RU2002124127A - Катализаторы эпоксидирования, содержащие металлы семейства лантаноидов - Google Patents
Катализаторы эпоксидирования, содержащие металлы семейства лантаноидовInfo
- Publication number
- RU2002124127A RU2002124127A RU2002124127/04A RU2002124127A RU2002124127A RU 2002124127 A RU2002124127 A RU 2002124127A RU 2002124127/04 A RU2002124127/04 A RU 2002124127/04A RU 2002124127 A RU2002124127 A RU 2002124127A RU 2002124127 A RU2002124127 A RU 2002124127A
- Authority
- RU
- Russia
- Prior art keywords
- carrier
- compound
- group
- lanthanide
- scandium
- Prior art date
Links
- 229910052747 lanthanoid Inorganic materials 0.000 title claims 5
- 150000002602 lanthanoids Chemical class 0.000 title claims 5
- 239000003054 catalyst Substances 0.000 title claims 2
- 238000006735 epoxidation reaction Methods 0.000 title claims 2
- 229910052751 metal Inorganic materials 0.000 title 1
- 239000002184 metal Substances 0.000 title 1
- 150000002739 metals Chemical class 0.000 title 1
- 150000001875 compounds Chemical class 0.000 claims 6
- 238000000034 method Methods 0.000 claims 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 4
- 229910052804 chromium Inorganic materials 0.000 claims 4
- 239000011651 chromium Substances 0.000 claims 4
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims 4
- 229910052737 gold Inorganic materials 0.000 claims 4
- 239000010931 gold Substances 0.000 claims 4
- 229910052735 hafnium Inorganic materials 0.000 claims 4
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims 4
- 229910052750 molybdenum Inorganic materials 0.000 claims 4
- 239000011733 molybdenum Substances 0.000 claims 4
- 229910052758 niobium Inorganic materials 0.000 claims 4
- 239000010955 niobium Substances 0.000 claims 4
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims 4
- 239000002245 particle Substances 0.000 claims 4
- 229910052706 scandium Inorganic materials 0.000 claims 4
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 claims 4
- 229910052715 tantalum Inorganic materials 0.000 claims 4
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims 4
- 229910052719 titanium Inorganic materials 0.000 claims 4
- 239000010936 titanium Substances 0.000 claims 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims 4
- 229910052721 tungsten Inorganic materials 0.000 claims 4
- 239000010937 tungsten Substances 0.000 claims 4
- 229910052720 vanadium Inorganic materials 0.000 claims 4
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims 4
- 229910052727 yttrium Inorganic materials 0.000 claims 4
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims 4
- 229910052726 zirconium Inorganic materials 0.000 claims 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 2
- 150000001336 alkenes Chemical class 0.000 claims 2
- 238000006243 chemical reaction Methods 0.000 claims 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 claims 1
- 229910001882 dioxygen Inorganic materials 0.000 claims 1
- -1 hydrogen Chemical compound 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 238000003980 solgel method Methods 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
- B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Epoxy Compounds (AREA)
Claims (6)
1. Способ эпоксидирования олефинов, использующий молекулярный кислород и водород, отличающийся тем, что в качестве катализатора применяется соединение, включающее золото, предпочтительно в виде частиц указанного в нанометрах размера, на носителе, где носитель содержит один или более элемент(ов), выбранных из группы, состоящей из скандия, иттрия, лантаноида, циркония, гафния, ванадия, ниобия, тантала, хрома, молибдена и/или вольфрама, и, по существу, не содержит титана.
2. Способ по п.1, отличающийся тем, что олефин выбирается из группы, состоящей из пропена и бутена.
3. Соединение, включающее золото, предпочтительно в виде частиц указанного в нанометрах размера, на носителе, где носитель содержит один или более элемент(ов), выбранных из группы, состоящей из скандия, иттрия, лантаноида, циркония, гафния, ванадия, ниобия, тантала, хрома, молибдена и/или вольфрама, и, по существу, не содержит титана.
4. Способ получения соединения по пп.1 и/или 3, отличающийся тем, что частицы золота указанного в нанометрах размера осаждаются на носителе, где носитель содержит один или более элемент(ов), выбранных из группы, состоящей из скандия, иттрия, лантаноида, циркония, гафния, ванадия, ниобия, тантала, хрома, молибдена и/или вольфрама, и, по существу, не содержит титана.
5. Способ получения соединения по п.4, отличающийся тем, что соединение получают с применением процесса золь-гель.
6. Способ катализирования химической реакции путем проведения упомянутой химической реакции в присутствии соединения, включающего золото, предпочтительно в виде частиц указанного в нанометрах размера, на носителе, где носитель содержит один или более элемент(ов), выбранных из группы, состоящей из скандия, иттрия, лантаноида, циркония, гафния, ванадия, ниобия, тантала, хрома, молибдена и/или вольфрама, и, по существу, не содержит титана.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP00102558A EP1125632A1 (en) | 2000-02-07 | 2000-02-07 | Process for the epoxidation of olefins using gold-containing catalysts |
| EP00102558.4 | 2000-02-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2002124127A true RU2002124127A (ru) | 2004-01-10 |
Family
ID=8167795
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2002124127/04A RU2002124127A (ru) | 2000-02-07 | 2001-01-25 | Катализаторы эпоксидирования, содержащие металлы семейства лантаноидов |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US6825366B2 (ru) |
| EP (2) | EP1125632A1 (ru) |
| JP (1) | JP2003523974A (ru) |
| KR (1) | KR20020082223A (ru) |
| CN (1) | CN1198684C (ru) |
| AU (1) | AU2001233708A1 (ru) |
| BR (1) | BR0108092A (ru) |
| CA (1) | CA2399114A1 (ru) |
| CZ (1) | CZ20022697A3 (ru) |
| HK (1) | HK1053076A1 (ru) |
| HU (1) | HUP0300554A2 (ru) |
| MX (1) | MXPA02007586A (ru) |
| PL (1) | PL364934A1 (ru) |
| RU (1) | RU2002124127A (ru) |
| TW (1) | TWI257322B (ru) |
| WO (1) | WO2001058585A1 (ru) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10247784A1 (de) * | 2002-10-14 | 2004-04-22 | Bayer Ag | Ein Katalysator für die Oxidation von Kohlenwasserstoffen zu Epoxiden |
| TWI261533B (en) * | 2002-12-31 | 2006-09-11 | Ind Tech Res Inst | Nano-gold catalyst and preparation of nano-gold catalyst |
| DE102006058800A1 (de) * | 2006-12-13 | 2008-06-19 | Wacker Chemie Ag | Verfahren zur Herstellung von Katalysatoren und deren Verwendung für die Gasphasenoxidation von Olefinen |
| CN102015100A (zh) * | 2008-04-30 | 2011-04-13 | 陶氏技术投资有限公司 | 多孔体前体,成形多孔体,用于制备它们的方法和基于它们的最终用途产品 |
| RU2016143167A (ru) * | 2014-04-22 | 2018-05-23 | Сабик Глобал Текнолоджис Б.В. | Способ синтеза наночастиц золота (au) на носителе для реакций эпоксидирования |
| CN106964337B (zh) * | 2016-01-14 | 2019-09-20 | 万华化学集团股份有限公司 | 一种环氧化催化剂的制备方法、及制备的环氧化催化剂及其应用 |
| CN113956216B (zh) * | 2021-11-09 | 2024-01-23 | 万华化学集团股份有限公司 | 一种环氧苯乙烷及其制备方法 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4447231A1 (de) * | 1994-12-30 | 1996-07-04 | Hoechst Ag | Verfahren zur Herstellung von Epoxiden durch Oxidation von Olefinen mit Luft oder Sauerstoff |
| IN169589B (ru) * | 1986-10-31 | 1991-11-16 | Shell Int Research | |
| US5051395A (en) * | 1989-09-25 | 1991-09-24 | Union Carbide Chemicals And Plastics Technology Corporation | Alkylene oxide catalysts having enhanced activity and/or efficiency |
| JP2615432B2 (ja) | 1994-10-28 | 1997-05-28 | 工業技術院長 | 金−酸化チタン含有触媒による炭化水素の部分酸化方法 |
| WO1997034692A1 (fr) | 1996-03-21 | 1997-09-25 | Japan As Represented By Director General Of Agency Of Industrial Science And Technology | Catalyseurs et procede pour l'oxydation partielle des hydrocarbures |
| KR100449422B1 (ko) | 1996-07-01 | 2005-02-23 | 다우 글로벌 테크놀로지스 인크. | 티타노실리케이트상의금을포함하는촉매조성물및이를사용하는올레핀옥사이드의제조방법 |
| US5703254A (en) * | 1996-10-02 | 1997-12-30 | Arco Chemical Technology, L.P. | Propylene oxide process using mixed precious metal catalyst supported on alkaline earth metal carbonate |
| DE69731363T2 (de) * | 1996-12-25 | 2005-12-22 | Agency Of Industrial Science And Technology | Verfahren zur Epoxid-Herstellung und Katalysator für die Verwendung darin |
| IT1298126B1 (it) | 1998-01-15 | 1999-12-20 | Enichem Spa | Procedimento per la preparazione di epossidi olefinici |
| DE19804712A1 (de) | 1998-02-06 | 1999-08-12 | Bayer Ag | Verfahren zur Standzeitverlängerung von mit Goldteilen belegten Trägerkatalysatoren für die Oxidation ungesättigter Kohlenwasserstoffe |
| IT1298337B1 (it) | 1998-03-05 | 1999-12-20 | Enichem Spa | Procedimento per la preparazione di epossidi olefinici. |
| US5939569A (en) * | 1998-03-10 | 1999-08-17 | Jones; C. Andrew | Epoxidation process |
-
2000
- 2000-02-07 EP EP00102558A patent/EP1125632A1/en not_active Withdrawn
-
2001
- 2001-01-08 TW TW090100322A patent/TWI257322B/zh not_active IP Right Cessation
- 2001-01-25 US US10/203,149 patent/US6825366B2/en not_active Expired - Fee Related
- 2001-01-25 HU HU0300554A patent/HUP0300554A2/hu unknown
- 2001-01-25 CN CNB01804588XA patent/CN1198684C/zh not_active Expired - Fee Related
- 2001-01-25 RU RU2002124127/04A patent/RU2002124127A/ru not_active Application Discontinuation
- 2001-01-25 MX MXPA02007586A patent/MXPA02007586A/es unknown
- 2001-01-25 KR KR1020027009986A patent/KR20020082223A/ko not_active Application Discontinuation
- 2001-01-25 WO PCT/EP2001/000809 patent/WO2001058585A1/en not_active Application Discontinuation
- 2001-01-25 EP EP01905685A patent/EP1257357A1/en not_active Withdrawn
- 2001-01-25 CA CA002399114A patent/CA2399114A1/en not_active Abandoned
- 2001-01-25 BR BR0108092-0A patent/BR0108092A/pt not_active IP Right Cessation
- 2001-01-25 AU AU2001233708A patent/AU2001233708A1/en not_active Abandoned
- 2001-01-25 JP JP2001557684A patent/JP2003523974A/ja active Pending
- 2001-01-25 CZ CZ20022697A patent/CZ20022697A3/cs unknown
- 2001-01-25 PL PL01364934A patent/PL364934A1/xx unknown
-
2003
- 2003-07-25 HK HK03105372.4A patent/HK1053076A1/zh unknown
Also Published As
| Publication number | Publication date |
|---|---|
| HK1053076A1 (zh) | 2003-10-10 |
| BR0108092A (pt) | 2002-10-29 |
| EP1257357A1 (en) | 2002-11-20 |
| EP1125632A1 (en) | 2001-08-22 |
| CA2399114A1 (en) | 2001-08-16 |
| CN1418129A (zh) | 2003-05-14 |
| CN1198684C (zh) | 2005-04-27 |
| US6825366B2 (en) | 2004-11-30 |
| TWI257322B (en) | 2006-07-01 |
| HUP0300554A2 (hu) | 2003-07-28 |
| AU2001233708A1 (en) | 2001-08-20 |
| KR20020082223A (ko) | 2002-10-30 |
| WO2001058585A1 (en) | 2001-08-16 |
| PL364934A1 (en) | 2004-12-27 |
| CZ20022697A3 (cs) | 2003-01-15 |
| JP2003523974A (ja) | 2003-08-12 |
| US20030060643A1 (en) | 2003-03-27 |
| MXPA02007586A (es) | 2003-01-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FA92 | Acknowledgement of application withdrawn (lack of supplementary materials submitted) |
Effective date: 20050413 |