RU2005141404A - Композиция, ингибирующая потускнение, и изделие, ее содержащее - Google Patents
Композиция, ингибирующая потускнение, и изделие, ее содержащее Download PDFInfo
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- RU2005141404A RU2005141404A RU2005141404/02A RU2005141404A RU2005141404A RU 2005141404 A RU2005141404 A RU 2005141404A RU 2005141404/02 A RU2005141404/02 A RU 2005141404/02A RU 2005141404 A RU2005141404 A RU 2005141404A RU 2005141404 A RU2005141404 A RU 2005141404A
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D81/24—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants
- B65D81/26—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators
- B65D81/266—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators for absorbing gases, e.g. oxygen absorbers or desiccants
- B65D81/267—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators for absorbing gases, e.g. oxygen absorbers or desiccants the absorber being in sheet form
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D81/24—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants
- B65D81/26—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3472—Five-membered rings
- C08K5/3475—Five-membered rings condensed with carbocyclic rings
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F15/00—Other methods of preventing corrosion or incrustation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Food Science & Technology (AREA)
- Packages (AREA)
- Wrappers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Laminated Bodies (AREA)
Claims (8)
1. Ингибирующая потускнение композиция, эффективная для защиты поверхности серебряного предмета, содержащего свыше 90% серебра, в случае когда поверхность подвергается обработке композицией в герметичном окружении, от потускнения в атмосфере, содержащей молекулярный кислород, содержащей сульфид водорода в интервале от 1 ч./млрд (часть на миллиард) до 10 ч./млн (часть на миллион), при относительной влажности 90% и при температуре 37,4°С (100°F) в течение, по меньшей мере, одного года, причем композиция по существу состоит из практически негидролизующегося полимера, в котором по существу гомогенно диспергирован от примерно 0,01 до 5 мас.% практически безводного поглотителя, выбранного из группы, состоящей из силиката щелочного металла и оксида цинка, в комбинации с 0-1% инертного активирующего вещества, при условии, что полимер имеет скорость проникновения водяного пара ((WVTR)(СПВП)), по меньшей мере, такую же высокую, как у полиэтилена низкой плотности.
2. Композиция по п.1, в которой полимер выбран из группы, состоящей из полиэтилена низкой плотности, полипропилена, сополимеров низших С2-С8-олефинов, сополимеров низших С2-С8-олефинов и этилен/винилового спирта, не являющегося биоразлагаемым сложного полиэфира, поливинилхлорида, полистирола, полиамида и биоразлагаемого сложного полиэфира, имеющего СПВП выше примерно 1,5 г/24 ч, измеренную на толщину 0,025 мм (1 мил) и площадь 645 см2 (100 дюйм2) при 37,4°С (100°F) и 98% относительной влажности ((RH)(ОВ)).
3. Композиция по п.2, в которой биоразлагаемый сложный полиэфир выбран из группы, состоящей из звездчатого -капролактона, -капролактона ((PCL) (ПКЛ)), сополимера гидроксибутират - валерат ((PHBV) (ПГБВ)), содержащего 8, 16 и 20% валерата; целлофановых пленок без покрытия и с нитроцеллюлозным покрытием; сшитого хитозана; пленок из смеси крахмал/этиленвиниловый спирт (St/EVOH); чистой EVOH-пленки (38% мол. этилена); и поликапролактона ((PCL)(ПКЛ)) с молекулярной массой примерно 80000 Д.
4. Композиция по п.1, в которой силикатом щелочного металла является силикат натрия, а активирующее вещество выбрано из группы, состоящей из коллоидального диоксида кремния и карбоната кальция, присутствующих в количестве в интервале от 0,01 до 1 мас.%.
5. Композиция по п.2, в которой композиция является прозрачной, и поглотитель и активирующее вещество имеют главный размер частиц в интервале от примерно 1 мкм до 53 мкм и по существу гомогенно диспергированы в полимере.
6. Изделие произвольных размера и формы, выполненное из полимера-основы, состоящего по существу из синтетической смолы, содержащей по существу однородно диспергированный в ней поглотитель, выбранный из группы, состоящей из оксида цинка и силиката щелочного металла, причем каждый присутствует в количестве от 0,01 до 5 мас.% полимера и от 0,0 до 1% инертного активирующего вещества, где каждый из поглотителя и активирующего вещества имеет главный размер частиц в интервале от 1 мкм до 53 мкм, и смола имеет скорость проникновения водяного пара ((WVTR)(СПВП)), которая является по существу такой же, как у смолы без поглотителя и активирующего вещества.
7. Изделие по п.6, в котором пленка представляет собой пленку из полимера низшего олефина, имеющего от 2 до 8 углеродных атомов, причем пленка имеет гладкие верхнюю и нижнюю поверхности и толщину в интервале от 0,0125 мм (0,5 мил или 0,0005 дюйм) до 0,125 мм (0,005 дюйм или 5 мил), и инертное активирующее вещество представляет собой неорганический диспергатор, выбранный из группы, состоящей из коллоидального диоксида кремния и карбоната кальция.
8. Способ защиты серебряного предмета от потускнения в атмосфере, вызывающей потускнение, который содержит размещение предмета в контейнере, выполненном из термоформуемой синтетической смолы, имеющей по существу однородно диспергированные в ней твердые частицы поглотителя, выбранного из группы, состоящей из оксида цинка и силиката щелочного металла, каждый из которых присутствует в количестве от 0,01 до 5 мас.% смолы, и от 0,0 до 1% инертного активирующего вещества, причем каждый наполнитель имеет главный размер частиц в интервале от 1 до 53 мкм, и смола имеет скорость проникновения водяного пара ((WVTR)(СПВП)), которая является по существу такой же, как у смолы без поглотителя и активирующего вещества.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/453,303 US20030207974A1 (en) | 2002-01-22 | 2003-06-03 | Tarnish inhibiting formula and tarnish inhibiting articles using same |
US10/453,303 | 2003-06-03 | ||
US10/676,760 US7261839B2 (en) | 2002-01-22 | 2003-10-01 | Tarnish inhibiting composition and article containing it |
US10/676,760 | 2003-10-01 |
Publications (2)
Publication Number | Publication Date |
---|---|
RU2005141404A true RU2005141404A (ru) | 2006-06-10 |
RU2309197C2 RU2309197C2 (ru) | 2007-10-27 |
Family
ID=35696242
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU2005141404/02A RU2309197C2 (ru) | 2003-06-03 | 2004-05-14 | Композиция, ингибирующая потускнение, и изделие, ее содержащее |
Country Status (11)
Country | Link |
---|---|
US (1) | US7261839B2 (ru) |
EP (1) | EP1633908B1 (ru) |
JP (1) | JP2006526707A (ru) |
KR (1) | KR100806977B1 (ru) |
CN (1) | CN100570004C (ru) |
BR (1) | BRPI0410799A (ru) |
CA (1) | CA2526519A1 (ru) |
MX (1) | MXPA05013093A (ru) |
PL (1) | PL1633908T3 (ru) |
RU (1) | RU2309197C2 (ru) |
WO (1) | WO2004108993A1 (ru) |
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DE202013004980U1 (de) | 2013-06-03 | 2013-06-25 | Branofilter Gmbh | Faserhaltiges Trägermaterial |
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KR101595094B1 (ko) | 2014-12-18 | 2016-02-18 | 한국화학연구원 | 비철금속 포장용 변색방지 필름 조성물 |
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JP7115827B2 (ja) * | 2017-07-26 | 2022-08-09 | 東洋製罐グループホールディングス株式会社 | 耐変色性に優れた樹脂成形体 |
DE202017004118U1 (de) | 2017-08-05 | 2017-09-29 | Corroyltic GmbH | Faserhaltiges Trägermaterial für Korrosionsschutzverpackungen |
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-
2003
- 2003-10-01 US US10/676,760 patent/US7261839B2/en not_active Expired - Lifetime
-
2004
- 2004-05-14 JP JP2006514884A patent/JP2006526707A/ja active Pending
- 2004-05-14 EP EP04752414A patent/EP1633908B1/en not_active Expired - Lifetime
- 2004-05-14 MX MXPA05013093A patent/MXPA05013093A/es active IP Right Grant
- 2004-05-14 PL PL04752414T patent/PL1633908T3/pl unknown
- 2004-05-14 BR BRPI0410799-3A patent/BRPI0410799A/pt not_active IP Right Cessation
- 2004-05-14 CA CA002526519A patent/CA2526519A1/en not_active Abandoned
- 2004-05-14 RU RU2005141404/02A patent/RU2309197C2/ru not_active IP Right Cessation
- 2004-05-14 KR KR1020057023256A patent/KR100806977B1/ko active IP Right Grant
- 2004-05-14 CN CNB2004800154254A patent/CN100570004C/zh not_active Expired - Lifetime
- 2004-05-14 WO PCT/US2004/015394 patent/WO2004108993A1/en active Search and Examination
Also Published As
Publication number | Publication date |
---|---|
EP1633908B1 (en) | 2012-04-11 |
JP2006526707A (ja) | 2006-11-24 |
RU2309197C2 (ru) | 2007-10-27 |
PL1633908T3 (pl) | 2012-11-30 |
US20040063837A1 (en) | 2004-04-01 |
KR100806977B1 (ko) | 2008-02-25 |
CN100570004C (zh) | 2009-12-16 |
CN1798877A (zh) | 2006-07-05 |
EP1633908A1 (en) | 2006-03-15 |
BRPI0410799A (pt) | 2006-06-20 |
CA2526519A1 (en) | 2004-12-16 |
MXPA05013093A (es) | 2006-05-25 |
WO2004108993A1 (en) | 2004-12-16 |
KR20060008329A (ko) | 2006-01-26 |
US7261839B2 (en) | 2007-08-28 |
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