NO319282B1 - Fremgangsmate for forsterkning av smeltestyrken av kopolymerer av polypropylen - Google Patents
Fremgangsmate for forsterkning av smeltestyrken av kopolymerer av polypropylen Download PDFInfo
- Publication number
- NO319282B1 NO319282B1 NO19986102A NO986102A NO319282B1 NO 319282 B1 NO319282 B1 NO 319282B1 NO 19986102 A NO19986102 A NO 19986102A NO 986102 A NO986102 A NO 986102A NO 319282 B1 NO319282 B1 NO 319282B1
- Authority
- NO
- Norway
- Prior art keywords
- initiator
- polymer
- polypropylene
- weight
- peroxydicarbonate
- Prior art date
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- 238000000034 method Methods 0.000 title claims abstract description 42
- 229920005606 polypropylene copolymer Polymers 0.000 title claims abstract description 39
- 239000000155 melt Substances 0.000 title claims abstract description 17
- 230000008569 process Effects 0.000 title abstract description 4
- 238000005728 strengthening Methods 0.000 title 1
- 239000003999 initiator Substances 0.000 claims abstract description 120
- 239000006185 dispersion Substances 0.000 claims abstract description 32
- 229920000642 polymer Polymers 0.000 claims abstract description 29
- 229920001577 copolymer Polymers 0.000 claims description 31
- -1 polypropylene Polymers 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 239000004743 Polypropylene Substances 0.000 claims description 17
- 238000012986 modification Methods 0.000 claims description 17
- 230000004048 modification Effects 0.000 claims description 17
- 239000002245 particle Substances 0.000 claims description 17
- 229920001155 polypropylene Polymers 0.000 claims description 17
- 239000000463 material Substances 0.000 claims description 13
- 239000011149 active material Substances 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- 239000002562 thickening agent Substances 0.000 claims description 11
- 238000000354 decomposition reaction Methods 0.000 claims description 10
- 239000007787 solid Substances 0.000 claims description 10
- 230000008014 freezing Effects 0.000 claims description 9
- 238000007710 freezing Methods 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- ZACVGCNKGYYQHA-UHFFFAOYSA-N 2-ethylhexoxycarbonyloxy 2-ethylhexyl carbonate Chemical group CCCCC(CC)COC(=O)OOC(=O)OCC(CC)CCCC ZACVGCNKGYYQHA-UHFFFAOYSA-N 0.000 claims description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
- 125000000129 anionic group Chemical group 0.000 claims description 6
- BEQKKZICTDFVMG-UHFFFAOYSA-N 1,2,3,4,6-pentaoxepane-5,7-dione Chemical compound O=C1OOOOC(=O)O1 BEQKKZICTDFVMG-UHFFFAOYSA-N 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000012876 carrier material Substances 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 230000000994 depressogenic effect Effects 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 4
- 239000003381 stabilizer Substances 0.000 claims description 4
- 238000001125 extrusion Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 125000005634 peroxydicarbonate group Chemical group 0.000 claims description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 3
- 239000004146 Propane-1,2-diol Substances 0.000 claims description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 2
- 229960004063 propylene glycol Drugs 0.000 claims description 2
- 235000013772 propylene glycol Nutrition 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 abstract description 6
- 238000010790 dilution Methods 0.000 abstract description 4
- 239000012895 dilution Substances 0.000 abstract description 4
- 230000002708 enhancing effect Effects 0.000 abstract 1
- 239000002609 medium Substances 0.000 description 15
- 239000000725 suspension Substances 0.000 description 14
- 238000002474 experimental method Methods 0.000 description 10
- 238000002360 preparation method Methods 0.000 description 10
- 150000002978 peroxides Chemical class 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 239000003963 antioxidant agent Substances 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- 230000008961 swelling Effects 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 229920000098 polyolefin Polymers 0.000 description 4
- 150000003254 radicals Chemical class 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- GTJOHISYCKPIMT-UHFFFAOYSA-N 2-methylundecane Chemical compound CCCCCCCCCC(C)C GTJOHISYCKPIMT-UHFFFAOYSA-N 0.000 description 3
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- SGVYKUFIHHTIFL-UHFFFAOYSA-N Isobutylhexyl Natural products CCCCCCCC(C)C SGVYKUFIHHTIFL-UHFFFAOYSA-N 0.000 description 3
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 230000003078 antioxidant effect Effects 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- VKPSKYDESGTTFR-UHFFFAOYSA-N isododecane Natural products CC(C)(C)CC(C)CC(C)(C)C VKPSKYDESGTTFR-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920005629 polypropylene homopolymer Polymers 0.000 description 3
- 230000009257 reactivity Effects 0.000 description 3
- 238000000518 rheometry Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- NOBYOEQUFMGXBP-UHFFFAOYSA-N (4-tert-butylcyclohexyl) (4-tert-butylcyclohexyl)oxycarbonyloxy carbonate Chemical compound C1CC(C(C)(C)C)CCC1OC(=O)OOC(=O)OC1CCC(C(C)(C)C)CC1 NOBYOEQUFMGXBP-UHFFFAOYSA-N 0.000 description 2
- DSCFFEYYQKSRSV-UHFFFAOYSA-N 1L-O1-methyl-muco-inositol Natural products COC1C(O)C(O)C(O)C(O)C1O DSCFFEYYQKSRSV-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 2
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 2
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- 239000012442 inert solvent Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N methylene hexane Natural products CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 239000011118 polyvinyl acetate Substances 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 230000002028 premature Effects 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000003340 retarding agent Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- OPQYOFWUFGEMRZ-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOC(=O)C(C)(C)C OPQYOFWUFGEMRZ-UHFFFAOYSA-N 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000003856 thermoforming Methods 0.000 description 2
- HGXJDMCMYLEZMJ-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOOC(=O)C(C)(C)C HGXJDMCMYLEZMJ-UHFFFAOYSA-N 0.000 description 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 1
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- YPIFGDQKSSMYHQ-UHFFFAOYSA-N 7,7-dimethyloctanoic acid Chemical compound CC(C)(C)CCCCCC(O)=O YPIFGDQKSSMYHQ-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- RUPBZQFQVRMKDG-UHFFFAOYSA-M Didecyldimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCC[N+](C)(C)CCCCCCCCCC RUPBZQFQVRMKDG-UHFFFAOYSA-M 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 229920003091 Methocel™ Polymers 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 229920005603 alternating copolymer Polymers 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 229960004670 didecyldimethylammonium chloride Drugs 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- QWVBGCWRHHXMRM-UHFFFAOYSA-N hexadecoxycarbonyloxy hexadecyl carbonate Chemical compound CCCCCCCCCCCCCCCCOC(=O)OOC(=O)OCCCCCCCCCCCCCCCC QWVBGCWRHHXMRM-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- QTEDUQSFCPUIOH-UEUBVZDRSA-N mastoparan-D Chemical compound CC[C@H](C)[C@H](N)C(=O)N[C@@H](CC(N)=O)C(=O)N[C@@H](CC(C)C)C(=O)N[C@@H](CCCCN)C(=O)N[C@@H](C)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](C)C(=O)N[C@@H](C)C(=O)N[C@H](C(=O)N[C@@H](C)C(=O)N[C@@H](CCCCN)C(=O)N[C@@H](CCCCN)C(=O)N[C@@H](CC(C)C)C(=O)N[C@@H](CC(C)C)C(N)=O)CC1=CC=CC=C1 QTEDUQSFCPUIOH-UEUBVZDRSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 229920000847 nonoxynol Polymers 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical class CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000006174 pH buffer Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- 150000002976 peresters Chemical class 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- IUGYQRQAERSCNH-UHFFFAOYSA-N pivalic acid Chemical compound CC(C)(C)C(O)=O IUGYQRQAERSCNH-UHFFFAOYSA-N 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000223 polyglycerol Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000005482 strain hardening Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- NMOALOSNPWTWRH-UHFFFAOYSA-N tert-butyl 7,7-dimethyloctaneperoxoate Chemical compound CC(C)(C)CCCCCC(=O)OOC(C)(C)C NMOALOSNPWTWRH-UHFFFAOYSA-N 0.000 description 1
- 238000009210 therapy by ultrasound Methods 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/50—Partial depolymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Graft Or Block Polymers (AREA)
- Polymerisation Methods In General (AREA)
- Laminated Bodies (AREA)
- Lining Or Joining Of Plastics Or The Like (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL1003406 | 1996-06-24 | ||
| PCT/EP1997/003097 WO1997049759A1 (en) | 1996-06-24 | 1997-06-12 | Process for enhancing the melt strength of polypropylene(co)polymers |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO986102D0 NO986102D0 (no) | 1998-12-23 |
| NO986102L NO986102L (no) | 1998-12-23 |
| NO319282B1 true NO319282B1 (no) | 2005-07-11 |
Family
ID=19763061
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO19986102A NO319282B1 (no) | 1996-06-24 | 1998-12-23 | Fremgangsmate for forsterkning av smeltestyrken av kopolymerer av polypropylen |
Country Status (23)
| Country | Link |
|---|---|
| EP (1) | EP0907677B1 (ru) |
| JP (1) | JP4129844B2 (ru) |
| KR (1) | KR100289196B1 (ru) |
| CN (1) | CN1101832C (ru) |
| AT (1) | ATE198608T1 (ru) |
| AU (1) | AU713948B2 (ru) |
| BR (1) | BR9709941A (ru) |
| CA (1) | CA2258954A1 (ru) |
| CZ (1) | CZ291628B6 (ru) |
| DE (1) | DE69703886T2 (ru) |
| DK (1) | DK0907677T3 (ru) |
| ES (1) | ES2154047T3 (ru) |
| HK (1) | HK1021197A1 (ru) |
| HU (1) | HUP9903593A3 (ru) |
| IL (1) | IL127700A (ru) |
| NO (1) | NO319282B1 (ru) |
| PL (1) | PL189967B1 (ru) |
| PT (1) | PT907677E (ru) |
| RU (1) | RU2167884C2 (ru) |
| TR (1) | TR199802604T2 (ru) |
| TW (1) | TW341579B (ru) |
| WO (1) | WO1997049759A1 (ru) |
| YU (1) | YU57998A (ru) |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3767992B2 (ja) * | 1997-07-18 | 2006-04-19 | 株式会社ジェイエスピー | 押出発泡用ポリプロピレン系樹脂およびその製造方法 |
| UA60351C2 (ru) | 1997-11-21 | 2003-10-15 | Акцо Нобель Н.В. | Экструзионный процесс для улучшения прочности при плавлении полипропилена |
| BR9907091A (pt) * | 1998-01-19 | 2001-09-04 | Polymers Australia Pty Ltd | Polipropileno modificado, e, processos para modificação de um (co)polìmero de polipropileno, para produzir um polipropileno modificado e, para modificação de um polìmero <244>-olefìnico |
| AU732342B2 (en) * | 1998-01-19 | 2001-04-12 | Polymers Australia Pty Limited | Process for increasing the melt strength of polypropylene |
| NO313835B1 (no) * | 1998-06-19 | 2002-12-09 | Borealis As | Fremgangsmate for forgrening av polypropylenmaterialer, fremgangsmate for forgrening og skumming av polypropylenmaterialer, og anvendelse av polymermaterialene oppnadd ved fremgangsmatene |
| JP2002080526A (ja) * | 2000-09-04 | 2002-03-19 | Grand Polymer Co Ltd | 改質ポリプロピレンの製造方法および発泡体 |
| EP1179544A1 (en) * | 2000-08-10 | 2002-02-13 | Grand Polymer Co., Ltd. | Modified polypropylene, process for preparing modified polypropylene, modified polypropylene composition and foamed product |
| EP1186618A1 (en) | 2000-09-08 | 2002-03-13 | ATOFINA Research | Controlled rheology polypropylene heterophasic copolymers |
| JP2003048996A (ja) * | 2001-08-02 | 2003-02-21 | Grand Polymer Co Ltd | シート用ポリプロピレン樹脂およびその製造方法 |
| EP1312617A1 (en) | 2001-11-14 | 2003-05-21 | ATOFINA Research | Impact strength polypropylene |
| EP1658315B1 (en) | 2003-08-27 | 2009-01-28 | Flexsys B.V. | Process for enhancing the melt strength of polypropylene |
| US7750086B2 (en) * | 2006-02-27 | 2010-07-06 | Equistar Chemicals, Lp | Solid state modification of propylene polymers |
| CN100448902C (zh) * | 2006-09-15 | 2009-01-07 | 中国科学院长春应用化学研究所 | 高熔体强度聚丙烯树脂及其制备方法 |
| JP2008222811A (ja) * | 2007-03-12 | 2008-09-25 | Japan Polypropylene Corp | 改質ポリプロピレン系樹脂の製造法 |
| DE102009026185A1 (de) * | 2009-07-16 | 2011-02-10 | Elantas Gmbh | Reaktiv-Systeme |
| JP2013539812A (ja) | 2010-10-14 | 2013-10-28 | リライアンス、インダストリーズ、リミテッド | 高溶融強度プロピレン系重合体の調製プロセス |
| JP2012201790A (ja) | 2011-03-25 | 2012-10-22 | Sumitomo Chemical Co Ltd | 変性プロピレン重合体の製造方法 |
| WO2014085878A1 (pt) | 2012-12-04 | 2014-06-12 | Braskem S.A. | Método de compatibilização de blendas de polipropileno, blenda de polipropileno e seu uso, produto e agente iniciador de compatibilização de blenda de polipropileno |
| CN106459432B (zh) * | 2014-06-12 | 2019-02-01 | 阿克苏诺贝尔化学品国际有限公司 | 提高聚丙烯的熔体强度的方法 |
| RU2692720C2 (ru) * | 2014-06-25 | 2019-06-26 | Эксонмобил Кемикэл Пейтентс Инк. | Полипропилен с высокой прочностью расплава и способ экструзии для сохранения прочности расплава |
| KR101949068B1 (ko) | 2015-02-04 | 2019-02-15 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 균형화된 변형 경화, 용융 강도, 및 전단 박화를 갖는 폴리프로필렌 |
| KR101938511B1 (ko) | 2015-02-04 | 2019-01-14 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 안정화된 밸런스의 용융 강도 및 변형 경화된 폴리프로필렌 |
| EP3800217B1 (en) * | 2015-02-10 | 2024-01-10 | Lummus Novolen Technology Gmbh | Methods for modifying the rheology of polymers |
| WO2016164111A1 (en) | 2015-04-10 | 2016-10-13 | Exxonmobil Chemical Patents Inc. | Extrusion of polypropylenes with organic peroxides |
| US10442879B2 (en) | 2015-04-28 | 2019-10-15 | Exxonmobil Chemical Patents Inc. | Propylene-based impact copolymers |
| US11559937B2 (en) * | 2016-08-30 | 2023-01-24 | Lummus Novolen Technology Gmbh | Polypropylene for additive manufacturing (3D printing) |
| EP3708594A4 (en) | 2017-11-09 | 2021-10-13 | Lotte Chemical Corporation | PROCESS FOR THE PRODUCTION OF HIGH MELT STRENGTH POLYPROPYLENE RESIN |
| WO2019121371A1 (en) * | 2017-12-19 | 2019-06-27 | Akzo Nobel Chemicals International B.V. | Formulation of di(4-tert-butylcyclohexyl) peroxydicarbonate |
| KR102671695B1 (ko) | 2018-11-29 | 2024-06-05 | 롯데케미칼 주식회사 | 우수한 용융 특성을 지닌 폴리프로필렌 수지 및 그 제조 방법 |
| CN115305644A (zh) * | 2022-07-30 | 2022-11-08 | 苏州大乘环保新材有限公司 | 碳纤雨水收集模块用滤透表层布及制备方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1495285C3 (de) * | 1963-03-02 | 1975-07-03 | Chemische Werke Huels Ag, 4370 Marl | Verfahren zur Erniedrigung des Molekulargewichts von Polyolefinen |
| NL8000260A (nl) * | 1980-01-16 | 1981-08-17 | Akzo Nv | Waterige peroxyde emulsie en de toepassing ervan in suspensie(co-)polymerisatiereacties. |
| US5260390A (en) * | 1980-01-16 | 1993-11-09 | Akzo N.V. | Peroxide emulsions containing an antifreezing compound |
| DE3015139A1 (de) * | 1980-04-19 | 1981-10-22 | Ackermann Albert Gmbh Co | Funktionssteckverbinder |
| FR2613722B1 (fr) * | 1987-04-07 | 1990-11-23 | Bp Chimie Sa | Procede de fabrication de granules d'homopolymere ou de copolymere de propylene |
| US5047485A (en) * | 1989-02-21 | 1991-09-10 | Himont Incorporated | Process for making a propylene polymer with free-end long chain branching and use thereof |
| US5416169A (en) * | 1992-11-26 | 1995-05-16 | Chisso Corporation | Polypropylene having a high melt-tensile strength, a process for producing the same and a molded product from the same |
-
1996
- 1996-11-13 TW TW085113873A patent/TW341579B/zh active
-
1997
- 1997-06-12 KR KR1019980710976A patent/KR100289196B1/ko not_active IP Right Cessation
- 1997-06-12 BR BR9709941A patent/BR9709941A/pt not_active IP Right Cessation
- 1997-06-12 CZ CZ19984288A patent/CZ291628B6/cs not_active IP Right Cessation
- 1997-06-12 HU HU9903593A patent/HUP9903593A3/hu unknown
- 1997-06-12 JP JP50222698A patent/JP4129844B2/ja not_active Expired - Fee Related
- 1997-06-12 PT PT97928199T patent/PT907677E/pt unknown
- 1997-06-12 PL PL97330900A patent/PL189967B1/pl not_active IP Right Cessation
- 1997-06-12 AT AT97928199T patent/ATE198608T1/de not_active IP Right Cessation
- 1997-06-12 DK DK97928199T patent/DK0907677T3/da active
- 1997-06-12 CN CN97195797A patent/CN1101832C/zh not_active Expired - Fee Related
- 1997-06-12 DE DE69703886T patent/DE69703886T2/de not_active Expired - Lifetime
- 1997-06-12 ES ES97928199T patent/ES2154047T3/es not_active Expired - Lifetime
- 1997-06-12 AU AU32584/97A patent/AU713948B2/en not_active Ceased
- 1997-06-12 WO PCT/EP1997/003097 patent/WO1997049759A1/en active IP Right Grant
- 1997-06-12 EP EP97928199A patent/EP0907677B1/en not_active Expired - Lifetime
- 1997-06-12 IL IL12770097A patent/IL127700A/xx not_active IP Right Cessation
- 1997-06-12 TR TR1998/02604T patent/TR199802604T2/xx unknown
- 1997-06-12 RU RU99101119/04A patent/RU2167884C2/ru not_active IP Right Cessation
- 1997-06-12 YU YU57998A patent/YU57998A/sh unknown
- 1997-06-12 CA CA002258954A patent/CA2258954A1/en not_active Abandoned
-
1998
- 1998-12-23 NO NO19986102A patent/NO319282B1/no not_active IP Right Cessation
-
1999
- 1999-12-09 HK HK99105750A patent/HK1021197A1/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| NO986102D0 (no) | 1998-12-23 |
| CN1101832C (zh) | 2003-02-19 |
| WO1997049759A1 (en) | 1997-12-31 |
| ES2154047T3 (es) | 2001-03-16 |
| JP2000516272A (ja) | 2000-12-05 |
| IL127700A (en) | 2001-03-19 |
| PT907677E (pt) | 2001-06-29 |
| KR20000022531A (ko) | 2000-04-25 |
| EP0907677B1 (en) | 2001-01-10 |
| AU3258497A (en) | 1998-01-14 |
| ATE198608T1 (de) | 2001-01-15 |
| RU2167884C2 (ru) | 2001-05-27 |
| PL189967B1 (pl) | 2005-10-31 |
| AU713948B2 (en) | 1999-12-16 |
| HUP9903593A2 (en) | 2000-07-28 |
| BR9709941A (pt) | 1999-08-10 |
| DE69703886D1 (de) | 2001-02-15 |
| HUP9903593A3 (en) | 2000-09-28 |
| HK1021197A1 (en) | 2000-06-02 |
| CN1223678A (zh) | 1999-07-21 |
| EP0907677A1 (en) | 1999-04-14 |
| IL127700A0 (en) | 1999-10-28 |
| DK0907677T3 (da) | 2001-05-21 |
| CZ291628B6 (cs) | 2003-04-16 |
| TW341579B (en) | 1998-10-01 |
| DE69703886T2 (de) | 2001-06-21 |
| CZ428898A3 (cs) | 2000-02-16 |
| TR199802604T2 (xx) | 1999-03-22 |
| KR100289196B1 (ko) | 2001-05-02 |
| CA2258954A1 (en) | 1997-12-31 |
| PL330900A1 (en) | 1999-06-07 |
| JP4129844B2 (ja) | 2008-08-06 |
| NO986102L (no) | 1998-12-23 |
| YU57998A (sh) | 1999-09-27 |
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