NO300896B1 - Fremgangsmåte til fremstilling av perleformede, ekspanderbare styrenpolymerisater - Google Patents
Fremgangsmåte til fremstilling av perleformede, ekspanderbare styrenpolymerisater Download PDFInfo
- Publication number
- NO300896B1 NO300896B1 NO932193A NO932193A NO300896B1 NO 300896 B1 NO300896 B1 NO 300896B1 NO 932193 A NO932193 A NO 932193A NO 932193 A NO932193 A NO 932193A NO 300896 B1 NO300896 B1 NO 300896B1
- Authority
- NO
- Norway
- Prior art keywords
- tert
- expandable styrene
- bead
- styrene
- shaped
- Prior art date
Links
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 title claims abstract description 50
- 238000000034 method Methods 0.000 title claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 claims abstract description 6
- FPCCSQOGAWCVBH-UHFFFAOYSA-N ketanserin Chemical compound C1=CC(F)=CC=C1C(=O)C1CCN(CCN2C(C3=CC=CC=C3NC2=O)=O)CC1 FPCCSQOGAWCVBH-UHFFFAOYSA-N 0.000 claims abstract 3
- 239000003999 initiator Substances 0.000 claims description 5
- 238000006116 polymerization reaction Methods 0.000 claims description 5
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 4
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 4
- 239000001273 butane Substances 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 239000007900 aqueous suspension Substances 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract description 30
- 229920000642 polymer Polymers 0.000 abstract description 18
- 239000002245 particle Substances 0.000 abstract description 3
- 239000003505 polymerization initiator Substances 0.000 abstract description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 6
- 239000006260 foam Substances 0.000 description 5
- 239000004604 Blowing Agent Substances 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 150000002978 peroxides Chemical class 0.000 description 4
- 238000010557 suspension polymerization reaction Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000001506 calcium phosphate Substances 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
- CRSOQBOWXPBRES-UHFFFAOYSA-N neopentane Chemical compound CC(C)(C)C CRSOQBOWXPBRES-UHFFFAOYSA-N 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 2
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 2
- 229940078499 tricalcium phosphate Drugs 0.000 description 2
- 229910000391 tricalcium phosphate Inorganic materials 0.000 description 2
- 235000019731 tricalcium phosphate Nutrition 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- DEIGXXQKDWULML-UHFFFAOYSA-N 1,2,5,6,9,10-hexabromocyclododecane Chemical compound BrC1CCC(Br)C(Br)CCC(Br)C(Br)CCC1Br DEIGXXQKDWULML-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical class C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- WAKZZMMCDILMEF-UHFFFAOYSA-H barium(2+);diphosphate Chemical compound [Ba+2].[Ba+2].[Ba+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O WAKZZMMCDILMEF-UHFFFAOYSA-H 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- QWTDNUCVQCZILF-UHFFFAOYSA-N iso-pentane Natural products CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- KKFHAJHLJHVUDM-UHFFFAOYSA-N n-vinylcarbazole Chemical compound C1=CC=C2N(C=C)C3=CC=CC=C3C2=C1 KKFHAJHLJHVUDM-UHFFFAOYSA-N 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F12/02—Monomers containing only one unsaturated aliphatic radical
- C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F12/06—Hydrocarbons
- C08F12/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/16—Making expandable particles
- C08J9/20—Making expandable particles by suspension polymerisation in the presence of the blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/18—Suspension polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/28—Oxygen or compounds releasing free oxygen
- C08F4/32—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
- C08J2325/06—Polystyrene
Landscapes
- Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4219379A DE4219379A1 (de) | 1992-06-13 | 1992-06-13 | Verfahren zur Herstellung von perlförmigen expandierbaren Styrolpolymerisaten |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO932193D0 NO932193D0 (no) | 1993-06-14 |
| NO932193L NO932193L (no) | 1993-12-14 |
| NO300896B1 true NO300896B1 (no) | 1997-08-11 |
Family
ID=6460938
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO932193A NO300896B1 (no) | 1992-06-13 | 1993-06-14 | Fremgangsmåte til fremstilling av perleformede, ekspanderbare styrenpolymerisater |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US5266603A (ko) |
| EP (1) | EP0574665B1 (ko) |
| JP (1) | JP2659506B2 (ko) |
| KR (1) | KR0138974B1 (ko) |
| CN (1) | CN1080293A (ko) |
| AT (1) | ATE138946T1 (ko) |
| BR (1) | BR9302291A (ko) |
| CA (1) | CA2098240A1 (ko) |
| DE (2) | DE4219379A1 (ko) |
| ES (1) | ES2088187T3 (ko) |
| FI (1) | FI932631A (ko) |
| MX (1) | MX9303462A (ko) |
| NO (1) | NO300896B1 (ko) |
| TW (1) | TW284775B (ko) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3908990A1 (de) * | 1989-03-18 | 1990-09-20 | Skf Gmbh | Vorrichtung zum beladen von messtischen |
| US5591778A (en) * | 1995-08-14 | 1997-01-07 | Basf Aktiengesellschaft | Process for the preparation of expandable polystyrene |
| US5760149A (en) * | 1996-08-23 | 1998-06-02 | Elf Atochem North America, Inc. | Poly(monoperoxycarbonates) |
| DE19749570A1 (de) * | 1997-11-10 | 1999-05-12 | Basf Ag | Verfahren zur Herstellung von expandierbaren Styrolpolymerisaten |
| WO1999054391A1 (en) * | 1998-04-17 | 1999-10-28 | Nova Chemicals (International) S.A. | Process for the preparation of expandable polymer particles |
| DE19835495A1 (de) * | 1998-08-06 | 2000-02-10 | Basf Ag | Verfahren zur Herstellung von expandierbaren Styrolpolymerisaten |
| EP1251143B1 (en) * | 2001-04-17 | 2012-07-18 | Total Petrochemicals Research Feluy | Monovinylaromatic polymer with improved stress crack resistance |
| US6608150B1 (en) * | 2002-10-08 | 2003-08-19 | Atofina Chemicals, Inc. | Preparation of expandable styrene polymers |
| DE102004034527A1 (de) * | 2004-07-15 | 2006-02-16 | Basf Ag | Verfahren zur Herstellung von expandierbaren Styrolpolymeren mit verbesserter Expandierbarkeit |
| BRPI0614787A2 (pt) * | 2005-08-08 | 2011-04-12 | Albemarle Corp | espumas poliméricas estirênicas retardadoras de chama e precursores da espuma |
| US9260650B2 (en) | 2012-08-29 | 2016-02-16 | Halliburton Energy Services, Inc. | Methods for hindering settling of proppant aggregates in subterranean operations |
| RU2624599C1 (ru) * | 2016-06-20 | 2017-07-04 | Российская Федерация, от имени которой выступает Государственная корпорация по атомной энергии "Росатом" (Госкорпорация "Росатом") | Устройство для регулирования положения крупногабаритного объекта |
| FR3105229B1 (fr) * | 2019-12-18 | 2022-04-01 | Arkema France | Procédé de polymérisation d’une suspension aqueuse de styrène à l’aide d’au moins un peroxyde organique hémi-peroxyacétal |
| CN113265017A (zh) * | 2021-05-24 | 2021-08-17 | 仲恺农业工程学院 | 用于制备聚苯乙烯的悬浮聚合方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE498376A (ko) * | 1948-09-28 | |||
| US3192169A (en) * | 1965-01-07 | 1965-06-29 | Kenneth W Doak | Method of making expandable polymeric styrene particles |
| DE2714800A1 (de) * | 1977-04-02 | 1978-10-12 | Basf Ag | Verfahren zur herstellung von vernetzten schaumfaehigen formkoerpern aus olefinpolymerisaten |
| US4129531A (en) * | 1977-12-14 | 1978-12-12 | Pennwalt Corporation | Crosslinking of polymers with azo-esters |
| US4465792A (en) * | 1982-06-24 | 1984-08-14 | Standard Oil Company, A Corporation Of Indiana | Process for producing flexible polyester foam |
| US4460748A (en) * | 1982-07-06 | 1984-07-17 | Luperox Gmbh | Process for crosslinking and, if desired, foaming natural or synthetic homo- and/or copolymers |
| DE3436877A1 (de) * | 1984-10-08 | 1986-04-10 | Luperox GmbH, 8870 Günzburg | Vernetzung von styrolpolymeren |
| US4692269A (en) * | 1985-09-25 | 1987-09-08 | Pennwalt Corporation | Gas-releasing composition for tailoring gas evolution of system |
| US4636528A (en) * | 1985-09-26 | 1987-01-13 | Pennwalt Corporation | Foaming of unsaturated polyester resin at elevated temperatures |
| JPH01161004A (ja) * | 1987-07-24 | 1989-06-23 | Kayaku Nuurii Kk | スチレンの懸濁重合方法 |
| DE4038044A1 (de) * | 1990-11-29 | 1992-06-04 | Basf Ag | Expandierbare styrolpolymerisate mit hoher expandierbarkeit |
-
1992
- 1992-06-13 DE DE4219379A patent/DE4219379A1/de not_active Withdrawn
-
1993
- 1993-03-11 US US08/029,616 patent/US5266603A/en not_active Expired - Fee Related
- 1993-04-10 TW TW082102679A patent/TW284775B/zh active
- 1993-04-14 DE DE59302797T patent/DE59302797D1/de not_active Revoked
- 1993-04-14 AT AT93106038T patent/ATE138946T1/de active
- 1993-04-14 ES ES93106038T patent/ES2088187T3/es not_active Expired - Lifetime
- 1993-04-14 EP EP93106038A patent/EP0574665B1/de not_active Revoked
- 1993-06-08 JP JP5137481A patent/JP2659506B2/ja not_active Expired - Lifetime
- 1993-06-09 FI FI932631A patent/FI932631A/fi unknown
- 1993-06-10 MX MX9303462A patent/MX9303462A/es not_active IP Right Cessation
- 1993-06-11 KR KR1019930010588A patent/KR0138974B1/ko not_active IP Right Cessation
- 1993-06-11 BR BR9302291A patent/BR9302291A/pt not_active Application Discontinuation
- 1993-06-11 CN CN93106865A patent/CN1080293A/zh active Pending
- 1993-06-11 CA CA002098240A patent/CA2098240A1/en not_active Abandoned
- 1993-06-14 NO NO932193A patent/NO300896B1/no unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US5266603A (en) | 1993-11-30 |
| JPH0680708A (ja) | 1994-03-22 |
| DE59302797D1 (de) | 1996-07-11 |
| EP0574665B1 (de) | 1996-06-05 |
| CN1080293A (zh) | 1994-01-05 |
| JP2659506B2 (ja) | 1997-09-30 |
| MX9303462A (es) | 1994-01-31 |
| ES2088187T3 (es) | 1996-08-01 |
| NO932193L (no) | 1993-12-14 |
| DE4219379A1 (de) | 1993-12-16 |
| NO932193D0 (no) | 1993-06-14 |
| FI932631A (fi) | 1993-12-14 |
| KR0138974B1 (ko) | 1998-05-01 |
| EP0574665A1 (de) | 1993-12-22 |
| FI932631A0 (fi) | 1993-06-09 |
| BR9302291A (pt) | 1994-01-11 |
| KR940000486A (ko) | 1994-01-03 |
| ATE138946T1 (de) | 1996-06-15 |
| CA2098240A1 (en) | 1993-12-14 |
| TW284775B (ko) | 1996-09-01 |
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