RU2006115613A - Каталитическая тримеризация олефиновых мономеров - Google Patents
Каталитическая тримеризация олефиновых мономеров Download PDFInfo
- Publication number
- RU2006115613A RU2006115613A RU2006115613/04A RU2006115613A RU2006115613A RU 2006115613 A RU2006115613 A RU 2006115613A RU 2006115613/04 A RU2006115613/04 A RU 2006115613/04A RU 2006115613 A RU2006115613 A RU 2006115613A RU 2006115613 A RU2006115613 A RU 2006115613A
- Authority
- RU
- Russia
- Prior art keywords
- sup
- composition according
- groups
- catalytic composition
- trimerization
- Prior art date
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/20—Olefin oligomerisation or telomerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/62—Chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/64—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/66—Tungsten
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24
- C07C2531/34—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24 of chromium, molybdenum or tungsten
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Claims (10)
1. Каталитическая композиция для тримеризации олефиновых мономеров, содержащая
а) источник хрома, молибдена или вольфрама;
b) лиганд общей формулы (I)
в которой Х означает бивалентную органическую мостиковую группу;
R1 и R3 независимо выбирают из углеводородных, замещенных углеводородных, гетероуглеводородных и замещенных гетероуглеводородных групп, с условием, что, когда R1 и R3 представляют собой циклоароматические группы, они не содержат полярных заместителей ни в одном из орто-положений;
R2 и R4 независимо выбирают из необязательно замещенных циклоароматических групп, причем каждый из R2 и R4 имеет полярный заместитель, по меньшей мере, в одном орто-положении; и
с) сокатализатор.
2. Каталитическая композиция по п.1, в которой бивалентная органическая мостиковая группа Х означает алкиленовую группу, которая содержит от 2 до 6 атомов углерода в мостике.
3. Каталитическая композиция по п.1 или 2, в которой бивалентная органическая мостиковая группа Х означает -СН2-СН2-.
4. Каталитическая композиция по п.1 или 2, в которой R1 и R3 независимо выбирают из необязательно замещенных фенильных групп, которые не содержат полярных заместителей ни в одном из орто-положений.
5. Каталитическая композиция по п.1 или 2, в которой R2 и R4 независимо выбирают из необязательно замещенных фенильных групп, при этом полярные заместители представляют собой необязательно разветвленные С1-С20алкоксигруппы.
6. Каталитическая композиция по п.1 или 2, в которой R2 и R4 означают 2-метоксифенильные группы.
7. Каталитическая композиция по п.1 или 2, в которой сокатализатор выбирают из метилалюмоксана или модифицированного метилалюмоксана.
8. Каталитическая композиция по п.1 или 2, в которой компонент а) представляет собой источник хрома.
9. Каталитическая композиция по п.8, в которой источник хрома представляет собой CrCl3.
10. Способ тримеризации олефиновых мономеров, включающий взаимодействие, по меньшей мере, одного олефинового мономера в условиях реакции тримеризации с каталитической композицией по любому из пп.1-9.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP03256426 | 2003-10-10 | ||
| EP03256426.2 | 2003-10-10 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2006115613A true RU2006115613A (ru) | 2007-11-20 |
| RU2352389C2 RU2352389C2 (ru) | 2009-04-20 |
Family
ID=34486412
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2006115613/04A RU2352389C2 (ru) | 2003-10-10 | 2004-10-07 | Каталитическая тримеризация олефиновых мономеров |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7273959B2 (ru) |
| EP (1) | EP1675679B1 (ru) |
| JP (1) | JP5372327B2 (ru) |
| CN (1) | CN1867401A (ru) |
| AT (1) | ATE516079T1 (ru) |
| CA (1) | CA2541697C (ru) |
| RU (1) | RU2352389C2 (ru) |
| WO (1) | WO2005039758A1 (ru) |
| ZA (1) | ZA200602478B (ru) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2467797C2 (ru) * | 2007-11-28 | 2012-11-27 | Линде Аг | Каталитическая композиция и способ олигомеризации этилена |
Families Citing this family (47)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7273959B2 (en) | 2003-10-10 | 2007-09-25 | Shell Oil Company | Catalytic trimerization of olefinic monomers |
| US7214639B2 (en) * | 2003-12-10 | 2007-05-08 | Council Of Scientific And Industrial Research | Immobilized metal complex catalysts, process for preparation thereof and use thereof |
| DE102005022593A1 (de) * | 2004-05-18 | 2006-02-16 | Sasol Wax (South Africa) (Pty.) Ltd. | Polymerisation von Olefinverbindungen |
| US7259123B2 (en) * | 2005-04-08 | 2007-08-21 | Shell Oil Company | Catalytic trimerization and tetramerization of olefinic monomers |
| JP2007039641A (ja) * | 2005-06-28 | 2007-02-15 | Sumitomo Chemical Co Ltd | オレフィンオリゴマーの製造方法 |
| BRPI0613432A2 (pt) † | 2005-07-12 | 2011-01-11 | Sasol Tech Pty Ltd | oligomerização de compostos olefìnicos na presença de um ativador contendo metal diluìdo |
| JP2007056002A (ja) * | 2005-07-27 | 2007-03-08 | Sumitomo Chemical Co Ltd | オレフィンオリゴマーの製造方法 |
| JP5443762B2 (ja) * | 2005-11-21 | 2014-03-19 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | オレフィンモノマーのオリゴマー化のための接触プロセス |
| CN101351269B (zh) * | 2005-11-21 | 2013-04-03 | 国际壳牌研究有限公司 | 烯烃单体的催化低聚 |
| US20070187787A1 (en) * | 2006-02-16 | 2007-08-16 | Ackerson Kristin M | Pixel sensor structure including light pipe and method for fabrication thereof |
| US8404915B2 (en) * | 2006-08-30 | 2013-03-26 | Exxonmobil Chemical Patents Inc. | Phosphine ligand-metal compositions, complexes, and catalysts for ethylene trimerizations |
| JP5456482B2 (ja) | 2006-12-22 | 2014-03-26 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | オレフィン系モノマーの接触的オリゴマー化のための配位子及びそれらの触媒系 |
| JP5421118B2 (ja) * | 2006-12-22 | 2014-02-19 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | オレフィンモノマーのオリゴマー化用配位子及び触媒 |
| US8138348B2 (en) * | 2007-01-08 | 2012-03-20 | Exxonmobil Chemical Patents Inc. | Methods for oligomerizing olefins with chromium pyridine mono-oxazoline catalysts |
| US8067609B2 (en) * | 2007-01-08 | 2011-11-29 | Exxonmobil Chemical Patents Inc. | Methods for oligomerizing olefins with chromium pyridine thioether catalysts |
| EP2114974A1 (en) * | 2007-01-08 | 2009-11-11 | ExxonMobil Chemical Patents Inc. | Methods for oligomerizing olefins with chromium pyridine ether catalysts |
| EP2121183A1 (en) * | 2007-01-08 | 2009-11-25 | ExxonMobil Chemical Patents Inc. | Chromium complexes of pyridine bis (oxazoline)-ligands for ethylene dimerization |
| KR101074223B1 (ko) | 2007-01-18 | 2011-10-14 | 에스케이종합화학 주식회사 | 에틸렌 삼량체화 촉매계 및 이를 이용한 1-헥센의 제조방법 |
| KR101074202B1 (ko) * | 2007-01-18 | 2011-10-14 | 에스케이종합화학 주식회사 | 에틸렌 사량체화 촉매계 및 이를 이용한 1-옥텐의 제조방법 |
| KR101095796B1 (ko) * | 2007-02-08 | 2011-12-21 | 에스케이종합화학 주식회사 | 담지용 에틸렌 사량체화 촉매계 및 이를 이용한 에틸렌 사량체화 방법 |
| BRPI0813779B1 (pt) | 2007-07-11 | 2018-06-26 | Saudi Basic Industries Corporation | Composição catalisadora e processo para a di-, tri- e/ou tetramerização de etileno |
| DE102007034621A1 (de) | 2007-07-25 | 2009-01-29 | Lanxess Deutschland Gmbh | Polyolreinigung |
| KR101057576B1 (ko) * | 2007-08-16 | 2011-08-17 | 에스케이종합화학 주식회사 | 선택적 에틸렌 올리머고화 촉매계 |
| ES2367133T3 (es) | 2008-04-04 | 2011-10-28 | Saudi Basic Industries Corporation | Catalizador para la oligomerización de etileno, procedimiento para la preparación del mismo y procedimiento de oligomerización que usa el mismo. |
| US8084659B2 (en) * | 2008-10-22 | 2011-12-27 | Lummus Technology, Inc. | Hexene upgrading |
| ES2371218T3 (es) | 2009-04-09 | 2011-12-28 | Saudi Basic Industries Corporation | Composición de catalizador y procedimiento para la oligomerización de etileno. |
| KR101846031B1 (ko) * | 2012-03-16 | 2018-04-05 | 에스케이이노베이션 주식회사 | 에틸렌으로부터 1-헥센 및/또는 1-옥텐을 제조하기 위한 촉매계 |
| RU2525118C1 (ru) * | 2013-03-28 | 2014-08-10 | Открытое акционерное общество "Нефтяная компания "Роснефть" | Каталитическая система процесса тримеризации этилена в альфа-олефины |
| JP6328268B2 (ja) * | 2014-01-06 | 2018-05-23 | サウディ ベーシック インダストリーズ コーポレイション | エチレン反応における触媒活性化のための改変された予備形成方法 |
| RU2549833C1 (ru) * | 2014-02-18 | 2015-04-27 | Открытое акционерное общество "Нефтяная компания "Роснефть" | Каталитический комплекс селективной тримеризации этилена в 1-гексен |
| RU2549897C1 (ru) * | 2014-02-18 | 2015-05-10 | Открытое акционерное общество "Нефтяная компания "Роснефть" | Каталитическая система тримеризации этилена в 1-гексен |
| RU2556636C1 (ru) * | 2014-06-26 | 2015-07-10 | Общество с ограниченной ответственностью "Объединенный центр исследований и разработок" (ООО "РН-ЦИР") | Каталитическая система тримеризации этилена в альфа-олефины с использованием комплекса хрома |
| CN105566026A (zh) * | 2014-10-08 | 2016-05-11 | 中国石油化工股份有限公司 | 一种乙烯三聚的方法 |
| US10329212B2 (en) | 2016-05-27 | 2019-06-25 | Chevron Phillips Chemical Company Lp | Reduced polymer formation for selective ethylene oligomerizations |
| US10414699B2 (en) | 2016-05-27 | 2019-09-17 | Chevron Phillips Chemical Company Lp | Process improvements in selective ethylene oligomerizations |
| US10414698B2 (en) | 2016-05-27 | 2019-09-17 | Chevron Phillips Chemical Company Lp | Reduced polymer formation for selective ethylene oligomerizations |
| KR102428770B1 (ko) * | 2016-07-14 | 2022-08-04 | 에스케이이노베이션 주식회사 | 에틸렌의 올리고머화 방법 |
| KR102018279B1 (ko) * | 2017-03-23 | 2019-09-04 | 에스케이이노베이션 주식회사 | 파울링 방지제 및 이를 이용한 올레핀의 올리고머화 방법 |
| US10232339B2 (en) | 2017-06-06 | 2019-03-19 | Chevron Phillips Chemical Company Lp | Fouling protection for an oligomerization reactor inlet |
| US10294171B2 (en) | 2017-09-22 | 2019-05-21 | Chevron Phillips Chemical Company Lp | Carbonyl-containing perfluorohydrocarbyl-N2-phosphinyl amidine compounds, chromium salt complexes and their use to oligomerize ethylene |
| US10183960B1 (en) | 2017-09-22 | 2019-01-22 | Chevron Phillips Chemical Company Lp | Perfluorohydrocarbyl-N2-phosphinyl amidine compounds, chromium salt complexes, catalyst systems, and their use to oligomerize ethylene |
| US10493442B2 (en) | 2017-09-22 | 2019-12-03 | Chevron Phillips Chemical Company Lp | Fluorinated N2-phosphinyl amidine compounds, chromium salt complexes, catalyst systems, and their use to oligomerize ethylene |
| US10464862B2 (en) | 2017-09-28 | 2019-11-05 | Chevron Phillips Chemical Company Lp | Oligomerization reactions using aluminoxanes |
| US11492305B1 (en) | 2021-11-08 | 2022-11-08 | Chevron Phillips Chemical Company, Lp | Chromium phosphinyl hydroisoindole amidine complexes for tetramerization of ethylene |
| US11583843B1 (en) | 2021-11-08 | 2023-02-21 | Chevron Phillips Chemical Company, Lp | Chromium phosphinyl isoindole amidine complexes for tetramerization of ethylene |
| US11505513B1 (en) | 2021-11-08 | 2022-11-22 | Chevron Phillips Chemical Company, Lp | Chromium bicyclic phosphinyl amidine complexes for tetramerization of ethylene |
| US12037301B1 (en) | 2022-12-20 | 2024-07-16 | King Fahd University Of Petroleum And Minerals | Chromium-catalyzed ethylene oligomerization with bulky functionalized N-aryl bisphosphineamine ligands |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5195563A (en) * | 1988-11-15 | 1993-03-23 | Oakleigh Limited C/O Havelet Trust Company International Limited | Flexible hose and fittings |
| US5376612A (en) * | 1989-08-10 | 1994-12-27 | Phillips Petroleum Company | Chromium catalysts and process for making chromium catalysts |
| US5811618A (en) * | 1991-10-16 | 1998-09-22 | Amoco Corporation | Ethylene trimerization |
| GB0016895D0 (en) * | 2000-07-11 | 2000-08-30 | Bp Chem Int Ltd | Olefin oligomerisation |
| EP1581343A1 (en) | 2002-12-20 | 2005-10-05 | Sasol Technology (PTY) Limited | Tandem tetramerisation-polymerisation of olefins |
| PL377406A1 (pl) | 2002-12-20 | 2006-02-06 | Sasol Technology (Pty) Limited | Tetrameryzacja olefin |
| US7273959B2 (en) | 2003-10-10 | 2007-09-25 | Shell Oil Company | Catalytic trimerization of olefinic monomers |
| CN101052605B (zh) | 2004-06-18 | 2011-12-21 | Sasol技术股份有限公司 | 烯属化合物在脂族介质中的低聚 |
| US7259123B2 (en) * | 2005-04-08 | 2007-08-21 | Shell Oil Company | Catalytic trimerization and tetramerization of olefinic monomers |
-
2004
- 2004-10-06 US US10/959,561 patent/US7273959B2/en not_active Expired - Fee Related
- 2004-10-07 AT AT04791172T patent/ATE516079T1/de not_active IP Right Cessation
- 2004-10-07 WO PCT/EP2004/052469 patent/WO2005039758A1/en active Search and Examination
- 2004-10-07 CA CA2541697A patent/CA2541697C/en not_active Expired - Fee Related
- 2004-10-07 CN CNA2004800296645A patent/CN1867401A/zh active Pending
- 2004-10-07 RU RU2006115613/04A patent/RU2352389C2/ru active
- 2004-10-07 EP EP04791172A patent/EP1675679B1/en not_active Expired - Lifetime
- 2004-10-07 JP JP2006530281A patent/JP5372327B2/ja not_active Expired - Fee Related
-
2006
- 2006-03-27 ZA ZA200602478A patent/ZA200602478B/en unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2467797C2 (ru) * | 2007-11-28 | 2012-11-27 | Линде Аг | Каталитическая композиция и способ олигомеризации этилена |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2541697A1 (en) | 2005-05-06 |
| ZA200602478B (en) | 2007-06-27 |
| JP5372327B2 (ja) | 2013-12-18 |
| RU2352389C2 (ru) | 2009-04-20 |
| WO2005039758A1 (en) | 2005-05-06 |
| US7273959B2 (en) | 2007-09-25 |
| EP1675679B1 (en) | 2011-07-13 |
| EP1675679A1 (en) | 2006-07-05 |
| CN1867401A (zh) | 2006-11-22 |
| ATE516079T1 (de) | 2011-07-15 |
| JP2007508128A (ja) | 2007-04-05 |
| US20050113622A1 (en) | 2005-05-26 |
| CA2541697C (en) | 2013-12-10 |
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