ATE516079T1 - Katalytische trimerisierung von olefinischen monomeren - Google Patents
Katalytische trimerisierung von olefinischen monomerenInfo
- Publication number
- ATE516079T1 ATE516079T1 AT04791172T AT04791172T ATE516079T1 AT E516079 T1 ATE516079 T1 AT E516079T1 AT 04791172 T AT04791172 T AT 04791172T AT 04791172 T AT04791172 T AT 04791172T AT E516079 T1 ATE516079 T1 AT E516079T1
- Authority
- AT
- Austria
- Prior art keywords
- sup
- line
- trimerization
- formulae
- catalyst composition
- Prior art date
Links
- 239000000178 monomer Substances 0.000 title abstract 4
- 238000005829 trimerization reaction Methods 0.000 title abstract 4
- 230000003197 catalytic effect Effects 0.000 title 1
- 239000003054 catalyst Substances 0.000 abstract 3
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 abstract 2
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 125000001424 substituent group Chemical group 0.000 abstract 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 239000011651 chromium Substances 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 229910052750 molybdenum Inorganic materials 0.000 abstract 1
- 239000011733 molybdenum Substances 0.000 abstract 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract 1
- 229910052721 tungsten Inorganic materials 0.000 abstract 1
- 239000010937 tungsten Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/20—Olefin oligomerisation or telomerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/62—Chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/64—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/66—Tungsten
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24
- C07C2531/34—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24 of chromium, molybdenum or tungsten
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP03256426 | 2003-10-10 | ||
| PCT/EP2004/052469 WO2005039758A1 (en) | 2003-10-10 | 2004-10-07 | Catalytic trimerization of olefinic monomers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE516079T1 true ATE516079T1 (de) | 2011-07-15 |
Family
ID=34486412
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT04791172T ATE516079T1 (de) | 2003-10-10 | 2004-10-07 | Katalytische trimerisierung von olefinischen monomeren |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7273959B2 (de) |
| EP (1) | EP1675679B1 (de) |
| JP (1) | JP5372327B2 (de) |
| CN (1) | CN1867401A (de) |
| AT (1) | ATE516079T1 (de) |
| CA (1) | CA2541697C (de) |
| RU (1) | RU2352389C2 (de) |
| WO (1) | WO2005039758A1 (de) |
| ZA (1) | ZA200602478B (de) |
Families Citing this family (49)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7273959B2 (en) | 2003-10-10 | 2007-09-25 | Shell Oil Company | Catalytic trimerization of olefinic monomers |
| US7214639B2 (en) * | 2003-12-10 | 2007-05-08 | Council Of Scientific And Industrial Research | Immobilized metal complex catalysts, process for preparation thereof and use thereof |
| US7285607B2 (en) * | 2004-05-18 | 2007-10-23 | Sasol, Chemical Industries, Limited | Polymerisation of olefinic compounds |
| US7259123B2 (en) * | 2005-04-08 | 2007-08-21 | Shell Oil Company | Catalytic trimerization and tetramerization of olefinic monomers |
| JP2007039641A (ja) * | 2005-06-28 | 2007-02-15 | Sumitomo Chemical Co Ltd | オレフィンオリゴマーの製造方法 |
| BRPI0613432A2 (pt) † | 2005-07-12 | 2011-01-11 | Sasol Tech Pty Ltd | oligomerização de compostos olefìnicos na presença de um ativador contendo metal diluìdo |
| JP2007056002A (ja) * | 2005-07-27 | 2007-03-08 | Sumitomo Chemical Co Ltd | オレフィンオリゴマーの製造方法 |
| JP5443762B2 (ja) * | 2005-11-21 | 2014-03-19 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | オレフィンモノマーのオリゴマー化のための接触プロセス |
| RU2008125139A (ru) * | 2005-11-21 | 2009-12-27 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) | Каталитическая олигомеризация олефиновых мономеров |
| US20070187787A1 (en) * | 2006-02-16 | 2007-08-16 | Ackerson Kristin M | Pixel sensor structure including light pipe and method for fabrication thereof |
| US8404915B2 (en) * | 2006-08-30 | 2013-03-26 | Exxonmobil Chemical Patents Inc. | Phosphine ligand-metal compositions, complexes, and catalysts for ethylene trimerizations |
| WO2008077911A1 (en) * | 2006-12-22 | 2008-07-03 | Shell Internationale Research Maatschappij B.V. | Ligands and catalyst systems for the oligomerization of olefinic monomers |
| CN101600723A (zh) | 2006-12-22 | 2009-12-09 | 国际壳牌研究有限公司 | 用于烯烃单体催化低聚的配体及其催化剂体系 |
| US8067609B2 (en) * | 2007-01-08 | 2011-11-29 | Exxonmobil Chemical Patents Inc. | Methods for oligomerizing olefins with chromium pyridine thioether catalysts |
| EP2104679A1 (de) * | 2007-01-08 | 2009-09-30 | ExxonMobil Chemical Patents Inc. | Verfahren zur oligomerisierung von olefinen mit chrom-pyridinmonooxazolin-katalysatoren |
| US20080182951A1 (en) * | 2007-01-08 | 2008-07-31 | Ackerman Lily J | Chromium Pyridine Bis(Oxazoline) And Related Catalysts For Ethylene Dimerization |
| EP2114974A1 (de) * | 2007-01-08 | 2009-11-11 | ExxonMobil Chemical Patents Inc. | Verfahren zur oligomerisierung von olefinen mit chrom-pyridinether-katalysatoren |
| KR101074202B1 (ko) * | 2007-01-18 | 2011-10-14 | 에스케이종합화학 주식회사 | 에틸렌 사량체화 촉매계 및 이를 이용한 1-옥텐의 제조방법 |
| KR101074223B1 (ko) | 2007-01-18 | 2011-10-14 | 에스케이종합화학 주식회사 | 에틸렌 삼량체화 촉매계 및 이를 이용한 1-헥센의 제조방법 |
| KR101095796B1 (ko) * | 2007-02-08 | 2011-12-21 | 에스케이종합화학 주식회사 | 담지용 에틸렌 사량체화 촉매계 및 이를 이용한 에틸렌 사량체화 방법 |
| RU2456078C2 (ru) | 2007-07-11 | 2012-07-20 | Линде Аг | Каталитическая композиция и способ ди-, три- и/или тетрамеризации этилена |
| DE102007034621A1 (de) | 2007-07-25 | 2009-01-29 | Lanxess Deutschland Gmbh | Polyolreinigung |
| KR101057576B1 (ko) * | 2007-08-16 | 2011-08-17 | 에스케이종합화학 주식회사 | 선택적 에틸렌 올리머고화 촉매계 |
| JP5462179B2 (ja) * | 2007-11-28 | 2014-04-02 | リンデ アーゲー | エチレンのオリゴマー化のための触媒組成物およびプロセス |
| ES2367133T3 (es) | 2008-04-04 | 2011-10-28 | Saudi Basic Industries Corporation | Catalizador para la oligomerización de etileno, procedimiento para la preparación del mismo y procedimiento de oligomerización que usa el mismo. |
| US8084659B2 (en) * | 2008-10-22 | 2011-12-27 | Lummus Technology, Inc. | Hexene upgrading |
| ATE516878T1 (de) | 2009-04-09 | 2011-08-15 | Saudi Basic Ind Corp | Katalysatorzusammensetzung und verfahren zur oligomerisierung von ethylen |
| RU2412002C1 (ru) * | 2009-07-13 | 2011-02-20 | ОТКРЫТОЕ АКЦИОНЕРНОЕ ОБЩЕСТВО "СИБУР Холдинг" | Способ получения каталитической системы для олигомеризации олефинов и способ олигомеризации олефинов |
| KR101846031B1 (ko) * | 2012-03-16 | 2018-04-05 | 에스케이이노베이션 주식회사 | 에틸렌으로부터 1-헥센 및/또는 1-옥텐을 제조하기 위한 촉매계 |
| RU2525118C1 (ru) * | 2013-03-28 | 2014-08-10 | Открытое акционерное общество "Нефтяная компания "Роснефть" | Каталитическая система процесса тримеризации этилена в альфа-олефины |
| RU2647238C2 (ru) * | 2014-01-06 | 2018-03-14 | Сауди Бейсик Индастриз Корпорейшн | Модифицированный способ предварительного образования для активации катализатора при реакциях этилена |
| RU2549833C1 (ru) * | 2014-02-18 | 2015-04-27 | Открытое акционерное общество "Нефтяная компания "Роснефть" | Каталитический комплекс селективной тримеризации этилена в 1-гексен |
| RU2549897C1 (ru) * | 2014-02-18 | 2015-05-10 | Открытое акционерное общество "Нефтяная компания "Роснефть" | Каталитическая система тримеризации этилена в 1-гексен |
| RU2556636C1 (ru) * | 2014-06-26 | 2015-07-10 | Общество с ограниченной ответственностью "Объединенный центр исследований и разработок" (ООО "РН-ЦИР") | Каталитическая система тримеризации этилена в альфа-олефины с использованием комплекса хрома |
| CN105566026A (zh) * | 2014-10-08 | 2016-05-11 | 中国石油化工股份有限公司 | 一种乙烯三聚的方法 |
| US10329212B2 (en) | 2016-05-27 | 2019-06-25 | Chevron Phillips Chemical Company Lp | Reduced polymer formation for selective ethylene oligomerizations |
| US10414699B2 (en) | 2016-05-27 | 2019-09-17 | Chevron Phillips Chemical Company Lp | Process improvements in selective ethylene oligomerizations |
| US10414698B2 (en) | 2016-05-27 | 2019-09-17 | Chevron Phillips Chemical Company Lp | Reduced polymer formation for selective ethylene oligomerizations |
| KR102428767B1 (ko) * | 2016-07-14 | 2022-08-04 | 에스케이이노베이션 주식회사 | 에틸렌의 올리고머화 방법 |
| KR102018279B1 (ko) * | 2017-03-23 | 2019-09-04 | 에스케이이노베이션 주식회사 | 파울링 방지제 및 이를 이용한 올레핀의 올리고머화 방법 |
| US10232339B2 (en) | 2017-06-06 | 2019-03-19 | Chevron Phillips Chemical Company Lp | Fouling protection for an oligomerization reactor inlet |
| US10183960B1 (en) | 2017-09-22 | 2019-01-22 | Chevron Phillips Chemical Company Lp | Perfluorohydrocarbyl-N2-phosphinyl amidine compounds, chromium salt complexes, catalyst systems, and their use to oligomerize ethylene |
| US10493442B2 (en) | 2017-09-22 | 2019-12-03 | Chevron Phillips Chemical Company Lp | Fluorinated N2-phosphinyl amidine compounds, chromium salt complexes, catalyst systems, and their use to oligomerize ethylene |
| US10294171B2 (en) | 2017-09-22 | 2019-05-21 | Chevron Phillips Chemical Company Lp | Carbonyl-containing perfluorohydrocarbyl-N2-phosphinyl amidine compounds, chromium salt complexes and their use to oligomerize ethylene |
| US10464862B2 (en) | 2017-09-28 | 2019-11-05 | Chevron Phillips Chemical Company Lp | Oligomerization reactions using aluminoxanes |
| US11505513B1 (en) | 2021-11-08 | 2022-11-22 | Chevron Phillips Chemical Company, Lp | Chromium bicyclic phosphinyl amidine complexes for tetramerization of ethylene |
| US11583843B1 (en) | 2021-11-08 | 2023-02-21 | Chevron Phillips Chemical Company, Lp | Chromium phosphinyl isoindole amidine complexes for tetramerization of ethylene |
| US11492305B1 (en) | 2021-11-08 | 2022-11-08 | Chevron Phillips Chemical Company, Lp | Chromium phosphinyl hydroisoindole amidine complexes for tetramerization of ethylene |
| US12037301B1 (en) | 2022-12-20 | 2024-07-16 | King Fahd University Of Petroleum And Minerals | Chromium-catalyzed ethylene oligomerization with bulky functionalized N-aryl bisphosphineamine ligands |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5195563A (en) * | 1988-11-15 | 1993-03-23 | Oakleigh Limited C/O Havelet Trust Company International Limited | Flexible hose and fittings |
| US5376612A (en) * | 1989-08-10 | 1994-12-27 | Phillips Petroleum Company | Chromium catalysts and process for making chromium catalysts |
| US5811618A (en) * | 1991-10-16 | 1998-09-22 | Amoco Corporation | Ethylene trimerization |
| US5859303A (en) * | 1995-12-18 | 1999-01-12 | Phillips Petroleum Company | Olefin production |
| GB0016895D0 (en) * | 2000-07-11 | 2000-08-30 | Bp Chem Int Ltd | Olefin oligomerisation |
| WO2004056480A1 (en) | 2002-12-20 | 2004-07-08 | Sasol Technology (Pty) Limited | Tandem tetramerisation-polymerisation of olefins |
| CA2510194C (en) | 2002-12-20 | 2012-01-31 | Sasol Technology (Pty) Ltd | Tetramerization of olefins |
| US7273959B2 (en) | 2003-10-10 | 2007-09-25 | Shell Oil Company | Catalytic trimerization of olefinic monomers |
| EP1756024B1 (de) | 2004-06-18 | 2018-08-15 | Sasol Technology (Pty) Ltd | Oligomerisation von olefinischen verbindungen in einem aliphatischen medium |
| US7259123B2 (en) * | 2005-04-08 | 2007-08-21 | Shell Oil Company | Catalytic trimerization and tetramerization of olefinic monomers |
-
2004
- 2004-10-06 US US10/959,561 patent/US7273959B2/en not_active Expired - Fee Related
- 2004-10-07 WO PCT/EP2004/052469 patent/WO2005039758A1/en not_active Ceased
- 2004-10-07 AT AT04791172T patent/ATE516079T1/de not_active IP Right Cessation
- 2004-10-07 EP EP04791172A patent/EP1675679B1/de not_active Expired - Lifetime
- 2004-10-07 CA CA2541697A patent/CA2541697C/en not_active Expired - Fee Related
- 2004-10-07 JP JP2006530281A patent/JP5372327B2/ja not_active Expired - Fee Related
- 2004-10-07 RU RU2006115613/04A patent/RU2352389C2/ru active
- 2004-10-07 CN CNA2004800296645A patent/CN1867401A/zh active Pending
-
2006
- 2006-03-27 ZA ZA200602478A patent/ZA200602478B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| RU2006115613A (ru) | 2007-11-20 |
| CN1867401A (zh) | 2006-11-22 |
| CA2541697A1 (en) | 2005-05-06 |
| RU2352389C2 (ru) | 2009-04-20 |
| JP5372327B2 (ja) | 2013-12-18 |
| CA2541697C (en) | 2013-12-10 |
| ZA200602478B (en) | 2007-06-27 |
| WO2005039758A1 (en) | 2005-05-06 |
| US20050113622A1 (en) | 2005-05-26 |
| JP2007508128A (ja) | 2007-04-05 |
| EP1675679A1 (de) | 2006-07-05 |
| EP1675679B1 (de) | 2011-07-13 |
| US7273959B2 (en) | 2007-09-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ATE516079T1 (de) | Katalytische trimerisierung von olefinischen monomeren | |
| ZA200708258B (en) | Catalytic trimerization and tetramerization of elefinic monomers | |
| ATE454214T1 (de) | Katalytische oligomerisierung von olefinischen monomeren | |
| GB0016895D0 (en) | Olefin oligomerisation | |
| RU2008125137A (ru) | Каталитический способ олигомеризации олефиновых мономеров | |
| BG100904A (bg) | Металоцени, метод за тяхното получаване, приложението им в катализатори за полимеризация на олефини | |
| DE69903849D1 (de) | Polymerisationskatalysator | |
| BR9506039A (pt) | Componentes e catalisadores para a polímerização de olefinas | |
| DE69116157D1 (de) | Trägerkatalysator für olefinpolymerisation mit monozyklopentadienylkomplexen von übergangsmetallen | |
| BR9806952A (pt) | Preparação de macrÈmeros contendo vinila. | |
| PT955304E (pt) | Complexo de metaloceno com pontes para a (co) polimerizacao de olefinas | |
| BR9705187A (pt) | Metalocenos. | |
| ATE346853T1 (de) | Lösliche spätübergangsmetallkatalysatoren für olefinpolymerisation | |
| BR0009363A (pt) | Processo para a polimerização de olefinas, sistemacatalisador, e, polìmero de olefina | |
| BR9804520A (pt) | Polimerização catalitica e processos para a mesma | |
| BR0313087A (pt) | Derivados de indenila tricìclico substituìdo com 4-arila contendo complexos de metais do grupo 4 e seu uso | |
| BR0203264A (pt) | Complexos de vanádio-imido-fosforaniminato para a polimerização de olefina | |
| MXPA02007950A (es) | Catalizadores para la polimerizacion de olefina. | |
| MX2024010013A (es) | Complejo organometalico, sistema catalizador de polimerizacion de olefina y proceso de polimerizacion. | |
| EA200101024A1 (ru) | Каталитические композиции на подложках для полимеризации олефинов с задержкой активности, способ их приготовления и их применение | |
| ATE364047T1 (de) | Monocyclopentadienylkomplexe | |
| ATE425172T1 (de) | Monocyclopentadienylkomplexe | |
| BR0203228A (pt) | Complexos de vanádio-imidoarila para a polimerização de olefina | |
| DE60224671D1 (de) | Verzweigte polymere auf alpha-olefin basis | |
| DE60317903D1 (de) | Katalysatorsystem für die polymerisation von olefinen |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RER | Ceased as to paragraph 5 lit. 3 law introducing patent treaties |