NO313642B1 - Tverrbundede fuktabsorberende akrylfibre og fremstillingsfremgangsmåter for disse - Google Patents
Tverrbundede fuktabsorberende akrylfibre og fremstillingsfremgangsmåter for disse Download PDFInfo
- Publication number
- NO313642B1 NO313642B1 NO20005834A NO20005834A NO313642B1 NO 313642 B1 NO313642 B1 NO 313642B1 NO 20005834 A NO20005834 A NO 20005834A NO 20005834 A NO20005834 A NO 20005834A NO 313642 B1 NO313642 B1 NO 313642B1
- Authority
- NO
- Norway
- Prior art keywords
- cross
- acrylic fibers
- moisture
- comonomer
- fibers
- Prior art date
Links
- 229920002972 Acrylic fiber Polymers 0.000 title claims description 67
- 238000004519 manufacturing process Methods 0.000 title claims description 13
- 239000002250 absorbent Substances 0.000 title description 7
- 230000002745 absorbent Effects 0.000 title description 7
- OAKJQQAXSVQMHS-UHFFFAOYSA-N hydrazine Substances NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 65
- 238000004132 cross linking Methods 0.000 claims description 48
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 40
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 30
- 238000006460 hydrolysis reaction Methods 0.000 claims description 26
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 24
- 239000002253 acid Substances 0.000 claims description 23
- 229920001577 copolymer Polymers 0.000 claims description 23
- 229910052757 nitrogen Inorganic materials 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 19
- 230000007062 hydrolysis Effects 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 15
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 15
- 238000010521 absorption reaction Methods 0.000 claims description 13
- 230000008961 swelling Effects 0.000 claims description 13
- -1 hydrazine compound Chemical class 0.000 claims description 12
- 150000003839 salts Chemical class 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 5
- 125000000542 sulfonic acid group Chemical group 0.000 claims description 2
- 239000000835 fiber Substances 0.000 description 30
- 238000006243 chemical reaction Methods 0.000 description 17
- 239000002994 raw material Substances 0.000 description 11
- 239000000243 solution Substances 0.000 description 11
- 238000002474 experimental method Methods 0.000 description 10
- 238000009987 spinning Methods 0.000 description 9
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 230000003578 releasing effect Effects 0.000 description 6
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- 230000007935 neutral effect Effects 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 3
- 125000002560 nitrile group Chemical group 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 238000004904 shortening Methods 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 230000015271 coagulation Effects 0.000 description 2
- 238000005345 coagulation Methods 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 description 2
- 230000003301 hydrolyzing effect Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 description 2
- 238000000954 titration curve Methods 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- 238000002166 wet spinning Methods 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- XEEYSDHEOQHCDA-UHFFFAOYSA-N 2-methylprop-2-ene-1-sulfonic acid Chemical compound CC(=C)CS(O)(=O)=O XEEYSDHEOQHCDA-UHFFFAOYSA-N 0.000 description 1
- SMTDFMMXJHYDDE-UHFFFAOYSA-N 2-prop-1-enylpyridine Chemical compound CC=CC1=CC=CC=N1 SMTDFMMXJHYDDE-UHFFFAOYSA-N 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- FUSNOPLQVRUIIM-UHFFFAOYSA-N 4-amino-2-(4,4-dimethyl-2-oxoimidazolidin-1-yl)-n-[3-(trifluoromethyl)phenyl]pyrimidine-5-carboxamide Chemical compound O=C1NC(C)(C)CN1C(N=C1N)=NC=C1C(=O)NC1=CC=CC(C(F)(F)F)=C1 FUSNOPLQVRUIIM-UHFFFAOYSA-N 0.000 description 1
- MAGFQRLKWCCTQJ-UHFFFAOYSA-N 4-ethenylbenzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=C(C=C)C=C1 MAGFQRLKWCCTQJ-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 229910017852 NH2NH2 Inorganic materials 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 1
- BIVUUOPIAYRCAP-UHFFFAOYSA-N aminoazanium;chloride Chemical compound Cl.NN BIVUUOPIAYRCAP-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- PTYMQUSHTAONGW-UHFFFAOYSA-N carbonic acid;hydrazine Chemical compound NN.OC(O)=O PTYMQUSHTAONGW-UHFFFAOYSA-N 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000012493 hydrazine sulfate Substances 0.000 description 1
- 229910000377 hydrazine sulfate Inorganic materials 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 210000003254 palate Anatomy 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
- D06M11/63—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with hydroxylamine or hydrazine
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/338—Organic hydrazines; Hydrazinium compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/26—Polymers or copolymers of unsaturated carboxylic acids or derivatives thereof
- D06M2101/28—Acrylonitrile; Methacrylonitrile
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Nonwoven Fabrics (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11074332A JP2998958B1 (ja) | 1999-03-18 | 1999-03-18 | 架橋アクリル系吸湿繊維及びその製造方法 |
| PCT/JP1999/005974 WO2000055417A1 (fr) | 1999-03-18 | 1999-10-28 | Fibre hygroscopique acrylique reticulee et son procede de production |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO20005834D0 NO20005834D0 (no) | 2000-11-17 |
| NO20005834L NO20005834L (no) | 2001-01-17 |
| NO313642B1 true NO313642B1 (no) | 2002-11-04 |
Family
ID=13544072
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO20005834A NO313642B1 (no) | 1999-03-18 | 2000-11-17 | Tverrbundede fuktabsorberende akrylfibre og fremstillingsfremgangsmåter for disse |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6736856B1 (ja) |
| EP (1) | EP1111122A4 (ja) |
| JP (1) | JP2998958B1 (ja) |
| KR (1) | KR20010043656A (ja) |
| CN (1) | CN1293258C (ja) |
| CA (1) | CA2332143C (ja) |
| NO (1) | NO313642B1 (ja) |
| WO (1) | WO2000055417A1 (ja) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7537823B2 (en) | 2001-01-26 | 2009-05-26 | Japan Exlan Company Limited | High-whiteness hygroscopic fiber |
| JP2005193853A (ja) * | 2004-01-09 | 2005-07-21 | Yokohama Rubber Co Ltd:The | 重荷重用空気入りタイヤ及びその製造方法 |
| WO2006006454A1 (ja) | 2004-07-14 | 2006-01-19 | Teijin Fibers Limited | 靴内部材および靴中敷きおよび長靴 |
| KR101593726B1 (ko) * | 2008-09-10 | 2016-02-18 | 니혼 엑스란 고교 (주) | 가교 아크릴레이트계 섬유 및 이의 제조방법 |
| CN101845745B (zh) * | 2009-03-26 | 2013-06-12 | 山东理工大学 | 高吸湿和阻燃多重功能改性腈纶的制造方法 |
| CN101962912A (zh) * | 2010-08-20 | 2011-02-02 | 山东理工大学 | 高吸湿吸水腈纶的制备方法 |
| CN104086699B (zh) * | 2014-07-04 | 2016-06-08 | 青岛科技大学 | 一种非共混型高稳定性聚丙烯酸酯吸水膨胀橡胶及其制备方法 |
| CN104562705B (zh) * | 2014-12-15 | 2016-06-29 | 河南省科学院化学研究所有限公司 | 大分子功能化的纤维材料及其合成方法 |
| CN106147959B (zh) | 2015-04-20 | 2019-08-20 | 中国石油化工股份有限公司 | 一种润滑剂组合物及其制备方法和应用 |
| JP6633183B2 (ja) * | 2016-03-25 | 2020-01-22 | 株式会社日本触媒 | 繊維処理剤 |
| US20230091300A1 (en) * | 2019-12-26 | 2023-03-23 | Kanagawa University | Crosslinked polymer compound and method for producing same, absorbent article, disposable diaper, sanitary article, treatment container, and treatment method |
| CN114686996B (zh) * | 2022-01-29 | 2023-04-18 | 军事科学院系统工程研究院军需工程技术研究所 | 一种吸湿发热纤维及其制造方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2623771B2 (ja) * | 1988-09-21 | 1997-06-25 | 日本エクスラン工業株式会社 | 高吸湿性繊維 |
| JP3196855B2 (ja) * | 1991-11-11 | 2001-08-06 | 東洋紡績株式会社 | 高吸放湿性繊維 |
| JP3196577B2 (ja) * | 1995-06-05 | 2001-08-06 | 日本エクスラン工業株式会社 | ｐＨ緩衝性吸湿性アクリル系繊維及びその製造方法 |
| JP3997438B2 (ja) * | 1995-08-04 | 2007-10-24 | 東洋紡績株式会社 | 低温再生型吸湿素子 |
| JP3369380B2 (ja) * | 1995-11-29 | 2003-01-20 | 東洋紡績株式会社 | 改善された高吸放湿性繊維及びその製造方法 |
| JP3271692B2 (ja) * | 1996-02-26 | 2002-04-02 | 日本エクスラン工業株式会社 | 酸・塩基性ガス吸収性繊維及びその構造物 |
| JP3030769B2 (ja) * | 1997-08-28 | 2000-04-10 | 東邦レーヨン株式会社 | 架橋アクリル系吸湿繊維及びその製造方法 |
| JP4273512B2 (ja) * | 1999-06-28 | 2009-06-03 | 日本エクスラン工業株式会社 | 吸放湿性重合体およびその成形体 |
-
1999
- 1999-03-18 JP JP11074332A patent/JP2998958B1/ja not_active Expired - Fee Related
- 1999-10-28 US US09/703,987 patent/US6736856B1/en not_active Expired - Fee Related
- 1999-10-28 CA CA002332143A patent/CA2332143C/en not_active Expired - Fee Related
- 1999-10-28 CN CNB998063401A patent/CN1293258C/zh not_active Expired - Fee Related
- 1999-10-28 KR KR1020007012847A patent/KR20010043656A/ko active IP Right Grant
- 1999-10-28 WO PCT/JP1999/005974 patent/WO2000055417A1/ja active IP Right Grant
- 1999-10-28 EP EP99951114A patent/EP1111122A4/en not_active Withdrawn
-
2000
- 2000-11-17 NO NO20005834A patent/NO313642B1/no unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP1111122A4 (en) | 2002-06-12 |
| EP1111122A1 (en) | 2001-06-27 |
| CN1293258C (zh) | 2007-01-03 |
| JP2000265365A (ja) | 2000-09-26 |
| KR20010043656A (ko) | 2001-05-25 |
| CN1301319A (zh) | 2001-06-27 |
| NO20005834L (no) | 2001-01-17 |
| US6736856B1 (en) | 2004-05-18 |
| JP2998958B1 (ja) | 2000-01-17 |
| NO20005834D0 (no) | 2000-11-17 |
| WO2000055417A1 (fr) | 2000-09-21 |
| CA2332143A1 (en) | 2000-09-21 |
| CA2332143C (en) | 2008-12-23 |
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