RO81241B - Procedeu pentru reducerea alcoxizilor metalelor de tranzitie - Google Patents

Procedeu pentru reducerea alcoxizilor metalelor de tranzitie

Info

Publication number
RO81241B
RO81241B RO100413A RO10041380A RO81241B RO 81241 B RO81241 B RO 81241B RO 100413 A RO100413 A RO 100413A RO 10041380 A RO10041380 A RO 10041380A RO 81241 B RO81241 B RO 81241B
Authority
RO
Romania
Prior art keywords
transition metal
tetravalent
reducing transition
valency
metal alcoxides
Prior art date
Application number
RO100413A
Other languages
English (en)
Other versions
RO81241A (ro
Inventor
Alberto Greco
Guglielmo Bertolini
Original Assignee
Anic S.P.A.
Snamprogetti S.P.A.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anic S.P.A., Snamprogetti S.P.A. filed Critical Anic S.P.A.
Publication of RO81241B publication Critical patent/RO81241B/ro
Publication of RO81241A publication Critical patent/RO81241A/ro

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/68—Preparation of metal alcoholates
    • C07C29/685—Preparation of metal alcoholates by converting O-metal groups to other O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

Inventia se refera la un procedeu de reducere a alcoxizii metalelor de tranzitie, selectate dintre: Ti-tetravalent, V tetravalent si pentavalent, Zr tetravalent, la alcoxizii corespunzatori cu valenta inferioara prin reactia dintre acesti alcoxizi ai metalelor cu valenta superioara în faza lichida, cu vapori ai metalelor cu valenta superioara în faza lichida, cu vapori ai metalelor alese dintre calciu, magneziu, aluminiu, la o temperatura de -80...+20 degree C. S-au obtinut astfel catalizatori foarte eficienti pentru polimerizarea compusilor nesaturati.
RO80100413A 1979-03-07 1980-03-07 Procedeu pentru reducerea alcoxizilor metalelor de tranzitie RO81241A (ro)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT20798/79A IT1113421B (it) 1979-03-07 1979-03-07 Metodo per la riduzione di alcossidi metallici e impiego dei composti cosi' ottenuti

Publications (2)

Publication Number Publication Date
RO81241B true RO81241B (ro) 1983-05-30
RO81241A RO81241A (ro) 1983-06-01

Family

ID=11172213

Family Applications (1)

Application Number Title Priority Date Filing Date
RO80100413A RO81241A (ro) 1979-03-07 1980-03-07 Procedeu pentru reducerea alcoxizilor metalelor de tranzitie

Country Status (31)

Country Link
US (1) US4333881A (ro)
JP (1) JPS55160784A (ro)
AR (1) AR226174A1 (ro)
AT (1) AT371796B (ro)
AU (1) AU528925B2 (ro)
BE (1) BE882137A (ro)
BR (1) BR8001392A (ro)
CA (1) CA1133018A (ro)
CH (1) CH646932A5 (ro)
CS (1) CS276219B6 (ro)
DD (1) DD149369A5 (ro)
DE (1) DE3008909C2 (ro)
DK (1) DK97380A (ro)
ES (1) ES489717A0 (ro)
FR (1) FR2450845B1 (ro)
GB (1) GB2046740B (ro)
HU (1) HU182108B (ro)
IE (1) IE49524B1 (ro)
IL (1) IL59534A (ro)
IN (2) IN154572B (ro)
IT (1) IT1113421B (ro)
LU (1) LU82228A1 (ro)
MX (1) MX153451A (ro)
NL (1) NL8001390A (ro)
NO (2) NO157579C (ro)
PT (1) PT70912A (ro)
RO (1) RO81241A (ro)
SE (2) SE448460B (ro)
SU (1) SU1319782A3 (ro)
YU (2) YU41035B (ro)
ZA (1) ZA801254B (ro)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4594439A (en) * 1980-08-06 1986-06-10 The Board Of Trustees Of The Leland Stanford Jr. University Method for asymmetric epoxidation
IT1139827B (it) * 1980-11-24 1986-09-24 Nat Distillers Chem Corp Composti intermetallici di alcossidi di ossidi di metalli di transizione polimeri
US4513095A (en) * 1980-11-24 1985-04-23 National Distillers And Chemical Corporation Intermetallic compounds of polymeric transition metal oxide alkoxides and catalytic use thereof
JPS57193491A (en) * 1981-05-25 1982-11-27 Nippon Soda Co Ltd Complex oxyalkoxide and its preparation
US4526724A (en) * 1983-09-30 1985-07-02 Standard Oil Company (Indiana) Process for the preparation of zero valent bis-arene transition metal compounds
US4609755A (en) * 1983-10-20 1986-09-02 Allied Colloids Limited Synthesis of vinyl esters
US4727165A (en) * 1983-11-18 1988-02-23 Phillips Petroleum Company Catalytically hydrogenated decomposible molybdenum compounds as oil hydrofining agents
US4740570A (en) * 1985-01-18 1988-04-26 E. I. Du Pont De Nemours And Company Metal halide vaporization into diluents
US4650778A (en) * 1985-01-18 1987-03-17 E. I. Du Pont De Nemours And Company Metal halide vaporization into diluents
US5039636A (en) * 1990-08-10 1991-08-13 Hercules Incorporated Preparation of aluminum titanate from an organometallic oligomer
US5536857A (en) * 1994-07-05 1996-07-16 Ford Motor Company Single source volatile precursor for SiO2.TiO2 powders and films
DE19545444A1 (de) * 1995-12-06 1997-06-12 Du Pont Alkoxide mit Erdalkalien und Titan, Zirkon und/oder Hafnium, deren Herstellung und Verwendung
RU2377245C1 (ru) * 2008-03-26 2009-12-27 Государственное образовательное учреждение высшего профессионального образования Курский государственный технический университет (КурскГТУ) Способ получения алкоголятов марганца
RU2471763C1 (ru) * 2011-12-27 2013-01-10 Федеральное государственное бюджетное учреждение науки Институт химии высокочистых веществ им. Г.Г. Девятых Российской академии наук (ИХВВ РАН) Способ получения двойного изопропилата магния-алюминия
RU2603771C1 (ru) * 2015-05-05 2016-11-27 Федеральное государственное унитарное предприятие "Ордена Ленина и ордена Трудового Красного Знамени Научно-исследовательский институт синтетического каучука имени академика С.В. Лебедева" (ФГУП НИИСК) Способ получения смешанных барийсодержащих алкоголятов

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE755750A (fr) * 1969-09-06 1971-02-15 Dynamit Nobel Ag Procede de preparation simultanee d'alcoolates d'alcalis et de composescomplexes solubles beta-dicetoniques du titane trivalent
GB1415508A (en) * 1972-07-24 1975-11-26 Albright & Wilson Diarene chromium compounds
GR60862B (en) * 1976-01-30 1978-09-01 Snam Progetti Process for olephines polymerization and compositions suitable for the polymerization

Also Published As

Publication number Publication date
GB2046740B (en) 1983-03-09
NO157579C (no) 1988-04-13
PT70912A (en) 1980-04-01
FR2450845A1 (fr) 1980-10-03
HU182108B (en) 1983-12-28
BE882137A (fr) 1980-09-08
AU5589780A (en) 1980-09-11
NO800628L (no) 1980-09-08
AT371796B (de) 1983-07-25
IN154572B (ro) 1984-11-10
NL8001390A (nl) 1980-09-09
LU82228A1 (fr) 1980-09-24
ATA124680A (de) 1982-12-15
DD149369A5 (de) 1981-07-08
YU1683A (en) 1983-12-31
YU42065B (en) 1988-04-30
SU1319782A3 (ru) 1987-06-23
MX153451A (es) 1986-10-16
IL59534A (en) 1985-10-31
AR226174A1 (es) 1982-06-15
SE448460B (sv) 1987-02-23
IT7920798A0 (it) 1979-03-07
CA1133018A (en) 1982-10-05
GB2046740A (en) 1980-11-19
IE800386L (en) 1980-09-07
ES8104328A1 (es) 1981-04-01
NO850883L (no) 1980-09-08
SE8500363L (sv) 1985-01-25
IE49524B1 (en) 1985-10-16
IN156280B (ro) 1985-06-15
DE3008909A1 (de) 1980-09-11
DK97380A (da) 1980-09-08
ES489717A0 (es) 1981-04-01
SE8500363D0 (sv) 1985-01-25
YU63880A (en) 1983-02-28
DE3008909C2 (de) 1983-06-09
CH646932A5 (it) 1984-12-28
CS276219B6 (en) 1992-04-15
JPS55160784A (en) 1980-12-13
SE8001727L (sv) 1980-09-08
SE460478B (sv) 1989-10-16
ZA801254B (en) 1981-03-25
RO81241A (ro) 1983-06-01
FR2450845B1 (fr) 1985-10-18
BR8001392A (pt) 1980-11-11
IT1113421B (it) 1986-01-20
US4333881A (en) 1982-06-08
AU528925B2 (en) 1983-05-19
JPS6340193B2 (ro) 1988-08-10
NO157579B (no) 1988-01-04
YU41035B (en) 1986-10-31

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