RU2013128615A - Бромированные неорганические сорбенты для снижения выбросов ртути - Google Patents
Бромированные неорганические сорбенты для снижения выбросов ртути Download PDFInfo
- Publication number
- RU2013128615A RU2013128615A RU2013128615/05A RU2013128615A RU2013128615A RU 2013128615 A RU2013128615 A RU 2013128615A RU 2013128615/05 A RU2013128615/05 A RU 2013128615/05A RU 2013128615 A RU2013128615 A RU 2013128615A RU 2013128615 A RU2013128615 A RU 2013128615A
- Authority
- RU
- Russia
- Prior art keywords
- brominated
- inorganic
- sorbent
- bromine
- source
- Prior art date
Links
- 239000002594 sorbent Substances 0.000 title claims abstract 33
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 title claims 2
- 229910052753 mercury Inorganic materials 0.000 title claims 2
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 claims abstract 38
- 239000000758 substrate Substances 0.000 claims abstract 22
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract 17
- 229910000042 hydrogen bromide Inorganic materials 0.000 claims abstract 14
- 229910052717 sulfur Inorganic materials 0.000 claims abstract 14
- 239000011593 sulfur Substances 0.000 claims abstract 14
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims abstract 12
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract 12
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims abstract 12
- 229910052794 bromium Inorganic materials 0.000 claims abstract 12
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract 12
- 239000010457 zeolite Substances 0.000 claims abstract 12
- 239000000203 mixture Substances 0.000 claims abstract 10
- 239000000243 solution Substances 0.000 claims abstract 5
- JYIBXUUINYLWLR-UHFFFAOYSA-N aluminum;calcium;potassium;silicon;sodium;trihydrate Chemical compound O.O.O.[Na].[Al].[Si].[K].[Ca] JYIBXUUINYLWLR-UHFFFAOYSA-N 0.000 claims abstract 4
- 239000007864 aqueous solution Substances 0.000 claims abstract 4
- UNYSKUBLZGJSLV-UHFFFAOYSA-L calcium;1,3,5,2,4,6$l^{2}-trioxadisilaluminane 2,4-dioxide;dihydroxide;hexahydrate Chemical compound O.O.O.O.O.O.[OH-].[OH-].[Ca+2].O=[Si]1O[Al]O[Si](=O)O1.O=[Si]1O[Al]O[Si](=O)O1 UNYSKUBLZGJSLV-UHFFFAOYSA-L 0.000 claims abstract 4
- 239000012159 carrier gas Substances 0.000 claims abstract 4
- 239000004568 cement Substances 0.000 claims abstract 4
- 229910052676 chabazite Inorganic materials 0.000 claims abstract 4
- 229910001603 clinoptilolite Inorganic materials 0.000 claims abstract 4
- 239000000428 dust Substances 0.000 claims abstract 4
- 229910001853 inorganic hydroxide Inorganic materials 0.000 claims abstract 4
- 230000031709 bromination Effects 0.000 claims abstract 2
- 238000005893 bromination reaction Methods 0.000 claims abstract 2
- 238000000034 method Methods 0.000 claims 15
- 238000002485 combustion reaction Methods 0.000 claims 5
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims 3
- 229910004298 SiO 2 Inorganic materials 0.000 claims 3
- 239000007789 gas Substances 0.000 claims 2
- 150000002500 ions Chemical class 0.000 claims 2
- 239000002245 particle Substances 0.000 claims 2
- 150000003839 salts Chemical class 0.000 claims 2
- 238000011144 upstream manufacturing Methods 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000000567 combustion gas Substances 0.000 claims 1
- 230000003750 conditioning effect Effects 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 239000013618 particulate matter Substances 0.000 claims 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/64—Heavy metals or compounds thereof, e.g. mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/025—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with wetted adsorbents; Chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/027—Compounds of F, Cl, Br, I
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/165—Natural alumino-silicates, e.g. zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
- B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/10—Oxidants
- B01D2251/108—Halogens or halogen compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
- B01D2253/108—Zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/25—Coated, impregnated or composite adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/60—Heavy metals or heavy metal compounds
- B01D2257/602—Mercury or mercury compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0283—Flue gases
Landscapes
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Treating Waste Gases (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US41607710P | 2010-11-22 | 2010-11-22 | |
| US61/416,077 | 2010-11-22 | ||
| PCT/US2011/060605 WO2012071206A1 (en) | 2010-11-22 | 2011-11-14 | Brominated inorganic sorbents for reduction of mercury emissions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2013128615A true RU2013128615A (ru) | 2014-12-27 |
Family
ID=45099183
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2013128615/05A RU2013128615A (ru) | 2010-11-22 | 2011-11-14 | Бромированные неорганические сорбенты для снижения выбросов ртути |
Country Status (16)
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9382672B2 (en) | 2010-12-06 | 2016-07-05 | Astec, Inc. | Apparatus and method for dryer performance optimization system |
| US8863404B1 (en) * | 2010-12-06 | 2014-10-21 | Astec, Inc. | Apparatus and method for dryer performance optimization system |
| DE102011103829A1 (de) * | 2011-06-01 | 2012-12-06 | Rheinbraun Brennstoff Gmbh | Verfahren zur Abscheidung von Quecksilber aus Rauchgasen von Hochtemperaturanlagen |
| DE102012012367B4 (de) * | 2012-06-21 | 2014-03-27 | Ftu Gmbh Forschung Und Technische Entwicklung Im Umweltschutz | Aktivierter trass,dessen herstellung und verwendung |
| US9199898B2 (en) | 2012-08-30 | 2015-12-01 | Chevron U.S.A. Inc. | Process, method, and system for removing heavy metals from fluids |
| WO2014039758A2 (en) | 2012-09-07 | 2014-03-13 | Chevron U.S.A. Inc. | Process, method, and system for removing heavy metals from fluids |
| US8551431B1 (en) * | 2013-01-28 | 2013-10-08 | Cabot Corporation | Mercury removal from flue gas streams using treated sorbents |
| GB2525524A (en) * | 2013-01-28 | 2015-10-28 | Cabot Corp | Mercury removal from flue gas streams using treated sorbents |
| WO2014164980A1 (en) * | 2013-03-13 | 2014-10-09 | Novinda Corporation | Supported sulfides for mercury capture |
| TWI619550B (zh) * | 2013-03-15 | 2018-04-01 | 亞比馬利股份有限公司 | 煙道氣吸附劑、其製造方法及其自氣流移除汞之用途 |
| DE102014113620A1 (de) | 2014-09-22 | 2016-03-24 | Ftu Gmbh | Puzzolane zur Abgasreinigung |
| CN104351065A (zh) * | 2014-11-25 | 2015-02-18 | 芜湖悠派卫生用品有限公司 | 一种矿质吸附猫砂及其制备方法 |
| BR112018003056B1 (pt) | 2015-08-21 | 2022-09-13 | Ecolab Usa Inc | Método e uso de ácido peracético para reduzir emissões de mercúrio |
| PE20180862A1 (es) | 2015-08-21 | 2018-05-22 | Ecolab Usa Inc | Formacion de complejos y remocion de mercurio de los sistemas de desulfuracion de gases de combustion |
| CN105854544A (zh) * | 2016-05-24 | 2016-08-17 | 南京华电节能环保设备有限公司 | 一种烟气的除汞净化方法 |
| US11110393B2 (en) | 2017-07-06 | 2021-09-07 | Ecolab Usa Inc. | Enhanced injection of mercury oxidants |
| EP3787810A1 (en) | 2018-05-04 | 2021-03-10 | Albemarle Corporation | Processes for reducing environmental availability of environmental pollutants |
| KR102248568B1 (ko) * | 2018-07-26 | 2021-05-06 | 한국원자력연구원 | 방사성 핵종 흡착제, 이의 제조방법 및 이를 이용한 방사성 핵종의 제거 방법 |
| EP4031275A1 (en) * | 2019-09-16 | 2022-07-27 | Albemarle Corporation | Processes for reducing environmental availability of environmental pollutants |
| KR20220064371A (ko) | 2019-09-16 | 2022-05-18 | 알베마를 코포레이션 | 환경 오염물질의 환경적 이용가능성을 줄이기 위한 방법 |
| KR20230019418A (ko) * | 2020-05-28 | 2023-02-08 | 알베마를 코포레이션 | 주위 환경의 메틸수은을 감소시키고 이의 식물 및 유기체로의 흡수를 제한하는 방법 |
| CN117751009A (zh) | 2021-07-30 | 2024-03-22 | 雅宝公司 | 用于抑制汞蒸气排放的方法 |
| CN113713769B (zh) * | 2021-09-06 | 2022-07-26 | 中南大学 | 一种改性炭基吸附剂及其制备方法和应用 |
| CN115445418B (zh) * | 2022-08-23 | 2024-06-14 | 国家能源集团新能源技术研究院有限公司 | 一种用于协同脱除燃煤烟气中汞和二氧化碳的系统及方法 |
| CN120202073A (zh) | 2022-10-26 | 2025-06-24 | 雅宝公司 | 用于降低环境污染物的环境有效性的方法 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3749754A (en) * | 1971-04-28 | 1973-07-31 | Exxon | Hydroisomerization process with hydrogen faujasite containing a group viii metal |
| US4101631A (en) | 1976-11-03 | 1978-07-18 | Union Carbide Corporation | Selective adsorption of mercury from gas streams |
| FR2438083A1 (fr) * | 1978-10-02 | 1980-04-30 | Mobil Oil Corp | Procede pour eliminer les composes azotes presents dans les hydrocarbures liquides |
| JPS61242901A (ja) * | 1985-04-17 | 1986-10-29 | Toyo Soda Mfg Co Ltd | 臭素回収用吸着剤及び臭素回収方法 |
| US5952541A (en) * | 1992-07-30 | 1999-09-14 | Exxon Chemical Patents, Inc. | Method of loading hydrogen halide onto an adsorbent to enable removal of lead impurities from liquid hydrocarbons |
| JPH08330720A (ja) | 1995-05-29 | 1996-12-13 | Temic Telefunken Microelectron Gmbh | 絶縁された線材をはんだ付けする方法 |
| TW510820B (en) | 1999-11-30 | 2002-11-21 | Japan Pionics | Method of cleaning of harmful gas and cleaning apparatus |
| US6610263B2 (en) | 2000-08-01 | 2003-08-26 | Enviroscrub Technologies Corporation | System and process for removal of pollutants from a gas stream |
| DE60328489D1 (de) | 2002-05-06 | 2009-09-03 | Sorbent Technologies Corp | Verfahren zur entfernung von quecksilber aus verbrennungsgasen |
| CN101553301A (zh) * | 2006-12-08 | 2009-10-07 | 普莱克斯技术有限公司 | 适用作水泥添加剂的水银吸附剂 |
| CN101274190A (zh) * | 2007-03-30 | 2008-10-01 | 高化环保技术有限公司 | 利用硫化处理铁氧化物的除汞用吸附剂及其制造方法 |
| US8906823B2 (en) * | 2007-09-24 | 2014-12-09 | Basf Corporation | Pollutant emission control sorbents and methods of manufacture and use |
| CN101502737A (zh) * | 2009-01-21 | 2009-08-12 | 东华大学 | 一种用溴化处理过的碳粉脱除燃煤烟气中重金属汞的方法及装置 |
| HUE030927T2 (en) | 2009-06-12 | 2017-06-28 | Albemarle Europe Sprl | SAPO molecular filter catalysts and their production and use |
| PL2555851T3 (pl) * | 2010-04-07 | 2022-01-10 | Calgon Carbon Corporation | Sposoby usuwania rtęci z gazów spalinowych |
| JP2013539413A (ja) * | 2010-08-30 | 2013-10-24 | アルベマール・コーポレーシヨン | 燃料燃焼時に生成される排出物から水銀を除去するための改良された吸着剤 |
| BR112013010543A2 (pt) * | 2010-11-03 | 2019-09-24 | Carus Corp | sorvente com base em manganês para a remoção de espécies de mercúrio de fluidos |
-
2011
- 2011-11-14 RU RU2013128615/05A patent/RU2013128615A/ru not_active Application Discontinuation
- 2011-11-14 JP JP2013539928A patent/JP2013544185A/ja not_active Withdrawn
- 2011-11-14 EP EP11791687.4A patent/EP2643071A1/en not_active Withdrawn
- 2011-11-14 US US13/988,166 patent/US20130272936A1/en not_active Abandoned
- 2011-11-14 CA CA2815090A patent/CA2815090A1/en not_active Abandoned
- 2011-11-14 PH PH1/2013/500868A patent/PH12013500868A1/en unknown
- 2011-11-14 CN CN201180055980XA patent/CN103338831A/zh active Pending
- 2011-11-14 BR BR112013012524A patent/BR112013012524A2/pt not_active IP Right Cessation
- 2011-11-14 WO PCT/US2011/060605 patent/WO2012071206A1/en not_active Ceased
- 2011-11-14 KR KR1020137012379A patent/KR20140002642A/ko not_active Withdrawn
- 2011-11-14 AU AU2011332149A patent/AU2011332149A1/en not_active Abandoned
- 2011-11-21 TW TW100142481A patent/TW201228722A/zh unknown
- 2011-11-22 AR ARP110104336A patent/AR083944A1/es unknown
-
2013
- 2013-04-29 ZA ZA2013/03131A patent/ZA201303131B/en unknown
- 2013-05-17 CL CL2013001404A patent/CL2013001404A1/es unknown
- 2013-05-20 CO CO13123628A patent/CO6801783A2/es active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| EP2643071A1 (en) | 2013-10-02 |
| ZA201303131B (en) | 2014-10-29 |
| CN103338831A (zh) | 2013-10-02 |
| CL2013001404A1 (es) | 2013-12-13 |
| AR083944A1 (es) | 2013-04-10 |
| TW201228722A (en) | 2012-07-16 |
| BR112013012524A2 (pt) | 2016-09-06 |
| JP2013544185A (ja) | 2013-12-12 |
| PH12013500868A1 (en) | 2013-06-03 |
| AU2011332149A1 (en) | 2013-06-13 |
| KR20140002642A (ko) | 2014-01-08 |
| CO6801783A2 (es) | 2013-11-29 |
| WO2012071206A1 (en) | 2012-05-31 |
| CA2815090A1 (en) | 2012-05-31 |
| US20130272936A1 (en) | 2013-10-17 |
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