PT1297039E - Floculantes poliméricos estruturalmente modificados - Google Patents
Floculantes poliméricos estruturalmente modificados Download PDFInfo
- Publication number
- PT1297039E PT1297039E PT01924646T PT01924646T PT1297039E PT 1297039 E PT1297039 E PT 1297039E PT 01924646 T PT01924646 T PT 01924646T PT 01924646 T PT01924646 T PT 01924646T PT 1297039 E PT1297039 E PT 1297039E
- Authority
- PT
- Portugal
- Prior art keywords
- polymer
- water
- polymers
- quot
- polymerization
- Prior art date
Links
- 229920000642 polymer Polymers 0.000 title claims description 302
- 239000008394 flocculating agent Substances 0.000 title description 12
- 239000000178 monomer Substances 0.000 claims description 96
- 239000000203 mixture Substances 0.000 claims description 83
- 239000000243 solution Substances 0.000 claims description 77
- 238000006116 polymerization reaction Methods 0.000 claims description 74
- 239000007864 aqueous solution Substances 0.000 claims description 60
- 238000000034 method Methods 0.000 claims description 58
- 150000003839 salts Chemical group 0.000 claims description 46
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 41
- 239000003607 modifier Substances 0.000 claims description 35
- 229920003169 water-soluble polymer Polymers 0.000 claims description 34
- 239000006185 dispersion Substances 0.000 claims description 33
- 239000003795 chemical substances by application Substances 0.000 claims description 31
- 238000012546 transfer Methods 0.000 claims description 28
- 125000002091 cationic group Chemical group 0.000 claims description 25
- 239000003431 cross linking reagent Substances 0.000 claims description 24
- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 claims description 17
- 229910001379 sodium hypophosphite Inorganic materials 0.000 claims description 17
- WQHCGPGATAYRLN-UHFFFAOYSA-N chloromethane;2-(dimethylamino)ethyl prop-2-enoate Chemical compound ClC.CN(C)CCOC(=O)C=C WQHCGPGATAYRLN-UHFFFAOYSA-N 0.000 claims description 16
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Chemical group OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 15
- 238000010526 radical polymerization reaction Methods 0.000 claims description 14
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical group COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 13
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 claims description 13
- 125000000129 anionic group Chemical group 0.000 claims description 13
- 239000000839 emulsion Substances 0.000 claims description 12
- 239000011734 sodium Chemical group 0.000 claims description 11
- NJSSICCENMLTKO-HRCBOCMUSA-N [(1r,2s,4r,5r)-3-hydroxy-4-(4-methylphenyl)sulfonyloxy-6,8-dioxabicyclo[3.2.1]octan-2-yl] 4-methylbenzenesulfonate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)O[C@H]1C(O)[C@@H](OS(=O)(=O)C=2C=CC(C)=CC=2)[C@@H]2OC[C@H]1O2 NJSSICCENMLTKO-HRCBOCMUSA-N 0.000 claims description 8
- 239000000499 gel Substances 0.000 claims description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 150000001298 alcohols Chemical class 0.000 claims description 4
- 150000001735 carboxylic acids Chemical class 0.000 claims description 4
- 229910001510 metal chloride Inorganic materials 0.000 claims description 4
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims description 4
- 150000003464 sulfur compounds Chemical class 0.000 claims description 4
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 claims description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical group CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 3
- WPKYZIPODULRBM-UHFFFAOYSA-N azane;prop-2-enoic acid Chemical group N.OC(=O)C=C WPKYZIPODULRBM-UHFFFAOYSA-N 0.000 claims description 3
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 claims description 3
- DZGUJOWBVDZNNF-UHFFFAOYSA-N azanium;2-methylprop-2-enoate Chemical group [NH4+].CC(=C)C([O-])=O DZGUJOWBVDZNNF-UHFFFAOYSA-N 0.000 claims description 2
- 230000000379 polymerizing effect Effects 0.000 claims description 2
- UZNHKBFIBYXPDV-UHFFFAOYSA-N trimethyl-[3-(2-methylprop-2-enoylamino)propyl]azanium;chloride Chemical group [Cl-].CC(=C)C(=O)NCCC[N+](C)(C)C UZNHKBFIBYXPDV-UHFFFAOYSA-N 0.000 claims description 2
- OEIXGLMQZVLOQX-UHFFFAOYSA-N trimethyl-[3-(prop-2-enoylamino)propyl]azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCCNC(=O)C=C OEIXGLMQZVLOQX-UHFFFAOYSA-N 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 description 65
- 235000002639 sodium chloride Nutrition 0.000 description 52
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 49
- 239000007787 solid Substances 0.000 description 38
- 230000014759 maintenance of location Effects 0.000 description 34
- 239000000126 substance Substances 0.000 description 33
- 239000012071 phase Substances 0.000 description 32
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 30
- 230000000977 initiatory effect Effects 0.000 description 27
- 238000004519 manufacturing process Methods 0.000 description 27
- 239000004280 Sodium formate Substances 0.000 description 25
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 25
- 235000019254 sodium formate Nutrition 0.000 description 25
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 24
- 235000012216 bentonite Nutrition 0.000 description 24
- 101150000595 CLMP gene Proteins 0.000 description 22
- 101100382322 Drosophila melanogaster Acam gene Proteins 0.000 description 22
- 239000011859 microparticle Substances 0.000 description 21
- 239000002002 slurry Substances 0.000 description 20
- 239000000440 bentonite Substances 0.000 description 19
- 229910000278 bentonite Inorganic materials 0.000 description 19
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 19
- -1 dialkylaminoalkyl acrylate Chemical compound 0.000 description 19
- 229920001577 copolymer Polymers 0.000 description 18
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 18
- 238000012360 testing method Methods 0.000 description 18
- 238000011282 treatment Methods 0.000 description 18
- LXEKPEMOWBOYRF-UHFFFAOYSA-N [2-[(1-azaniumyl-1-imino-2-methylpropan-2-yl)diazenyl]-2-methylpropanimidoyl]azanium;dichloride Chemical compound Cl.Cl.NC(=N)C(C)(C)N=NC(C)(C)C(N)=N LXEKPEMOWBOYRF-UHFFFAOYSA-N 0.000 description 17
- 239000012986 chain transfer agent Substances 0.000 description 17
- 229910052757 nitrogen Inorganic materials 0.000 description 17
- 230000009467 reduction Effects 0.000 description 17
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 16
- 239000000123 paper Substances 0.000 description 16
- 239000000047 product Substances 0.000 description 16
- 238000003756 stirring Methods 0.000 description 16
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 15
- 230000008569 process Effects 0.000 description 15
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 14
- 238000005189 flocculation Methods 0.000 description 14
- 230000016615 flocculation Effects 0.000 description 14
- 239000007788 liquid Substances 0.000 description 14
- 239000011541 reaction mixture Substances 0.000 description 14
- 238000004132 cross linking Methods 0.000 description 13
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 12
- 239000002245 particle Substances 0.000 description 12
- 239000004094 surface-active agent Substances 0.000 description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 11
- ZWAPMFBHEQZLGK-UHFFFAOYSA-N 5-(dimethylamino)-2-methylidenepentanamide Chemical compound CN(C)CCCC(=C)C(N)=O ZWAPMFBHEQZLGK-UHFFFAOYSA-N 0.000 description 10
- 239000004971 Cross linker Substances 0.000 description 10
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 10
- 230000008859 change Effects 0.000 description 10
- 239000000725 suspension Substances 0.000 description 10
- 239000004815 dispersion polymer Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 239000003921 oil Substances 0.000 description 9
- 238000010926 purge Methods 0.000 description 9
- 239000003643 water by type Substances 0.000 description 9
- OZAIFHULBGXAKX-VAWYXSNFSA-N AIBN Substances N#CC(C)(C)\N=N\C(C)(C)C#N OZAIFHULBGXAKX-VAWYXSNFSA-N 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 239000000654 additive Substances 0.000 description 8
- 239000008367 deionised water Substances 0.000 description 8
- 229910021641 deionized water Inorganic materials 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 8
- 239000012299 nitrogen atmosphere Substances 0.000 description 8
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 8
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 7
- 239000004908 Emulsion polymer Substances 0.000 description 7
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 description 7
- 239000001361 adipic acid Substances 0.000 description 7
- 235000011037 adipic acid Nutrition 0.000 description 7
- CEJFYGPXPSZIID-UHFFFAOYSA-N chloromethylbenzene;2-(dimethylamino)ethyl prop-2-enoate Chemical group ClCC1=CC=CC=C1.CN(C)CCOC(=O)C=C CEJFYGPXPSZIID-UHFFFAOYSA-N 0.000 description 7
- 238000004090 dissolution Methods 0.000 description 7
- 238000001035 drying Methods 0.000 description 7
- 230000003311 flocculating effect Effects 0.000 description 7
- 238000010904 focused beam reflectance measurement Methods 0.000 description 7
- 150000003254 radicals Chemical class 0.000 description 7
- 239000007762 w/o emulsion Substances 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 229920002472 Starch Polymers 0.000 description 6
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 6
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 6
- 235000011130 ammonium sulphate Nutrition 0.000 description 6
- 239000006085 branching agent Substances 0.000 description 6
- 239000000701 coagulant Substances 0.000 description 6
- 238000009300 dissolved air flotation Methods 0.000 description 6
- 239000003999 initiator Substances 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 239000010690 paraffinic oil Substances 0.000 description 6
- 239000010802 sludge Substances 0.000 description 6
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 6
- 239000008107 starch Substances 0.000 description 6
- 235000019698 starch Nutrition 0.000 description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 5
- 239000004809 Teflon Substances 0.000 description 5
- 229920006362 Teflon® Polymers 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 229920006322 acrylamide copolymer Polymers 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 239000003245 coal Substances 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 239000000835 fiber Substances 0.000 description 5
- 239000000945 filler Substances 0.000 description 5
- 230000002209 hydrophobic effect Effects 0.000 description 5
- 239000004816 latex Substances 0.000 description 5
- 229920000126 latex Polymers 0.000 description 5
- QYZFTMMPKCOTAN-UHFFFAOYSA-N n-[2-(2-hydroxyethylamino)ethyl]-2-[[1-[2-(2-hydroxyethylamino)ethylamino]-2-methyl-1-oxopropan-2-yl]diazenyl]-2-methylpropanamide Chemical compound OCCNCCNC(=O)C(C)(C)N=NC(C)(C)C(=O)NCCNCCO QYZFTMMPKCOTAN-UHFFFAOYSA-N 0.000 description 5
- 238000004062 sedimentation Methods 0.000 description 5
- 239000011780 sodium chloride Substances 0.000 description 5
- 229910052938 sodium sulfate Inorganic materials 0.000 description 5
- 235000011152 sodium sulphate Nutrition 0.000 description 5
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 4
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 230000009471 action Effects 0.000 description 4
- 229940037003 alum Drugs 0.000 description 4
- 238000005352 clarification Methods 0.000 description 4
- 239000000706 filtrate Substances 0.000 description 4
- 235000019253 formic acid Nutrition 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 238000000265 homogenisation Methods 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 239000000376 reactant Substances 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 150000003926 acrylamides Chemical class 0.000 description 3
- 239000002390 adhesive tape Substances 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 229920003118 cationic copolymer Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 230000001112 coagulating effect Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethanethiol Chemical compound CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000006194 liquid suspension Substances 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- BDERNNFJNOPAEC-UHFFFAOYSA-N n-propyl alcohol Natural products CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 3
- 239000004533 oil dispersion Substances 0.000 description 3
- 239000006174 pH buffer Substances 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 229940047670 sodium acrylate Drugs 0.000 description 3
- 239000004317 sodium nitrate Substances 0.000 description 3
- 235000010344 sodium nitrate Nutrition 0.000 description 3
- KOUDKOMXLMXFKX-UHFFFAOYSA-N sodium oxido(oxo)phosphanium hydrate Chemical compound O.[Na+].[O-][PH+]=O KOUDKOMXLMXFKX-UHFFFAOYSA-N 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- 239000002351 wastewater Substances 0.000 description 3
- PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 description 2
- WYGWHHGCAGTUCH-UHFFFAOYSA-N 2-[(2-cyano-4-methylpentan-2-yl)diazenyl]-2,4-dimethylpentanenitrile Chemical compound CC(C)CC(C)(C#N)N=NC(C)(C#N)CC(C)C WYGWHHGCAGTUCH-UHFFFAOYSA-N 0.000 description 2
- BTYIFQSAIPDZQW-UHFFFAOYSA-N 2-propan-2-yl-4,5-dihydro-1h-imidazole Chemical compound CC(C)C1=NCCN1 BTYIFQSAIPDZQW-UHFFFAOYSA-N 0.000 description 2
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 2
- PGFZYOCLSPEKSN-UHFFFAOYSA-N 5,5-dimethyl-1,3-diazabicyclo[2.2.0]hex-3-ene dihydrochloride Chemical compound Cl.Cl.CC1(C)CN2CN=C12 PGFZYOCLSPEKSN-UHFFFAOYSA-N 0.000 description 2
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical class [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 239000011837 N,N-methylenebisacrylamide Substances 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical group OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000012726 Water-in-Oil Emulsion Polymerization Methods 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 239000002671 adjuvant Substances 0.000 description 2
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 2
- 229940073608 benzyl chloride Drugs 0.000 description 2
- 229920006317 cationic polymer Polymers 0.000 description 2
- 239000002738 chelating agent Substances 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 2
- CABNOUKVIDTFBB-UHFFFAOYSA-N chloromethane;prop-2-enamide Chemical compound ClC.NC(=O)C=C CABNOUKVIDTFBB-UHFFFAOYSA-N 0.000 description 2
- 239000008119 colloidal silica Substances 0.000 description 2
- 229920006037 cross link polymer Polymers 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 125000004386 diacrylate group Chemical group 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- 229920006158 high molecular weight polymer Polymers 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 229920000831 ionic polymer Polymers 0.000 description 2
- 238000005065 mining Methods 0.000 description 2
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 description 2
- 229920002401 polyacrylamide Polymers 0.000 description 2
- 229920000867 polyelectrolyte Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000009877 rendering Methods 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 2
- 235000019345 sodium thiosulphate Nutrition 0.000 description 2
- BWYYYTVSBPRQCN-UHFFFAOYSA-M sodium;ethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=C BWYYYTVSBPRQCN-UHFFFAOYSA-M 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 238000010561 standard procedure Methods 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- VPYJNCGUESNPMV-UHFFFAOYSA-N triallylamine Chemical compound C=CCN(CC=C)CC=C VPYJNCGUESNPMV-UHFFFAOYSA-N 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 1
- FDRMJKDXTZDBHQ-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate;methyl hydrogen sulfate Chemical group COS([O-])(=O)=O.C[NH+](C)CCOC(=O)C(C)=C FDRMJKDXTZDBHQ-UHFFFAOYSA-N 0.000 description 1
- SSZXAJUPVKMUJH-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate;hydrochloride Chemical class Cl.CN(C)CCOC(=O)C=C SSZXAJUPVKMUJH-UHFFFAOYSA-N 0.000 description 1
- RFPLNIBCLGFBKV-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate;methyl hydrogen sulfate Chemical group COS([O-])(=O)=O.C[NH+](C)CCOC(=O)C=C RFPLNIBCLGFBKV-UHFFFAOYSA-N 0.000 description 1
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 description 1
- HWSSEYVMGDIFMH-UHFFFAOYSA-N 2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOC(=O)C(C)=C HWSSEYVMGDIFMH-UHFFFAOYSA-N 0.000 description 1
- QBQSKYIIEGLPJT-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.OCCOC(=O)C=C QBQSKYIIEGLPJT-UHFFFAOYSA-N 0.000 description 1
- QENRKQYUEGJNNZ-UHFFFAOYSA-N 2-methyl-1-(prop-2-enoylamino)propane-1-sulfonic acid Chemical compound CC(C)C(S(O)(=O)=O)NC(=O)C=C QENRKQYUEGJNNZ-UHFFFAOYSA-N 0.000 description 1
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- RUACIFFMSHZUKZ-UHFFFAOYSA-O 3-Acrylamidopropyl trimethylammonium Chemical compound C[N+](C)(C)CCCNC(=O)C=C RUACIFFMSHZUKZ-UHFFFAOYSA-O 0.000 description 1
- GNSFRPWPOGYVLO-UHFFFAOYSA-N 3-hydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCO GNSFRPWPOGYVLO-UHFFFAOYSA-N 0.000 description 1
- NYUTUWAFOUJLKI-UHFFFAOYSA-N 3-prop-2-enoyloxypropane-1-sulfonic acid Chemical compound OS(=O)(=O)CCCOC(=O)C=C NYUTUWAFOUJLKI-UHFFFAOYSA-N 0.000 description 1
- HDWNKEWYEDOKIZ-UHFFFAOYSA-N 5-(diethylamino)-2-methylidenepentanamide Chemical compound CCN(CC)CCCC(=C)C(N)=O HDWNKEWYEDOKIZ-UHFFFAOYSA-N 0.000 description 1
- NLHGHROUDDOASY-UHFFFAOYSA-N 5-(dimethylamino)-2-methylidenepentanamide;methyl hydrogen sulfate Chemical compound COS(O)(=O)=O.CN(C)CCCC(=C)C(N)=O NLHGHROUDDOASY-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 101100020619 Arabidopsis thaliana LATE gene Proteins 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- ABNOQBKRHYWXCF-UHFFFAOYSA-N C(Cl)Cl.C(C(=C)C)(=O)OCCN(C)C Chemical group C(Cl)Cl.C(C(=C)C)(=O)OCCN(C)C ABNOQBKRHYWXCF-UHFFFAOYSA-N 0.000 description 1
- YOLNLPIJKSBMCF-UHFFFAOYSA-N COC(COC=C[SiH3])OC Chemical compound COC(COC=C[SiH3])OC YOLNLPIJKSBMCF-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 241000724205 Rice stripe tenuivirus Species 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- 239000004990 Smectic liquid crystal Substances 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical class CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 229940048053 acrylate Drugs 0.000 description 1
- 229920006397 acrylic thermoplastic Polymers 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000001356 alkyl thiols Chemical class 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 229910052782 aluminium Chemical class 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical class [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- UKXSKSHDVLQNKG-UHFFFAOYSA-N benzilic acid Chemical compound C=1C=CC=CC=1C(O)(C(=O)O)C1=CC=CC=C1 UKXSKSHDVLQNKG-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 235000011148 calcium chloride Nutrition 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 238000007707 calorimetry Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000002801 charged material Substances 0.000 description 1
- 238000012824 chemical production Methods 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- WBPHXNIYQYJTFJ-UHFFFAOYSA-N chloromethane 5-(dimethylamino)-2-methylpent-2-enoic acid Chemical compound CCl.CN(C)CCC=C(C(=O)O)C WBPHXNIYQYJTFJ-UHFFFAOYSA-N 0.000 description 1
- BHDFTVNXJDZMQK-UHFFFAOYSA-N chloromethane;2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical class ClC.CN(C)CCOC(=O)C(C)=C BHDFTVNXJDZMQK-UHFFFAOYSA-N 0.000 description 1
- ZTUMLBMROBHIIH-UHFFFAOYSA-N chloromethylbenzene;2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical group ClCC1=CC=CC=C1.CN(C)CCOC(=O)C(C)=C ZTUMLBMROBHIIH-UHFFFAOYSA-N 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- JCRDPEHHTDKTGB-UHFFFAOYSA-N dimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;chloride Chemical group Cl.CN(C)CCOC(=O)C(C)=C JCRDPEHHTDKTGB-UHFFFAOYSA-N 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 150000002019 disulfides Chemical class 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000005188 flotation Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- 238000004442 gravimetric analysis Methods 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000003295 industrial effluent Substances 0.000 description 1
- 239000008235 industrial water Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- DNHVXYDGZKWYNU-UHFFFAOYSA-N lead;hydrate Chemical compound O.[Pb] DNHVXYDGZKWYNU-UHFFFAOYSA-N 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000010297 mechanical methods and process Methods 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 1
- 229940117841 methacrylic acid copolymer Drugs 0.000 description 1
- 229940050176 methyl chloride Drugs 0.000 description 1
- VNLHWLYAOHNSCH-UHFFFAOYSA-N methyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[NH+](C)CC=C VNLHWLYAOHNSCH-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- OVHHHVAVHBHXAK-UHFFFAOYSA-N n,n-diethylprop-2-enamide Chemical compound CCN(CC)C(=O)C=C OVHHHVAVHBHXAK-UHFFFAOYSA-N 0.000 description 1
- 229940088644 n,n-dimethylacrylamide Drugs 0.000 description 1
- YLGYACDQVQQZSW-UHFFFAOYSA-N n,n-dimethylprop-2-enamide Chemical compound CN(C)C(=O)C=C YLGYACDQVQQZSW-UHFFFAOYSA-N 0.000 description 1
- KMLONCKJQMYVCO-UHFFFAOYSA-N n-buta-1,3-dienylacetamide Chemical compound CC(=O)NC=CC=C KMLONCKJQMYVCO-UHFFFAOYSA-N 0.000 description 1
- YRVUCYWJQFRCOB-UHFFFAOYSA-N n-butylprop-2-enamide Chemical compound CCCCNC(=O)C=C YRVUCYWJQFRCOB-UHFFFAOYSA-N 0.000 description 1
- ZQXSMRAEXCEDJD-UHFFFAOYSA-N n-ethenylformamide Chemical compound C=CNC=O ZQXSMRAEXCEDJD-UHFFFAOYSA-N 0.000 description 1
- ILCQQHAOOOVHQJ-UHFFFAOYSA-N n-ethenylprop-2-enamide Chemical compound C=CNC(=O)C=C ILCQQHAOOOVHQJ-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 239000010893 paper waste Substances 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000548 poly(silane) polymer Polymers 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 229920001592 potato starch Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- FJWSMXKFXFFEPV-UHFFFAOYSA-N prop-2-enamide;hydrochloride Chemical compound Cl.NC(=O)C=C FJWSMXKFXFFEPV-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- ROSDSFDQCJNGOL-UHFFFAOYSA-N protonated dimethyl amine Natural products CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 1
- 239000007870 radical polymerization initiator Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229910000275 saponite Inorganic materials 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 125000005624 silicic acid group Chemical class 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- SONHXMAHPHADTF-UHFFFAOYSA-M sodium;2-methylprop-2-enoate Chemical group [Na+].CC(=C)C([O-])=O SONHXMAHPHADTF-UHFFFAOYSA-M 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 239000001593 sorbitan monooleate Substances 0.000 description 1
- 235000011069 sorbitan monooleate Nutrition 0.000 description 1
- 229940035049 sorbitan monooleate Drugs 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- FBWNMEQMRUMQSO-UHFFFAOYSA-N tergitol NP-9 Chemical compound CCCCCCCCCC1=CC=C(OCCOCCOCCOCCOCCOCCOCCOCCOCCO)C=C1 FBWNMEQMRUMQSO-UHFFFAOYSA-N 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- 150000003585 thioureas Chemical class 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical compound [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 description 1
- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/14—Flotation machines
- B03D1/1431—Dissolved air flotation machines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/10—Aqueous solvent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/10—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of amides or imides
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Biotechnology (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Treatment Of Sludge (AREA)
- Polymerisation Methods In General (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/606,581 US6605674B1 (en) | 2000-06-29 | 2000-06-29 | Structurally-modified polymer flocculants |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PT1297039E true PT1297039E (pt) | 2012-06-06 |
Family
ID=24428554
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PT01924646T PT1297039E (pt) | 2000-06-29 | 2001-04-03 | Floculantes poliméricos estruturalmente modificados |
Country Status (21)
| Country | Link |
|---|---|
| US (2) | US6605674B1 (enExample) |
| EP (1) | EP1297039B1 (enExample) |
| JP (1) | JP5078214B2 (enExample) |
| KR (1) | KR100814675B1 (enExample) |
| CN (1) | CN1239544C (enExample) |
| AR (1) | AR030425A1 (enExample) |
| AT (1) | ATE548397T1 (enExample) |
| AU (2) | AU5128201A (enExample) |
| BR (1) | BR0110429A (enExample) |
| CA (1) | CA2406270C (enExample) |
| DK (1) | DK1297039T3 (enExample) |
| ES (1) | ES2382025T3 (enExample) |
| MX (1) | MX227471B (enExample) |
| MY (1) | MY124884A (enExample) |
| NO (1) | NO333034B1 (enExample) |
| NZ (1) | NZ522047A (enExample) |
| PT (1) | PT1297039E (enExample) |
| RU (1) | RU2243240C2 (enExample) |
| TW (1) | TWI275600B (enExample) |
| WO (1) | WO2002002662A1 (enExample) |
| ZA (1) | ZA200208420B (enExample) |
Families Citing this family (137)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6696067B2 (en) * | 2001-04-12 | 2004-02-24 | Ondeo Nalco Company | Cosmetic compositions containing dispersion polymers |
| US20040087717A1 (en) * | 2002-11-04 | 2004-05-06 | Ge Betz, Inc. | Modified polymeric flocculants with improved performance characteristics |
| US8971913B2 (en) * | 2003-06-27 | 2015-03-03 | Qualcomm Incorporated | Method and apparatus for wireless network hybrid positioning |
| DE10337764A1 (de) * | 2003-08-14 | 2005-03-17 | Stockhausen Gmbh | Pulverförmige, wasserlösliche kationische Polymerzusammensetzung, Verfahren zu ihrer Herstellung und ihre Verwendung |
| US8491753B2 (en) * | 2004-10-15 | 2013-07-23 | Nalco Company | Composition and method for improving retention and drainage in papermaking processes by activating microparticles with a promoter-flocculant system |
| US20060084771A1 (en) * | 2004-10-15 | 2006-04-20 | Wong Shing Jane B | Method of preparing modified diallyl-N,N-disubstituted ammonium halide polymers |
| US7473334B2 (en) * | 2004-10-15 | 2009-01-06 | Nalco Company | Method of preparing modified diallyl-N,N-disubstituted ammonium halide polymers |
| EP1940891A1 (en) * | 2005-10-24 | 2008-07-09 | Ciba Holding Inc. | High molecular weight poly(dially dialkyl) ammonium salts |
| DE102005051906A1 (de) * | 2005-10-29 | 2007-05-03 | Basf Construction Polymers Gmbh | Mischpolymer auf Basis olefinischer Sulfonsäuren |
| US7981250B2 (en) * | 2006-09-14 | 2011-07-19 | Kemira Oyj | Method for paper processing |
| US8900641B2 (en) * | 2006-12-28 | 2014-12-02 | Nalco Company | Antimicrobial composition |
| CN101675004B (zh) * | 2007-04-20 | 2013-05-08 | 氰特技术公司 | 含硅聚合物对提高bayer加工中赤泥絮凝的用途 |
| US8088250B2 (en) | 2008-11-26 | 2012-01-03 | Nalco Company | Method of increasing filler content in papermaking |
| US9752283B2 (en) | 2007-09-12 | 2017-09-05 | Ecolab Usa Inc. | Anionic preflocculation of fillers used in papermaking |
| FR2922767B1 (fr) * | 2007-10-24 | 2009-12-18 | Seppic Sa | Procede de preparation d'une composition vaccinale comprenant au moins un antigene et au moins un adjuvant. |
| EP2346786B1 (en) * | 2008-10-17 | 2015-09-16 | Cytec Technology Corporation | Use of silicon-containing polymers for improved flocculation of solids in processes for the production of alumina from bauxite |
| US8865632B1 (en) | 2008-11-10 | 2014-10-21 | Cesi Chemical, Inc. | Drag-reducing copolymer compositions |
| US20100170856A1 (en) * | 2009-01-06 | 2010-07-08 | Branning Merle L | Improvement separation of solids from liquids by the use of quick inverting and dispersing flocculants |
| US8097687B2 (en) | 2009-02-09 | 2012-01-17 | Nalco Company | Multifunctional azo initiators for free radical polymerizations: uses thereof |
| US20100204361A1 (en) | 2009-02-09 | 2010-08-12 | Kurian Pious V | Novel multifunctional azo initiators for free radical polymerizations: methods of preparation |
| CA2777748C (en) | 2009-10-20 | 2017-09-19 | Soane Energy Llc | Proppants for hydraulic fracturing technologies |
| CN101775148B (zh) * | 2009-12-30 | 2011-07-20 | 山东大学 | 一种微凝胶复合水凝胶的制备方法 |
| EA018089B1 (ru) * | 2010-01-12 | 2013-05-30 | Каграман Союн Оглы Гасанов | Сорбент для обезвреживания нефтезагрязненных почвогрунтов |
| US20130048571A1 (en) * | 2010-02-12 | 2013-02-28 | Cytec Technology Corp. | Flocculant compositions containing silicon-containing polymers |
| CN101786647B (zh) * | 2010-03-19 | 2012-05-23 | 常州友邦净水材料有限公司 | 用于去除聚氯化铝中不溶物质的加速沉降型絮凝剂及其制备方法 |
| JP5630782B2 (ja) * | 2010-03-23 | 2014-11-26 | ハイモ株式会社 | 汚泥脱水剤および汚泥脱水方法 |
| KR101154359B1 (ko) * | 2010-04-14 | 2012-06-15 | 주식회사 화성산업 | 유기응결제를 함유한 w/o형 에멀젼 중합체 및 그 제조방법 |
| FI20105813A0 (fi) * | 2010-07-20 | 2010-07-20 | Kemira Oyj | Menetelmä ja järjestelmä vesipitoisen virran ominaisuuksien monitoroimiseksi |
| FI20105814A0 (fi) * | 2010-07-20 | 2010-07-20 | Kemira Oyj | Menetelmä ja järjestelmä vesipitoisten virtojen käsittelemiseksi |
| US8298508B2 (en) * | 2010-08-09 | 2012-10-30 | Nalco Company | Recovery of alumina trihydrate during the bayer process using cross-linked polysaccharides |
| US9199855B2 (en) | 2010-08-09 | 2015-12-01 | Nalco Company | Chemical treatment to improve red mud separation and washing in the bayer process |
| US9102995B2 (en) | 2010-08-09 | 2015-08-11 | Nalco Company | Cross-linked ethylsulfonated dihydroxypropyl cellulose |
| FR2965564B1 (fr) * | 2010-09-30 | 2012-10-26 | Rhodia Operations | Preparation de polymeres hydrophiles de haute masse par polymerisation radicalaire controlee |
| CN102040271A (zh) * | 2010-11-17 | 2011-05-04 | 常州大学 | 聚铁硅型复合无机高分子絮凝剂的沉降剂制备及应用方法 |
| US9297244B2 (en) | 2011-08-31 | 2016-03-29 | Self-Suspending Proppant Llc | Self-suspending proppants for hydraulic fracturing comprising a coating of hydrogel-forming polymer |
| RU2602250C2 (ru) | 2011-08-31 | 2016-11-10 | Селф-Саспендинг Проппант Ллс | Самосуспендирующиеся проппанты для гидравлического разрыва пласта |
| US20140000891A1 (en) | 2012-06-21 | 2014-01-02 | Self-Suspending Proppant Llc | Self-suspending proppants for hydraulic fracturing |
| US9868896B2 (en) | 2011-08-31 | 2018-01-16 | Self-Suspending Proppant Llc | Self-suspending proppants for hydraulic fracturing |
| PL2768779T3 (pl) * | 2011-10-19 | 2019-06-28 | Solenis Technologies Cayman, L.P. | Kompozycja zawierająca niejonowy środek powierzchniowo czynny i polimer jonowy |
| CN103132383B (zh) * | 2011-11-25 | 2017-04-12 | 纳尔科公司 | 在造纸中用于改善纸强度助剂性能的浆料预处理 |
| WO2013153004A1 (en) | 2012-04-13 | 2013-10-17 | Basf Se | New cationic polymers |
| US20130274369A1 (en) | 2012-04-13 | 2013-10-17 | Basf Se | New cationic polymers |
| CN104302739B (zh) | 2012-04-18 | 2016-06-29 | 通用电气公司 | 处理焦化厂中的冲洗液系统的方法 |
| WO2013179139A1 (en) | 2012-05-30 | 2013-12-05 | Kemira Oyj | Compositions and methods of making paper products |
| CN102718302A (zh) * | 2012-06-09 | 2012-10-10 | 四川师范大学 | 一种有机两性高分子絮凝剂及制备方法 |
| CN102774944A (zh) * | 2012-06-10 | 2012-11-14 | 四川师范大学 | 一种有机两性高分子絮凝剂及制备方法 |
| CN102718303A (zh) * | 2012-06-10 | 2012-10-10 | 四川师范大学 | 一种有机共聚两性高分子絮凝剂及制备方法 |
| CN102701355A (zh) * | 2012-06-10 | 2012-10-03 | 四川师范大学 | 一种有机两性高分子絮凝剂及制备方法 |
| CN102701354A (zh) * | 2012-06-10 | 2012-10-03 | 四川师范大学 | 一种有机两性高分子絮凝剂及制备方法 |
| CN102701356A (zh) * | 2012-06-10 | 2012-10-03 | 四川师范大学 | 一种有机两性高分子絮凝剂及制备方法 |
| CN102701357A (zh) * | 2012-06-11 | 2012-10-03 | 四川师范大学 | 一种有机共聚两性高分子絮凝剂及制备方法 |
| CN102701358A (zh) * | 2012-06-11 | 2012-10-03 | 四川师范大学 | 一种水溶性有机共聚两性高分子絮凝剂及制备方法 |
| CN102701359A (zh) * | 2012-06-11 | 2012-10-03 | 四川师范大学 | 一种水溶性有机两性高分子絮凝剂及制备方法 |
| CN102701367A (zh) * | 2012-06-12 | 2012-10-03 | 四川师范大学 | 一种水溶性有机共聚两性高分子絮凝剂及制备方法 |
| CN102701366A (zh) * | 2012-06-12 | 2012-10-03 | 四川师范大学 | 一种有机共聚两性高分子絮凝剂及制备方法 |
| CN102701369A (zh) * | 2012-06-12 | 2012-10-03 | 四川师范大学 | 一种水溶性有机共聚两性高分子絮凝剂及制备方法 |
| CN102701370A (zh) * | 2012-06-12 | 2012-10-03 | 四川师范大学 | 一种水溶性有机共聚两性高分子絮凝剂及制备方法 |
| CN102701361A (zh) * | 2012-06-12 | 2012-10-03 | 四川师范大学 | 一种水溶性有机两性共聚物絮凝剂及制备方法 |
| CN102701364A (zh) * | 2012-06-12 | 2012-10-03 | 四川师范大学 | 一种水溶性有机两性共聚物絮凝剂及制备方法 |
| CN102701368A (zh) * | 2012-06-12 | 2012-10-03 | 四川师范大学 | 一种有机共聚两性高分子絮凝剂及制备方法 |
| CN102689962A (zh) * | 2012-06-12 | 2012-09-26 | 四川师范大学 | 一种水溶性有机两性共聚物絮凝剂及制备方法 |
| CN102701363A (zh) * | 2012-06-12 | 2012-10-03 | 四川师范大学 | 一种有机共聚两性高分子絮凝剂及制备方法 |
| CN102701362A (zh) * | 2012-06-12 | 2012-10-03 | 四川师范大学 | 一种有机两性高分子絮凝剂及制备方法 |
| CN102701371A (zh) * | 2012-06-12 | 2012-10-03 | 四川师范大学 | 一种水溶性有机两性高分子絮凝剂及制备方法 |
| CN102689963A (zh) * | 2012-06-12 | 2012-09-26 | 四川师范大学 | 一种有机共聚两性高分子絮凝剂及制备方法 |
| CN102701360A (zh) * | 2012-06-12 | 2012-10-03 | 四川师范大学 | 一种有机两性高分子絮凝剂及制备方法 |
| CN102718304A (zh) * | 2012-06-13 | 2012-10-10 | 四川师范大学 | 一种水溶性有机共聚两性高分子絮凝剂及制备方法 |
| CN102689967A (zh) * | 2012-06-13 | 2012-09-26 | 四川师范大学 | 一种水溶性有机两性高分子絮凝剂及制备方法 |
| CN102786130A (zh) * | 2012-06-13 | 2012-11-21 | 四川师范大学 | 一种有机两性高分子絮凝剂及制备方法 |
| CN102765792A (zh) * | 2012-06-13 | 2012-11-07 | 四川师范大学 | 一种水溶性有机两性高分子絮凝剂及制备方法 |
| CN102701372A (zh) * | 2012-06-13 | 2012-10-03 | 四川师范大学 | 一种水溶性有机两性高分子絮凝剂及制备方法 |
| CN102757120A (zh) * | 2012-06-13 | 2012-10-31 | 四川师范大学 | 一种水溶性有机两性共聚物絮凝剂及制备方法 |
| CN102701349A (zh) * | 2012-06-13 | 2012-10-03 | 四川师范大学 | 一种水溶性有机两性共聚物絮凝剂及制备方法 |
| CN102701376A (zh) * | 2012-06-13 | 2012-10-03 | 四川师范大学 | 一种水溶性有机两性共聚物絮凝剂及制备方法 |
| CN102795699A (zh) * | 2012-06-13 | 2012-11-28 | 四川师范大学 | 一种水溶性有机两性共聚物絮凝剂及制备方法 |
| CN102718305A (zh) * | 2012-06-13 | 2012-10-10 | 四川师范大学 | 一种水溶性有机两性高分子絮凝剂及制备方法 |
| CN102701374A (zh) * | 2012-06-13 | 2012-10-03 | 四川师范大学 | 一种水溶性有机两性高分子絮凝剂及制备方法 |
| CN102701375A (zh) * | 2012-06-13 | 2012-10-03 | 四川师范大学 | 一种水溶性有机两性高分子絮凝剂及制备方法 |
| CN102701350A (zh) * | 2012-06-13 | 2012-10-03 | 四川师范大学 | 一种水溶性有机两性共聚物絮凝剂及制备方法 |
| CN102689966A (zh) * | 2012-06-13 | 2012-09-26 | 四川师范大学 | 一种有机共聚两性高分子絮凝剂及制备方法 |
| CN102718306A (zh) * | 2012-06-13 | 2012-10-10 | 四川师范大学 | 一种有机共聚两性高分子絮凝剂及制备方法 |
| CN102701373A (zh) * | 2012-06-13 | 2012-10-03 | 四川师范大学 | 一种水溶性有机共聚两性高分子絮凝剂及制备方法 |
| CN102765793A (zh) * | 2012-06-13 | 2012-11-07 | 四川师范大学 | 一种水溶性有机共聚两性高分子絮凝剂及制备方法 |
| CN102689972A (zh) * | 2012-06-14 | 2012-09-26 | 四川师范大学 | 一种有机两性高分子絮凝剂及制备方法 |
| CN102701383A (zh) * | 2012-06-14 | 2012-10-03 | 四川师范大学 | 一种有机共聚两性高分子絮凝剂及制备方法 |
| CN102786125A (zh) * | 2012-06-14 | 2012-11-21 | 四川师范大学 | 一种水溶性有机两性共聚物絮凝剂及制备方法 |
| CN102701381A (zh) * | 2012-06-14 | 2012-10-03 | 四川师范大学 | 一种水溶性有机两性高分子絮凝剂及制备方法 |
| CN102701384A (zh) * | 2012-06-14 | 2012-10-03 | 四川师范大学 | 一种有机两性高分子絮凝剂及制备方法 |
| CN102701382A (zh) * | 2012-06-14 | 2012-10-03 | 四川师范大学 | 一种水溶性有机共聚两性高分子絮凝剂及制备方法 |
| CN102689971A (zh) * | 2012-06-14 | 2012-09-26 | 四川师范大学 | 一种水溶性有机两性共聚物絮凝剂及制备方法 |
| CN102689969A (zh) * | 2012-06-14 | 2012-09-26 | 四川师范大学 | 一种水溶性有机共聚两性高分子絮凝剂及制备方法 |
| CN102701379A (zh) * | 2012-06-14 | 2012-10-03 | 四川师范大学 | 一种有机共聚两性高分子絮凝剂及制备方法 |
| CN102774945A (zh) * | 2012-06-14 | 2012-11-14 | 四川师范大学 | 一种有机两性高分子絮凝剂及制备方法 |
| CN102701377A (zh) * | 2012-06-14 | 2012-10-03 | 四川师范大学 | 一种水溶性有机两性高分子絮凝剂及制备方法 |
| CN102689970A (zh) * | 2012-06-14 | 2012-09-26 | 四川师范大学 | 一种水溶性有机共聚两性高分子絮凝剂及制备方法 |
| CN102765794A (zh) * | 2012-06-14 | 2012-11-07 | 四川师范大学 | 一种水溶性有机两性共聚物絮凝剂及制备方法 |
| CN102786132A (zh) * | 2012-06-15 | 2012-11-21 | 四川师范大学 | 一种水溶性有机共聚两性高分子絮凝剂及制备方法 |
| CN102701386A (zh) * | 2012-06-15 | 2012-10-03 | 四川师范大学 | 一种水溶性有机两性共聚物絮凝剂及制备方法 |
| CN102786131A (zh) * | 2012-06-15 | 2012-11-21 | 四川师范大学 | 一种有机共聚两性高分子絮凝剂及制备方法 |
| CN102701385A (zh) * | 2012-06-15 | 2012-10-03 | 四川师范大学 | 一种水溶性有机两性高分子絮凝剂及制备方法 |
| US9656914B2 (en) | 2013-05-01 | 2017-05-23 | Ecolab Usa Inc. | Rheology modifying agents for slurries |
| US9303360B2 (en) | 2013-08-08 | 2016-04-05 | Ecolab Usa Inc. | Use of nanocrystaline cellulose and polymer grafted nanocrystaline cellulose for increasing retention in papermaking process |
| US9410288B2 (en) | 2013-08-08 | 2016-08-09 | Ecolab Usa Inc. | Use of nanocrystaline cellulose and polymer grafted nanocrystaline cellulose for increasing retention in papermaking process |
| US9034145B2 (en) | 2013-08-08 | 2015-05-19 | Ecolab Usa Inc. | Use of nanocrystaline cellulose and polymer grafted nanocrystaline cellulose for increasing retention, wet strength, and dry strength in papermaking process |
| US10576424B2 (en) * | 2013-09-17 | 2020-03-03 | Bl Technologies, Inc. | Ion exchange polymers and a method for making ion exchange polymers |
| JP2015136648A (ja) * | 2014-01-22 | 2015-07-30 | 壽昭 落合 | 凝集処理方法 |
| AU2014379659B2 (en) | 2014-01-22 | 2017-06-22 | Halliburton Energy Services, Inc. | Clusters of micron-and nano-sized proppant for use in subterranean operations |
| US9834730B2 (en) | 2014-01-23 | 2017-12-05 | Ecolab Usa Inc. | Use of emulsion polymers to flocculate solids in organic liquids |
| US9932521B2 (en) | 2014-03-05 | 2018-04-03 | Self-Suspending Proppant, Llc | Calcium ion tolerant self-suspending proppants |
| CA2959560C (en) * | 2014-08-29 | 2020-02-25 | Solenis Technologies, L.P. | Powdery water-soluble cationic polymer composition |
| CN105696406A (zh) | 2014-11-26 | 2016-06-22 | 埃科莱布美国股份有限公司 | 一种增加纸制品灰分的造纸方法及纸制品 |
| CN105199036A (zh) * | 2015-10-13 | 2015-12-30 | 扬州大学 | 一种丙烯酸铵/丙烯酰胺共聚型乳液絮凝剂及其制备方法 |
| CA3001717A1 (en) | 2015-10-15 | 2017-04-20 | Ecolab Usa Inc. | Nanocrystalline cellulose and polymer-grafted nanocrystalline cellulose as rheology modifying agents for magnesium oxide and lime slurries |
| AR106581A1 (es) | 2015-11-04 | 2018-01-31 | Ecolab Usa Inc | Composiciones reductoras de fricción formuladas con salmuera de alta concentración |
| US10427950B2 (en) | 2015-12-04 | 2019-10-01 | Ecolab Usa Inc. | Recovery of mining processing product using boronic acid-containing polymers |
| ES2809023T3 (es) | 2016-05-23 | 2021-03-02 | Ecolab Usa Inc | Composiciones desinfectantes, de higienización, de limpieza ácida con reducción de la formación de neblina a través del uso de polímeros de emulsión de agua en aceite de alto peso molecular |
| EP3464541B1 (en) | 2016-05-23 | 2020-04-29 | Ecolab USA Inc. | Reduced misting alkaline and neutral cleaning, sanitizing, and disinfecting compositions via the use of high molecular weight water-in-oil emulsion polymers |
| AU2017297452B2 (en) | 2016-07-15 | 2021-10-28 | Ecolab Usa Inc. | Method for improving overflow clarity in production of coal |
| CN106589242A (zh) * | 2016-12-10 | 2017-04-26 | 钦州学院 | 一种结构改性絮凝剂及其制备方法 |
| CN106698541A (zh) * | 2016-12-10 | 2017-05-24 | 钦州学院 | 一种水处理组合物及其制备方法 |
| CN106622681B (zh) * | 2016-12-16 | 2019-11-19 | 中蓝连海设计研究院有限公司 | 一种矿泥絮凝剂及其制备方法和用途 |
| CN110392528A (zh) | 2017-03-01 | 2019-10-29 | 埃科莱布美国股份有限公司 | 通过高分子量聚合物减少吸入危险的消毒剂和杀菌剂 |
| CN110997593B (zh) | 2017-07-17 | 2023-01-24 | 埃科莱布美国股份有限公司 | 使浆料的流变性改性的方法 |
| WO2019115882A1 (en) | 2017-12-15 | 2019-06-20 | Kemira Oyj | Method for treating aqueous feed by dissolved gas flotation |
| WO2020106655A1 (en) | 2018-11-21 | 2020-05-28 | Self-Suspending Proppant Llc | Salt-tolerant self-suspending proppants made without extrusion |
| CN109679008B (zh) * | 2019-01-14 | 2021-04-30 | 东营市诺尔化工有限责任公司 | 一种驱油用超高分子量阴离子型聚丙烯酰胺及其制备方法和应用 |
| CA3146010C (en) | 2019-07-12 | 2024-06-04 | Ecolab Usa Inc. | Reduced mist alkaline cleaner via the use of alkali soluble emulsion polymers |
| CN110903015B (zh) * | 2019-11-30 | 2021-12-07 | 河南永泽环境科技有限公司 | 一种环保复合型污泥调理剂的生产方法 |
| KR102256143B1 (ko) * | 2019-12-03 | 2021-05-26 | 주식회사 한솔케미칼 | 고분자량의 수분산성 음이온 고분자 분산액 및 그 제조방법 |
| CN116057081A (zh) * | 2020-06-05 | 2023-05-02 | 日本瑞翁株式会社 | 辊加工性和班伯里加工性优异的丙烯酸橡胶胶包 |
| KR20230020397A (ko) * | 2020-06-05 | 2023-02-10 | 니폰 제온 가부시키가이샤 | 보존 안정성이나 밴버리 가공성이 우수한 아크릴 고무 베일 |
| CN111946278A (zh) * | 2020-08-19 | 2020-11-17 | 中国地质科学院探矿工艺研究所 | 一种地质岩心钻探废弃冲洗液的无害化处理方法 |
| WO2022061104A1 (en) | 2020-09-18 | 2022-03-24 | Ecolab Usa Inc. | Reduced misting peracid based cleaning, sanitizing, and disinfecting compositions via the use of high molecular weight polymers |
| CN112480310B (zh) * | 2020-12-08 | 2022-10-28 | 爱森(中国)絮凝剂有限公司 | 一种交联型阳离子聚丙烯酰胺污泥脱水剂及其制备方法 |
| WO2022174005A1 (en) | 2021-02-12 | 2022-08-18 | Ecolab Usa Inc. | Purification of bauxite ores using boronic acid-functional compounds |
| JP2023039016A (ja) * | 2021-09-08 | 2023-03-20 | サニーサービス株式会社 | 超微粉炭ケーキの製造方法 |
| CN116354393B (zh) * | 2023-05-05 | 2023-10-20 | 广东惠云钛业股份有限公司 | 一种微米级钛白粉的制备方法 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3557061A (en) * | 1969-01-16 | 1971-01-19 | Rohm & Haas | Stabilized suspension polymerization |
| DE201237T1 (de) | 1985-04-25 | 1988-01-14 | Allied Colloids Group Ltd., Bradford, Yorkshire | Flockungsverfahren. |
| US4913775A (en) | 1986-01-29 | 1990-04-03 | Allied Colloids Ltd. | Production of paper and paper board |
| GB8602121D0 (en) * | 1986-01-29 | 1986-03-05 | Allied Colloids Ltd | Paper & paper board |
| US5081182A (en) * | 1986-05-19 | 1992-01-14 | Exxon Chemical Patents Inc. | Cationic monomer delayed addition process |
| US5110864A (en) * | 1986-05-19 | 1992-05-05 | Exxon Chemical Patents Inc. | Cationic monomer delayed addition process |
| JPS63281313A (ja) | 1987-05-12 | 1988-11-17 | Sumitomo Electric Ind Ltd | 耐熱電線 |
| CA1331251C (en) | 1988-05-20 | 1994-08-02 | Peter Flesher | Particulate polymers, their production and uses |
| GB8821310D0 (en) * | 1988-09-12 | 1988-10-12 | Dow Chemical Co | Process for production of high molecular weight copolymers of diallyl dimethyl ammonium chloride & acrylamide in solution |
| GB8821311D0 (en) * | 1988-09-12 | 1988-10-12 | Dow Chemical Co | Process for production of high molecular weight copolymers of diallyl dimethyl ammonium chloride & acrylamide in aqueous dispersed phase |
| MX18620A (es) | 1988-12-19 | 1993-10-01 | American Cyanamid Co | Floculante polimerico de alto desempeño, proceso para su preparacion, metodo para la liberacion de agua de un dispersion de solidos suspendidos y metodo de floculacion de una dispersion de solidos suspendidos |
| DE68921053T3 (de) * | 1988-12-19 | 2004-07-22 | Cytec Technology Corp., Wilmington | Hochleistungs-Polymer-Flokkuliermittel. |
| FR2692292B1 (fr) | 1992-06-11 | 1994-12-02 | Snf Sa | Procédé de fabrication d'un papier ou d'un carton à rétention améliorée. |
| EP0615387B1 (en) * | 1992-08-27 | 1999-10-13 | Kabushiki Kaisha Toshiba | Moving picture encoder |
| US5518634A (en) * | 1993-12-27 | 1996-05-21 | Nalco Chemical Company | Coagulant for twin belt filter presses |
| US6335404B1 (en) * | 1994-04-05 | 2002-01-01 | Rohm And Haas Company | Aqueous process for preparing aqueous weight carboxyl containing polymers |
| RU2085510C1 (ru) * | 1994-10-25 | 1997-07-27 | Российский федеральный ядерный центр - Всероссийский научно-исследовательский институт технической физики | Способ очистки сточных вод |
| US6103839A (en) * | 1998-05-11 | 2000-08-15 | Nalco Chemical Company | Horizontally flowing continuous free radical polymerization process for manufacturing water-soluble polymers from monomers in aqueous solution |
| US6294622B1 (en) * | 1999-09-27 | 2001-09-25 | Ecole Polytechnique Federale De Lausanne (Epfl) | Polymer flocculants with improved dewatering characteristics |
| US6592718B1 (en) | 2001-09-06 | 2003-07-15 | Ondeo Nalco Company | Method of improving retention and drainage in a papermaking process using a diallyl-N,N-disubstituted ammonium halide-acrylamide copolymer and a structurally modified cationic polymer |
-
2000
- 2000-06-29 US US09/606,581 patent/US6605674B1/en not_active Expired - Lifetime
-
2001
- 2001-04-03 AU AU5128201A patent/AU5128201A/xx active Pending
- 2001-04-03 EP EP01924646A patent/EP1297039B1/en not_active Revoked
- 2001-04-03 CN CNB018087825A patent/CN1239544C/zh not_active Expired - Lifetime
- 2001-04-03 RU RU2002128923/04A patent/RU2243240C2/ru active
- 2001-04-03 JP JP2002507911A patent/JP5078214B2/ja not_active Expired - Lifetime
- 2001-04-03 CA CA2406270A patent/CA2406270C/en not_active Expired - Lifetime
- 2001-04-03 PT PT01924646T patent/PT1297039E/pt unknown
- 2001-04-03 NZ NZ522047A patent/NZ522047A/en not_active IP Right Cessation
- 2001-04-03 WO PCT/US2001/010867 patent/WO2002002662A1/en not_active Ceased
- 2001-04-03 KR KR1020027014556A patent/KR100814675B1/ko not_active Expired - Lifetime
- 2001-04-03 ES ES01924646T patent/ES2382025T3/es not_active Expired - Lifetime
- 2001-04-03 AU AU2001251282A patent/AU2001251282B2/en not_active Expired
- 2001-04-03 DK DK01924646.1T patent/DK1297039T3/da active
- 2001-04-03 MX MXPA02010628 patent/MX227471B/es active IP Right Grant
- 2001-04-03 BR BR0110429-2A patent/BR0110429A/pt not_active Application Discontinuation
- 2001-04-03 AT AT01924646T patent/ATE548397T1/de active
- 2001-04-17 TW TW090109150A patent/TWI275600B/zh not_active IP Right Cessation
- 2001-06-06 AR ARP010102699A patent/AR030425A1/es active IP Right Grant
- 2001-06-27 MY MYPI20013025 patent/MY124884A/xx unknown
-
2002
- 2002-10-17 ZA ZA200208420A patent/ZA200208420B/en unknown
- 2002-10-21 NO NO20025045A patent/NO333034B1/no not_active IP Right Cessation
-
2003
- 2003-07-17 US US10/621,529 patent/US6753388B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| AU2001251282B2 (en) | 2007-01-25 |
| WO2002002662A1 (en) | 2002-01-10 |
| NO20025045L (no) | 2002-12-16 |
| CA2406270C (en) | 2010-06-01 |
| NO20025045D0 (no) | 2002-10-21 |
| ES2382025T3 (es) | 2012-06-04 |
| JP2004502802A (ja) | 2004-01-29 |
| MX227471B (es) | 2005-04-27 |
| EP1297039A4 (en) | 2004-11-03 |
| CN1426429A (zh) | 2003-06-25 |
| ZA200208420B (en) | 2003-10-17 |
| AR030425A1 (es) | 2003-08-20 |
| NO333034B1 (no) | 2013-02-18 |
| MY124884A (en) | 2006-07-31 |
| KR20030022789A (ko) | 2003-03-17 |
| EP1297039A1 (en) | 2003-04-02 |
| TWI275600B (en) | 2007-03-11 |
| RU2243240C2 (ru) | 2004-12-27 |
| BR0110429A (pt) | 2003-02-04 |
| US6605674B1 (en) | 2003-08-12 |
| ATE548397T1 (de) | 2012-03-15 |
| EP1297039B1 (en) | 2012-03-07 |
| DK1297039T3 (da) | 2012-06-11 |
| CA2406270A1 (en) | 2002-01-10 |
| MXPA02010628A (es) | 2004-05-17 |
| KR100814675B1 (ko) | 2008-03-18 |
| US6753388B1 (en) | 2004-06-22 |
| NZ522047A (en) | 2004-09-24 |
| AU5128201A (en) | 2002-01-14 |
| CN1239544C (zh) | 2006-02-01 |
| JP5078214B2 (ja) | 2012-11-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| PT1297039E (pt) | Floculantes poliméricos estruturalmente modificados | |
| AU2001251282A1 (en) | Structurally-modified polymer flocculants | |
| JP4132017B2 (ja) | 高分子量水溶性双性イオン性ポリマー | |
| KR101457740B1 (ko) | 중합체 응고제를 함유하는 역상 유화 중합체 | |
| US5840804A (en) | Crosslinked water-soluble polymer dispersions | |
| JP4219169B2 (ja) | 汚泥脱水用陽イオンラテックスターポリマー | |
| CN102482361B (zh) | 水包水型聚合物分散体中的阴离子型交联聚合物 | |
| BRPI0912939B1 (pt) | Dispersão de polímero aquosa, processo para produzir uma dispersão de polímero aquosa, uso de uma dispersão de polímero aquosa e processo para a produção de papel | |
| ES2327661T3 (es) | Retencion y drenaje mojados en la fabricacion de papel. | |
| JP4167972B2 (ja) | 有機汚泥の脱水方法 | |
| JP2008525665A (ja) | 紙製造における改善された歩留まりおよび濾水 | |
| JP2003155689A (ja) | 紙の製造方法 | |
| JP3110992B2 (ja) | 白水の有価物回収剤 | |
| JP4942415B2 (ja) | 抄紙方法 |