TW201228722A - Inorganic sorbents for reduction of mercury emissions - Google Patents
Inorganic sorbents for reduction of mercury emissions Download PDFInfo
- Publication number
- TW201228722A TW201228722A TW100142481A TW100142481A TW201228722A TW 201228722 A TW201228722 A TW 201228722A TW 100142481 A TW100142481 A TW 100142481A TW 100142481 A TW100142481 A TW 100142481A TW 201228722 A TW201228722 A TW 201228722A
- Authority
- TW
- Taiwan
- Prior art keywords
- inorganic
- bromine
- source
- brominated
- adsorbent
- Prior art date
Links
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 title claims abstract description 58
- 229910052753 mercury Inorganic materials 0.000 title claims abstract description 54
- 239000002594 sorbent Substances 0.000 title claims abstract description 23
- 230000009467 reduction Effects 0.000 title description 4
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims abstract description 143
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims abstract description 127
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical group Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 claims abstract description 127
- 229910052794 bromium Inorganic materials 0.000 claims abstract description 126
- 238000000034 method Methods 0.000 claims abstract description 72
- 229910000042 hydrogen bromide Inorganic materials 0.000 claims abstract description 47
- 239000000203 mixture Substances 0.000 claims abstract description 38
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 149
- 239000003463 adsorbent Substances 0.000 claims description 148
- 229910052717 sulfur Inorganic materials 0.000 claims description 134
- 239000011593 sulfur Substances 0.000 claims description 134
- 239000000758 substrate Substances 0.000 claims description 98
- 239000011159 matrix material Substances 0.000 claims description 51
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 38
- 239000010457 zeolite Substances 0.000 claims description 38
- 229910021536 Zeolite Inorganic materials 0.000 claims description 34
- 239000000243 solution Substances 0.000 claims description 34
- 239000007789 gas Substances 0.000 claims description 31
- 239000000567 combustion gas Substances 0.000 claims description 25
- 239000002245 particle Substances 0.000 claims description 23
- UNYSKUBLZGJSLV-UHFFFAOYSA-L calcium;1,3,5,2,4,6$l^{2}-trioxadisilaluminane 2,4-dioxide;dihydroxide;hexahydrate Chemical compound O.O.O.O.O.O.[OH-].[OH-].[Ca+2].O=[Si]1O[Al]O[Si](=O)O1.O=[Si]1O[Al]O[Si](=O)O1 UNYSKUBLZGJSLV-UHFFFAOYSA-L 0.000 claims description 22
- 229910052676 chabazite Inorganic materials 0.000 claims description 21
- 238000002347 injection Methods 0.000 claims description 21
- 239000007924 injection Substances 0.000 claims description 21
- 230000031709 bromination Effects 0.000 claims description 20
- 238000005893 bromination reaction Methods 0.000 claims description 20
- 239000004568 cement Substances 0.000 claims description 15
- 239000000428 dust Substances 0.000 claims description 14
- 229910001853 inorganic hydroxide Inorganic materials 0.000 claims description 14
- 239000007788 liquid Substances 0.000 claims description 14
- 239000012159 carrier gas Substances 0.000 claims description 13
- -1 sulfur ions Chemical class 0.000 claims description 12
- 239000000126 substance Substances 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 150000003839 salts Chemical class 0.000 claims description 9
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 8
- 239000007864 aqueous solution Substances 0.000 claims description 7
- JYIBXUUINYLWLR-UHFFFAOYSA-N aluminum;calcium;potassium;silicon;sodium;trihydrate Chemical compound O.O.O.[Na].[Al].[Si].[K].[Ca] JYIBXUUINYLWLR-UHFFFAOYSA-N 0.000 claims description 5
- 229910001603 clinoptilolite Inorganic materials 0.000 claims description 5
- 238000002485 combustion reaction Methods 0.000 claims description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 238000011144 upstream manufacturing Methods 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 230000003750 conditioning effect Effects 0.000 claims description 3
- 150000002500 ions Chemical class 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 229910052593 corundum Inorganic materials 0.000 claims description 2
- 150000002431 hydrogen Chemical class 0.000 claims description 2
- 239000008187 granular material Substances 0.000 claims 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims 1
- 108010068370 Glutens Proteins 0.000 claims 1
- YADDYKXZVNQFBH-UHFFFAOYSA-N argon;hydrobromide Chemical compound [Ar].Br YADDYKXZVNQFBH-UHFFFAOYSA-N 0.000 claims 1
- 235000021312 gluten Nutrition 0.000 claims 1
- 235000001508 sulfur Nutrition 0.000 description 122
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 19
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 14
- 239000003546 flue gas Substances 0.000 description 14
- 238000012360 testing method Methods 0.000 description 13
- 239000005864 Sulphur Substances 0.000 description 12
- 238000010438 heat treatment Methods 0.000 description 11
- 239000003054 catalyst Substances 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 6
- 239000012717 electrostatic precipitator Substances 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000001179 sorption measurement Methods 0.000 description 5
- 241000269350 Anura Species 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000010881 fly ash Substances 0.000 description 4
- 239000011261 inert gas Substances 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 241000894007 species Species 0.000 description 4
- 239000004575 stone Substances 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052902 vermiculite Inorganic materials 0.000 description 3
- 239000010455 vermiculite Substances 0.000 description 3
- 235000019354 vermiculite Nutrition 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 239000002734 clay mineral Substances 0.000 description 2
- 230000005284 excitation Effects 0.000 description 2
- 239000010433 feldspar Substances 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- 150000007529 inorganic bases Chemical class 0.000 description 2
- 229910052809 inorganic oxide Inorganic materials 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229910003455 mixed metal oxide Inorganic materials 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 229910052707 ruthenium Inorganic materials 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical group [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 2
- 235000019345 sodium thiosulphate Nutrition 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 2
- 150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 238000000844 transformation Methods 0.000 description 2
- RGCKGOZRHPZPFP-UHFFFAOYSA-N Alizarin Natural products C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- 101150118484 Macf1 gene Proteins 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910052772 Samarium Inorganic materials 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- WWFZRAYTGNKUQC-UHFFFAOYSA-H [Al+3].[Y+3].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O Chemical compound [Al+3].[Y+3].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O WWFZRAYTGNKUQC-UHFFFAOYSA-H 0.000 description 1
- QBSQAZUTHKDLIF-UHFFFAOYSA-N [Ar].Br.Br Chemical compound [Ar].Br.Br QBSQAZUTHKDLIF-UHFFFAOYSA-N 0.000 description 1
- GZZMEFFUSRGCNW-UHFFFAOYSA-N [Br].[Br] Chemical compound [Br].[Br] GZZMEFFUSRGCNW-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- HFVAFDPGUJEFBQ-UHFFFAOYSA-M alizarin red S Chemical compound [Na+].O=C1C2=CC=CC=C2C(=O)C2=C1C=C(S([O-])(=O)=O)C(O)=C2O HFVAFDPGUJEFBQ-UHFFFAOYSA-M 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000003842 bromide salts Chemical class 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 244000309466 calf Species 0.000 description 1
- QGJOPFRUJISHPQ-NJFSPNSNSA-N carbon disulfide-14c Chemical compound S=[14C]=S QGJOPFRUJISHPQ-NJFSPNSNSA-N 0.000 description 1
- 239000012018 catalyst precursor Substances 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000007580 dry-mixing Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000012013 faujasite Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 1
- 229910001701 hydrotalcite Inorganic materials 0.000 description 1
- 229960001545 hydrotalcite Drugs 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 235000014413 iron hydroxide Nutrition 0.000 description 1
- NCNCGGDMXMBVIA-UHFFFAOYSA-L iron(ii) hydroxide Chemical compound [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000003863 metallic catalyst Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000013612 plasmid Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 description 1
- 229910052594 sapphire Inorganic materials 0.000 description 1
- 239000010980 sapphire Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052665 sodalite Inorganic materials 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003463 sulfur Chemical class 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- NVSDADJBGGUCLP-UHFFFAOYSA-N trisulfur Chemical compound S=S=S NVSDADJBGGUCLP-UHFFFAOYSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/64—Heavy metals or compounds thereof, e.g. mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/025—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with wetted adsorbents; Chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/027—Compounds of F, Cl, Br, I
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/165—Natural alumino-silicates, e.g. zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
- B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/10—Oxidants
- B01D2251/108—Halogens or halogen compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
- B01D2253/108—Zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/25—Coated, impregnated or composite adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/60—Heavy metals or heavy metal compounds
- B01D2257/602—Mercury or mercury compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0283—Flue gases
Landscapes
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Treating Waste Gases (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US41607710P | 2010-11-22 | 2010-11-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW201228722A true TW201228722A (en) | 2012-07-16 |
Family
ID=45099183
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW100142481A TW201228722A (en) | 2010-11-22 | 2011-11-21 | Inorganic sorbents for reduction of mercury emissions |
Country Status (16)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI619550B (zh) * | 2013-03-15 | 2018-04-01 | 亞比馬利股份有限公司 | 煙道氣吸附劑、其製造方法及其自氣流移除汞之用途 |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9382672B2 (en) | 2010-12-06 | 2016-07-05 | Astec, Inc. | Apparatus and method for dryer performance optimization system |
| US8863404B1 (en) * | 2010-12-06 | 2014-10-21 | Astec, Inc. | Apparatus and method for dryer performance optimization system |
| DE102011103829A1 (de) * | 2011-06-01 | 2012-12-06 | Rheinbraun Brennstoff Gmbh | Verfahren zur Abscheidung von Quecksilber aus Rauchgasen von Hochtemperaturanlagen |
| DE102012012367B4 (de) * | 2012-06-21 | 2014-03-27 | Ftu Gmbh Forschung Und Technische Entwicklung Im Umweltschutz | Aktivierter trass,dessen herstellung und verwendung |
| US9199898B2 (en) | 2012-08-30 | 2015-12-01 | Chevron U.S.A. Inc. | Process, method, and system for removing heavy metals from fluids |
| WO2014039758A2 (en) | 2012-09-07 | 2014-03-13 | Chevron U.S.A. Inc. | Process, method, and system for removing heavy metals from fluids |
| US8551431B1 (en) * | 2013-01-28 | 2013-10-08 | Cabot Corporation | Mercury removal from flue gas streams using treated sorbents |
| GB2525524A (en) * | 2013-01-28 | 2015-10-28 | Cabot Corp | Mercury removal from flue gas streams using treated sorbents |
| WO2014164980A1 (en) * | 2013-03-13 | 2014-10-09 | Novinda Corporation | Supported sulfides for mercury capture |
| DE102014113620A1 (de) | 2014-09-22 | 2016-03-24 | Ftu Gmbh | Puzzolane zur Abgasreinigung |
| CN104351065A (zh) * | 2014-11-25 | 2015-02-18 | 芜湖悠派卫生用品有限公司 | 一种矿质吸附猫砂及其制备方法 |
| BR112018003056B1 (pt) | 2015-08-21 | 2022-09-13 | Ecolab Usa Inc | Método e uso de ácido peracético para reduzir emissões de mercúrio |
| PE20180862A1 (es) | 2015-08-21 | 2018-05-22 | Ecolab Usa Inc | Formacion de complejos y remocion de mercurio de los sistemas de desulfuracion de gases de combustion |
| CN105854544A (zh) * | 2016-05-24 | 2016-08-17 | 南京华电节能环保设备有限公司 | 一种烟气的除汞净化方法 |
| US11110393B2 (en) | 2017-07-06 | 2021-09-07 | Ecolab Usa Inc. | Enhanced injection of mercury oxidants |
| EP3787810A1 (en) | 2018-05-04 | 2021-03-10 | Albemarle Corporation | Processes for reducing environmental availability of environmental pollutants |
| KR102248568B1 (ko) * | 2018-07-26 | 2021-05-06 | 한국원자력연구원 | 방사성 핵종 흡착제, 이의 제조방법 및 이를 이용한 방사성 핵종의 제거 방법 |
| EP4031275A1 (en) * | 2019-09-16 | 2022-07-27 | Albemarle Corporation | Processes for reducing environmental availability of environmental pollutants |
| KR20220064371A (ko) | 2019-09-16 | 2022-05-18 | 알베마를 코포레이션 | 환경 오염물질의 환경적 이용가능성을 줄이기 위한 방법 |
| KR20230019418A (ko) * | 2020-05-28 | 2023-02-08 | 알베마를 코포레이션 | 주위 환경의 메틸수은을 감소시키고 이의 식물 및 유기체로의 흡수를 제한하는 방법 |
| CN117751009A (zh) | 2021-07-30 | 2024-03-22 | 雅宝公司 | 用于抑制汞蒸气排放的方法 |
| CN113713769B (zh) * | 2021-09-06 | 2022-07-26 | 中南大学 | 一种改性炭基吸附剂及其制备方法和应用 |
| CN115445418B (zh) * | 2022-08-23 | 2024-06-14 | 国家能源集团新能源技术研究院有限公司 | 一种用于协同脱除燃煤烟气中汞和二氧化碳的系统及方法 |
| CN120202073A (zh) | 2022-10-26 | 2025-06-24 | 雅宝公司 | 用于降低环境污染物的环境有效性的方法 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3749754A (en) * | 1971-04-28 | 1973-07-31 | Exxon | Hydroisomerization process with hydrogen faujasite containing a group viii metal |
| US4101631A (en) | 1976-11-03 | 1978-07-18 | Union Carbide Corporation | Selective adsorption of mercury from gas streams |
| FR2438083A1 (fr) * | 1978-10-02 | 1980-04-30 | Mobil Oil Corp | Procede pour eliminer les composes azotes presents dans les hydrocarbures liquides |
| JPS61242901A (ja) * | 1985-04-17 | 1986-10-29 | Toyo Soda Mfg Co Ltd | 臭素回収用吸着剤及び臭素回収方法 |
| US5952541A (en) * | 1992-07-30 | 1999-09-14 | Exxon Chemical Patents, Inc. | Method of loading hydrogen halide onto an adsorbent to enable removal of lead impurities from liquid hydrocarbons |
| JPH08330720A (ja) | 1995-05-29 | 1996-12-13 | Temic Telefunken Microelectron Gmbh | 絶縁された線材をはんだ付けする方法 |
| TW510820B (en) | 1999-11-30 | 2002-11-21 | Japan Pionics | Method of cleaning of harmful gas and cleaning apparatus |
| US6610263B2 (en) | 2000-08-01 | 2003-08-26 | Enviroscrub Technologies Corporation | System and process for removal of pollutants from a gas stream |
| DE60328489D1 (de) | 2002-05-06 | 2009-09-03 | Sorbent Technologies Corp | Verfahren zur entfernung von quecksilber aus verbrennungsgasen |
| CN101553301A (zh) * | 2006-12-08 | 2009-10-07 | 普莱克斯技术有限公司 | 适用作水泥添加剂的水银吸附剂 |
| CN101274190A (zh) * | 2007-03-30 | 2008-10-01 | 高化环保技术有限公司 | 利用硫化处理铁氧化物的除汞用吸附剂及其制造方法 |
| US8906823B2 (en) * | 2007-09-24 | 2014-12-09 | Basf Corporation | Pollutant emission control sorbents and methods of manufacture and use |
| CN101502737A (zh) * | 2009-01-21 | 2009-08-12 | 东华大学 | 一种用溴化处理过的碳粉脱除燃煤烟气中重金属汞的方法及装置 |
| HUE030927T2 (en) | 2009-06-12 | 2017-06-28 | Albemarle Europe Sprl | SAPO molecular filter catalysts and their production and use |
| PL2555851T3 (pl) * | 2010-04-07 | 2022-01-10 | Calgon Carbon Corporation | Sposoby usuwania rtęci z gazów spalinowych |
| JP2013539413A (ja) * | 2010-08-30 | 2013-10-24 | アルベマール・コーポレーシヨン | 燃料燃焼時に生成される排出物から水銀を除去するための改良された吸着剤 |
| BR112013010543A2 (pt) * | 2010-11-03 | 2019-09-24 | Carus Corp | sorvente com base em manganês para a remoção de espécies de mercúrio de fluidos |
-
2011
- 2011-11-14 RU RU2013128615/05A patent/RU2013128615A/ru not_active Application Discontinuation
- 2011-11-14 JP JP2013539928A patent/JP2013544185A/ja not_active Withdrawn
- 2011-11-14 EP EP11791687.4A patent/EP2643071A1/en not_active Withdrawn
- 2011-11-14 US US13/988,166 patent/US20130272936A1/en not_active Abandoned
- 2011-11-14 CA CA2815090A patent/CA2815090A1/en not_active Abandoned
- 2011-11-14 PH PH1/2013/500868A patent/PH12013500868A1/en unknown
- 2011-11-14 CN CN201180055980XA patent/CN103338831A/zh active Pending
- 2011-11-14 BR BR112013012524A patent/BR112013012524A2/pt not_active IP Right Cessation
- 2011-11-14 WO PCT/US2011/060605 patent/WO2012071206A1/en not_active Ceased
- 2011-11-14 KR KR1020137012379A patent/KR20140002642A/ko not_active Withdrawn
- 2011-11-14 AU AU2011332149A patent/AU2011332149A1/en not_active Abandoned
- 2011-11-21 TW TW100142481A patent/TW201228722A/zh unknown
- 2011-11-22 AR ARP110104336A patent/AR083944A1/es unknown
-
2013
- 2013-04-29 ZA ZA2013/03131A patent/ZA201303131B/en unknown
- 2013-05-17 CL CL2013001404A patent/CL2013001404A1/es unknown
- 2013-05-20 CO CO13123628A patent/CO6801783A2/es active IP Right Grant
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI619550B (zh) * | 2013-03-15 | 2018-04-01 | 亞比馬利股份有限公司 | 煙道氣吸附劑、其製造方法及其自氣流移除汞之用途 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2643071A1 (en) | 2013-10-02 |
| ZA201303131B (en) | 2014-10-29 |
| CN103338831A (zh) | 2013-10-02 |
| CL2013001404A1 (es) | 2013-12-13 |
| RU2013128615A (ru) | 2014-12-27 |
| AR083944A1 (es) | 2013-04-10 |
| BR112013012524A2 (pt) | 2016-09-06 |
| JP2013544185A (ja) | 2013-12-12 |
| PH12013500868A1 (en) | 2013-06-03 |
| AU2011332149A1 (en) | 2013-06-13 |
| KR20140002642A (ko) | 2014-01-08 |
| CO6801783A2 (es) | 2013-11-29 |
| WO2012071206A1 (en) | 2012-05-31 |
| CA2815090A1 (en) | 2012-05-31 |
| US20130272936A1 (en) | 2013-10-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TW201228722A (en) | Inorganic sorbents for reduction of mercury emissions | |
| CN102413899B (zh) | 用于汞的氧化和移除的吸附剂 | |
| AU2003232091B2 (en) | Sorbents and methods for the removal of mercury from combustion gases | |
| US8551431B1 (en) | Mercury removal from flue gas streams using treated sorbents | |
| CA2584327C (en) | Sorbents for the oxidation and removal of mercury | |
| JP5722888B2 (ja) | 燃焼排ガス中のダイオキシンおよび重金属を低減するための固体無機組成物、その製法およびその利用法 | |
| US20130125750A1 (en) | Reduction of Mercury Emissions From Cement Plants | |
| AU2009296691A1 (en) | Bromine chloride compositions for removing mercury from emissions produced during fuel combustion | |
| WO2005120686A1 (ja) | 一酸化炭素除去用触媒及び該触媒を用いた一酸化炭素除去方法 | |
| MX2013004850A (es) | Sorbente a base de manganeso para remocion de especies de mercurio de los fluidos. | |
| TWI541063B (zh) | 酸性氣體處理劑及其製造方法 | |
| CN102164651A (zh) | 吸附剂组合物和用于减少燃气流中的汞排放的方法 | |
| JP4648977B2 (ja) | 高温用途のハロゲン化物捕捉剤 | |
| CN104394960A (zh) | 净化液体的介质,其制备方法及其应用 | |
| CN107073395B (zh) | 净化流体的方法 | |
| Puccini et al. | The effect of flue gas contaminants on CO2 capture at high temperature by Li4SiO4-based sorbents | |
| HK1190107A (en) | Brominated inorganic sorbents for reduction of mercury emissions | |
| CN102892481A (zh) | 来自水泥厂的汞排放的降低 | |
| WO2014077979A1 (en) | Activated carbon from boiler ash residue | |
| KR100567411B1 (ko) | 다이옥신 제거용 흡착제 및 상기 흡착제를 제조하는 방법 | |
| TW201021899A (en) | Bromine chloride compositions for removing mercury from emissions produced during fuel combustion |