BR9914738A - Processo de copolimerização de olefinas com hafnocenos ligados por pontes - Google Patents
Processo de copolimerização de olefinas com hafnocenos ligados por pontesInfo
- Publication number
- BR9914738A BR9914738A BR9914738-6A BR9914738A BR9914738A BR 9914738 A BR9914738 A BR 9914738A BR 9914738 A BR9914738 A BR 9914738A BR 9914738 A BR9914738 A BR 9914738A
- Authority
- BR
- Brazil
- Prior art keywords
- polymerization
- olefin
- cyclopentadienyl
- aromatic fused
- ring substituted
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Patente de Invenção: <B>"PROCESSO DE COPOLIMERIZAçãO DE OLEFINAS COM HAFNOCENOS LIGADOS POR PONTES"<D>. A invenção refere-se a processos de polimerização de olefinas usando complexos de catalisadores de hafnoceno ligados por pontes que são surpreendentemente estáveis sob processos de polimerização de olefinas à alta temperatura tal que copolímeros de olefinas podem ser preparados com altos pesos moleculares e atividades catalíticas. Mais especificamente, a invenção é um processo de polimerização para copolímeros de etileno que apresentam um índice de fusão de cerca de 0,850 a cerca de 0,930, processo este que compreende contactar, sob condições homogêneas de polimerização a uma temperatura de reação sob ou acima de 60°C a 225°C, etileno e um ou mais comonómeros capazes de polimerização por inserção com um complexo de catalisador de hafnoceno ligados por pontes derivado de: A) um composto organometálico de bisciclopentadienil háfnio que apresenta: i) pelo menos um ligante ciclopentadienila não-substituída ou ligante ciclopentadienila substituída com anel aromático fundido; ii) um ligante ciclopentadienila substituída com anel aromático fundido; iii) e uma ponte covalente que conecta os dois ligantes ciclopentadienila, ponte esta que compreende um único átomos de carbono ou silício com dois grupos arila, cada um substituído com um grupo C~ 1~-C~ 20~ hidrocarbila ou hidrocarbilsilila pelo menos um dos quais é um substituinte C~ 3~ linear ou superior; e B) um co-catalisador de ativação.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10532998P | 1998-10-23 | 1998-10-23 | |
PCT/US1999/024600 WO2000024792A1 (en) | 1998-10-23 | 1999-10-21 | Olefin copolymerization process with bridged hafnocenes |
Publications (1)
Publication Number | Publication Date |
---|---|
BR9914738A true BR9914738A (pt) | 2001-07-03 |
Family
ID=22305204
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR9914738-6A BR9914738A (pt) | 1998-10-23 | 1999-10-21 | Processo de copolimerização de olefinas com hafnocenos ligados por pontes |
Country Status (14)
Country | Link |
---|---|
EP (1) | EP1129115B1 (pt) |
JP (1) | JP5255740B2 (pt) |
KR (1) | KR100621299B1 (pt) |
CN (1) | CN1125834C (pt) |
AT (1) | ATE284421T1 (pt) |
AU (1) | AU761531B2 (pt) |
BR (1) | BR9914738A (pt) |
CA (1) | CA2343768A1 (pt) |
DE (1) | DE69922536T2 (pt) |
ES (1) | ES2235549T3 (pt) |
MX (1) | MXPA01003977A (pt) |
RU (1) | RU2228937C2 (pt) |
TW (1) | TW486489B (pt) |
WO (1) | WO2000024792A1 (pt) |
Families Citing this family (40)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20020107343A1 (en) | 2001-02-08 | 2002-08-08 | Mitsui Chemicals, Inc. | Ethylene polymer, preparation process thereof and molded articles of the same |
DE60238049D1 (de) * | 2001-04-12 | 2010-12-02 | Exxonmobil Chem Patents Inc | Verfahren zur Polymerisation von Propylen und Ethylen in Lösung |
AU2003286667A1 (en) * | 2002-10-28 | 2004-05-25 | Exxonmobil Chemical Patents, Inc. | Low density ethylene copolymer, a process for making same and blends comprising such copolymer |
CN102936304B (zh) * | 2004-03-24 | 2014-10-22 | 埃克森美孚化学专利公司 | 乙烯共聚体及其生产方法、含有乙烯共聚体的组合物和电装置 |
US7517939B2 (en) | 2006-02-02 | 2009-04-14 | Chevron Phillips Chemical Company, Lp | Polymerization catalysts for producing high molecular weight polymers with low levels of long chain branching |
US7576163B2 (en) | 2006-03-31 | 2009-08-18 | Chevron Phillips Chemical Company, Lp | Polymerization catalysts for producing polymers with low levels of long chain branching |
TWI404730B (zh) * | 2007-02-05 | 2013-08-11 | Univation Tech Llc | 控制聚合物性質之方法 |
WO2009123609A1 (en) | 2008-03-31 | 2009-10-08 | Advanced Elastomer Systems, L.P. | Thermoplastic vulcanizates |
EP2516708B1 (en) | 2009-12-23 | 2016-02-17 | Invista Technologies S.à.r.l. | Polyolefin elastic fiber |
CN102770590B (zh) | 2009-12-23 | 2015-04-29 | 英威达技术有限公司 | 包含聚烯烃弹性纤维的织物的制备方法 |
KR20120114314A (ko) | 2009-12-23 | 2012-10-16 | 인비스타 테크놀러지스 에스.에이.알.엘. | 점착 방지 첨가제를 함유하는 탄성 섬유 |
MX2012007401A (es) | 2009-12-23 | 2012-07-17 | Invista Tech Sarl | Articulos elasticos que incluyen fibra elastica de poliolefina. |
WO2011087729A2 (en) | 2010-01-14 | 2011-07-21 | Exxonmobil Chemical Patents Inc. | Processes and apparatus for polymer finishing and packaging |
WO2011087731A1 (en) | 2010-01-14 | 2011-07-21 | Exxonmobil Chemical Patents Inc. | Processes and apparatus for continuous solution polymerization |
CN104428326A (zh) * | 2012-09-27 | 2015-03-18 | 埃克森美孚化学专利公司 | 乙烯基封端聚合物及其制造方法 |
US8937139B2 (en) | 2012-10-25 | 2015-01-20 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
US8895679B2 (en) | 2012-10-25 | 2014-11-25 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
US9034991B2 (en) | 2013-01-29 | 2015-05-19 | Chevron Phillips Chemical Company Lp | Polymer compositions and methods of making and using same |
US8877672B2 (en) | 2013-01-29 | 2014-11-04 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
CN107075209B (zh) * | 2014-09-30 | 2020-05-19 | 埃克森美孚化学专利公司 | 低乙烯的无定形丙烯-乙烯-二烯三元共聚物组合物 |
EP3307794B1 (en) | 2015-06-15 | 2019-02-27 | ExxonMobil Chemical Patents Inc. | Process for continuous solution polymerization |
WO2018022263A1 (en) | 2016-07-29 | 2018-02-01 | Exxonmobil Chemical Patents Inc. | Polymerization processes using high molecular weight polyhydric quenching agents |
US11352376B2 (en) | 2016-11-18 | 2022-06-07 | Borealis Ag | Catalysts |
KR102543361B1 (ko) * | 2016-12-15 | 2023-06-13 | 보레알리스 아게 | 고온 용액 중합 공정으로 폴리에틸렌 공중합체를 제조하기 위한 새로운 촉매 시스템 |
EP3555148B1 (en) * | 2016-12-15 | 2023-04-05 | Borealis AG | Catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process |
EP3562831B1 (en) | 2016-12-29 | 2021-10-20 | Borealis AG | Catalysts |
US10508179B2 (en) | 2017-02-28 | 2019-12-17 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizate prepared with oil-extended, bimodal metallocene-synthesized EPDM |
US11192963B2 (en) | 2017-03-30 | 2021-12-07 | Borealis Ag | Borate-activated metallocene catalysts |
WO2018178151A1 (en) | 2017-03-30 | 2018-10-04 | Borealis Ag | Aluminoxane-activated metallocene catalysts |
WO2019179959A1 (en) | 2018-03-19 | 2019-09-26 | Borealis Ag | Catalysts for olefin polymerization |
CN112424241B (zh) | 2018-06-28 | 2023-06-06 | 博里利斯股份公司 | 催化剂 |
CN112703210B (zh) | 2018-07-23 | 2022-10-28 | 埃克森美孚化学专利公司 | 制备双峰橡胶、热塑性硫化橡胶和由其制成的制品 |
WO2020060745A1 (en) | 2018-09-19 | 2020-03-26 | Exxonmobil Chemical Patents Inc. | Devolatilization processes |
WO2020167399A1 (en) | 2019-02-11 | 2020-08-20 | Exxonmobil Chemical Patents Inc. | Biphasic polymerization processes and ethylene-based polyolefins therefrom |
CA3037415A1 (en) * | 2019-03-20 | 2020-09-20 | Nova Chemicals Corporation | Synthesis of metallocene polymerization catalyst |
JP2022528937A (ja) | 2019-04-12 | 2022-06-16 | ボレアリス エージー | 触媒系 |
US20230002525A1 (en) | 2019-12-17 | 2023-01-05 | Exxonmobil Chemical Patents Inc. | Solution Polymerization Process for Making High-Density Polyethylene with Long-Chain Branching |
EP3845572A1 (en) * | 2020-01-02 | 2021-07-07 | Borealis AG | Process for the polymerization of olefins in solution with controlled activity of catalyst in reactor outlet stream |
JP2023532133A (ja) | 2020-07-02 | 2023-07-26 | セラニーズ・インターナショナル・コーポレーション | メタロセン多峰性コポリマーゴムを含有する熱可塑性加硫物組成物およびその製造方法 |
WO2023097161A1 (en) | 2021-11-23 | 2023-06-01 | Exxonmobil Chemical Patents Inc. | Plants and processes for forming polymers |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3392205B2 (ja) * | 1994-03-11 | 2003-03-31 | 三井化学株式会社 | 新規遷移金属化合物およびこれを用いたオレフィンの重合方法 |
BR9604776A (pt) * | 1995-03-10 | 1998-06-23 | Dow Chemical Co | Componente de catalisador sustentado catalisador sustentado processo para preparar um componente de catalisador sustentado e um catalisador sustentado aduto de um composto organometálico processo de polimerizaçao por adiç o composto complexo e método para preparar um composto complexo |
DE69720823T2 (de) * | 1996-01-25 | 2004-01-22 | Tosoh Corp., Shinnanyo | Verfahren zur Olefinpolymerisierung unter Verwendung eines Übergangsmetallkatalysators. |
US5856256A (en) * | 1996-02-20 | 1999-01-05 | Northwestern University | Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations |
ATE202365T1 (de) * | 1996-08-13 | 2001-07-15 | Basell Polyolefine Gmbh | Geträgertes katalysatorsystem, verfahren zu seiner herstellung und seine verwendung zur polymerisation von olefinen |
ATE293132T1 (de) * | 1998-03-04 | 2005-04-15 | Exxonmobil Chem Patents Inc | Nicht koordinierende anionen für die polymerisation von olefinen |
-
1999
- 1999-10-21 CA CA002343768A patent/CA2343768A1/en not_active Abandoned
- 1999-10-21 WO PCT/US1999/024600 patent/WO2000024792A1/en active IP Right Grant
- 1999-10-21 AT AT99971005T patent/ATE284421T1/de not_active IP Right Cessation
- 1999-10-21 DE DE69922536T patent/DE69922536T2/de not_active Expired - Lifetime
- 1999-10-21 JP JP2000578361A patent/JP5255740B2/ja not_active Expired - Fee Related
- 1999-10-21 RU RU2001113443/04A patent/RU2228937C2/ru not_active IP Right Cessation
- 1999-10-21 AU AU14484/00A patent/AU761531B2/en not_active Ceased
- 1999-10-21 ES ES99971005T patent/ES2235549T3/es not_active Expired - Lifetime
- 1999-10-21 EP EP99971005A patent/EP1129115B1/en not_active Expired - Lifetime
- 1999-10-21 CN CN99812494A patent/CN1125834C/zh not_active Expired - Lifetime
- 1999-10-21 KR KR1020017004872A patent/KR100621299B1/ko not_active IP Right Cessation
- 1999-10-21 MX MXPA01003977A patent/MXPA01003977A/es unknown
- 1999-10-21 BR BR9914738-6A patent/BR9914738A/pt not_active IP Right Cessation
- 1999-10-22 TW TW088118343A patent/TW486489B/zh not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
MXPA01003977A (es) | 2003-06-06 |
DE69922536D1 (de) | 2005-01-13 |
KR100621299B1 (ko) | 2006-09-13 |
CA2343768A1 (en) | 2000-05-04 |
JP2002528576A (ja) | 2002-09-03 |
EP1129115A1 (en) | 2001-09-05 |
ATE284421T1 (de) | 2004-12-15 |
RU2228937C2 (ru) | 2004-05-20 |
AU761531B2 (en) | 2003-06-05 |
TW486489B (en) | 2002-05-11 |
EP1129115B1 (en) | 2004-12-08 |
KR20010075644A (ko) | 2001-08-09 |
WO2000024792A1 (en) | 2000-05-04 |
CN1324370A (zh) | 2001-11-28 |
ES2235549T3 (es) | 2005-07-01 |
AU1448400A (en) | 2000-05-15 |
DE69922536T2 (de) | 2005-12-15 |
CN1125834C (zh) | 2003-10-29 |
JP5255740B2 (ja) | 2013-08-07 |
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B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE A 6A, 7A E 8A ANUIDADES. |
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B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 1913 DE 04/09/2007. |