RU2078753C1 - Способ получения смеси, содержащей циклический насыщенный алканон и соответствующий ему алканол - Google Patents

Способ получения смеси, содержащей циклический насыщенный алканон и соответствующий ему алканол Download PDF

Info

Publication number
RU2078753C1
RU2078753C1 SU925011237A SU5011237A RU2078753C1 RU 2078753 C1 RU2078753 C1 RU 2078753C1 SU 925011237 A SU925011237 A SU 925011237A SU 5011237 A SU5011237 A SU 5011237A RU 2078753 C1 RU2078753 C1 RU 2078753C1
Authority
RU
Russia
Prior art keywords
mixture
catalyst
alkyl
silica
oxidation
Prior art date
Application number
SU925011237A
Other languages
English (en)
Russian (ru)
Inventor
Хюбертюс Вилхелмюс Янссен Людовикюс
Хогендорн Петер
Франсискюс Крагтен Ибалдюс
Анна Христиан Баур Генрикюс
Original Assignee
Дсм Н.В.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Дсм Н.В. filed Critical Дсм Н.В.
Application granted granted Critical
Publication of RU2078753C1 publication Critical patent/RU2078753C1/ru

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B01J31/1625—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts immobilised by covalent linkages, i.e. pendant complexes with optional linking groups
    • B01J31/1633—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts immobilised by covalent linkages, i.e. pendant complexes with optional linking groups covalent linkages via silicon containing groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/226—Sulfur, e.g. thiocarbamates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
    • B01J2531/22—Magnesium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
    • B01J2531/56—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/64—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/617—500-1000 m2/g
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered
    • C07C2601/20—Systems containing only non-condensed rings with a ring being at least seven-membered the ring being twelve-membered
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
SU925011237A 1991-03-25 1992-03-24 Способ получения смеси, содержащей циклический насыщенный алканон и соответствующий ему алканол RU2078753C1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL9100521 1991-03-25
NL9100521A NL9100521A (nl) 1991-03-25 1991-03-25 Werkwijze voor de bereiding van een alkanon en/of alkanol.

Publications (1)

Publication Number Publication Date
RU2078753C1 true RU2078753C1 (ru) 1997-05-10

Family

ID=19859052

Family Applications (1)

Application Number Title Priority Date Filing Date
SU925011237A RU2078753C1 (ru) 1991-03-25 1992-03-24 Способ получения смеси, содержащей циклический насыщенный алканон и соответствующий ему алканол

Country Status (20)

Country Link
US (1) US5298665A (enExample)
EP (1) EP0577709B1 (enExample)
JP (1) JP3386827B2 (enExample)
CN (1) CN1047587C (enExample)
AU (1) AU1567692A (enExample)
BR (1) BR9205790A (enExample)
CA (1) CA2106863C (enExample)
CZ (1) CZ288134B6 (enExample)
DE (1) DE69216596T2 (enExample)
ES (1) ES2097909T3 (enExample)
HU (1) HU213837B (enExample)
IL (1) IL101350A (enExample)
MX (1) MX9201301A (enExample)
NL (1) NL9100521A (enExample)
PL (1) PL167350B1 (enExample)
RU (1) RU2078753C1 (enExample)
SK (1) SK102993A3 (enExample)
TW (1) TW198711B (enExample)
WO (1) WO1992016487A1 (enExample)
ZA (1) ZA922150B (enExample)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2154050C1 (ru) * 1999-01-19 2000-08-10 Ярославский государственный технический университет Способ получения циклоалканонов c8-c12
RU2233830C2 (ru) * 1999-12-17 2004-08-10 Родиа Полиамид Интермедиэйтс Способ получения смесей спиртов с кетонами
RU2288211C2 (ru) * 2001-10-30 2006-11-27 Родиа Полиамид Интермедиэйтс Способ каталитического разложения циклоалкилгидропероксидов c6-c12
RU2373181C2 (ru) * 2004-12-07 2009-11-20 Родиа Шими Способ получения циклогексанона

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE1007904A3 (nl) * 1993-12-23 1995-11-14 Dsm Nv Werkwijze voor de bereiding van een alkanol en/of een alkanon.
DE19540497A1 (de) * 1995-10-31 1997-05-07 Degussa Sulfonat- und mercaptogruppenhaltige anorganische Trägermaterialien, Verfahren zu ihrer Herstellung und Verwendung als Katalysatoren
GB2314517A (en) * 1996-06-28 1998-01-07 Contract Chemicals Limited Catalyst and its use in epoxidation
WO1998009931A1 (en) 1996-09-03 1998-03-12 E.I. Du Pont De Nemours And Company Hydroperoxide decomposition processes
CA2279493A1 (en) * 1997-02-11 1998-08-13 E.I. Du Pont De Nemours And Company Hydroperoxide decomposition process
US6160183A (en) * 1998-02-10 2000-12-12 E. I. Du Pont De Nemours And Company Direct oxidation of cycloalkanes
EP1159240A1 (en) * 1999-03-10 2001-12-05 E.I. Du Pont De Nemours And Company Hydroperoxide decomposition process
CN1203041C (zh) * 2000-08-18 2005-05-25 纳幕尔杜邦公司 改良的氢过氧化物分解催化剂
FR2823745A1 (fr) * 2001-04-20 2002-10-25 Rhodia Polyamide Intermediates Procede de decomposition catalytique des hydroperoxydes organiques
JP2007223992A (ja) * 2006-02-27 2007-09-06 Sumitomo Chemical Co Ltd シクロアルカノール及び／又はシクロアルカノンの製造方法
US7442841B2 (en) * 2006-08-18 2008-10-28 Invista North America S.A R.L. Extraction process
US7417003B2 (en) * 2006-12-29 2008-08-26 Uop Llc Solid acid catalyst and process for decomposition of cumene hydroperoxide
JP5176928B2 (ja) * 2008-09-17 2013-04-03 住友化学株式会社 シクロアルカノール及び／又はシクロアルカノンの製造方法
CN102397794B (zh) * 2010-09-17 2013-09-11 中国科学院大连化学物理研究所 一种络合催化剂体系及其在分解环烷基过氧化氢中的应用
US20130184494A1 (en) * 2010-10-01 2013-07-18 USE Industries, Ltd. Oxidation Catalyst for Hydrocarbon Compound, and Method and Apparatus for Producing Oxide of Hydrocarbon Compound Using Same
EP2446965A1 (en) * 2010-11-02 2012-05-02 Evonik Degussa GmbH Process for preparation of supported catalysts and use of the catalyst for the esterification of free fatty acids in vegetable oil
KR20170088937A (ko) * 2014-11-28 2017-08-02 로디아 오퍼레이션스 알코올 및/또는 케톤의 제조방법
JPWO2017057141A1 (ja) * 2015-10-01 2018-07-19 株式会社ダイセル 酸化反応用触媒、及びそれを用いたフローリアクター
HUE060530T2 (hu) 2015-10-01 2023-03-28 Monsanto Technology Llc Eljárás halonitroaromás vegyületek katalitikus hidrogénezésére
CN110498735A (zh) * 2019-08-27 2019-11-26 浙江工业大学 钴(ii)盐/锌(ii)盐协同催化分子氧选择性氧化环烷烃制备环烷醇和环烷酮的方法

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2497349A (en) * 1947-08-01 1950-02-14 Union Oil Co Production of alicyclic alcohols
US2851496A (en) * 1954-07-27 1958-09-09 Du Pont Preparation of oxidation products of cyclohexane
FR1505363A (fr) * 1966-04-20 1967-12-15 Rhone Poulenc Sa Perfectionnement à la préparation des cycloalcanols et des mélanges cycloalcanols/cycloalcanones
GB1159006A (en) * 1966-07-11 1969-07-23 Ici Ltd Process for the Oxidation of Hydrocarbons.
FR1530986A (fr) * 1966-07-11 1968-06-28 Ici Ltd Procédé d'oxydation d'hydrocarbures
GB1212824A (en) 1967-04-04 1970-11-18 Ici Ltd Production of alcohols and ketones
GB1449124A (en) * 1972-11-08 1976-09-15 Burmah Oil Trading Ltd Production of phenols
US4482752A (en) * 1974-02-19 1984-11-13 Mobil Oil Corporation Organic compound conversion
GB1502767A (en) * 1974-05-06 1978-03-01 Burmah Oil Trading Ltd Production of phenols
US4459427A (en) * 1981-10-31 1984-07-10 The British Petroleum Company P.L.C. Process for the conversion of an alkane to a mixture of an alcohol and a ketone
DE3222144A1 (de) * 1982-06-11 1983-12-15 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von cyclohexanol und cyclohexanon
US4490566A (en) * 1983-05-06 1984-12-25 Mobil Oil Corporation Production of phenol
EP0180269B1 (en) * 1984-11-02 1990-06-27 Shell Internationale Researchmaatschappij B.V. Catalyst preparation
NL8802592A (nl) * 1988-10-21 1990-05-16 Stamicarbon Werkwijze voor de bereiding van een k/a-mengsel.
US4898987A (en) * 1989-03-17 1990-02-06 Texaco Chemical Company Method for production of phenol/acetone from cumene hydroperoxide

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
J. Org. Chem., v.56, (1991), p.1981 - 1983. Патент США N 4499305, кл. С 07С 45/53, 1985. Патент США N 4482746, кл. С 07С 45/53, 1984. *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2154050C1 (ru) * 1999-01-19 2000-08-10 Ярославский государственный технический университет Способ получения циклоалканонов c8-c12
RU2233830C2 (ru) * 1999-12-17 2004-08-10 Родиа Полиамид Интермедиэйтс Способ получения смесей спиртов с кетонами
RU2288211C2 (ru) * 2001-10-30 2006-11-27 Родиа Полиамид Интермедиэйтс Способ каталитического разложения циклоалкилгидропероксидов c6-c12
RU2373181C2 (ru) * 2004-12-07 2009-11-20 Родиа Шими Способ получения циклогексанона

Also Published As

Publication number Publication date
MX9201301A (es) 1992-10-01
AU1567692A (en) 1992-10-21
TW198711B (enExample) 1993-01-21
DE69216596T2 (de) 1997-07-31
CN1066839A (zh) 1992-12-09
IL101350A0 (en) 1992-11-15
JPH05112486A (ja) 1993-05-07
PL167350B1 (pl) 1995-08-31
HU9302711D0 (en) 1993-12-28
US5298665A (en) 1994-03-29
EP0577709A1 (en) 1994-01-12
HUT64733A (en) 1994-02-28
SK102993A3 (en) 1994-03-09
IL101350A (en) 1996-03-31
ZA922150B (en) 1992-12-30
CA2106863C (en) 2003-03-11
JP3386827B2 (ja) 2003-03-17
BR9205790A (pt) 1994-06-28
CN1047587C (zh) 1999-12-22
WO1992016487A1 (en) 1992-10-01
NL9100521A (nl) 1992-10-16
CZ9302004A3 (en) 1994-04-13
EP0577709B1 (en) 1997-01-08
DE69216596D1 (de) 1997-02-20
CA2106863A1 (en) 1992-09-26
ES2097909T3 (es) 1997-04-16
CZ288134B6 (en) 2001-05-16
HU213837B (en) 1997-10-28

Similar Documents

Publication Publication Date Title
RU2078753C1 (ru) Способ получения смеси, содержащей циклический насыщенный алканон и соответствующий ему алканол
Zhao et al. A highly efficient oxidation of cyclohexane over Au/ZSM-5 molecular sieve catalyst with oxygen as oxidant
US5739076A (en) Catalysts and their use in oxidation of saturated hydrocarbons
EP0659726B1 (en) Process for preparing a cycloalkanone and/or a cycloalkanol
JP2003529582A (ja) 芳香族アルコール、特にフェノールの製造方法
JP2012517429A (ja) フェノールの製造方法
CA2369269A1 (en) Process for production of oximes cocatalysed by ammonium salts or substituted ammonium salts
US20020058840A1 (en) Process for preparing oximes
RU2233830C2 (ru) Способ получения смесей спиртов с кетонами
SK280850B6 (sk) Spôsob výroby cykloalkanónu a/alebo cykloalkanolu
US5830429A (en) Metal silicate compositions and catalysts
US20060041172A1 (en) Catalysts for cycloalkanes oxidation and decomposition of cycloalkyl hydroperoxide
AU642724B2 (en) Preparation of ketones and/or alcohols
SK12312001A3 (sk) Rozkladný proces hydroperoxidov
CA2142852A1 (en) Epoxidation catalyst
CN108329191B (zh) 一种环己烷氧化液加工的方法
CN108117087B (zh) 含硅分子筛及其制备方法
CN116332200B (zh) 钛硅分子筛及其制备方法和制备环己酮肟的方法、制备己内酯的方法
CN114345405B (zh) 一种负载成型钛硅分子筛及其制备方法，一种苯二酚的制备方法
CN111072528A (zh) 一种制备亚砜的方法
EP4238955A1 (en) Method for preparing linear hydrocarbon double acid with cyclic hydrocarbon oxidation catalyst
DE102004042522A1 (de) Oligomerer Oxidationskatalysator
JP2020058981A (ja) エステルの製造方法
JPH0248540A (ja) ｐ−メンタ−１，８−ジエン−４−オールの製造方法
WO1993008159A1 (en) Process for the preparation of a ketoxime