GB1159006A - Process for the Oxidation of Hydrocarbons. - Google Patents

Process for the Oxidation of Hydrocarbons.

Info

Publication number
GB1159006A
GB1159006A GB1690/67A GB169067A GB1159006A GB 1159006 A GB1159006 A GB 1159006A GB 1690/67 A GB1690/67 A GB 1690/67A GB 169067 A GB169067 A GB 169067A GB 1159006 A GB1159006 A GB 1159006A
Authority
GB
United Kingdom
Prior art keywords
oxidation
hydroperoxy
methyl
polyphosphate
cumene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1690/67A
Inventor
Eric Sydney Hunt
Alexander James Strath Sorrie
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB1690/67A priority Critical patent/GB1159006A/en
Priority to NL6709408A priority patent/NL6709408A/xx
Priority to BE701233D priority patent/BE701233A/xx
Priority to FR113886A priority patent/FR1530986A/en
Publication of GB1159006A publication Critical patent/GB1159006A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/04—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/04—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic
    • C07C409/08—Compounds containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/04—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic
    • C07C409/08—Compounds containing six-membered aromatic rings
    • C07C409/10—Cumene hydroperoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/36—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in compounds containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1,159,006. Hydrocarbon hydroperoxides. IMPERIAL CHEMICAL INDUSTRIES Ltd. 21 June, 1967 [11 July, 1966; 27 Oct., 1966; 12 Jan., 1967], Nos. 30973/66, 48255/66 and 1690/67. Heading C2C. Hydrocarbon hydroperoxides are obtained by liquid phase oxidation of alkanes, aralkanes and cycloalkanes with molecular oxygen in a reactor in which the walls have been pretreated with a polyphosphate, the oxygen partial pressure being greater than 1 atmos. absolute. The preferred polyphosphate is sodium pyrophosphate. The reaction is preferably effected at 80-140‹ C. Oxidation initiators may be included in the reaction solution, e.g. peroxides or azobisisobutyronitrile. Examples relate to the oxidation of isopentane to 2-methyl-2-hydroperoxy-butane, 3 - methylheptane to 3 - methyl - 3 - hydroperoxy heptane, and cumene to α-cumene hydroperoxide.
GB1690/67A 1966-07-11 1966-07-11 Process for the Oxidation of Hydrocarbons. Expired GB1159006A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
GB1690/67A GB1159006A (en) 1966-07-11 1966-07-11 Process for the Oxidation of Hydrocarbons.
NL6709408A NL6709408A (en) 1966-07-11 1967-07-06
BE701233D BE701233A (en) 1966-07-11 1967-07-11
FR113886A FR1530986A (en) 1966-07-11 1967-07-11 Hydrocarbon oxidation process

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB1690/67A GB1159006A (en) 1966-07-11 1966-07-11 Process for the Oxidation of Hydrocarbons.
GB3097366 1966-07-11
GB4825566 1966-10-27

Publications (1)

Publication Number Publication Date
GB1159006A true GB1159006A (en) 1969-07-23

Family

ID=27253929

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1690/67A Expired GB1159006A (en) 1966-07-11 1966-07-11 Process for the Oxidation of Hydrocarbons.

Country Status (3)

Country Link
BE (1) BE701233A (en)
GB (1) GB1159006A (en)
NL (1) NL6709408A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2631016A1 (en) * 1975-07-10 1977-01-27 Halcon International Inc PROCESS FOR THE PRODUCTION OF ORGANOHYDROPEROXIDES
US4028423A (en) * 1968-04-18 1977-06-07 Sun Oil Company Oxidation of aliphatic and alicyclic hydrocarbons
EP0230254A2 (en) * 1986-01-17 1987-07-29 BASF Aktiengesellschaft Process for the treatment of reaction mixtures containing cyclohexanol, cyclohexanone and cyclohexyl-hydroperoxide
US5298665A (en) * 1991-03-25 1994-03-29 Dsm N.V. Process for preparing an alkanone and/or alkanol

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4028423A (en) * 1968-04-18 1977-06-07 Sun Oil Company Oxidation of aliphatic and alicyclic hydrocarbons
DE2631016A1 (en) * 1975-07-10 1977-01-27 Halcon International Inc PROCESS FOR THE PRODUCTION OF ORGANOHYDROPEROXIDES
EP0230254A2 (en) * 1986-01-17 1987-07-29 BASF Aktiengesellschaft Process for the treatment of reaction mixtures containing cyclohexanol, cyclohexanone and cyclohexyl-hydroperoxide
EP0230254A3 (en) * 1986-01-17 1987-08-26 Basf Aktiengesellschaft Process for the treatment of reaction mixtures containing cyclohexanol, cyclohexanone and cyclohexyl-hydroperoxide
US5298665A (en) * 1991-03-25 1994-03-29 Dsm N.V. Process for preparing an alkanone and/or alkanol

Also Published As

Publication number Publication date
NL6709408A (en) 1968-01-12
BE701233A (en) 1968-01-11

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Legal Events

Date Code Title Description
414F Notice of opposition given (sect. 14/1949)
414E Application relinquished (sect. 14/1949)
CSNS Application of which complete specification have been accepted and published, but patent is not sealed