RU2012145609A - Ламинированный лист вспененной фенольной смолы и способ его производства - Google Patents

Ламинированный лист вспененной фенольной смолы и способ его производства Download PDF

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RU2012145609A
RU2012145609A RU2012145609/05A RU2012145609A RU2012145609A RU 2012145609 A RU2012145609 A RU 2012145609A RU 2012145609/05 A RU2012145609/05 A RU 2012145609/05A RU 2012145609 A RU2012145609 A RU 2012145609A RU 2012145609 A RU2012145609 A RU 2012145609A
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phenolic resin
foamed phenolic
foamed
less
laminated sheet
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Масато ХАМАДЗИМА
Йосимицу ИНОУЕ
Хисаси МИХОРИ
Йосихито ФУКАСАВА
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Асахи Касеи Констракшн Матириалс Корпорейшн
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    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/42—Layered products comprising a layer of synthetic resin comprising condensation resins of aldehydes, e.g. with phenols, ureas or melamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
    • B32B5/20—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material foamed in situ
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B29/00—Layered products comprising a layer of paper or cardboard
    • B32B29/002—Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B29/007—Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material next to a foam layer
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    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/245—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it being a foam layer
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    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
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    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
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    • B32—LAYERED PRODUCTS
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B2266/00—Composition of foam
    • B32B2266/02—Organic
    • B32B2266/0214—Materials belonging to B32B27/00
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/306—Resistant to heat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B2419/00—Buildings or parts thereof
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08J2361/04—Condensation polymers of aldehydes or ketones with phenols only
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  • Laminated Bodies (AREA)

Abstract

1. Ламинированный лист вспененной фенольной смолы, содержащий:вспененную фенольную смолу; илицевой материал для покрытия поверхности вспененной фенольной смолы,причем вспененная фенольная смола содержит углеводород, хлорированный алифатический углеводород или их комбинацию,плотность вспененной фенольной смолы составляет 10 кг/мили больше и 100 кг/мили меньше,средний диаметр ячеек вспененной фенольной смолы составляет 5 мкм или больше и 200 мкм или меньше,содержание закрытых ячеек вспененной фенольной смолы составляет 85% или больше и 99% или меньше, иабсолютная величина степени изменения размеров вспененной фенольной смолы после 70°С в течение 48 часов составляет 0,49% или меньше.2. Ламинированный лист вспененной фенольной смолы по п.1, где содержание летучих компонентов вспененной фенольной смолы составляет 1,0% масс. или больше и 7,0% или меньше.3. Ламинированный лист вспененной фенольной смолы по п.1 или 2, где вспененная фенольная смола содержит углеводород и хлорированный алифатический углеводород.4. Ламинированный лист вспененной фенольной смолы по п.1 или 2, где скорость кислородной проницаемости лицевого материала составляет 4,5 см/24 ч·мили больше.5. Ламинированный лист вспененной фенольной смолы по п.1 или 2, где теплопроводность вспененной фенольной смолы составляет от 0,0150 до 0,0250 Вт/м·К.6. Способ изготовления ламинированного листа вспененной фенольной смолы, включающий:вспенивание и отверждение вспениваемой композиции фенольной смолы на лицевом материале,причем вспениваемая композиция фенольной смолы содержит:фенольную смолу;катализатор отверждения;вспенивающий агент, содержащий углеводород, хлорированны�

Claims (6)

1. Ламинированный лист вспененной фенольной смолы, содержащий:
вспененную фенольную смолу; и
лицевой материал для покрытия поверхности вспененной фенольной смолы,
причем вспененная фенольная смола содержит углеводород, хлорированный алифатический углеводород или их комбинацию,
плотность вспененной фенольной смолы составляет 10 кг/м3 или больше и 100 кг/м3 или меньше,
средний диаметр ячеек вспененной фенольной смолы составляет 5 мкм или больше и 200 мкм или меньше,
содержание закрытых ячеек вспененной фенольной смолы составляет 85% или больше и 99% или меньше, и
абсолютная величина степени изменения размеров вспененной фенольной смолы после 70°С в течение 48 часов составляет 0,49% или меньше.
2. Ламинированный лист вспененной фенольной смолы по п.1, где содержание летучих компонентов вспененной фенольной смолы составляет 1,0% масс. или больше и 7,0% или меньше.
3. Ламинированный лист вспененной фенольной смолы по п.1 или 2, где вспененная фенольная смола содержит углеводород и хлорированный алифатический углеводород.
4. Ламинированный лист вспененной фенольной смолы по п.1 или 2, где скорость кислородной проницаемости лицевого материала составляет 4,5 см3/24 ч·м2 или больше.
5. Ламинированный лист вспененной фенольной смолы по п.1 или 2, где теплопроводность вспененной фенольной смолы составляет от 0,0150 до 0,0250 Вт/м·К.
6. Способ изготовления ламинированного листа вспененной фенольной смолы, включающий:
вспенивание и отверждение вспениваемой композиции фенольной смолы на лицевом материале,
причем вспениваемая композиция фенольной смолы содержит:
фенольную смолу;
катализатор отверждения;
вспенивающий агент, содержащий углеводород, хлорированный алифатический углеводород или их комбинацию; и
поверхностно-активное вещество;
содержание свободного фенола фенольной смолы составляет 1,0% масс. или больше и 4,3% масс. или меньше,
содержание воды фенольной смолы составляет 1,0% масс. или больше и 10,0% масс. или меньше, и
вязкость фенольной смолы при 40°С составляет 5000 мПа сек или больше и 100000 мПа·с или меньше.
RU2012145609/05A 2010-03-26 2011-03-25 Ламинированный лист вспененной фенольной смолы и способ его производства RU2540308C2 (ru)

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JP2010073018 2010-03-26
JP2010-073018 2010-03-26
PCT/JP2011/057409 WO2011118793A1 (ja) 2010-03-26 2011-03-25 フェノール樹脂発泡体積層板及びその製造方法

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EP2933286B1 (en) * 2012-12-11 2018-07-11 Asahi Kasei Construction Materials Corporation Phenolic resin foam and method for producing same
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JP6441656B2 (ja) * 2014-12-10 2018-12-19 旭化成建材株式会社 フェノール樹脂発泡体積層板及びその製造方法
KR20210029303A (ko) * 2015-03-24 2021-03-15 아사히 가세이 겐자이 가부시키가이샤 페놀 수지 발포체 및 그 제조 방법
JP6523829B2 (ja) * 2015-07-01 2019-06-05 旭化成建材株式会社 フェノール樹脂発泡板
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