Ag | Composición de polipropileno para aplicaciones de espuma |
| WO2018132368A1 (en) * | 2017-01-10 | 2018-07-19 | Celanese International Corporation | Long fiber-reinforced propylene composition for use in a thin part |
| CN110291140A (zh) | 2017-01-10 | 2019-09-27 | 国际人造丝公司 | 具有低排放的高流动纤维增强的丙烯组合物 |
| WO2019066670A1 (ru) * | 2017-09-26 | 2019-04-04 | Закрытое акционерное общество "Уральский завод полимерных технологий "Маяк" | Стальная труба и способ получения радиационно-модифицированного покрытия |
| EP3461860A1 (en) | 2017-09-29 | 2019-04-03 | Borealis AG | Reinforced polypropylene composition |
| PL3495422T3 (pl) * | 2017-12-05 | 2021-05-31 | Borealis Ag | Kompozycja polipropylenowa wzmocniona włóknami |
| EP3495421B2 (en) * | 2017-12-05 | 2024-03-13 | Borealis AG | Fiber reinforced polypropylene composition |
| WO2019241066A1 (en) * | 2018-06-11 | 2019-12-19 | W.R. Grace & Co.-Conn. | Propylene-ethylene random copolymers with low xs/et ratio and high mfr |
| EP3604425A1 (en) | 2018-07-31 | 2020-02-05 | Borealis AG | Foamed polypropylene composition comprising polymeric fibers |
| WO2020152315A1 (en) * | 2019-01-25 | 2020-07-30 | Abu Dhabi Polymers Co. Ltd (Borouge) L.L.C. | Foamable polypropylene composition with excellent mechanical performance |
| EP3913005A1 (en) * | 2020-05-22 | 2021-11-24 | Borealis AG | Glass fiber reinforced composite with narrow mwd polypropylene |
| CN116745358A (zh) * | 2021-01-27 | 2023-09-12 | 博里利斯股份有限公司 | 包含聚丙烯聚合物和回收塑料材料的聚烯烃组合物 |
| EP4286476B1 (en) * | 2022-05-31 | 2025-01-22 | Borealis AG | Glass fiber composite |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2154657C2 (ru) * | 1992-06-27 | 2000-08-20 | ТАРГОР ГмбХ | Полипропиленовая формовочная смесь для изготовления фасонных деталей с декоративной поверхностью |
| EP1357144A1 (en) * | 2002-04-24 | 2003-10-29 | Borealis GmbH | Polypropylene compositions |
| CN101568589A (zh) * | 2006-12-20 | 2009-10-28 | 巴塞尔聚烯烃意大利有限责任公司 | 填充的聚烯烃组合物 |
Family Cites Families (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61281144A (ja) | 1985-06-06 | 1986-12-11 | Idemitsu Petrochem Co Ltd | 光沢性の良好なポリプロピレン樹脂組成物 |
| FI80055C (fi) | 1986-06-09 | 1990-04-10 | Neste Oy | Foerfarande foer framstaellning av katalytkomponenter foer polymerisation av olefiner. |
| US5077255A (en) | 1986-09-09 | 1991-12-31 | Exxon Chemical Patents Inc. | New supported polymerization catalyst |
| US5036034A (en) | 1989-10-10 | 1991-07-30 | Fina Technology, Inc. | Catalyst for producing hemiisotactic polypropylene |
| US5382459A (en) | 1989-10-20 | 1995-01-17 | Toyoda Gosei Co., Ltd. | Glass fiber reinforced resin composition and wheel cap formed of same |
| US5234879A (en) | 1990-12-19 | 1993-08-10 | Neste Oy | Method for the modification of catalysts intended for the polymerization of olefins |
| FI86866C (fi) | 1990-12-19 | 1992-10-26 | Neste Oy | Foerfarande foer modifiering av katalysatorer avsedda foer polymerisation av olefiner |
| FI86867C (fi) | 1990-12-28 | 1992-10-26 | Neste Oy | Flerstegsprocess foer framstaellning av polyeten |
| FI88047C (fi) | 1991-05-09 | 1993-03-25 | Neste Oy | Pao tvenne elektrondonorer baserad katalysator foer polymerisation av olefiner |
| FI88048C (fi) | 1991-05-09 | 1993-03-25 | Neste Oy | Grovkornig polyolefin, dess framstaellningsmetod och en i metoden anvaend katalysator |
| US5416228A (en) | 1991-10-07 | 1995-05-16 | Fina Technology, Inc. | Process and catalyst for producing isotactic polyolefins |
| IT1260495B (it) | 1992-05-29 | 1996-04-09 | Himont Inc | Concentrati adatti alla preparazione di poliolefine funzionalizzate e processo di funzionalizzazione mediante detti concentrati |
| AT403376B (de) | 1995-07-03 | 1998-01-26 | Danubia Petrochem Polymere | Metallocene mit silylsubstituierten brücken und deren einsatz für die olefinpolymerisation |
| FI104826B (fi) | 1996-01-30 | 2000-04-14 | Borealis As | Heteroatomilla substituoituja metalloseeniyhdisteitä olefiinipolymerointikatalyytti-systeemejä varten ja menetelmä niiden valmistamiseksi |
| FI971565A7 (fi) | 1997-04-14 | 1998-10-15 | Borealis As | Olefiinien polymerointiin tarkoitettujen katalysaattorisysteemien substituoituja metalloseeniyhdisteitä, niiden välituotteet ja valmistusmenetelmä |
| GB9708487D0 (en) | 1997-04-25 | 1997-06-18 | Bp Chem Int Ltd | Novel catalysts for olefin polymerisation |
| EP1028123A3 (de) | 1997-06-10 | 2004-12-01 | Peroxid-Chemie GmbH & Co. KG. | Verfahren zur Herstellung von Metallocen-Verbindungen |
| FI111848B (fi) | 1997-06-24 | 2003-09-30 | Borealis Tech Oy | Menetelmä ja laitteisto propeenin homo- ja kopolymeerien valmistamiseksi |
| KR100516336B1 (ko) | 1997-09-05 | 2005-09-22 | 비피 케미칼즈 리미티드 | 중합 촉매 |
| GB9721559D0 (en) | 1997-10-11 | 1997-12-10 | Bp Chem Int Ltd | Novel polymerisation catalysts |
| FI974175A7 (fi) | 1997-11-07 | 1999-05-08 | Borealis As | Menetelmä polypropeenin valmistamiseksi |
| FI980342A0 (fi) | 1997-11-07 | 1998-02-13 | Borealis As | Polymerroer och -roerkopplingar |
| DE69812710T2 (de) | 1997-12-23 | 2003-10-23 | Borealis Technology Oy, Porvoo | Löslicher magnesiumhalogenidkomplex, herstellung und verwendung |
| GB9826874D0 (en) | 1998-12-07 | 1999-01-27 | Borealis As | Process |
| FI990003A7 (fi) | 1999-01-04 | 2000-07-05 | Borealis Polymers Oy | Polymeerikoostumus, menetelmä sen valmistamiseksi ja siitä valmistetut kalvot |
| FI991057A0 (fi) | 1999-05-07 | 1999-05-07 | Borealis As | Korkean jäykkyyden propeenipolymeerit ja menetelmä niiden valmistamiseksi |
| CN100519600C (zh) | 2002-06-25 | 2009-07-29 | 玻利阿黎斯技术有限公司 | 提高了抗刮性的聚烯烃及其制备方法 |
| EP1484343A1 (en) | 2003-06-06 | 2004-12-08 | Universiteit Twente | Process for the catalytic polymerization of olefins, a reactor system and its use in the same process |
| US8008388B2 (en) | 2005-12-14 | 2011-08-30 | Ferro Corporation | Weatherable glass fiber reinforced polyolefin composition |
| WO2008074715A1 (en) | 2006-12-20 | 2008-06-26 | Basell Poliolefine Italia S.R.L. | Filled polyolefin compositions |
| SI2308923T1 (sl) | 2009-10-09 | 2012-08-31 | Borealis Ag | Kompozit iz steklenih vlaken z izboljšano obdelovalnostjo |
-
2013
- 2013-03-27 PL PL13716980T patent/PL2834301T3/pl unknown
- 2013-03-27 CN CN201380018515.8A patent/CN104204070A/zh active Pending
- 2013-03-27 IN IN7937DEN2014 patent/IN2014DN07937A/en unknown
- 2013-03-27 MX MX2014011617A patent/MX349998B/es active IP Right Grant
- 2013-03-27 EP EP13716980.1A patent/EP2834301B1/en active Active
- 2013-03-27 KR KR1020147029908A patent/KR101495488B1/ko active Active
- 2013-03-27 US US14/389,543 patent/US9650504B2/en active Active
- 2013-03-27 ES ES13716980.1T patent/ES2604902T3/es active Active
- 2013-03-27 RU RU2014143382/04A patent/RU2588568C2/ru active
- 2013-03-27 BR BR112014024333-6A patent/BR112014024333B1/pt active IP Right Grant
- 2013-03-27 WO PCT/EP2013/056578 patent/WO2013149915A1/en not_active Ceased
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2154657C2 (ru) * | 1992-06-27 | 2000-08-20 | ТАРГОР ГмбХ | Полипропиленовая формовочная смесь для изготовления фасонных деталей с декоративной поверхностью |
| EP1357144A1 (en) * | 2002-04-24 | 2003-10-29 | Borealis GmbH | Polypropylene compositions |
| CN101568589A (zh) * | 2006-12-20 | 2009-10-28 | 巴塞尔聚烯烃意大利有限责任公司 | 填充的聚烯烃组合物 |
Non-Patent Citations (1)
| Title |
|---|
| ИВАНЮКОВ Д.В. и др. Полипропилен (Свойства и применение). - М.: Химия, 1974, с.141 - 142, 146,148. * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2699810C1 (ru) * | 2016-07-25 | 2019-09-11 | Бореалис Аг | Вязкая композиция пропилена с хорошей стабильностью размеров и отличным внешним видом поверхности |
| RU2721714C1 (ru) * | 2016-07-25 | 2020-05-21 | Бореалис Аг | Соединения для наружных элементов автомобиля с высокой текучестью и отличным внешним видом поверхности |
| US10941288B2 (en) | 2016-07-25 | 2021-03-09 | Borealis Ag | Stiff propylene composition with good dimensional stability and excellent surface appearance |
| US11111371B2 (en) | 2016-07-25 | 2021-09-07 | Borealis Ag | High flow automotive exterior compounds with excellent surface appearance |
| RU2733961C1 (ru) * | 2017-02-21 | 2020-10-08 | Милликен Энд Компани | Способ получения гетерофазных полимерных композиций |
| RU2754224C1 (ru) * | 2018-07-13 | 2021-08-30 | Бореалис Аг | Композиция гетерофазного полипропилена с улучшенным балансом свойств |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20140134718A (ko) | 2014-11-24 |
| RU2014143382A (ru) | 2016-05-27 |
| BR112014024333B1 (pt) | 2020-12-22 |
| US9650504B2 (en) | 2017-05-16 |
| MX349998B (es) | 2017-08-23 |
| EP2834301A1 (en) | 2015-02-11 |
| CN104204070A (zh) | 2014-12-10 |
| PL2834301T3 (pl) | 2017-07-31 |
| EP2834301B1 (en) | 2016-09-14 |
| US20150368449A1 (en) | 2015-12-24 |
| IN2014DN07937A (enExample) | 2015-05-01 |
| ES2604902T3 (es) | 2017-03-09 |
| WO2013149915A1 (en) | 2013-10-10 |
| KR101495488B1 (ko) | 2015-02-24 |
| MX2014011617A (es) | 2015-01-19 |
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