RU2005128272A - Комплексный носитель катализаторов полимеризации пропилена, каталитический компонент и катализатор, включающий указанный компонент - Google Patents
Комплексный носитель катализаторов полимеризации пропилена, каталитический компонент и катализатор, включающий указанный компонент Download PDFInfo
- Publication number
- RU2005128272A RU2005128272A RU2005128272/04A RU2005128272A RU2005128272A RU 2005128272 A RU2005128272 A RU 2005128272A RU 2005128272/04 A RU2005128272/04 A RU 2005128272/04A RU 2005128272 A RU2005128272 A RU 2005128272A RU 2005128272 A RU2005128272 A RU 2005128272A
- Authority
- RU
- Russia
- Prior art keywords
- optionally halogenated
- aliphatic
- group
- complex carrier
- silicon oxide
- Prior art date
Links
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title claims 16
- 230000003197 catalytic effect Effects 0.000 title claims 9
- 239000002685 polymerization catalyst Substances 0.000 title claims 7
- 239000003054 catalyst Substances 0.000 title claims 2
- 239000002245 particle Substances 0.000 claims 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 15
- 229910052814 silicon oxide Inorganic materials 0.000 claims 15
- 125000001931 aliphatic group Chemical group 0.000 claims 14
- -1 magnesium halide Chemical class 0.000 claims 14
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 14
- 150000001875 compounds Chemical class 0.000 claims 12
- 125000003118 aryl group Chemical group 0.000 claims 11
- 125000000753 cycloalkyl group Chemical group 0.000 claims 11
- 125000001424 substituent group Chemical group 0.000 claims 11
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims 10
- 125000002877 alkyl aryl group Chemical group 0.000 claims 10
- 125000003710 aryl alkyl group Chemical group 0.000 claims 10
- 239000000203 mixture Substances 0.000 claims 9
- 239000000725 suspension Substances 0.000 claims 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 8
- 125000000217 alkyl group Chemical group 0.000 claims 8
- 229910052736 halogen Inorganic materials 0.000 claims 8
- 238000006116 polymerization reaction Methods 0.000 claims 8
- 238000001035 drying Methods 0.000 claims 6
- 150000002367 halogens Chemical class 0.000 claims 6
- 229910052739 hydrogen Inorganic materials 0.000 claims 6
- 239000001257 hydrogen Substances 0.000 claims 6
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 6
- 150000003609 titanium compounds Chemical class 0.000 claims 6
- 125000005907 alkyl ester group Chemical group 0.000 claims 5
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims 5
- 238000006243 chemical reaction Methods 0.000 claims 5
- 150000004292 cyclic ethers Chemical class 0.000 claims 5
- 229910001629 magnesium chloride Inorganic materials 0.000 claims 5
- 239000012798 spherical particle Substances 0.000 claims 5
- 230000015572 biosynthetic process Effects 0.000 claims 4
- 229910052749 magnesium Inorganic materials 0.000 claims 4
- 239000011777 magnesium Substances 0.000 claims 4
- 238000001694 spray drying Methods 0.000 claims 4
- 239000010936 titanium Substances 0.000 claims 4
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims 3
- 239000002253 acid Substances 0.000 claims 3
- 229910052782 aluminium Inorganic materials 0.000 claims 3
- 229910052794 bromium Inorganic materials 0.000 claims 3
- 229910052801 chlorine Inorganic materials 0.000 claims 3
- 150000002148 esters Chemical class 0.000 claims 3
- 229910052731 fluorine Inorganic materials 0.000 claims 3
- 125000005843 halogen group Chemical group 0.000 claims 3
- 230000003993 interaction Effects 0.000 claims 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 2
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 claims 2
- 239000007795 chemical reaction product Substances 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- 229910052710 silicon Inorganic materials 0.000 claims 2
- 239000010703 silicon Substances 0.000 claims 2
- 239000011949 solid catalyst Substances 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- 150000001298 alcohols Chemical class 0.000 claims 1
- 125000005234 alkyl aluminium group Chemical group 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims 1
- 235000013601 eggs Nutrition 0.000 claims 1
- 150000002170 ethers Chemical class 0.000 claims 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N glutaric acid Chemical class OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 claims 1
- 125000001188 haloalkyl group Chemical group 0.000 claims 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims 1
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- 150000002690 malonic acid derivatives Chemical class 0.000 claims 1
- 235000011007 phosphoric acid Nutrition 0.000 claims 1
- 150000003016 phosphoric acids Chemical class 0.000 claims 1
- 125000005498 phthalate group Chemical class 0.000 claims 1
- 125000005547 pivalate group Chemical group 0.000 claims 1
- 150000003377 silicon compounds Chemical class 0.000 claims 1
- 238000005507 spraying Methods 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 150000003900 succinic acid esters Chemical class 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerization Catalysts (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03105214 CN1218971C (zh) | 2003-02-24 | 2003-02-24 | 用于烯烃聚合催化剂的复合载体及其催化剂组分和催化剂 |
| CN03105214.2 | 2003-02-24 | ||
| CN03153662.X | 2003-08-20 | ||
| CNB03153662XA CN1297574C (zh) | 2003-08-20 | 2003-08-20 | 用于烯烃聚合的催化剂组分及其催化剂 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2005128272A true RU2005128272A (ru) | 2006-08-10 |
Family
ID=32909293
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2005128272/04A RU2005128272A (ru) | 2003-02-24 | 2004-02-17 | Комплексный носитель катализаторов полимеризации пропилена, каталитический компонент и катализатор, включающий указанный компонент |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US20040229748A1 (https=) |
| EP (1) | EP1609805B1 (https=) |
| JP (1) | JP2006523730A (https=) |
| KR (1) | KR20060013486A (https=) |
| CA (1) | CA2516693A1 (https=) |
| RU (1) | RU2005128272A (https=) |
| WO (1) | WO2004074329A1 (https=) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2644212C2 (ru) * | 2010-12-21 | 2018-02-09 | У.Р.Грейс Энд Ко.-Конн. | Каталитическая композиция с галогенмалонатным внутренним донором электронов и полимер из нее |
| RU2839601C1 (ru) * | 2020-09-05 | 2025-05-06 | Чайна Петролеум Энд Кемикал Корпорейшн | Носитель для катализатора полимеризации олефинов и его применение, катализатор полимеризации олефинов и его применение и способ полимеризации олефинов |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7071137B2 (en) * | 2004-08-25 | 2006-07-04 | Novolen Technology Holdings, C.V. | Method of making a ziegler-natta catalyst |
| US20060046928A1 (en) * | 2004-08-25 | 2006-03-02 | Klendworth Douglas D | Ziegler-natta catalyst and method for making and using same |
| US7402546B2 (en) * | 2004-09-23 | 2008-07-22 | Equistar Chemicals, Lp | Magnesium chloride support |
| US8344080B2 (en) * | 2005-03-07 | 2013-01-01 | Licai Wang | Catalyst for olefin polymerization and method of preparation thereof |
| WO2007051410A1 (fr) * | 2005-10-31 | 2007-05-10 | China Petroleum & Chemical Corporation | Composant catalytique destine a la polymerisation de l’ethylene, sa preparation et catalyseur le contenant |
| EP1857475A1 (en) * | 2006-04-24 | 2007-11-21 | Total Petrochemicals Research Feluy | Use of Ziegler-Natta catalyst to make a polypropylene homopolymer or random copolymer having a high melt flow rate |
| JP5394231B2 (ja) | 2006-04-24 | 2014-01-22 | トタル リサーチ アンド テクノロジー フエリユイ | 高い溶融流動性を有するプロピレンの単独重合体またはランダム共重合体の製造でのチーグラー‐ナッタ触媒の使用 |
| ATE528324T1 (de) * | 2007-11-30 | 2011-10-15 | Borealis Tech Oy | Katalysator mit niedriger oberfläche |
| US7786237B2 (en) * | 2008-02-01 | 2010-08-31 | Fina Technology, Inc. | Polyethylene materials prepared using mixed ziegler-natta catalysts systems |
| KR101213827B1 (ko) * | 2008-04-08 | 2012-12-18 | 미쓰이 가가쿠 가부시키가이샤 | 에틸렌 중합용 고체상 타이타늄 촉매 성분, 에틸렌 중합용 촉매 및 에틸렌의 중합 방법 |
| CN101554595B (zh) * | 2009-05-18 | 2011-02-02 | 中国石油化工股份有限公司 | 一种烯烃聚合用催化剂载体及其制备方法和应用 |
| BR112012000866B1 (pt) | 2009-07-15 | 2021-07-20 | China Petroleum & Chemical Corporation | Aduto de halogeneto de magnésio, processo para a preparação do mesmo, componente catalisador útil na polimerização de olefinas, catalisador e processo para a polimerização de olefinas |
| SA3686B1 (ar) * | 2009-10-16 | 2014-10-22 | China Petroleum& Chemical Corp | مكون حفاز لبلمرة الأولفين وحفاز يشتمل عليه |
| WO2012091684A1 (en) * | 2010-12-30 | 2012-07-05 | Irpc Public Company Limited | A catalyst for olefin polymerisation and a method for the preparation thereof |
| US9522968B2 (en) * | 2012-11-26 | 2016-12-20 | Lummus Novolen Technology Gmbh | High performance Ziegler-Natta catalyst systems, process for producing such MgCl2 based catalysts and use thereof |
| US9481741B2 (en) * | 2012-11-26 | 2016-11-01 | Lummus Novolen Technology Gmbh | High performance Ziegler-Natta catalyst systems, process for producing such supported catalysts and use thereof |
| JP6177938B2 (ja) * | 2013-03-15 | 2017-08-09 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | プロピレン三元重合体の製造工程、およびそれにより得たプロピレン三元重合体 |
| CN104558282B (zh) | 2013-10-18 | 2017-02-15 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分及其制备方法和用于烯烃聚合的催化剂与应用 |
| JP6397908B2 (ja) | 2013-10-18 | 2018-09-26 | 中国石油化工股▲ふん▼有限公司 | オレフィン重合触媒用球状担体、触媒成分、触媒、及びそれらの調製方法 |
| US9593184B2 (en) | 2014-10-28 | 2017-03-14 | Formosa Plastics Corporation, Usa | Oxalic acid diamides as modifiers for polyolefin catalysts |
| EP3018150B1 (en) | 2014-11-07 | 2020-03-11 | Indian Oil Corporation Limited | Process for the preparation of spherical catalyst particles |
| KR102753112B1 (ko) * | 2018-11-22 | 2025-01-14 | 롯데케미칼 주식회사 | 폴리올레핀 합성용 촉매의 제조방법 |
| CN114149523B (zh) * | 2020-09-05 | 2022-11-18 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂球形载体及其制备方法与应用和一种催化剂及其应用 |
| CN116023543B (zh) * | 2021-10-27 | 2024-08-02 | 中国石油化工股份有限公司 | 烯烃聚合用催化剂组分、烯烃聚合用催化剂及其应用 |
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| ZA796613B (en) * | 1978-12-28 | 1980-11-26 | Union Carbide Corp | Spheroidal polymerization catalyst process for preparing and use for ethylene polymerization |
| IT1136627B (it) * | 1981-05-21 | 1986-09-03 | Euteco Impianti Spa | Catalizzatore supportato per la polimerizzazione di etilene |
| US5089460A (en) * | 1989-07-26 | 1992-02-18 | Academy Of Applied Science, Inc. | Vanadium catalyst systems for olefin polymerization |
| JP2566829B2 (ja) * | 1989-08-03 | 1996-12-25 | 日本石油株式会社 | ポリオレフィンの製造方法 |
| US6172173B1 (en) * | 1991-01-18 | 2001-01-09 | The Dow Chemical Company | Silica supported transition metal catalyst |
| US6747113B1 (en) * | 1991-01-18 | 2004-06-08 | The Dow Chemical Company | Silica supported transition metal catalyst |
| IT1250706B (it) * | 1991-07-25 | 1995-04-21 | Enichem Polimeri | Catalizzatore per la polimerizzazione di olefine |
| DE4128829A1 (de) * | 1991-08-30 | 1993-03-04 | Basf Ag | Verfahren zum herstellen von homo- und copolymerisaten des propens mittels eines ziegler-nata-katalysatorsystems |
| IT1254223B (it) * | 1992-02-26 | 1995-09-14 | Enichem Polimeri | Catalizzatore per la polimerizzazione di olefine |
| US5290745A (en) * | 1992-08-10 | 1994-03-01 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing ethylene polymers having reduced hexane extractable content |
| CA2138312A1 (en) * | 1993-12-17 | 1995-06-18 | Eric Allan Lucas | Process for producing ethylene polymers having reduced hexane extractable content |
| US5561095A (en) * | 1994-03-31 | 1996-10-01 | Exxon Chemical Patents Inc. | Supported lewis acid catalysts for hydrocarbon conversion reactions |
| US5661097A (en) * | 1994-08-12 | 1997-08-26 | The Dow Chemical Company | Supported olefin polymerization catalyst |
| US5716558A (en) * | 1994-11-14 | 1998-02-10 | Union Carbide Chemicals & Plastics Technology Corporation | Method for producing coating powders catalysts and drier water-borne coatings by spraying compositions with compressed fluids |
| US7049377B1 (en) * | 1995-02-21 | 2006-05-23 | Basell Poliolefine Italia S.R.L. | 1,3-diethers and components and catalysts for the polymerization of olefins, containing said diethers |
| IT1274253B (it) * | 1995-02-21 | 1997-07-15 | Himont Inc | Processo per la preparazione di componenti catalitici solidi per la polimerizzazione di olefine |
| US5895770A (en) * | 1995-02-28 | 1999-04-20 | Pq Corporation | Olefin polymerization catalysts with specific silica supports |
| DE19545499A1 (de) * | 1995-12-06 | 1997-06-12 | Basf Ag | Verbesserte statistische Propylencopolymerisate |
| JP2000513402A (ja) * | 1996-06-21 | 2000-10-10 | ダブリュー・アール・グレース・アンド・カンパニー―コーン | 凝集担体およびそれに保持されたオレフィン重合触媒 |
| FR2769245B1 (fr) * | 1997-10-02 | 1999-10-29 | Atochem Elf Sa | Support solide activateur des catalyseurs metallocenes en polymerisation des olefines, son procede de preparation, systeme catalytique et procede de polymerisation correspondants |
| CN1098866C (zh) * | 1998-01-14 | 2003-01-15 | 中国石油化工集团公司 | 气相法全密度聚乙烯高效催化剂 |
| US6313061B1 (en) * | 1998-12-22 | 2001-11-06 | W. R. Grace & Co.-Conn. | Method of making frangible spray dried agglomerated supports and olefin polymerization catalysts supported thereon |
| JP4419228B2 (ja) * | 1999-10-27 | 2010-02-24 | 旭硝子株式会社 | 球状シリカ粒子の製造方法および触媒担体 |
| US6399535B1 (en) * | 1999-11-01 | 2002-06-04 | W. R. Grace & Co.-Conn. | Coordination catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation |
| CN1137155C (zh) * | 1999-12-06 | 2004-02-04 | 中国石油化工集团公司 | 用于烯烃聚合或共聚合的催化剂体系 |
| DE10002653A1 (de) * | 2000-01-21 | 2001-07-26 | Targor Gmbh | Neuartige Katalysatorsysteme vom Typ der Ziegler-Natta-Katalysatoren |
| CN1181105C (zh) * | 2000-08-22 | 2004-12-22 | 中国石油化工股份有限公司 | 用于乙烯聚合或共聚合的高活性硅胶载体催化剂组分及其催化剂和该催化剂的应用 |
| JP2002173504A (ja) * | 2000-11-29 | 2002-06-21 | Basell Technology Co Bv | オレフィン重合用触媒およびオレフィン重合方法 |
| US6982237B2 (en) * | 2002-07-15 | 2006-01-03 | Univation Technologies, Llc | Spray-dried polymerization catalyst and polymerization processes employing same |
| US6806221B2 (en) * | 2002-07-15 | 2004-10-19 | Dow Global Technologies Inc. | Method for preparing a spray-dried composition for use as a polymerization catalyst |
-
2004
- 2004-02-17 WO PCT/CN2004/000126 patent/WO2004074329A1/zh not_active Ceased
- 2004-02-17 JP JP2006501450A patent/JP2006523730A/ja active Pending
- 2004-02-17 EP EP04711555A patent/EP1609805B1/en not_active Expired - Lifetime
- 2004-02-17 RU RU2005128272/04A patent/RU2005128272A/ru not_active Application Discontinuation
- 2004-02-17 CA CA002516693A patent/CA2516693A1/en not_active Abandoned
- 2004-02-17 KR KR1020057015694A patent/KR20060013486A/ko not_active Withdrawn
- 2004-02-19 US US10/783,096 patent/US20040229748A1/en not_active Abandoned
-
2006
- 2006-03-07 US US11/369,793 patent/US20060154806A1/en not_active Abandoned
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2644212C2 (ru) * | 2010-12-21 | 2018-02-09 | У.Р.Грейс Энд Ко.-Конн. | Каталитическая композиция с галогенмалонатным внутренним донором электронов и полимер из нее |
| RU2839601C1 (ru) * | 2020-09-05 | 2025-05-06 | Чайна Петролеум Энд Кемикал Корпорейшн | Носитель для катализатора полимеризации олефинов и его применение, катализатор полимеризации олефинов и его применение и способ полимеризации олефинов |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1609805A1 (en) | 2005-12-28 |
| WO2004074329A1 (en) | 2004-09-02 |
| KR20060013486A (ko) | 2006-02-10 |
| EP1609805B1 (en) | 2012-10-17 |
| JP2006523730A (ja) | 2006-10-19 |
| EP1609805A4 (en) | 2008-05-21 |
| US20060154806A1 (en) | 2006-07-13 |
| US20040229748A1 (en) | 2004-11-18 |
| CA2516693A1 (en) | 2004-09-02 |
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