RU2008142934A - Катализатор гидрокрекинга и способ получения основного компонента топлива - Google Patents
Катализатор гидрокрекинга и способ получения основного компонента топлива Download PDFInfo
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- RU2008142934A RU2008142934A RU2008142934/04A RU2008142934A RU2008142934A RU 2008142934 A RU2008142934 A RU 2008142934A RU 2008142934/04 A RU2008142934/04 A RU 2008142934/04A RU 2008142934 A RU2008142934 A RU 2008142934A RU 2008142934 A RU2008142934 A RU 2008142934A
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- Prior art keywords
- usy zeolite
- catalyst according
- catalyst
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- 239000003054 catalyst Substances 0.000 title claims abstract 19
- 238000004517 catalytic hydrocracking Methods 0.000 title claims abstract 5
- 239000000446 fuel Substances 0.000 title claims abstract 3
- 238000004519 manufacturing process Methods 0.000 title claims abstract 3
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract 14
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract 14
- 239000010457 zeolite Substances 0.000 claims abstract 14
- 239000011973 solid acid Substances 0.000 claims abstract 6
- 238000002441 X-ray diffraction Methods 0.000 claims abstract 4
- 229930195733 hydrocarbon Natural products 0.000 claims abstract 4
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract 4
- 230000000737 periodic effect Effects 0.000 claims abstract 4
- 239000007858 starting material Substances 0.000 claims abstract 4
- 229910000510 noble metal Inorganic materials 0.000 claims abstract 3
- 239000002253 acid Substances 0.000 claims abstract 2
- 150000007513 acids Chemical class 0.000 claims abstract 2
- CSDREXVUYHZDNP-UHFFFAOYSA-N alumanylidynesilicon Chemical compound [Al].[Si] CSDREXVUYHZDNP-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000002245 particle Substances 0.000 claims abstract 2
- UVGLBOPDEUYYCS-UHFFFAOYSA-N silicon zirconium Chemical compound [Si].[Zr] UVGLBOPDEUYYCS-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000012188 paraffin wax Substances 0.000 claims 2
- DJPURDPSZFLWGC-UHFFFAOYSA-N alumanylidyneborane Chemical compound [Al]#B DJPURDPSZFLWGC-UHFFFAOYSA-N 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- -1 aluminum-boron oxides Chemical class 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
- B01J29/12—Noble metals
- B01J29/126—Y-type faujasite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
- C10G47/12—Inorganic carriers
- C10G47/16—Crystalline alumino-silicate carriers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
- C10G47/12—Inorganic carriers
- C10G47/16—Crystalline alumino-silicate carriers
- C10G47/18—Crystalline alumino-silicate carriers the catalyst containing platinum group metals or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/12—Silica and alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/20—After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1022—Fischer-Tropsch products
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Abstract
1. Катализатор для гидрокрекинга парафиновых углеводородов, содержащий USY цеолит, производный NaY, который применяют как исходное соединение, и имеющий пик интенсивности 30 или менее, проявляющийся на 111 поверхности при изучении дифракцией рентгеновских лучей, и благородный металл группы VIII Периодической системы. ! 2. Катализатор по п.1, где средний размер частиц USY цеолита составляет 1,0 мкм или менее. ! 3. Катализатор по любому из пп.1 или 2, дополнительно содержащий аморфную твердую кислоту. ! 4. Катализатор по п.3, где аморфная твердая кислота представляет собой один тип или более типов кислот, выбранных из группы, состоящей из оксидов кремния-алюминия, кремния-циркония и алюминия-бора. ! 5. Катализатор по любому из пп.1 или 2, где содержание USY цеолита составляет от 0,1 до 15 мас.%. ! 6. Катализатор по п.3, где содержание USY цеолита составляет от 0,1 до 15 мас.%. ! 7. Катализатор по п.4, где содержание USY цеолита составляет от 0,1 до 15 мас.%. ! 8. Катализатор по п.3, где массовое соотношение аморфной твердой кислоты к USY цеолиту составляет 1 или более и 60 или менее. ! 9. Способ получения основного компонента топлива, включающий гидрокрекинг парафиновых углеводородов с применением катализатора, содержащего USY цеолит, производный из NaY, который применяют в качестве исходного соединения, и пик интенсивности 30 или менее, проявляющийся на 111 поверхности при изучении диффракцией рентгеновских лучей, и благородный металл группы VIII Периодической таблицы.
Claims (9)
1. Катализатор для гидрокрекинга парафиновых углеводородов, содержащий USY цеолит, производный NaY, который применяют как исходное соединение, и имеющий пик интенсивности 30 или менее, проявляющийся на 111 поверхности при изучении дифракцией рентгеновских лучей, и благородный металл группы VIII Периодической системы.
2. Катализатор по п.1, где средний размер частиц USY цеолита составляет 1,0 мкм или менее.
3. Катализатор по любому из пп.1 или 2, дополнительно содержащий аморфную твердую кислоту.
4. Катализатор по п.3, где аморфная твердая кислота представляет собой один тип или более типов кислот, выбранных из группы, состоящей из оксидов кремния-алюминия, кремния-циркония и алюминия-бора.
5. Катализатор по любому из пп.1 или 2, где содержание USY цеолита составляет от 0,1 до 15 мас.%.
6. Катализатор по п.3, где содержание USY цеолита составляет от 0,1 до 15 мас.%.
7. Катализатор по п.4, где содержание USY цеолита составляет от 0,1 до 15 мас.%.
8. Катализатор по п.3, где массовое соотношение аморфной твердой кислоты к USY цеолиту составляет 1 или более и 60 или менее.
9. Способ получения основного компонента топлива, включающий гидрокрекинг парафиновых углеводородов с применением катализатора, содержащего USY цеолит, производный из NaY, который применяют в качестве исходного соединения, и пик интенсивности 30 или менее, проявляющийся на 111 поверхности при изучении диффракцией рентгеновских лучей, и благородный металл группы VIII Периодической таблицы.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006-094963 | 2006-03-30 | ||
| JP2006094963 | 2006-03-30 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2008142934A true RU2008142934A (ru) | 2010-05-10 |
| RU2417839C2 RU2417839C2 (ru) | 2011-05-10 |
Family
ID=38563469
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2008142934/04A RU2417839C2 (ru) | 2006-03-30 | 2007-03-22 | Катализатор гидрокрекинга и способ получения основного компонента топлива |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US8288303B2 (ru) |
| EP (1) | EP2000203A4 (ru) |
| CN (1) | CN101410182A (ru) |
| AU (1) | AU2007233022B2 (ru) |
| MY (1) | MY149329A (ru) |
| RU (1) | RU2417839C2 (ru) |
| WO (1) | WO2007114200A1 (ru) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007114012A1 (ja) * | 2006-03-31 | 2007-10-11 | Nippon Oil Corporation | 水素化分解触媒および燃料基材の製造方法 |
| JP5268177B2 (ja) | 2007-05-01 | 2013-08-21 | Ｊｘ日鉱日石エネルギー株式会社 | 液体燃料の製造方法 |
| US11440815B2 (en) | 2013-02-22 | 2022-09-13 | Anschutz Exploration Corporation | Method and system for removing hydrogen sulfide from sour oil and sour water |
| US9708196B2 (en) | 2013-02-22 | 2017-07-18 | Anschutz Exploration Corporation | Method and system for removing hydrogen sulfide from sour oil and sour water |
| US9364773B2 (en) | 2013-02-22 | 2016-06-14 | Anschutz Exploration Corporation | Method and system for removing hydrogen sulfide from sour oil and sour water |
| CA2843041C (en) | 2013-02-22 | 2017-06-13 | Anschutz Exploration Corporation | Method and system for removing hydrogen sulfide from sour oil and sour water |
Family Cites Families (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2995423A (en) * | 1957-09-20 | 1961-08-08 | Union Carbide Corp | Crystalline zeolite m |
| US3130007A (en) | 1961-05-12 | 1964-04-21 | Union Carbide Corp | Crystalline zeolite y |
| US3622501A (en) | 1969-04-10 | 1971-11-23 | Standard Oil Co | Catalyst and hydrocarbon processes employing same |
| JPS5250355B2 (ru) | 1973-06-01 | 1977-12-23 | ||
| US3862898A (en) | 1973-07-30 | 1975-01-28 | Pullman Inc | Process for the production of olefinically unsaturated hydrocarbons |
| US3993557A (en) | 1974-03-27 | 1976-11-23 | Pine Lloyd A | Hydrocarbon conversion process employing boria-alumina compositions |
| US4182693A (en) | 1975-10-28 | 1980-01-08 | Exxon Research & Engineering Co. | Hydrocarbon treating catalyst |
| US4600498A (en) | 1979-10-15 | 1986-07-15 | Union Oil Company Of California | Mild hydrocracking with a zeolite catalyst containing silica-alumina |
| JPS57207546A (en) | 1981-06-13 | 1982-12-20 | Shokubai Kasei Kogyo Kk | Hydrocracking catalyst composition and its production |
| JPS59203639A (ja) | 1983-05-06 | 1984-11-17 | Chiyoda Chem Eng & Constr Co Ltd | 炭化水素の水素化分解用触媒 |
| JPS59216635A (ja) | 1983-05-25 | 1984-12-06 | Res Assoc Residual Oil Process<Rarop> | 炭化水素転化用結晶性触媒組成物およびその製法 |
| US4584089A (en) | 1983-10-24 | 1986-04-22 | Standard Oil Company (Indiana) | Borosilicate-containing catalyst and reforming processes employing same |
| JPH0631333B2 (ja) | 1984-11-22 | 1994-04-27 | 重質油対策技術研究組合 | 炭化水素類の水素化分解方法 |
| US4789654A (en) | 1985-03-29 | 1988-12-06 | Catalysts & Chemicals Industries Co., Ltd. | Hydrotreating catalysts |
| JPH02214544A (ja) | 1989-02-16 | 1990-08-27 | Nippon Oil Co Ltd | 重質石油類の水素化分解触媒 |
| US5073530A (en) * | 1989-05-10 | 1991-12-17 | Chevron Research And Technology Company | Hydrocracking catalyst and process |
| US5120425A (en) | 1989-07-07 | 1992-06-09 | Chevron Research Company | Use of zeolite SSZ-33 in hydrocarbon conversion processes |
| US5401704A (en) | 1990-10-23 | 1995-03-28 | Mobil Oil Corporation | Hydrocracking catalyst and process using small crystal size zeolite Y |
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| US5242677A (en) * | 1992-06-11 | 1993-09-07 | Pq Corporation | Stable zeolite of low unit cell constant and method of making same |
| US5318692A (en) | 1992-11-30 | 1994-06-07 | Exxon Research And Engineering Company | FCC for producing low emission fuels from high hydrogen and low nitrogen and aromatic feeds |
| JP2547968B2 (ja) | 1994-05-30 | 1996-10-30 | ユーオーピー | 硫黄に感受性のある成分を含む耐硫黄改質触媒系および同触媒系を用いた炭化水素の改質プロセス |
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| WO2004028688A1 (ja) | 2002-09-24 | 2004-04-08 | Nippon Oil Corporation | 水素化分解触媒および液状炭化水素の製造方法 |
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| JP4267936B2 (ja) | 2003-02-24 | 2009-05-27 | 新日本石油株式会社 | 水素化分解触媒および液状炭化水素の製造方法 |
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| JP4313237B2 (ja) * | 2004-03-29 | 2009-08-12 | 新日本石油株式会社 | 水素化分解触媒および液状炭化水素の製造方法 |
-
2007
- 2007-03-22 EP EP07740182A patent/EP2000203A4/en not_active Withdrawn
- 2007-03-22 WO PCT/JP2007/056744 patent/WO2007114200A1/ja active Application Filing
- 2007-03-22 CN CNA2007800114797A patent/CN101410182A/zh active Pending
- 2007-03-22 RU RU2008142934/04A patent/RU2417839C2/ru not_active IP Right Cessation
- 2007-03-22 US US12/294,922 patent/US8288303B2/en not_active Expired - Fee Related
- 2007-03-22 MY MYPI20083918A patent/MY149329A/en unknown
- 2007-03-22 AU AU2007233022A patent/AU2007233022B2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| US20100170828A1 (en) | 2010-07-08 |
| EP2000203A4 (en) | 2012-07-25 |
| US8288303B2 (en) | 2012-10-16 |
| MY149329A (en) | 2013-08-30 |
| CN101410182A (zh) | 2009-04-15 |
| RU2417839C2 (ru) | 2011-05-10 |
| AU2007233022A1 (en) | 2007-10-11 |
| AU2007233022B2 (en) | 2011-11-17 |
| EP2000203A1 (en) | 2008-12-10 |
| WO2007114200A1 (ja) | 2007-10-11 |
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