GB1306087A - - Google Patents
Info
- Publication number
- GB1306087A GB1306087A GB6255269A GB1306087DA GB1306087A GB 1306087 A GB1306087 A GB 1306087A GB 6255269 A GB6255269 A GB 6255269A GB 1306087D A GB1306087D A GB 1306087DA GB 1306087 A GB1306087 A GB 1306087A
- Authority
- GB
- United Kingdom
- Prior art keywords
- feedstock
- steam
- sulphur
- pentane
- iso
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000005864 Sulphur Substances 0.000 abstract 3
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 abstract 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 abstract 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 abstract 2
- 229930195734 saturated hydrocarbon Natural products 0.000 abstract 2
- 229930195735 unsaturated hydrocarbon Natural products 0.000 abstract 2
- 101710178035 Chorismate synthase 2 Proteins 0.000 abstract 1
- 101710152694 Cysteine synthase 2 Proteins 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006555 catalytic reaction Methods 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052735 hafnium Inorganic materials 0.000 abstract 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 239000011572 manganese Substances 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
- 238000004230 steam cracking Methods 0.000 abstract 1
- -1 sulphur compound Chemical class 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
- C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
- C07C4/06—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
- C07C2523/04—Alkali metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/26—Chromium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/32—Manganese, technetium or rhenium
- C07C2523/34—Manganese
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/745—Iron
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S585/00—Chemistry of hydrocarbon compounds
- Y10S585/949—Miscellaneous considerations
- Y10S585/95—Prevention or removal of corrosion or solid deposits
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
1306087 Steam cracking FLUOR CORP and H F A TOPSOE 9 Dec 1970 [23 Dec 1969] 62652/70 Heading C5E [Also in Division B1] Unsaturated hydrocarbons are produced by a gaseous catalytic reaction in which a feedstock substantially comprising saturated hydrocarbons is contacted at a temperature below 1000 C. and a pressure of 0À1-50 atm. abs. in the presence of steam with a catalyst comprising at least one oxide of zirconium or hafnium, active alumina, at least one oxide of chromium, manganese or iron, and a compound of an alkali metal or alkaline earth metal, these components being present in specified quantities (see Division B1). A minor proportion of unsaturated hydrocarbons may be added to the saturated hydrocarbon feed. The reaction is suitably carried out in the presence of sulphur added to the feedstock, e.g. as free sulphur, CS 2 , H 2 S or an organic sulphur compound. The steam/feedstock weight ratio should be 0À01 : 1À0 to 10À0: 1À0. In the examples a naphtha comprising iso-pentane, n-pentane, iso-hexane, n-hexane and aromatics in specified proportions is converted to give ethylene and propylene.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB6255269 | 1969-12-23 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1306087A true GB1306087A (en) | 1973-02-07 |
Family
ID=10488257
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB6255269A Expired GB1306087A (en) | 1969-12-23 | 1969-12-23 |
Country Status (9)
Country | Link |
---|---|
US (1) | US3725495A (en) |
CA (1) | CA973152A (en) |
DE (1) | DE2063172A1 (en) |
DK (1) | DK139907B (en) |
ES (1) | ES386738A1 (en) |
FR (1) | FR2072015B1 (en) |
GB (1) | GB1306087A (en) |
NL (1) | NL7018312A (en) |
ZA (1) | ZA708259B (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4579997A (en) * | 1985-07-25 | 1986-04-01 | Phillips Petroleum Company | Olefin production over catalytic oxides of Mn and at least one of Nb and a lanthanide |
US4613722A (en) * | 1985-07-25 | 1986-09-23 | Phillips Petroleum Company | Dehydrogenation of C3 and C4 hydrocarbons over an iron-based catalyst |
US4620051A (en) * | 1985-07-25 | 1986-10-28 | Philips Petroleum Company | Dehydrogenation and cracking of C3 and C4 hydrocarbons to less saturated hydrocarbons |
US4620052A (en) * | 1985-07-25 | 1986-10-28 | Phillips Petroleum Company | Dehydrogenation and cracking of C3 and C4 hydrocarbons |
US4621163A (en) * | 1985-07-25 | 1986-11-04 | Phillips Petroleum Company | Conversion of C3 and C4 hydrocarbons to less saturated hydrocarbons |
US4621162A (en) * | 1985-07-25 | 1986-11-04 | Phillips Petroleum Company | Method for conversion of C3 and C4 hydrocarbons to olefinic products |
US4658081A (en) * | 1985-07-25 | 1987-04-14 | Phillips Petroleum Company | Propylene and ethylene selectivity with H2 S |
Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4093536A (en) * | 1974-04-15 | 1978-06-06 | Phillips Petroleum Company | Catalytic cracking and dehydrocyclizing of alkanes using alkaline earth oxides promoted with manganese oxide and/or rhenium oxide |
US3985641A (en) * | 1974-04-15 | 1976-10-12 | Phillips Petroleum Company | Catalytic cracking of alkanes |
US3948755A (en) * | 1974-05-31 | 1976-04-06 | Standard Oil Company | Process for recovering and upgrading hydrocarbons from oil shale and tar sands |
US3948754A (en) * | 1974-05-31 | 1976-04-06 | Standard Oil Company | Process for recovering and upgrading hydrocarbons from oil shale and tar sands |
GB1492880A (en) * | 1975-09-25 | 1977-11-23 | British Petroleum Co | Olefins production |
GB1493888A (en) * | 1975-09-25 | 1977-11-30 | British Petroleum Co | Olefins production |
NL8003313A (en) * | 1980-06-06 | 1982-01-04 | Shell Int Research | METHOD FOR PREPARING MIDDLE DISTILLATES. |
US4451578A (en) * | 1982-04-26 | 1984-05-29 | United Technologies Corporation | Iron oxide catalyst for steam reforming |
US5093540A (en) * | 1990-08-31 | 1992-03-03 | Shell Oil Company | Process for selectively converting linear paraffins to linear alpha olefins |
US7012038B2 (en) * | 2002-06-12 | 2006-03-14 | Engelhard Corporation | Paraffin dehydrogenation catalyst |
WO2005094992A1 (en) * | 2004-03-31 | 2005-10-13 | China Petroleum & Chemical Corporation | A catalyst containing zeolite for hydrocarbon converting and preparation thereof, and a hydrocarbon oil converting method using said catalyst |
CN101134172B (en) | 2006-08-31 | 2010-10-27 | 中国石油化工股份有限公司 | Hydrocarbons conversion catalyzer |
CN101134913B (en) * | 2006-08-31 | 2011-05-18 | 中国石油化工股份有限公司 | Hydrocarbons catalytic conversion method |
KR100931792B1 (en) * | 2007-05-25 | 2009-12-11 | 주식회사 엘지화학 | Catalyst for pyrolysis of hydrocarbon steam, preparation method thereof and preparation method of olefin using the same |
CN101332433B (en) * | 2007-06-27 | 2011-07-20 | 中国石油化工股份有限公司 | Catalytic cracking catalyst, preparation method and use thereof |
KR100999304B1 (en) * | 2007-07-05 | 2010-12-08 | 주식회사 엘지화학 | Method for Thermal-Cracking of Hydrocarbon for Preparing Olefins |
US8471082B2 (en) * | 2008-03-14 | 2013-06-25 | Catalytic Distillation Technologies | Process for converting methane to ethylene |
US8163170B2 (en) * | 2008-12-02 | 2012-04-24 | Lummus Technology Inc. | Coil for pyrolysis heater and method of cracking |
US8835347B2 (en) * | 2009-06-05 | 2014-09-16 | Basf Corporation | Alkane dehydrogenation catalysts |
US8481451B2 (en) * | 2009-06-08 | 2013-07-09 | Lg Chem, Ltd. | Catalyst for hydrocarbon steam cracking, method of preparing the same and method of preparing olefin by using the same |
ES2974266T3 (en) | 2018-09-27 | 2024-06-26 | Shanghai Supezet Eng Tech Co Ltd | Naphtha catalytic cracking method |
CN109232153B (en) * | 2018-09-27 | 2020-05-05 | 上海卓然工程技术股份有限公司 | Method for preparing low-carbon olefin from naphtha |
US11225612B2 (en) | 2020-03-27 | 2022-01-18 | Saudi Arabian Oil Company | Catalyst and process for catalytic steam cracking of heavy distillate |
US11866397B1 (en) | 2023-03-14 | 2024-01-09 | Saudi Arabian Oil Company | Process configurations for enhancing light olefin selectivity by steam catalytic cracking of heavy feedstock |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2392750A (en) * | 1942-08-22 | 1946-01-08 | Standard Oil Dev Co | Dehydrogenation of hydrocarbons |
US2754354A (en) * | 1952-08-18 | 1956-07-10 | Price Carl | Insulator |
US2894046A (en) * | 1957-04-12 | 1959-07-07 | Universal Oil Prod Co | Manufacture of para-xylene |
US2941016A (en) * | 1957-11-05 | 1960-06-14 | Hoechst Ag | Process for preparing aromatic hydrocarbons |
US3179602A (en) * | 1961-09-06 | 1965-04-20 | Monsanto Co | Preparation of a chromia-alumina hydrocarbon conversion catalyst |
NL6905469A (en) * | 1968-04-09 | 1969-10-13 | ||
FR1603019A (en) * | 1968-05-30 | 1971-03-15 | ||
FR1603110A (en) * | 1968-06-25 | 1971-03-22 |
-
1969
- 1969-12-23 GB GB6255269A patent/GB1306087A/en not_active Expired
-
1970
- 1970-12-07 ZA ZA708259A patent/ZA708259B/en unknown
- 1970-12-16 NL NL7018312A patent/NL7018312A/xx not_active Application Discontinuation
- 1970-12-17 US US00099271A patent/US3725495A/en not_active Expired - Lifetime
- 1970-12-21 FR FR7045992A patent/FR2072015B1/fr not_active Expired
- 1970-12-21 DK DK647170AA patent/DK139907B/en not_active IP Right Cessation
- 1970-12-22 CA CA101,322A patent/CA973152A/en not_active Expired
- 1970-12-22 ES ES386738A patent/ES386738A1/en not_active Expired
- 1970-12-22 DE DE19702063172 patent/DE2063172A1/en active Pending
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4579997A (en) * | 1985-07-25 | 1986-04-01 | Phillips Petroleum Company | Olefin production over catalytic oxides of Mn and at least one of Nb and a lanthanide |
US4613722A (en) * | 1985-07-25 | 1986-09-23 | Phillips Petroleum Company | Dehydrogenation of C3 and C4 hydrocarbons over an iron-based catalyst |
US4620051A (en) * | 1985-07-25 | 1986-10-28 | Philips Petroleum Company | Dehydrogenation and cracking of C3 and C4 hydrocarbons to less saturated hydrocarbons |
US4620052A (en) * | 1985-07-25 | 1986-10-28 | Phillips Petroleum Company | Dehydrogenation and cracking of C3 and C4 hydrocarbons |
US4621163A (en) * | 1985-07-25 | 1986-11-04 | Phillips Petroleum Company | Conversion of C3 and C4 hydrocarbons to less saturated hydrocarbons |
US4621162A (en) * | 1985-07-25 | 1986-11-04 | Phillips Petroleum Company | Method for conversion of C3 and C4 hydrocarbons to olefinic products |
US4658081A (en) * | 1985-07-25 | 1987-04-14 | Phillips Petroleum Company | Propylene and ethylene selectivity with H2 S |
US4705769A (en) * | 1985-07-25 | 1987-11-10 | Phillips Petroleum Company | Composition of matter for conversion of C3 and C4 hydrocarbons |
US4705772A (en) * | 1985-07-25 | 1987-11-10 | Phillips Petroleum Company | Composition of matter and method for conversion of C3 and C4 hydrocarbons |
AU568247B2 (en) * | 1985-07-25 | 1987-12-17 | Phillips Petroleum Co. | Selective production of ethylene and propylene |
US4829041A (en) * | 1985-07-25 | 1989-05-09 | Phillips Petroleum Company | Composition of matter and method for conversion of C3 and C4 hydrocarbons |
Also Published As
Publication number | Publication date |
---|---|
DE2063172A1 (en) | 1971-07-01 |
DK139907C (en) | 1979-10-08 |
FR2072015A1 (en) | 1971-09-24 |
ES386738A1 (en) | 1974-02-01 |
DK139907B (en) | 1979-05-14 |
FR2072015B1 (en) | 1975-01-10 |
US3725495A (en) | 1973-04-03 |
ZA708259B (en) | 1971-08-25 |
NL7018312A (en) | 1971-06-25 |
CA973152A (en) | 1975-08-19 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PCNP | Patent ceased through non-payment of renewal fee |