RU2263688C2 - Смеси стабилизаторов для полиолефинов - Google Patents
Смеси стабилизаторов для полиолефинов Download PDFInfo
- Publication number
- RU2263688C2 RU2263688C2 RU2002123336/04A RU2002123336A RU2263688C2 RU 2263688 C2 RU2263688 C2 RU 2263688C2 RU 2002123336/04 A RU2002123336/04 A RU 2002123336/04A RU 2002123336 A RU2002123336 A RU 2002123336A RU 2263688 C2 RU2263688 C2 RU 2263688C2
- Authority
- RU
- Russia
- Prior art keywords
- compound
- denotes
- butyl
- component
- stabilizer mixture
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 76
- 239000003381 stabilizer Substances 0.000 title claims abstract description 46
- 229920000098 polyolefin Polymers 0.000 title claims abstract description 28
- -1 amine compound Chemical class 0.000 claims abstract description 232
- 150000001875 compounds Chemical class 0.000 claims abstract description 136
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 66
- 229920000642 polymer Polymers 0.000 claims abstract description 40
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 26
- 230000000087 stabilizing effect Effects 0.000 claims abstract description 6
- 230000002378 acidificating effect Effects 0.000 claims abstract description 5
- 230000003647 oxidation Effects 0.000 claims abstract description 5
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 5
- 230000006378 damage Effects 0.000 claims abstract description 3
- 229920001577 copolymer Polymers 0.000 claims description 47
- 239000004952 Polyamide Substances 0.000 claims description 29
- 229920002647 polyamide Polymers 0.000 claims description 29
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 24
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 23
- 229920006324 polyoxymethylene Polymers 0.000 claims description 23
- 229930040373 Paraformaldehyde Natural products 0.000 claims description 18
- 150000001412 amines Chemical class 0.000 claims description 16
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 16
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 16
- 229920002554 vinyl polymer Polymers 0.000 claims description 15
- 239000004743 Polypropylene Substances 0.000 claims description 14
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 14
- 150000003839 salts Chemical class 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 12
- 125000002252 acyl group Chemical group 0.000 claims description 12
- 239000004417 polycarbonate Substances 0.000 claims description 12
- 229920000515 polycarbonate Polymers 0.000 claims description 12
- 229920001155 polypropylene Polymers 0.000 claims description 12
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 10
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 claims description 10
- 229920002292 Nylon 6 Polymers 0.000 claims description 9
- 229920002319 Poly(methyl acrylate) Polymers 0.000 claims description 9
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 9
- 229920000728 polyester Polymers 0.000 claims description 9
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 9
- 239000000047 product Substances 0.000 claims description 9
- 229920002614 Polyether block amide Polymers 0.000 claims description 8
- 239000004698 Polyethylene Substances 0.000 claims description 8
- 229920000573 polyethylene Polymers 0.000 claims description 8
- 229920000877 Melamine resin Polymers 0.000 claims description 7
- 150000001298 alcohols Chemical class 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 229920002635 polyurethane Polymers 0.000 claims description 7
- 239000004814 polyurethane Substances 0.000 claims description 7
- WTVNFKVGGUWHQC-UHFFFAOYSA-N decane-2,4-dione Chemical compound CCCCCCC(=O)CC(C)=O WTVNFKVGGUWHQC-UHFFFAOYSA-N 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 6
- 239000000178 monomer Substances 0.000 claims description 6
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-L Malonate Chemical compound [O-]C(=O)CC([O-])=O OFOBLEOULBTSOW-UHFFFAOYSA-L 0.000 claims description 5
- 229920000299 Nylon 12 Polymers 0.000 claims description 5
- XITRBUPOXXBIJN-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 XITRBUPOXXBIJN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052736 halogen Inorganic materials 0.000 claims description 5
- 150000002367 halogens Chemical class 0.000 claims description 5
- 229910017053 inorganic salt Inorganic materials 0.000 claims description 5
- 229920000647 polyepoxide Polymers 0.000 claims description 5
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 5
- 239000011118 polyvinyl acetate Substances 0.000 claims description 5
- 125000001424 substituent group Chemical group 0.000 claims description 5
- 239000004925 Acrylic resin Substances 0.000 claims description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 4
- 229920002302 Nylon 6,6 Polymers 0.000 claims description 4
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 4
- 229920000180 alkyd Polymers 0.000 claims description 4
- 235000013877 carbamide Nutrition 0.000 claims description 4
- 150000004292 cyclic ethers Chemical class 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 4
- 229920006380 polyphenylene oxide Polymers 0.000 claims description 4
- 150000003672 ureas Chemical class 0.000 claims description 4
- 239000004593 Epoxy Substances 0.000 claims description 3
- 229920000571 Nylon 11 Polymers 0.000 claims description 3
- 229920002396 Polyurea Polymers 0.000 claims description 3
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 3
- 239000001913 cellulose Substances 0.000 claims description 3
- 229920002678 cellulose Polymers 0.000 claims description 3
- 239000003822 epoxy resin Substances 0.000 claims description 3
- 229920001519 homopolymer Polymers 0.000 claims description 3
- 150000007974 melamines Chemical class 0.000 claims description 3
- 150000002989 phenols Chemical class 0.000 claims description 3
- 229920002492 poly(sulfone) Polymers 0.000 claims description 3
- 229920000058 polyacrylate Polymers 0.000 claims description 3
- 229920000768 polyamine Polymers 0.000 claims description 3
- 229920001228 polyisocyanate Polymers 0.000 claims description 3
- 239000005056 polyisocyanate Substances 0.000 claims description 3
- 229920001955 polyphenylene ether Polymers 0.000 claims description 3
- 229920006337 unsaturated polyester resin Polymers 0.000 claims description 3
- JMUOXOJMXILBTE-UHFFFAOYSA-N (2,2,6,6-tetramethylpiperidin-4-yl) octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 JMUOXOJMXILBTE-UHFFFAOYSA-N 0.000 claims description 2
- BCBGEMJMQQZQOB-UHFFFAOYSA-N 2,2,6,6-tetramethyl-n-[6-[(2,2,6,6-tetramethylpiperidine-4-carbonyl)amino]hexyl]piperidine-4-carboxamide Chemical compound C1C(C)(C)NC(C)(C)CC1C(=O)NCCCCCCNC(=O)C1CC(C)(C)NC(C)(C)C1 BCBGEMJMQQZQOB-UHFFFAOYSA-N 0.000 claims description 2
- QGWXNCIQTGYQLM-UHFFFAOYSA-N 2-methyl-n-(2,2,6,6-tetramethylpiperidin-4-yl)-2-[(2,2,6,6-tetramethylpiperidin-4-yl)amino]propanamide Chemical compound C1C(C)(C)NC(C)(C)CC1NC(=O)C(C)(C)NC1CC(C)(C)NC(C)(C)C1 QGWXNCIQTGYQLM-UHFFFAOYSA-N 0.000 claims description 2
- UXSDANKXUCYTPV-UHFFFAOYSA-N CC1(NC(CC(C1)OC(=O)C(C(C)(C(=O)OCCCCCCCCCCCCC)C(=O)OC1CC(NC(C1)(C)C)(C)C)(C)C(=O)OCCCCCCCCCCCCC)(C)C)C Chemical compound CC1(NC(CC(C1)OC(=O)C(C(C)(C(=O)OCCCCCCCCCCCCC)C(=O)OC1CC(NC(C1)(C)C)(C)C)(C)C(=O)OCCCCCCCCCCCCC)(C)C)C UXSDANKXUCYTPV-UHFFFAOYSA-N 0.000 claims description 2
- MRUCBLPUXLABRC-UHFFFAOYSA-N CN1C(CC(CC1(C)C)OC(=O)C(C(C)(C(=O)OCCCCCCCCCCCCC)C(=O)OC1CC(N(C(C1)(C)C)C)(C)C)(C)C(=O)OCCCCCCCCCCCCC)(C)C Chemical compound CN1C(CC(CC1(C)C)OC(=O)C(C(C)(C(=O)OCCCCCCCCCCCCC)C(=O)OC1CC(N(C(C1)(C)C)C)(C)C)(C)C(=O)OCCCCCCCCCCCCC)(C)C MRUCBLPUXLABRC-UHFFFAOYSA-N 0.000 claims description 2
- 229920003188 Nylon 3 Polymers 0.000 claims description 2
- 229920012266 Poly(ether sulfone) PES Polymers 0.000 claims description 2
- 229930182556 Polyacetal Natural products 0.000 claims description 2
- 239000004693 Polybenzimidazole Substances 0.000 claims description 2
- 239000004695 Polyether sulfone Substances 0.000 claims description 2
- 239000004697 Polyetherimide Substances 0.000 claims description 2
- 239000004642 Polyimide Substances 0.000 claims description 2
- 229920000800 acrylic rubber Polymers 0.000 claims description 2
- RSOILICUEWXSLA-UHFFFAOYSA-N bis(1,2,2,6,6-pentamethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)N(C)C(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)N(C)C(C)(C)C1 RSOILICUEWXSLA-UHFFFAOYSA-N 0.000 claims description 2
- OSIVCXJNIBEGCL-UHFFFAOYSA-N bis(2,2,6,6-tetramethyl-1-octoxypiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)N(OCCCCCCCC)C(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)N(OCCCCCCCC)C(C)(C)C1 OSIVCXJNIBEGCL-UHFFFAOYSA-N 0.000 claims description 2
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 claims description 2
- 125000003700 epoxy group Chemical group 0.000 claims description 2
- 229920006228 ethylene acrylate copolymer Polymers 0.000 claims description 2
- 239000013067 intermediate product Substances 0.000 claims description 2
- 239000012948 isocyanate Substances 0.000 claims description 2
- 150000002513 isocyanates Chemical class 0.000 claims description 2
- 229920002006 poly(N-vinylimidazole) polymer Polymers 0.000 claims description 2
- 229920000090 poly(aryl ether) Polymers 0.000 claims description 2
- 229920003055 poly(ester-imide) Polymers 0.000 claims description 2
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 2
- 229920002480 polybenzimidazole Polymers 0.000 claims description 2
- 229920001225 polyester resin Polymers 0.000 claims description 2
- 239000004645 polyester resin Substances 0.000 claims description 2
- 229920006393 polyether sulfone Polymers 0.000 claims description 2
- 229920001601 polyetherimide Polymers 0.000 claims description 2
- 229920001721 polyimide Polymers 0.000 claims description 2
- 239000004626 polylactic acid Substances 0.000 claims description 2
- WUPCFMITFBVJMS-UHFFFAOYSA-N tetrakis(1,2,2,6,6-pentamethylpiperidin-4-yl) butane-1,2,3,4-tetracarboxylate Chemical compound C1C(C)(C)N(C)C(C)(C)CC1OC(=O)CC(C(=O)OC1CC(C)(C)N(C)C(C)(C)C1)C(C(=O)OC1CC(C)(C)N(C)C(C)(C)C1)CC(=O)OC1CC(C)(C)N(C)C(C)(C)C1 WUPCFMITFBVJMS-UHFFFAOYSA-N 0.000 claims description 2
- NZNAAUDJKMURFU-UHFFFAOYSA-N tetrakis(2,2,6,6-tetramethylpiperidin-4-yl) butane-1,2,3,4-tetracarboxylate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CC(C(=O)OC1CC(C)(C)NC(C)(C)C1)C(C(=O)OC1CC(C)(C)NC(C)(C)C1)CC(=O)OC1CC(C)(C)NC(C)(C)C1 NZNAAUDJKMURFU-UHFFFAOYSA-N 0.000 claims description 2
- MJPPGVVIDGQOQT-UHFFFAOYSA-N 2-bromo-5-(2-bromo-2-nitroethenyl)furan Chemical compound [O-][N+](=O)C(Br)=CC1=CC=C(Br)O1 MJPPGVVIDGQOQT-UHFFFAOYSA-N 0.000 claims 2
- LCIYFINKFGDAHD-UHFFFAOYSA-N azepane;3-nitrobenzoic acid Chemical compound C1CCCNCC1.OC(=O)C1=CC=CC([N+]([O-])=O)=C1 LCIYFINKFGDAHD-UHFFFAOYSA-N 0.000 claims 2
- 150000001241 acetals Chemical class 0.000 claims 1
- 150000001299 aldehydes Chemical class 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract 1
- 239000002861 polymer material Substances 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 description 34
- 229910052757 nitrogen Inorganic materials 0.000 description 34
- 150000003254 radicals Chemical class 0.000 description 27
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 21
- 125000002947 alkylene group Chemical group 0.000 description 19
- 239000011575 calcium Substances 0.000 description 18
- 239000007983 Tris buffer Substances 0.000 description 15
- 125000001931 aliphatic group Chemical group 0.000 description 15
- 125000000753 cycloalkyl group Chemical group 0.000 description 15
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 14
- 125000003118 aryl group Chemical group 0.000 description 14
- 239000011777 magnesium Substances 0.000 description 14
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 12
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 11
- 239000004305 biphenyl Substances 0.000 description 11
- 235000010290 biphenyl Nutrition 0.000 description 10
- 125000004432 carbon atom Chemical group C* 0.000 description 10
- 150000002148 esters Chemical group 0.000 description 10
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 10
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 10
- XTFIVUDBNACUBN-UHFFFAOYSA-N 1,3,5-trinitro-1,3,5-triazinane Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)C1 XTFIVUDBNACUBN-UHFFFAOYSA-N 0.000 description 9
- 238000010521 absorption reaction Methods 0.000 description 9
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 8
- 229920001684 low density polyethylene Polymers 0.000 description 8
- 239000004702 low-density polyethylene Substances 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 8
- 230000006641 stabilisation Effects 0.000 description 8
- 238000011105 stabilization Methods 0.000 description 8
- 239000011701 zinc Substances 0.000 description 8
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 7
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 7
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 7
- 125000003884 phenylalkyl group Chemical group 0.000 description 7
- 0 CCCCCCN(C1CC(C)(C)N(C)C(C)(C)C1)C(C(C)=*C)=O Chemical compound CCCCCCN(C1CC(C)(C)N(C)C(C)(C)C1)C(C(C)=*C)=O 0.000 description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 125000003342 alkenyl group Chemical group 0.000 description 6
- 125000003710 aryl alkyl group Chemical group 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 6
- 239000000460 chlorine Substances 0.000 description 6
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 6
- 239000004700 high-density polyethylene Substances 0.000 description 6
- 239000004611 light stabiliser Substances 0.000 description 6
- 229920000193 polymethacrylate Polymers 0.000 description 6
- 239000012321 sodium triacetoxyborohydride Substances 0.000 description 6
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 5
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 5
- 239000012964 benzotriazole Substances 0.000 description 5
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 5
- 229910052801 chlorine Inorganic materials 0.000 description 5
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 5
- 229920001903 high density polyethylene Polymers 0.000 description 5
- 229920000570 polyether Polymers 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 4
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 4
- BPXVHIRIPLPOPT-UHFFFAOYSA-N 1,3,5-tris(2-hydroxyethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound OCCN1C(=O)N(CCO)C(=O)N(CCO)C1=O BPXVHIRIPLPOPT-UHFFFAOYSA-N 0.000 description 4
- ALVZNPYWJMLXKV-UHFFFAOYSA-N 1,9-Nonanediol Chemical compound OCCCCCCCCCO ALVZNPYWJMLXKV-UHFFFAOYSA-N 0.000 description 4
- NARVIWMVBMUEOG-UHFFFAOYSA-N 2-Hydroxy-propylene Natural products CC(O)=C NARVIWMVBMUEOG-UHFFFAOYSA-N 0.000 description 4
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 4
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 4
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 4
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 4
- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 125000003277 amino group Chemical group 0.000 description 4
- FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 4
- 125000001309 chloro group Chemical group Cl* 0.000 description 4
- 125000002993 cycloalkylene group Chemical group 0.000 description 4
- 125000004427 diamine group Chemical group 0.000 description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 4
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 description 4
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 4
- FPQJEXTVQZHURJ-UHFFFAOYSA-N n,n'-bis(2-hydroxyethyl)oxamide Chemical compound OCCNC(=O)C(=O)NCCO FPQJEXTVQZHURJ-UHFFFAOYSA-N 0.000 description 4
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 4
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 4
- 125000004430 oxygen atom Chemical group O* 0.000 description 4
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 4
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 229920005629 polypropylene homopolymer Polymers 0.000 description 4
- 238000003825 pressing Methods 0.000 description 4
- 229960004063 propylene glycol Drugs 0.000 description 4
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- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- MQOCIYICOGDBSG-UHFFFAOYSA-M potassium;hexadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCC([O-])=O MQOCIYICOGDBSG-UHFFFAOYSA-M 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical class C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- UFUASNAHBMBJIX-UHFFFAOYSA-N propan-1-one Chemical compound CC[C]=O UFUASNAHBMBJIX-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 125000006233 propoxy propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])OC([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000005767 propoxymethyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])[#8]C([H])([H])* 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical class [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Chemical class 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- IJRHDFLHUATAOS-DPMBMXLASA-M sodium ricinoleate Chemical compound [Na+].CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O IJRHDFLHUATAOS-DPMBMXLASA-M 0.000 description 1
- 229940074404 sodium succinate Drugs 0.000 description 1
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical class [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229940114926 stearate Drugs 0.000 description 1
- 229920000638 styrene acrylonitrile Polymers 0.000 description 1
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical group O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- MHSKRLJMQQNJNC-UHFFFAOYSA-N terephthalamide Chemical compound NC(=O)C1=CC=C(C(N)=O)C=C1 MHSKRLJMQQNJNC-UHFFFAOYSA-N 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- OLBWDGJTEXRJLY-UHFFFAOYSA-N tetradecyl 3-(2,2,4,4-tetramethyl-21-oxo-7-oxa-3,20-diazadispiro[5.1.11^{8}.2^{6}]henicosan-20-yl)propanoate Chemical compound O1C2(CCCCCCCCCCC2)N(CCC(=O)OCCCCCCCCCCCCCC)C(=O)C21CC(C)(C)NC(C)(C)C2 OLBWDGJTEXRJLY-UHFFFAOYSA-N 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- YODZTKMDCQEPHD-UHFFFAOYSA-N thiodiglycol Chemical compound OCCSCCO YODZTKMDCQEPHD-UHFFFAOYSA-N 0.000 description 1
- KJAMZCVTJDTESW-UHFFFAOYSA-N tiracizine Chemical compound C1CC2=CC=CC=C2N(C(=O)CN(C)C)C2=CC(NC(=O)OCC)=CC=C21 KJAMZCVTJDTESW-UHFFFAOYSA-N 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 235000010215 titanium dioxide Nutrition 0.000 description 1
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 1
- 229960000984 tocofersolan Drugs 0.000 description 1
- AOBORMOPSGHCAX-DGHZZKTQSA-N tocofersolan Chemical compound OCCOC(=O)CCC(=O)OC1=C(C)C(C)=C2O[C@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C AOBORMOPSGHCAX-DGHZZKTQSA-N 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- 235000019149 tocopherols Nutrition 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- 125000005591 trimellitate group Chemical group 0.000 description 1
- CYTQBVOFDCPGCX-UHFFFAOYSA-N trimethyl phosphite Chemical compound COP(OC)OC CYTQBVOFDCPGCX-UHFFFAOYSA-N 0.000 description 1
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 1
- CNUJLMSKURPSHE-UHFFFAOYSA-N trioctadecyl phosphite Chemical compound CCCCCCCCCCCCCCCCCCOP(OCCCCCCCCCCCCCCCCCC)OCCCCCCCCCCCCCCCCCC CNUJLMSKURPSHE-UHFFFAOYSA-N 0.000 description 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
- PKYCTRXXOZUHFK-UHFFFAOYSA-N tris(1,2,2,6,6-pentamethylpiperidin-4-yl) phosphite Chemical compound C1C(C)(C)N(C)C(C)(C)CC1OP(OC1CC(C)(C)N(C)C(C)(C)C1)OC1CC(C)(C)N(C)C(C)(C)C1 PKYCTRXXOZUHFK-UHFFFAOYSA-N 0.000 description 1
- TZCXWPBSZLCVFR-UHFFFAOYSA-N tris(2,2,6,6-tetramethyl-1-propylpiperidin-4-yl) phosphate Chemical compound C1C(C)(C)N(CCC)C(C)(C)CC1OP(=O)(OC1CC(C)(C)N(CCC)C(C)(C)C1)OC1CC(C)(C)N(CCC)C(C)(C)C1 TZCXWPBSZLCVFR-UHFFFAOYSA-N 0.000 description 1
- GPRWRDWHHCQROU-UHFFFAOYSA-N tris(2,2,6,6-tetramethyl-1-propylpiperidin-4-yl) phosphite Chemical compound C1C(C)(C)N(CCC)C(C)(C)CC1OP(OC1CC(C)(C)N(CCC)C(C)(C)C1)OC1CC(C)(C)N(CCC)C(C)(C)C1 GPRWRDWHHCQROU-UHFFFAOYSA-N 0.000 description 1
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 description 1
- 229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920001866 very low density polyethylene Polymers 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
- BOXSVZNGTQTENJ-UHFFFAOYSA-L zinc dibutyldithiocarbamate Chemical compound [Zn+2].CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC BOXSVZNGTQTENJ-UHFFFAOYSA-L 0.000 description 1
- 229940098697 zinc laurate Drugs 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- GPYYEEJOMCKTPR-UHFFFAOYSA-L zinc;dodecanoate Chemical compound [Zn+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O GPYYEEJOMCKTPR-UHFFFAOYSA-L 0.000 description 1
- 150000007934 α,β-unsaturated carboxylic acids Chemical class 0.000 description 1
- 239000002076 α-tocopherol Substances 0.000 description 1
- 235000004835 α-tocopherol Nutrition 0.000 description 1
- 239000011590 β-tocopherol Substances 0.000 description 1
- 235000007680 β-tocopherol Nutrition 0.000 description 1
- 239000002478 γ-tocopherol Substances 0.000 description 1
- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1
- QUEDXNHFTDJVIY-DQCZWYHMSA-N γ-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-DQCZWYHMSA-N 0.000 description 1
- 239000002446 δ-tocopherol Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/005—Stabilisers against oxidation, heat, light, ozone
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3442—Heterocyclic compounds having nitrogen in the ring having two nitrogen atoms in the ring
- C08K5/3462—Six-membered rings
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Hydrogenated Pyridines (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (2)
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| EP00810149.5 | 2000-02-22 | ||
| EP00810149 | 2000-02-22 |
Publications (2)
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| RU2002123336A RU2002123336A (ru) | 2004-01-20 |
| RU2263688C2 true RU2263688C2 (ru) | 2005-11-10 |
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| RU2002123336/04A RU2263688C2 (ru) | 2000-02-22 | 2001-02-15 | Смеси стабилизаторов для полиолефинов |
Country Status (16)
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| US (1) | US6869992B2 (enExample) |
| EP (1) | EP1263855B1 (enExample) |
| JP (1) | JP4733898B2 (enExample) |
| KR (1) | KR100727524B1 (enExample) |
| CN (1) | CN100429259C (enExample) |
| AT (1) | ATE388988T1 (enExample) |
| AU (1) | AU2001233764A1 (enExample) |
| BR (1) | BR0108512B1 (enExample) |
| CA (1) | CA2400413C (enExample) |
| DE (1) | DE60133181T2 (enExample) |
| ES (1) | ES2301528T3 (enExample) |
| IN (1) | IN2002CH01489A (enExample) |
| MX (1) | MXPA02008161A (enExample) |
| PT (1) | PT1263855E (enExample) |
| RU (1) | RU2263688C2 (enExample) |
| WO (1) | WO2001062836A1 (enExample) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2491308C2 (ru) * | 2008-04-30 | 2013-08-27 | Эвоник Дегусса Гмбх | Полимерная композиция, содержащая фенольную смолу |
| RU2691718C2 (ru) * | 2015-02-20 | 2019-06-17 | Басф Се | Светостабилизированные полиолефиновые пленки, ленты и мононити |
| RU2800783C1 (ru) * | 2015-02-20 | 2023-07-28 | Басф Се | Смесь светостабилизаторов для полиолефиновой пленки, ленты или мононити |
| US12269938B2 (en) | 2018-12-04 | 2025-04-08 | Basf Se | Polyethylene or polypropylene articles |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030225191A1 (en) * | 2002-04-12 | 2003-12-04 | Francois Gugumus | Stabilizer mixtures |
| ATE346883T1 (de) * | 2003-07-18 | 2006-12-15 | Ciba Sc Holding Ag | Flammwidrige polymilchsäure |
| EP1854840B1 (en) * | 2005-02-25 | 2012-03-28 | Sumitomo Chemical Company, Limited | Master batch for resins |
| CN100400584C (zh) * | 2006-06-09 | 2008-07-09 | 河南高分子合金有限公司 | 高分子塑料合金热熔厚膜衬里用复合粉 |
| JP5224497B2 (ja) * | 2007-02-22 | 2013-07-03 | 株式会社Ａｄｅｋａ | 樹脂組成物 |
| US8501842B2 (en) * | 2007-12-21 | 2013-08-06 | Sumitomo Chemical Company, Limited | Polypropylene resin composition and molded article |
| US9062143B2 (en) | 2008-02-08 | 2015-06-23 | Dow Global Technologies Llc | Water-redispersible polymer powder |
| WO2010072768A1 (de) * | 2008-12-23 | 2010-07-01 | Basf Se | Uv-absorber agglomerate |
| US8691002B2 (en) | 2009-01-19 | 2014-04-08 | Basf Se | Organic black pigments and their preparation |
| IT1399477B1 (it) * | 2010-03-15 | 2013-04-19 | 3V Sigma Spa | Miscele di ammine stericamente impedite per la stabilizzazione di polimeri |
| RU2012145171A (ru) * | 2010-03-25 | 2014-04-27 | Басф Се | Огнезащитные композиции солей фосфиновых кислот и нитроксильных производных |
| JP5379181B2 (ja) * | 2010-04-20 | 2013-12-25 | ダウ グローバル テクノロジーズ エルエルシー | 低カルボキシル化スチレンブタジエンベースのラテックスから製造された再分散可能なポリマー粉体 |
| US8366822B2 (en) | 2011-06-20 | 2013-02-05 | Dow Global Technologies Llc | Cementitious tile adhesives and method of applying the same to a tile substrate |
| WO2013045205A1 (de) | 2011-09-29 | 2013-04-04 | Styrolution GmbH | Stabilisierte formmassen aus polyamid und asa-copolymeren |
| KR20140096036A (ko) | 2011-09-29 | 2014-08-04 | 스티롤루션 게엠베하 | 안정화 폴리카르보네이트/아크릴로니트릴/스티렌/아크릴산 에스테르 성형 화합물 |
| WO2013053649A1 (de) | 2011-10-13 | 2013-04-18 | Styrolution GmbH | Stabilisierte polyamid-abs formmassen |
| US10640620B2 (en) * | 2012-03-22 | 2020-05-05 | Mitsubishi Chemical Corporation | Acrylic resin composition for film |
| EP2840112B1 (en) * | 2013-08-21 | 2019-04-10 | Baerlocher GmbH | Stabilized polymer compositions and methods of making same |
| US9598541B2 (en) * | 2013-06-04 | 2017-03-21 | Pbi Performance Products, Inc. | Method of making polybenzimidazole |
| JP6646043B2 (ja) * | 2014-05-15 | 2020-02-14 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 高度に有効な安定剤 |
| DE102017203164A1 (de) | 2017-02-27 | 2018-08-30 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Effiziente phosphorhaltige Stabilisatoren auf Basis von Diphenyl-amin und heterocyclischer Diphenylamin-Derivate |
| WO2018165641A1 (en) | 2017-03-10 | 2018-09-13 | Advansix Resins & Chemicals Llc | Wire and cable jacket composition of pa6/66 copolymer base resin for improved processability and properties |
| US10214836B1 (en) | 2017-08-18 | 2019-02-26 | Glen Raven, Inc. | Acrylic compositions including a hindered amine light stabilizer and methods of making and using the same |
| US11767616B2 (en) | 2017-08-18 | 2023-09-26 | Glen Raven, Inc. | Acrylic compositions including a hindered amine light stabilizer and methods of making and using the same |
| EP3578599A1 (en) * | 2018-06-08 | 2019-12-11 | Cytec Industries Inc. | Granular stabilizer compositions for use in polymer resins and methods of making same |
| DE102019200905A1 (de) * | 2019-01-24 | 2020-07-30 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verfahren zur Stabilisierung von halogenfreien thermoplastischen Kunststoff-Rezyklaten, Kunststoff-Zusammensetzung, Stabilisator-Zusammensetzung sowie Verwendung der Stabilisator-Zusammensetzung |
| CN112961405A (zh) * | 2021-02-09 | 2021-06-15 | 双键化工（上海）有限公司 | 一种用于聚烯烃木塑复合材料的高耐候性光稳定剂及复合光稳定剂 |
| CN115612213B (zh) * | 2021-07-12 | 2024-03-01 | 合肥杰事杰新材料股份有限公司 | 一种耐候聚丙烯复合材料及其制备方法和应用 |
| CN114605624B (zh) * | 2022-02-25 | 2024-05-10 | 天集化工助剂（沧州）有限公司 | 一种聚合型光稳定剂以及制备与应用 |
| CN116003680B (zh) * | 2022-12-26 | 2024-07-09 | 天集化工助剂（沧州）有限公司 | 一种聚合型抗光老型多功能添加剂及其制备方法和应用 |
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| TW358820B (en) | 1995-04-11 | 1999-05-21 | Ciba Sc Holding Ag | Synergistic stabilizer mixture |
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-
2001
- 2001-02-15 RU RU2002123336/04A patent/RU2263688C2/ru not_active IP Right Cessation
- 2001-02-15 US US10/182,073 patent/US6869992B2/en not_active Expired - Fee Related
- 2001-02-15 BR BRPI0108512-3A patent/BR0108512B1/pt not_active IP Right Cessation
- 2001-02-15 CA CA002400413A patent/CA2400413C/en not_active Expired - Fee Related
- 2001-02-15 CN CNB018054579A patent/CN100429259C/zh not_active Expired - Fee Related
- 2001-02-15 PT PT01905773T patent/PT1263855E/pt unknown
- 2001-02-15 MX MXPA02008161A patent/MXPA02008161A/es active IP Right Grant
- 2001-02-15 WO PCT/EP2001/001685 patent/WO2001062836A1/en not_active Ceased
- 2001-02-15 AT AT01905773T patent/ATE388988T1/de active
- 2001-02-15 KR KR1020027010787A patent/KR100727524B1/ko not_active Expired - Fee Related
- 2001-02-15 DE DE60133181T patent/DE60133181T2/de not_active Expired - Lifetime
- 2001-02-15 JP JP2001562615A patent/JP4733898B2/ja not_active Expired - Fee Related
- 2001-02-15 ES ES01905773T patent/ES2301528T3/es not_active Expired - Lifetime
- 2001-02-15 EP EP01905773A patent/EP1263855B1/en not_active Expired - Lifetime
- 2001-02-15 AU AU2001233764A patent/AU2001233764A1/en not_active Abandoned
-
2002
- 2002-09-19 IN IN1489CH2002 patent/IN2002CH01489A/en unknown
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| EP0220897A1 (en) * | 1985-10-17 | 1987-05-06 | Sumitomo Chemical Company, Limited | Polyolefin compositions |
| RU2086540C1 (ru) * | 1989-03-21 | 1997-08-10 | Циба-Гейги АГ | Этиленово-ненасыщенные полимеризующиеся мономеры на основе производного пиперидина |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2491308C2 (ru) * | 2008-04-30 | 2013-08-27 | Эвоник Дегусса Гмбх | Полимерная композиция, содержащая фенольную смолу |
| RU2691718C2 (ru) * | 2015-02-20 | 2019-06-17 | Басф Се | Светостабилизированные полиолефиновые пленки, ленты и мононити |
| US10689495B2 (en) | 2015-02-20 | 2020-06-23 | Basf Se | Light stabilized polyolefin films, tapes and monofilaments |
| US11021585B2 (en) | 2015-02-20 | 2021-06-01 | Basf Se | Light stabilized polyolefin films, tapes and monofilaments |
| RU2800783C1 (ru) * | 2015-02-20 | 2023-07-28 | Басф Се | Смесь светостабилизаторов для полиолефиновой пленки, ленты или мононити |
| RU2820503C2 (ru) * | 2018-12-04 | 2024-06-04 | Басф Се | Изделия из полиэтилена или полипропилена |
| US12269938B2 (en) | 2018-12-04 | 2025-04-08 | Basf Se | Polyethylene or polypropylene articles |
| RU2815313C2 (ru) * | 2018-12-21 | 2024-03-13 | Басф Се | Полипропиленовая композиция |
| RU2830535C2 (ru) * | 2019-07-09 | 2024-11-22 | Басф Се | Таблетирование специфических полимерных стабилизаторов |
| RU2835555C1 (ru) * | 2021-04-22 | 2025-02-27 | Милликен Энд Компани | Полиэтиленовые полимерные композиции и изготовленные из них изделия |
| RU2835554C1 (ru) * | 2021-04-22 | 2025-02-27 | Милликен Энд Компани | Полиэтиленовые полимерные композиции и изготовленные из них изделия |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1263855B1 (en) | 2008-03-12 |
| ES2301528T3 (es) | 2008-07-01 |
| US20030069337A1 (en) | 2003-04-10 |
| BR0108512B1 (pt) | 2012-07-24 |
| WO2001062836A1 (en) | 2001-08-30 |
| JP2003524047A (ja) | 2003-08-12 |
| CA2400413C (en) | 2010-01-12 |
| JP4733898B2 (ja) | 2011-07-27 |
| PT1263855E (pt) | 2008-04-16 |
| CN1404501A (zh) | 2003-03-19 |
| IN2002CH01489A (en) | 2005-01-28 |
| DE60133181D1 (de) | 2008-04-24 |
| MX235505B (enExample) | 2006-04-05 |
| AU2001233764A1 (en) | 2001-09-03 |
| CA2400413A1 (en) | 2001-08-30 |
| IN205902B (enExample) | 2007-06-29 |
| BR0108512A (pt) | 2002-12-17 |
| CN100429259C (zh) | 2008-10-29 |
| KR100727524B1 (ko) | 2007-06-14 |
| ATE388988T1 (de) | 2008-03-15 |
| US6869992B2 (en) | 2005-03-22 |
| EP1263855A1 (en) | 2002-12-11 |
| DE60133181T2 (de) | 2009-03-12 |
| RU2002123336A (ru) | 2004-01-20 |
| MXPA02008161A (es) | 2002-11-29 |
| KR20020075922A (ko) | 2002-10-07 |
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Legal Events
| Date | Code | Title | Description |
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| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20090216 |