RU2227138C2 - Синтез сложных эфиров - Google Patents
Синтез сложных эфиров Download PDFInfo
- Publication number
- RU2227138C2 RU2227138C2 RU2001103140/04A RU2001103140A RU2227138C2 RU 2227138 C2 RU2227138 C2 RU 2227138C2 RU 2001103140/04 A RU2001103140/04 A RU 2001103140/04A RU 2001103140 A RU2001103140 A RU 2001103140A RU 2227138 C2 RU2227138 C2 RU 2227138C2
- Authority
- RU
- Russia
- Prior art keywords
- metal compounds
- impurities
- preceding paragraph
- reactor
- heteropolyacid catalyst
- Prior art date
Links
- 230000015572 biosynthetic process Effects 0.000 title abstract 2
- 238000003786 synthesis reaction Methods 0.000 title abstract 2
- 150000002148 esters Chemical class 0.000 title 1
- 238000000034 method Methods 0.000 claims abstract 18
- 239000012535 impurity Substances 0.000 claims abstract 10
- 150000002736 metal compounds Chemical class 0.000 claims abstract 10
- 239000003054 catalyst Substances 0.000 claims abstract 9
- 239000011964 heteropoly acid Substances 0.000 claims abstract 8
- 239000003153 chemical reaction reagent Substances 0.000 claims abstract 7
- 229910052751 metal Inorganic materials 0.000 claims abstract 7
- 239000002184 metal Substances 0.000 claims abstract 7
- 150000001336 alkenes Chemical class 0.000 claims abstract 4
- 238000006243 chemical reaction Methods 0.000 claims abstract 4
- 150000002739 metals Chemical class 0.000 claims abstract 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract 4
- -1 aliphatic monocarboxylic acid Chemical class 0.000 claims abstract 3
- 229920006395 saturated elastomer Polymers 0.000 claims abstract 3
- 125000001931 aliphatic group Chemical group 0.000 claims abstract 2
- 239000012808 vapor phase Substances 0.000 claims abstract 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 6
- 239000011241 protective layer Substances 0.000 claims 3
- 239000000376 reactant Substances 0.000 claims 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 2
- 239000002253 acid Substances 0.000 claims 2
- 238000005260 corrosion Methods 0.000 claims 2
- 230000007797 corrosion Effects 0.000 claims 2
- 239000010410 layer Substances 0.000 claims 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical class C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- 150000007513 acids Chemical class 0.000 claims 1
- 229910000323 aluminium silicate Inorganic materials 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 claims 1
- 229910052804 chromium Inorganic materials 0.000 claims 1
- 239000011651 chromium Substances 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 239000003456 ion exchange resin Substances 0.000 claims 1
- 229920003303 ion-exchange polymer Polymers 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- 229910052750 molybdenum Inorganic materials 0.000 claims 1
- 239000011733 molybdenum Substances 0.000 claims 1
- 150000002763 monocarboxylic acids Chemical class 0.000 claims 1
- 229910052759 nickel Inorganic materials 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 239000010457 zeolite Substances 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract 2
- 230000000694 effects Effects 0.000 abstract 1
- 230000002779 inactivation Effects 0.000 abstract 1
- 230000003993 interaction Effects 0.000 abstract 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9815135.0 | 1998-07-14 | ||
| GBGB9815135.0A GB9815135D0 (en) | 1998-07-14 | 1998-07-14 | Ester synthesis |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2001103140A RU2001103140A (ru) | 2003-11-10 |
| RU2227138C2 true RU2227138C2 (ru) | 2004-04-20 |
Family
ID=10835401
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2001103140/04A RU2227138C2 (ru) | 1998-07-14 | 1999-07-01 | Синтез сложных эфиров |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US6794535B2 (enExample) |
| EP (1) | EP1097121B1 (enExample) |
| JP (1) | JP2002520381A (enExample) |
| KR (1) | KR100663685B1 (enExample) |
| CN (1) | CN1160302C (enExample) |
| AT (1) | ATE261926T1 (enExample) |
| AU (1) | AU4632499A (enExample) |
| BR (1) | BR9911956A (enExample) |
| CA (1) | CA2337034C (enExample) |
| DE (1) | DE69915627T2 (enExample) |
| ES (1) | ES2217769T3 (enExample) |
| GB (1) | GB9815135D0 (enExample) |
| ID (1) | ID28030A (enExample) |
| MX (1) | MXPA01000494A (enExample) |
| MY (1) | MY126512A (enExample) |
| RU (1) | RU2227138C2 (enExample) |
| TW (1) | TWI222438B (enExample) |
| WO (1) | WO2000003967A1 (enExample) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE69804751T2 (de) * | 1997-12-23 | 2002-11-21 | Bp Chemicals Ltd., London | Estersynthese |
| US20040242918A1 (en) * | 2000-06-27 | 2004-12-02 | Showa Denko K.K | Support and catalyst for use in producing lower aliphatic carboxylic acid ester, process for producing the catalyst and process for producing lower aliphatic carboxylic acid ester using the catalyst |
| DE10036959A1 (de) * | 2000-07-28 | 2002-02-07 | Basf Ag | Verfahren zur Herstellung von tert.-Butylestern aliphatischer C1-C4-Carbonsäuren |
| JP2004018404A (ja) * | 2002-06-13 | 2004-01-22 | Showa Denko Kk | 低級脂肪族カルボン酸エステルの製造方法及び該製造方法で製造された低級脂肪族カルボン酸エステル |
| JP2004083473A (ja) * | 2002-08-27 | 2004-03-18 | Showa Denko Kk | 低級脂肪族カルボン酸エステルの製造方法及び該製造方法で製造された低級脂肪族カルボン酸エステル |
| GB0320692D0 (en) * | 2003-09-03 | 2003-10-01 | Bp Chem Int Ltd | Ester synthesis |
| GB0410603D0 (en) * | 2004-05-12 | 2004-06-16 | Bp Chem Int Ltd | Ester synthesis |
| US20080088187A1 (en) * | 2006-10-17 | 2008-04-17 | Hitachi, Ltd | Electric Motor with Reduced EMI |
| EP1992601A1 (en) † | 2007-05-11 | 2008-11-19 | Ineos Europe Limited | Dehydration of alcohols over supported heteropolyacids |
| CN100432039C (zh) * | 2007-07-11 | 2008-11-12 | 胡先念 | 一种保护制备低级脂肪酸酯所用酸性离子交换树脂催化剂方法 |
| CN102757341A (zh) * | 2011-04-27 | 2012-10-31 | 中国石油化工集团公司 | 一种醋酸乙酯和/或醋酸异丙酯的制备方法 |
| JP6986908B2 (ja) * | 2017-09-05 | 2021-12-22 | 昭和電工株式会社 | 脂肪族カルボン酸エステルの製造方法 |
| JP6910252B2 (ja) | 2017-09-05 | 2021-07-28 | 昭和電工株式会社 | シリカ担体の製造方法 |
| WO2023112488A1 (ja) * | 2021-12-15 | 2023-06-22 | 株式会社レゾナック | 酢酸エチルの製造方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5241106A (en) * | 1991-10-22 | 1993-08-31 | Mitsui Toatsu Chemicals, Inc. | Process for producing ethyl acetate |
| US5457228A (en) * | 1990-10-31 | 1995-10-10 | Daicel Chemical Industries, Ltd. | Method for producing lower alkyl acetate |
| US5466876A (en) * | 1993-03-22 | 1995-11-14 | Bp Chemicals Limited | Process for the removal of corrosion metal contaminants from liquid compositions |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3644497A (en) * | 1968-11-01 | 1972-02-22 | Celanese Corp | Conversion of ethylenically unsaturated compounds using heteropoly-molybdic and heteropolytungstic acids as catalysts |
| JPS5452025A (en) * | 1977-09-28 | 1979-04-24 | Tokuyama Soda Co Ltd | Preparation of ester |
| JPS57106640A (en) * | 1980-12-25 | 1982-07-02 | Idemitsu Kosan Co Ltd | Preparation of carboxylates |
| CA1185260A (en) * | 1981-04-24 | 1985-04-09 | Kazuhisa Nakajima | Process for preparing acetic acid esters |
| JPS59231027A (ja) * | 1983-06-13 | 1984-12-25 | Japan Organo Co Ltd | 固体酸触媒を用いる有機反応方法 |
| US4927954A (en) * | 1983-06-28 | 1990-05-22 | Union Carbide Chemicals And Plastics Company, Inc. | Continuous process for producing secondary alcohols and carboxylic acid esters |
| JPH0611724B2 (ja) | 1985-03-05 | 1994-02-16 | 川崎化成工業株式会社 | コハク酸の製造法 |
| JP2730696B2 (ja) | 1989-05-22 | 1998-03-25 | 日本ケッチェン株式会社 | 炭化水素油の脱スケール剤および水素化処理触媒 |
| EP0562139B1 (en) * | 1992-03-25 | 1995-12-13 | Showa Denko Kabushiki Kaisha | Process for preparation of lower fatty acid ester |
| JP2674699B2 (ja) * | 1993-06-29 | 1997-11-12 | 昭和電工株式会社 | 酢酸エチルの製法とその製造装置 |
| DE69618032T2 (de) * | 1995-08-02 | 2002-06-27 | Bp Chemicals Ltd., London | Estersynthese |
-
1998
- 1998-07-14 GB GBGB9815135.0A patent/GB9815135D0/en not_active Ceased
-
1999
- 1999-07-01 KR KR1020017000559A patent/KR100663685B1/ko not_active Expired - Fee Related
- 1999-07-01 JP JP2000560077A patent/JP2002520381A/ja active Pending
- 1999-07-01 WO PCT/GB1999/002101 patent/WO2000003967A1/en not_active Ceased
- 1999-07-01 BR BR9911956-0A patent/BR9911956A/pt not_active Application Discontinuation
- 1999-07-01 MX MXPA01000494A patent/MXPA01000494A/es not_active IP Right Cessation
- 1999-07-01 CN CNB998086053A patent/CN1160302C/zh not_active Expired - Fee Related
- 1999-07-01 EP EP99929534A patent/EP1097121B1/en not_active Expired - Lifetime
- 1999-07-01 AT AT99929534T patent/ATE261926T1/de not_active IP Right Cessation
- 1999-07-01 DE DE69915627T patent/DE69915627T2/de not_active Expired - Fee Related
- 1999-07-01 AU AU46324/99A patent/AU4632499A/en not_active Abandoned
- 1999-07-01 ES ES99929534T patent/ES2217769T3/es not_active Expired - Lifetime
- 1999-07-01 CA CA002337034A patent/CA2337034C/en not_active Expired - Fee Related
- 1999-07-01 ID IDW20010094A patent/ID28030A/id unknown
- 1999-07-01 RU RU2001103140/04A patent/RU2227138C2/ru not_active IP Right Cessation
- 1999-07-13 TW TW088111866A patent/TWI222438B/zh not_active IP Right Cessation
- 1999-07-13 MY MYPI99002948A patent/MY126512A/en unknown
-
2001
- 2001-01-03 US US09/752,834 patent/US6794535B2/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5457228A (en) * | 1990-10-31 | 1995-10-10 | Daicel Chemical Industries, Ltd. | Method for producing lower alkyl acetate |
| US5241106A (en) * | 1991-10-22 | 1993-08-31 | Mitsui Toatsu Chemicals, Inc. | Process for producing ethyl acetate |
| US5466876A (en) * | 1993-03-22 | 1995-11-14 | Bp Chemicals Limited | Process for the removal of corrosion metal contaminants from liquid compositions |
Also Published As
| Publication number | Publication date |
|---|---|
| DE69915627T2 (de) | 2005-02-03 |
| MXPA01000494A (es) | 2002-06-04 |
| KR100663685B1 (ko) | 2007-01-02 |
| EP1097121A1 (en) | 2001-05-09 |
| US20010029307A1 (en) | 2001-10-11 |
| BR9911956A (pt) | 2001-11-27 |
| CA2337034A1 (en) | 2000-01-27 |
| AU4632499A (en) | 2000-02-07 |
| MY126512A (en) | 2006-10-31 |
| CA2337034C (en) | 2007-09-18 |
| CN1309629A (zh) | 2001-08-22 |
| ES2217769T3 (es) | 2004-11-01 |
| TWI222438B (en) | 2004-10-21 |
| ID28030A (id) | 2001-05-03 |
| DE69915627D1 (en) | 2004-04-22 |
| JP2002520381A (ja) | 2002-07-09 |
| GB9815135D0 (en) | 1998-09-09 |
| US6794535B2 (en) | 2004-09-21 |
| ATE261926T1 (de) | 2004-04-15 |
| KR20010071891A (ko) | 2001-07-31 |
| WO2000003967A1 (en) | 2000-01-27 |
| EP1097121B1 (en) | 2004-03-17 |
| CN1160302C (zh) | 2004-08-04 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20090702 |