RU2019136972A - Замещенные сукцинимидные производные в качестве пестицидов - Google Patents

Замещенные сукцинимидные производные в качестве пестицидов Download PDF

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RU2019136972A
RU2019136972A RU2019136972A RU2019136972A RU2019136972A RU 2019136972 A RU2019136972 A RU 2019136972A RU 2019136972 A RU2019136972 A RU 2019136972A RU 2019136972 A RU2019136972 A RU 2019136972A RU 2019136972 A RU2019136972 A RU 2019136972A
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Карстен Кёрбер
Николас ХУВИЛЕР
Арун Нарине
Биргит Гоккель
Мартин Джон Маклафлин
Франц-Йозеф Браун
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Басф Се
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Claims (38)

1. Сукцинимидные соединения формулы I
Figure 00000001
,
где W-Z представляет собой -O-N=, -CH2-N= или -СН2-СН=;
R1 представляет собой галогенметил;
R2a представляет собой галоген, галогенметил или галогенметокси;
R2b, R2c независимо представляют собой Н или радикал согласно определению для R2a;
R3 представляет собой галоген, CN, NO2, C12-алкил, галогенметил, C12-алкокси, S(O)m12-алкил, C12-галогеналкокси или S(O)m-C1-C2-галогеналкил;
R4 представляет собой Н или радикал согласно определению для R3; или
R3 и R4 вместе с атомами углерода, к которым они присоединены, образуют 5- или 6-членное насыщенное, частично или полностью ненасыщенное карбоциклическое кольцо;
R5, R6 независимо представляют собой Н, CN, C110-алкил, С38-циклоалкил, С210-алкенил, С38-циклоалкенил, С210-алкинил, OR10, S(O)mR10, S(O)mN(R10)2, N(R10)2, где указанные алифатические группы не замещены, частично или полностью галогенированы и/или замещены одним или несколькими Ra; фенил, который не замещен или замещен одним или несколькими RA; и 3-7-членный насыщенный, частично или полностью ненасыщенный гетероцикл, содержащий 1, 2 или 3 гетероатома О, N(O)n или S(O)m в качестве кольцевых членов, где указанный гетероцикл не замещен или замещен одним или несколькими RA,
R10 независимо представляет собой Н, C16-алкил, C16-галогеналкил, С38-циклоалкил, С38-циклоалкил-С14-алкил, С38-галогенциклоалкил, С26-алкенил, С26-галогеналкенил, С26-алкинил, С26-галогеналкинил, где указанные группы не замещены или замещены одним или несколькими Ra,
Ra представляет собой CN, N3, NO2, SCN, SF5, Si(С14-алкил)3, ORa1, OSO2Ra1, S(O)nRa1, N(Ra2)Ra3, C(=O)N(Ra2)Ra3, C(=S)N(Ra2)Ra3, C(=O)Ra1, C(=O)ORa1, CH=NORa1, С38-циклоалкил, С38-галогенциклоалкил, где указанные циклические фрагменты могут быть замещены Ra4; фенил, который не замещен или замещен одним или несколькими RA; и 3-7-членный насыщенный, частично или полностью ненасыщенный гетероцикл, содержащий 1, 2 или 3 гетероатома О, N(O)n или S(O)m в качестве кольцевых членов, где указанный гетероцикл не замещен или замещен одним или несколькими RA,
m представляет собой 0, 1 или 2;
n представляет собой 0 или 1;
Ra1 представляет собой Н, C16-алкил, C16-галогеналкил, С24-алкенил, С24-алкинил, CH2-CN, С36-циклоалкил, С36-галогенциклоалкил, С3-C6-циклоалкилметил, С36-галогенциклоалкилметил, фенил и гетарил, где указанные ароматические кольца не замещены или частично или полностью замещены RA;
Ra2 представляет собой Н или C16-алкил,
Ra3 представляет собой Н, C16-алкил, C16-галогеналкил, С26-алкенил, С26-галогеналкенил, С26-алкинил, С26-галогеналкинил или С36-циклоалкил, С36-галогенциклоалкил, С36-циклоалкилметил или С36-галогенциклоалкилметил, где указанные кольца не замещены или замещены циано;
Ra4 независимо представляет собой ОН, CN, C16-алкокси, C16-галогеналкокси, S(O)m16-алкил, S(O)m16-галогеналкил, C(=O)N(Ra2)Ra3, С36-циклоалкил или С36-галогенциклоалкил, где циклы не замещены или замещены одним или несколькими Ra11; или
фенил, частично или полностью ненасыщенный гетероцикл, где кольца не замещены или замещены одним или несколькими RA;
Ra11 независимо представляет собой ОН, циано, C12-алкил или С12-галогеналкил;
RA независимо выбран из галогена, CN, NO2, С14-алкила, С14-галогеналкила, С24-алкенила, С24-галогеналкенила, С24-алкинила, С24-галогеналкинила, С36-циклоалкила, С36-галогенциклоалкила, С14-алкокси, С14-галогеналкокси, S(O)m14-алкила, S(O)m14-галогеналкила, С14-алкилкарбонила, С14-галогеналкилкарбонила, C(=O)N(Ra2)Ra3; или
два RA, присутствующие на одном и том же атоме углерода насыщенного или частично насыщенного кольца, могут образовывать вместе =O или =S; или
два RA, присутствующие на одном и том же S или SO кольцевом члене гетероциклического кольца, могут вместе образовывать группу =N(С16-алкил), =NO(С16-алкил), =NN(Н)(С16-алкил) или =NN(С16-алкил)2;
и их N-оксиды, стереоизомеры и приемлемые в сельском хозяйстве или ветеринарии соли.
2. Соединения формулы I по п. 1, которые соответствуют формуле I.a
Figure 00000002
.
3. Соединения формулы I по п. 1 или 2, которые соответствуют формуле I.Aa
Figure 00000003
.
4. Соединения формулы I по любому из пп. 1-3, которые соответствуют формуле I.1
Figure 00000004
.
5. Соединения формулы I по любому из пп.1-3, которые соответствуют формуле I.2
Figure 00000005
.
6. Соединения формулы I по любому из пп. 1-3, которые соответствуют формуле I.3
Figure 00000006
.
7. Соединения формулы I по любому из пп. 1-6, где R1 представляет собой галогенметил.
8. Соединения формулы I по любому из пп. 1-7, где R3 представляет собой галоген, NO2, CN, СН3, фторметил, CF3, SCH3 или ОСН3, и R4 представляет собой Н.
9. Соединения формулы I по любому из пп. 1-8, где R5 представляет собой Н, C16-алкил, С36-циклоалкил, С26-алкенил или С26-алкинил.
10. Соединения формулы I по любому из пп. 1-9, где R6 представляет собой C16-алкил, который не замещен или замещен фенилом или С(=O)-С16-алкокси; или R6 представляет собой С14-алкил, C1-C3-галогеналкил, С34-циклоалкил, C13-алкокси, C13-галогеналкокси, С14-алкиламино и ди-С14-алкиламино.
RU2019136972A 2017-04-26 2018-04-24 Замещенные сукцинимидные производные в качестве пестицидов RU2019136972A (ru)

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