NO318680B1 - Metode for a fremstille krystallinsk, mikroporost metalloaluminofosfat fra et fast legeme og anvendelse derav - Google Patents
Metode for a fremstille krystallinsk, mikroporost metalloaluminofosfat fra et fast legeme og anvendelse derav Download PDFInfo
- Publication number
- NO318680B1 NO318680B1 NO20015437A NO20015437A NO318680B1 NO 318680 B1 NO318680 B1 NO 318680B1 NO 20015437 A NO20015437 A NO 20015437A NO 20015437 A NO20015437 A NO 20015437A NO 318680 B1 NO318680 B1 NO 318680B1
- Authority
- NO
- Norway
- Prior art keywords
- sapo
- particles
- metal
- elapo
- synthesis
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 40
- 239000007787 solid Substances 0.000 title claims description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 58
- 238000003786 synthesis reaction Methods 0.000 claims description 42
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 36
- 239000000203 mixture Substances 0.000 claims description 35
- 230000015572 biosynthetic process Effects 0.000 claims description 34
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 30
- 239000007788 liquid Substances 0.000 claims description 29
- 238000004519 manufacturing process Methods 0.000 claims description 29
- 229940073455 tetraethylammonium hydroxide Drugs 0.000 claims description 28
- LRGJRHZIDJQFCL-UHFFFAOYSA-M tetraethylazanium;hydroxide Chemical compound [OH-].CC[N+](CC)(CC)CC LRGJRHZIDJQFCL-UHFFFAOYSA-M 0.000 claims description 28
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 claims description 27
- 239000002245 particle Substances 0.000 claims description 27
- 229910017119 AlPO Inorganic materials 0.000 claims description 23
- 239000011541 reaction mixture Substances 0.000 claims description 21
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 claims description 18
- 239000000377 silicon dioxide Substances 0.000 claims description 18
- 239000003054 catalyst Substances 0.000 claims description 17
- 239000003795 chemical substances by application Substances 0.000 claims description 16
- 238000002425 crystallisation Methods 0.000 claims description 15
- 230000008025 crystallization Effects 0.000 claims description 15
- 239000002808 molecular sieve Substances 0.000 claims description 15
- 239000011148 porous material Substances 0.000 claims description 15
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 15
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 claims description 14
- 239000000376 reactant Substances 0.000 claims description 14
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 claims description 14
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 12
- 229910052751 metal Inorganic materials 0.000 claims description 12
- 239000002184 metal Substances 0.000 claims description 12
- 229910052710 silicon Inorganic materials 0.000 claims description 11
- 239000010703 silicon Substances 0.000 claims description 11
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 9
- 229940043279 diisopropylamine Drugs 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 8
- 150000001336 alkenes Chemical class 0.000 claims description 8
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 claims description 8
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 claims description 8
- 239000013078 crystal Substances 0.000 claims description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 238000001027 hydrothermal synthesis Methods 0.000 claims description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- 239000011651 chromium Substances 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 239000010941 cobalt Substances 0.000 claims description 4
- 229910017052 cobalt Inorganic materials 0.000 claims description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 241000269350 Anura Species 0.000 claims description 2
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 claims description 2
- XOBKSJJDNFUZPF-UHFFFAOYSA-N Methoxyethane Chemical compound CCOC XOBKSJJDNFUZPF-UHFFFAOYSA-N 0.000 claims description 2
- 239000003463 adsorbent Substances 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims 1
- 238000002441 X-ray diffraction Methods 0.000 description 38
- 239000000463 material Substances 0.000 description 28
- 238000002156 mixing Methods 0.000 description 17
- 239000000843 powder Substances 0.000 description 14
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 8
- 229910052698 phosphorus Inorganic materials 0.000 description 8
- 239000000523 sample Substances 0.000 description 8
- 229910001220 stainless steel Inorganic materials 0.000 description 8
- 239000010935 stainless steel Substances 0.000 description 8
- 239000010457 zeolite Substances 0.000 description 8
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical group O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 7
- 239000000499 gel Substances 0.000 description 7
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 6
- 238000010335 hydrothermal treatment Methods 0.000 description 6
- 239000011159 matrix material Substances 0.000 description 6
- 239000011574 phosphorus Substances 0.000 description 6
- 229910021536 Zeolite Inorganic materials 0.000 description 5
- 230000003197 catalytic effect Effects 0.000 description 5
- 239000003153 chemical reaction reagent Substances 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 229910019142 PO4 Inorganic materials 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 239000004809 Teflon Substances 0.000 description 4
- 229920006362 Teflon® Polymers 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- 235000021317 phosphate Nutrition 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 229910001408 cation oxide Inorganic materials 0.000 description 3
- 239000006259 organic additive Substances 0.000 description 3
- -1 silica hydroxides Chemical class 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- 239000002178 crystalline material Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004817 gas chromatography Methods 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 239000013074 reference sample Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- 238000001694 spray drying Methods 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- MYXKPFMQWULLOH-UHFFFAOYSA-M tetramethylazanium;hydroxide;pentahydrate Chemical compound O.O.O.O.O.[OH-].C[N+](C)(C)C MYXKPFMQWULLOH-UHFFFAOYSA-M 0.000 description 2
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- 241000282326 Felis catus Species 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- RGYJAUFQHNHJMU-UHFFFAOYSA-K aluminum;azanium;hydroxide;phosphate Chemical compound [NH4+].[OH-].[Al+3].[O-]P([O-])([O-])=O RGYJAUFQHNHJMU-UHFFFAOYSA-K 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 239000000017 hydrogel Substances 0.000 description 1
- 239000011872 intimate mixture Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000006069 physical mixture Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000013341 scale-up Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000004876 x-ray fluorescence Methods 0.000 description 1
- 239000012690 zeolite precursor Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/82—Phosphates
- B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
- B01J29/85—Silicoaluminophosphates [SAPO compounds]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/82—Phosphates
- B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
- C01B37/065—Aluminophosphates containing other elements, e.g. metals, boron the other elements being metals only
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
- C01B37/08—Silicoaluminophosphates [SAPO compounds], e.g. CoSAPO
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/42—Catalytic treatment
- C10G3/44—Catalytic treatment characterised by the catalyst used
- C10G3/45—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/42—Catalytic treatment
- C10G3/44—Catalytic treatment characterised by the catalyst used
- C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
- C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0027—Powdering
- B01J37/0045—Drying a slurry, e.g. spray drying
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/82—Phosphates
- C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
- C07C2529/85—Silicoaluminophosphates (SAPO compounds)
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/20—C2-C4 olefins
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Catalysts (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Priority Applications (15)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NO20015437A NO318680B1 (no) | 2001-11-07 | 2001-11-07 | Metode for a fremstille krystallinsk, mikroporost metalloaluminofosfat fra et fast legeme og anvendelse derav |
EP02778112A EP1461288B1 (en) | 2001-11-07 | 2002-11-06 | Method of synthesising crystalline microporous metalloaluminophosphate from a solid body |
US10/494,862 US7341706B2 (en) | 2001-11-07 | 2002-11-06 | Method of synthesising crystalline microporous metalloaluminophosphate for a solid body |
CA2465947A CA2465947C (en) | 2001-11-07 | 2002-11-06 | Method of synthesising crystalline microporous metalloaluminophosphate from a solid body |
CNB02826598XA CN1308236C (zh) | 2001-11-07 | 2002-11-06 | 由固体基质合成结晶微孔金属铝磷酸盐的方法 |
PT02778112T PT1461288E (pt) | 2001-11-07 | 2002-11-06 | Processo para síntese de metaloaluminofosfato microporoso cristalino a partir de um corpo sólido. |
BR0214000-4A BR0214000A (pt) | 2001-11-07 | 2002-11-06 | Método de sìntese de metaloaluminofosfato (elapo) microporoso cristalino a partir de um corpo sólido, e, uso de partìculas |
ES02778112T ES2284936T3 (es) | 2001-11-07 | 2002-11-06 | Metodo para sintetizar metaloaluminofosfato microporoso cristalino a partir de un cuerpo solido. |
DK02778112T DK1461288T3 (da) | 2001-11-07 | 2002-11-06 | Metode til syntese af krystallinsk mikroprröds metalloaluminophosphat fra et fast legeme |
MXPA04004420A MXPA04004420A (es) | 2001-11-07 | 2002-11-06 | Metodo para sintetizar metaloaluminofosfato microporoso cristalino de un cuerpo solido. |
RU2004117071/15A RU2311343C2 (ru) | 2001-11-07 | 2002-11-06 | Способ синтеза кристаллического микропористого металлоалюмофосфата из твердого вещества |
DE60219357T DE60219357T2 (de) | 2001-11-07 | 2002-11-06 | Verfahren zur synthese von kristallinem mikroporösem metalloaluminiumphosphat aus einem festen körper |
PCT/NO2002/000407 WO2003040037A1 (en) | 2001-11-07 | 2002-11-06 | Method of synthesising crystalline microporous metalloaluminophosphate from a solid body |
AT02778112T ATE358653T1 (de) | 2001-11-07 | 2002-11-06 | Verfahren zur synthese von kristallinem mikroporösem metalloaluminiumphosphat aus einem festen körper |
AU2002339763A AU2002339763B2 (en) | 2001-11-07 | 2002-11-06 | Method of synthesising crystalline microporous metalloaluminophosphate from a solid body |
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Application Number | Priority Date | Filing Date | Title |
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NO20015437A NO318680B1 (no) | 2001-11-07 | 2001-11-07 | Metode for a fremstille krystallinsk, mikroporost metalloaluminofosfat fra et fast legeme og anvendelse derav |
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Publication Number | Publication Date |
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NO20015437D0 NO20015437D0 (no) | 2001-11-07 |
NO20015437L NO20015437L (no) | 2003-05-08 |
NO318680B1 true NO318680B1 (no) | 2005-04-25 |
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NO20015437A NO318680B1 (no) | 2001-11-07 | 2001-11-07 | Metode for a fremstille krystallinsk, mikroporost metalloaluminofosfat fra et fast legeme og anvendelse derav |
Country Status (15)
Country | Link |
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US (1) | US7341706B2 (es) |
EP (1) | EP1461288B1 (es) |
CN (1) | CN1308236C (es) |
AT (1) | ATE358653T1 (es) |
AU (1) | AU2002339763B2 (es) |
BR (1) | BR0214000A (es) |
CA (1) | CA2465947C (es) |
DE (1) | DE60219357T2 (es) |
DK (1) | DK1461288T3 (es) |
ES (1) | ES2284936T3 (es) |
MX (1) | MXPA04004420A (es) |
NO (1) | NO318680B1 (es) |
PT (1) | PT1461288E (es) |
RU (1) | RU2311343C2 (es) |
WO (1) | WO2003040037A1 (es) |
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EP1733004B1 (en) | 2004-04-05 | 2012-09-12 | ExxonMobil Chemical Patents Inc. | Crystalline intergrowth material, its synthesis and its use in the conversion of oxygenates to olefins |
CN1304291C (zh) * | 2004-06-09 | 2007-03-14 | 中国科学院上海硅酸盐研究所 | 一种无机微孔磷酸镍钴类分子筛材料及其合成方法 |
US7067095B1 (en) * | 2004-12-09 | 2006-06-27 | Exxonmobil Chemical Patents Inc. | Synthesis of silicoaluminophosphate molecular sieves |
US20070059236A1 (en) * | 2005-09-09 | 2007-03-15 | Broach Robert W | Molecular sieves with high selectivity towards light olefins in methanol to olefin conversion |
MY153638A (en) * | 2006-05-15 | 2015-03-13 | Univ Colorado Regents | High flux selectivity sapo-34 membranes for co2/ch4 separations |
TW200904752A (en) * | 2007-03-09 | 2009-02-01 | Univ Colorado Regents | Synthesis of zeolites and zeolite membranes using multiple structure directing agents |
MY146586A (en) * | 2007-03-26 | 2012-08-30 | Pq Corp | Novel microporous crystalline material comprising a molecular sieve or zeolite having an 8-ring pore opening structure and methods of making and using same |
CA2724351A1 (en) * | 2008-05-15 | 2009-11-19 | Shell Oil Company | Method of making a high-performance supported gas separation molecular sieve membrane using a shortened crystallization time |
US8680317B2 (en) | 2008-07-31 | 2014-03-25 | Celanese International Corporation | Processes for making ethyl acetate from acetic acid |
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EP2161243A1 (en) | 2008-08-29 | 2010-03-10 | Total Petrochemicals Research Feluy | Method for preparing metalloaluminophosphate (MeAPO) molecular sieves |
EP2161242A1 (en) | 2008-08-29 | 2010-03-10 | Total Petrochemicals Research Feluy | Method for Preparing Crystalline Metalloaluminophosphate (MeAPO) Molecular Sieve from Amorphous Materials |
US7820853B2 (en) | 2008-12-31 | 2010-10-26 | Celanese International Corporation | Integrated process for the production of vinyl acetate from acetic acid via ethyl acetate |
GB0900198D0 (en) * | 2009-01-07 | 2009-02-11 | Univ Southampton | Ammoximation process |
HUE030927T2 (en) | 2009-06-12 | 2017-06-28 | Albemarle Europe Sprl | SAPO molecular filter catalysts and their production and use |
US8680321B2 (en) | 2009-10-26 | 2014-03-25 | Celanese International Corporation | Processes for making ethanol from acetic acid using bimetallic catalysts |
US8211821B2 (en) | 2010-02-01 | 2012-07-03 | Celanese International Corporation | Processes for making tin-containing catalysts |
US8460405B2 (en) | 2010-02-02 | 2013-06-11 | Celanese International Corporation | Ethanol compositions |
US8541633B2 (en) | 2010-02-02 | 2013-09-24 | Celanese International Corporation | Processes for producing anhydrous ethanol compositions |
US8222466B2 (en) | 2010-02-02 | 2012-07-17 | Celanese International Corporation | Process for producing a water stream from ethanol production |
US8858659B2 (en) | 2010-02-02 | 2014-10-14 | Celanese International Corporation | Processes for producing denatured ethanol |
US8932372B2 (en) | 2010-02-02 | 2015-01-13 | Celanese International Corporation | Integrated process for producing alcohols from a mixed acid feed |
AU2011223580B2 (en) * | 2010-03-04 | 2014-03-27 | Shell Internationale Research Maatschappij B.V. | Method of making SAPO-34 membranes for use in gas separations |
AU2011245307B2 (en) | 2010-04-29 | 2014-10-09 | The Regents Of The University Of Colorado, A Body Corporate | High flux SAPO-34 membranes for CO2/CH4 separation and template removal method |
US8569551B2 (en) | 2010-05-07 | 2013-10-29 | Celanese International Corporation | Alcohol production process integrating acetic acid feed stream comprising water from carbonylation process |
CN102350297B (zh) * | 2011-09-14 | 2013-06-12 | 安徽师范大学 | 一种吸附剂、制备方法及其应用 |
US8907142B2 (en) | 2011-12-29 | 2014-12-09 | Celanese International Corporation | Process for promoting catalyst activity for ethyl acetate conversion |
JP6171559B2 (ja) * | 2012-05-24 | 2017-08-02 | 東ソー株式会社 | シリコアルミノリン酸塩、その製造方法及びそれを含む固体酸触媒 |
EP2902362B1 (en) | 2012-09-26 | 2017-06-21 | Dalian Institute Of Chemical Physics, Chinese Academy of Sciences | Sapo-34 molecular sieve and synthesis method thereof |
US8772553B2 (en) | 2012-10-26 | 2014-07-08 | Celanese International Corporation | Hydrogenation reaction conditions for producing ethanol |
US8957262B2 (en) | 2012-11-20 | 2015-02-17 | Celanese International Corporation | Olefin hydration for hydrogenation processes |
US20140171713A1 (en) * | 2012-12-14 | 2014-06-19 | Uop Llc | Nano sapo-35 and method of making |
KR20170044145A (ko) | 2014-08-22 | 2017-04-24 | 더블유.알. 그레이스 앤드 캄파니-콘. | 모노아이소프로판올아민을 사용하여 실리코알루미노포스페이트-34 분자체를 합성하는 방법 |
GB2540832B (en) * | 2015-02-20 | 2019-04-17 | Johnson Matthey Plc | Bi-metal molecular sieve catalysts |
WO2017204993A1 (en) | 2016-05-25 | 2017-11-30 | Uop Llc | High charge density metallophosphate molecular sieves |
US20170354951A1 (en) | 2016-06-10 | 2017-12-14 | Chevron U.S.A. Inc. | Hydrophobic adsorbents and mercury removal processes therewith |
CN108249458B (zh) * | 2018-03-19 | 2021-03-09 | 深圳科冠华太新材料技术有限公司 | 一种金属改性sapo-34分子筛的合成方法 |
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US4973785A (en) * | 1984-04-13 | 1990-11-27 | Uop | Molecular sieve compositions |
US4861743A (en) * | 1987-11-25 | 1989-08-29 | Uop | Process for the production of molecular sieves |
US5514362A (en) * | 1994-05-03 | 1996-05-07 | Chevron U.S.A. Inc. | Preparation of non-zeolitic molecular sieves |
NO304108B1 (no) * | 1996-10-09 | 1998-10-26 | Polymers Holding As | En mikroporos silikoaluminofosfat-sammensetning, katalytisk materiale som omfatter denne sammensetningen og fremgangsmate for fremstilling derav, og bruken av disse for a fremstille olefiner fra metanol |
US6004527A (en) * | 1997-09-29 | 1999-12-21 | Abb Lummus Global Inc. | Method for making molecular sieves and novel molecular sieve compositions |
-
2001
- 2001-11-07 NO NO20015437A patent/NO318680B1/no not_active IP Right Cessation
-
2002
- 2002-11-06 AU AU2002339763A patent/AU2002339763B2/en not_active Ceased
- 2002-11-06 DK DK02778112T patent/DK1461288T3/da active
- 2002-11-06 RU RU2004117071/15A patent/RU2311343C2/ru not_active IP Right Cessation
- 2002-11-06 WO PCT/NO2002/000407 patent/WO2003040037A1/en active IP Right Grant
- 2002-11-06 CN CNB02826598XA patent/CN1308236C/zh not_active Expired - Fee Related
- 2002-11-06 CA CA2465947A patent/CA2465947C/en not_active Expired - Fee Related
- 2002-11-06 US US10/494,862 patent/US7341706B2/en not_active Expired - Fee Related
- 2002-11-06 BR BR0214000-4A patent/BR0214000A/pt not_active Application Discontinuation
- 2002-11-06 DE DE60219357T patent/DE60219357T2/de not_active Expired - Lifetime
- 2002-11-06 ES ES02778112T patent/ES2284936T3/es not_active Expired - Lifetime
- 2002-11-06 PT PT02778112T patent/PT1461288E/pt unknown
- 2002-11-06 MX MXPA04004420A patent/MXPA04004420A/es active IP Right Grant
- 2002-11-06 AT AT02778112T patent/ATE358653T1/de not_active IP Right Cessation
- 2002-11-06 EP EP02778112A patent/EP1461288B1/en not_active Revoked
Also Published As
Publication number | Publication date |
---|---|
ATE358653T1 (de) | 2007-04-15 |
DK1461288T3 (da) | 2007-08-13 |
EP1461288A1 (en) | 2004-09-29 |
EP1461288B1 (en) | 2007-04-04 |
MXPA04004420A (es) | 2004-08-11 |
DE60219357D1 (de) | 2007-05-16 |
US7341706B2 (en) | 2008-03-11 |
RU2004117071A (ru) | 2005-05-20 |
WO2003040037A1 (en) | 2003-05-15 |
CA2465947C (en) | 2011-04-19 |
NO20015437D0 (no) | 2001-11-07 |
NO20015437L (no) | 2003-05-08 |
CA2465947A1 (en) | 2003-05-15 |
DE60219357T2 (de) | 2007-12-13 |
US20050003956A1 (en) | 2005-01-06 |
ES2284936T3 (es) | 2007-11-16 |
BR0214000A (pt) | 2004-11-03 |
CN1308236C (zh) | 2007-04-04 |
CN1610648A (zh) | 2005-04-27 |
PT1461288E (pt) | 2007-07-03 |
AU2002339763B2 (en) | 2008-06-12 |
RU2311343C2 (ru) | 2007-11-27 |
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