NL1011394C2 - Bereiding van sterisch gehinderde amine-ethers. - Google Patents

Info

Publication number

NL1011394C2

NL1011394C2 NL1011394A NL1011394A NL1011394C2 NL 1011394 C2 NL1011394 C2 NL 1011394C2 NL 1011394 A NL1011394 A NL 1011394A NL 1011394 A NL1011394 A NL 1011394A NL 1011394 C2 NL1011394 C2 NL 1011394C2

Authority

NL

Netherlands

Prior art keywords

alkyl

formula

group

substituted

independently

Prior art date

1998-02-25

Links

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• -1 amine ethers Chemical class 0.000 title claims description 224
• 238000002360 preparation method Methods 0.000 title claims description 19
• 150000001875 compounds Chemical class 0.000 claims description 148
• 229910052739 hydrogen Inorganic materials 0.000 claims description 104
• 239000000203 mixture Substances 0.000 claims description 99
• 239000001257 hydrogen Substances 0.000 claims description 81
• 125000000217 alkyl group Chemical group 0.000 claims description 76
• 229910052799 carbon Inorganic materials 0.000 claims description 66
• 125000003118 aryl group Chemical group 0.000 claims description 57
• 125000004432 carbon atom Chemical group C* 0.000 claims description 54
• 125000000753 cycloalkyl group Chemical group 0.000 claims description 52
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 47
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 47
• 229910052736 halogen Inorganic materials 0.000 claims description 46
• 150000002367 halogens Chemical group 0.000 claims description 45
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 44
• 125000001931 aliphatic group Chemical group 0.000 claims description 39
• 238000000034 method Methods 0.000 claims description 38
• 229910052757 nitrogen Inorganic materials 0.000 claims description 37
• 229910052760 oxygen Inorganic materials 0.000 claims description 35
• 125000002947 alkylene group Chemical group 0.000 claims description 34
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 34
• 239000001301 oxygen Substances 0.000 claims description 34
• GJVFBWCTGUSGDD-UHFFFAOYSA-L pentamethonium bromide Chemical compound [Br-].[Br-].C[N+](C)(C)CCCCC[N+](C)(C)C GJVFBWCTGUSGDD-UHFFFAOYSA-L 0.000 claims description 34
• 238000000576 coating method Methods 0.000 claims description 33
• 150000002431 hydrogen Chemical class 0.000 claims description 31
• 239000002253 acid Substances 0.000 claims description 30
• 239000003381 stabilizer Substances 0.000 claims description 30
• 125000003342 alkenyl group Chemical group 0.000 claims description 26
• 229910052751 metal Inorganic materials 0.000 claims description 23
• 239000002184 metal Substances 0.000 claims description 22
• 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 20
• 229910052698 phosphorus Inorganic materials 0.000 claims description 20
• OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 19
• 239000011230 binding agent Substances 0.000 claims description 19
• 239000011574 phosphorus Chemical group 0.000 claims description 19
• OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 18
• 239000002904 solvent Substances 0.000 claims description 18
• 125000006575 electron-withdrawing group Chemical group 0.000 claims description 17
• 125000005842 heteroatom Chemical group 0.000 claims description 16
• 229930195733 hydrocarbon Natural products 0.000 claims description 16
• 125000005647 linker group Chemical group 0.000 claims description 16
• 230000008569 process Effects 0.000 claims description 16
• 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 15
• 239000003795 chemical substances by application Substances 0.000 claims description 15
• 150000002430 hydrocarbons Chemical class 0.000 claims description 15
• 125000003884 phenylalkyl group Chemical group 0.000 claims description 15
• 125000002252 acyl group Chemical group 0.000 claims description 14
• 125000003545 alkoxy group Chemical group 0.000 claims description 14
• 125000004122 cyclic group Chemical group 0.000 claims description 14
• IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 14
• 239000000126 substance Substances 0.000 claims description 14
• 239000004215 Carbon black (E152) Substances 0.000 claims description 13
• 239000011248 coating agent Substances 0.000 claims description 13
• 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 12
• 125000003506 n-propoxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])O* 0.000 claims description 12
• 125000004433 nitrogen atom Chemical group N* 0.000 claims description 12
• 229920000620 organic polymer Polymers 0.000 claims description 12
• 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 12
• NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 11
• 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 claims description 11
• 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 11
• 239000000463 material Substances 0.000 claims description 11
• 230000000087 stabilizing effect Effects 0.000 claims description 11
• 229910052717 sulfur Inorganic materials 0.000 claims description 11
• 239000011593 sulfur Chemical group 0.000 claims description 11
• 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 10
• QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 10
• 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims description 9
• 229920001169 thermoplastic Polymers 0.000 claims description 9
• 125000003031 C5-C7 cycloalkylene group Chemical group 0.000 claims description 8
• 230000015556 catabolic process Effects 0.000 claims description 8
• 238000006731 degradation reaction Methods 0.000 claims description 8
• XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 7
• XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical group NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 7
• 125000000732 arylene group Chemical group 0.000 claims description 7
• 239000003063 flame retardant Substances 0.000 claims description 7
• 238000007254 oxidation reaction Methods 0.000 claims description 7
• 230000001590 oxidative effect Effects 0.000 claims description 7
• 125000004430 oxygen atom Chemical group O* 0.000 claims description 7
• 229910052710 silicon Inorganic materials 0.000 claims description 7
• 239000010703 silicon Chemical group 0.000 claims description 7
• 239000004416 thermosoftening plastic Substances 0.000 claims description 7
• 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 7
• 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 claims description 6
• HWRLEEPNFJNTOP-UHFFFAOYSA-N 2-(1,3,5-triazin-2-yl)phenol Chemical class OC1=CC=CC=C1C1=NC=NC=N1 HWRLEEPNFJNTOP-UHFFFAOYSA-N 0.000 claims description 6
• 125000004648 C2-C8 alkenyl group Chemical group 0.000 claims description 6
• 125000003710 aryl alkyl group Chemical group 0.000 claims description 6
• WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 6
• 125000004093 cyano group Chemical group *C#N 0.000 claims description 6
• 125000001188 haloalkyl group Chemical group 0.000 claims description 6
• 239000004611 light stabiliser Substances 0.000 claims description 6
• 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 6
• 239000011368 organic material Substances 0.000 claims description 6
• 239000000049 pigment Substances 0.000 claims description 6
• OLRJXMHANKMLTD-UHFFFAOYSA-N silyl Chemical compound [SiH3] OLRJXMHANKMLTD-UHFFFAOYSA-N 0.000 claims description 6
• 229920002554 vinyl polymer Polymers 0.000 claims description 6
• 125000006839 xylylene group Chemical group 0.000 claims description 6
• 239000006096 absorbing agent Substances 0.000 claims description 5
• 238000005984 hydrogenation reaction Methods 0.000 claims description 5
• 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 5
• 125000001181 organosilyl group Chemical group [SiH3]* 0.000 claims description 5
• 239000007800 oxidant agent Substances 0.000 claims description 5
• 230000003647 oxidation Effects 0.000 claims description 5
• AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 claims description 5
• 125000001424 substituent group Chemical group 0.000 claims description 5
• 125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 claims description 4
• HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 4
• 125000004453 alkoxycarbonyl group Chemical group 0.000 claims description 4
• KXDHJXZQYSOELW-UHFFFAOYSA-N carbonic acid monoamide Natural products NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims description 4
• 125000002993 cycloalkylene group Chemical group 0.000 claims description 4
• WMNPPTFIWBUUQT-NAWIUCTOSA-N G12 Chemical compound C1=NC(C(NC(N)=N2)=O)=C2N1[C@@H]([C@@H]1O)O[C@H](COP(O)(=O)O[C@H]2[C@H]([C@@H](O[C@@H]2COP(O)(=O)O[C@H]2[C@H]([C@@H](O[C@@H]2COP(O)(=O)O[C@H]2[C@H]([C@@H](O[C@@H]2COP(O)(=O)O[C@H]2[C@H]([C@@H](O[C@@H]2COP(O)(=O)O[C@H]2[C@H]([C@@H](O[C@@H]2COP(O)(=O)O[C@H]2[C@H]([C@@H](O[C@@H]2COP(O)(=O)O[C@H]2[C@H]([C@@H](O[C@@H]2COP(O)(=O)O[C@H]2[C@H]([C@@H](O[C@@H]2COP(O)(=O)O[C@H]2[C@H]([C@@H](O[C@@H]2COP(O)(=O)O[C@H]2[C@H]([C@@H](O[C@@H]2CO)N2C3=C(C(NC(N)=N3)=O)N=C2)O)N2C3=C(C(NC(N)=N3)=O)N=C2)O)N2C3=C(C(NC(N)=N3)=O)N=C2)O)N2C3=C(C(NC(N)=N3)=O)N=C2)O)N2C3=C(C(NC(N)=N3)=O)N=C2)O)N2C3=C(C(NC(N)=N3)=O)N=C2)O)N2C3=C(C(NC(N)=N3)=O)N=C2)O)N2C3=C(C(NC(N)=N3)=O)N=C2)O)N2C3=C(C(NC(N)=N3)=O)N=C2)O)N2C3=C(C(NC(N)=N3)=O)N=C2)O)[C@H]1OP(O)(=O)OC[C@H]([C@@H](O)[C@H]1O)O[C@H]1N1C(N=C(NC2=O)N)=C2N=C1 WMNPPTFIWBUUQT-NAWIUCTOSA-N 0.000 claims description 3
• 150000007933 aliphatic carboxylic acids Chemical class 0.000 claims description 3
• 125000004450 alkenylene group Chemical group 0.000 claims description 3
• 239000003963 antioxidant agent Substances 0.000 claims description 3
• 229910002091 carbon monoxide Inorganic materials 0.000 claims description 3
• 230000026030 halogenation Effects 0.000 claims description 3
• 238000005658 halogenation reaction Methods 0.000 claims description 3
• 150000002978 peroxides Chemical class 0.000 claims description 3
• 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 3
• XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical class OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 claims description 3
• 239000004014 plasticizer Substances 0.000 claims description 3
• KJAMZCVTJDTESW-UHFFFAOYSA-N tiracizine Chemical compound C1CC2=CC=CC=C2N(C(=O)CN(C)C)C2=CC(NC(=O)OCC)=CC=C21 KJAMZCVTJDTESW-UHFFFAOYSA-N 0.000 claims description 3
• 229910052720 vanadium Inorganic materials 0.000 claims description 3
• 150000007934 α,β-unsaturated carboxylic acids Chemical class 0.000 claims description 3
• RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 2
• YHCGGLXPGFJNCO-UHFFFAOYSA-N 2-(2H-benzotriazol-4-yl)phenol Chemical class OC1=CC=CC=C1C1=CC=CC2=C1N=NN2 YHCGGLXPGFJNCO-UHFFFAOYSA-N 0.000 claims description 2
• XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical class [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims description 2
• 239000012965 benzophenone Substances 0.000 claims description 2
• 150000008366 benzophenones Chemical class 0.000 claims description 2
• 239000000975 dye Substances 0.000 claims description 2
• 150000002823 nitrates Chemical class 0.000 claims description 2
• 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 2
• 229910052707 ruthenium Inorganic materials 0.000 claims description 2
• 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 claims 6
• 125000001589 carboacyl group Chemical group 0.000 claims 2
• 150000001735 carboxylic acids Chemical class 0.000 claims 2
• UUFQTNFCRMXOAE-UHFFFAOYSA-N 1-methylmethylene Chemical compound C[CH] UUFQTNFCRMXOAE-UHFFFAOYSA-N 0.000 claims 1
• 101001053401 Arabidopsis thaliana Acid beta-fructofuranosidase 3, vacuolar Proteins 0.000 claims 1
• 125000004423 acyloxy group Chemical group 0.000 claims 1
• 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
• 230000009974 thixotropic effect Effects 0.000 claims 1
• 239000000243 solution Substances 0.000 description 55
• YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 51
• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 49
• 229920001577 copolymer Polymers 0.000 description 40
• BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 40
• 239000000047 product Substances 0.000 description 40
• 229920000642 polymer Polymers 0.000 description 37
• 150000003254 radicals Chemical class 0.000 description 36
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 32
• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 27
• 239000003054 catalyst Substances 0.000 description 27
• 150000001721 carbon Chemical group 0.000 description 25
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 23
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 22
• 150000001412 amines Chemical class 0.000 description 22
• 229920005989 resin Polymers 0.000 description 22
• 239000011347 resin Substances 0.000 description 22
• 238000003756 stirring Methods 0.000 description 22
• 239000003973 paint Substances 0.000 description 21
• 229910000027 potassium carbonate Inorganic materials 0.000 description 20
• 239000008199 coating composition Substances 0.000 description 19
• 150000002148 esters Chemical group 0.000 description 19
• 229920001684 low density polyethylene Polymers 0.000 description 19
• 239000004702 low-density polyethylene Substances 0.000 description 19
• 235000011181 potassium carbonates Nutrition 0.000 description 18
• 239000007787 solid Substances 0.000 description 18
• 239000004743 Polypropylene Substances 0.000 description 17
• 239000012044 organic layer Substances 0.000 description 17
• 229920001155 polypropylene Polymers 0.000 description 17
• 238000006243 chemical reaction Methods 0.000 description 15
• 239000000843 powder Substances 0.000 description 14
• NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 13
• QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 12
• CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 12
• KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 12
• 239000004952 Polyamide Substances 0.000 description 12
• 239000007859 condensation product Substances 0.000 description 12
• MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 12
• 229920002647 polyamide Polymers 0.000 description 12
• 229920000515 polycarbonate Polymers 0.000 description 12
• 239000004417 polycarbonate Substances 0.000 description 12
• 239000008096 xylene Substances 0.000 description 12
• PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 11
• 239000011572 manganese Substances 0.000 description 11
• 229920000728 polyester Polymers 0.000 description 11
• 229910052938 sodium sulfate Inorganic materials 0.000 description 11
• 235000011152 sodium sulphate Nutrition 0.000 description 11
• VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 10
• 239000005977 Ethylene Substances 0.000 description 10
• 229920000877 Melamine resin Polymers 0.000 description 10
• ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 10
• 239000004698 Polyethylene Substances 0.000 description 10
• 150000001252 acrylic acid derivatives Chemical class 0.000 description 10
• 229910052794 bromium Inorganic materials 0.000 description 10
• 238000001723 curing Methods 0.000 description 10
• 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 10
• 239000010410 layer Substances 0.000 description 10
• 229920000573 polyethylene Polymers 0.000 description 10
• 239000004814 polyurethane Substances 0.000 description 10
• NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 9
• 239000000654 additive Substances 0.000 description 9
• 239000000460 chlorine Substances 0.000 description 9
• 238000001914 filtration Methods 0.000 description 9
• VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 9
• BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 9
• 229920002857 polybutadiene Polymers 0.000 description 9
• 229920000647 polyepoxide Polymers 0.000 description 9
• 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 9
• 238000005160 1H NMR spectroscopy Methods 0.000 description 8
• WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 8
• RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
• 239000005062 Polybutadiene Substances 0.000 description 8
• 239000004721 Polyphenylene oxide Substances 0.000 description 8
• 239000007983 Tris buffer Substances 0.000 description 8
• BHELZAPQIKSEDF-UHFFFAOYSA-N allyl bromide Chemical compound BrCC=C BHELZAPQIKSEDF-UHFFFAOYSA-N 0.000 description 8
• 150000008064 anhydrides Chemical class 0.000 description 8
• GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 8
• KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 8
• 238000001035 drying Methods 0.000 description 8
• 239000003921 oil Substances 0.000 description 8
• 229920002635 polyurethane Polymers 0.000 description 8
• 229910001220 stainless steel Inorganic materials 0.000 description 8
• 239000010935 stainless steel Substances 0.000 description 8
• 239000000758 substrate Substances 0.000 description 8
• 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 7
• 239000007864 aqueous solution Substances 0.000 description 7
• QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 7
• 239000012964 benzotriazole Substances 0.000 description 7
• 229920001903 high density polyethylene Polymers 0.000 description 7
• 239000004700 high-density polyethylene Substances 0.000 description 7
• 229910052748 manganese Inorganic materials 0.000 description 7
• 239000000575 pesticide Substances 0.000 description 7
• 229920000570 polyether Polymers 0.000 description 7
• 238000006116 polymerization reaction Methods 0.000 description 7
• 229920006324 polyoxymethylene Polymers 0.000 description 7
• 230000006641 stabilisation Effects 0.000 description 7
• 238000011105 stabilization Methods 0.000 description 7
• 239000004925 Acrylic resin Substances 0.000 description 6
• UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
• YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
• 239000004594 Masterbatch (MB) Substances 0.000 description 6
• LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 6
• CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
• HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
• 150000001732 carboxylic acid derivatives Chemical class 0.000 description 6
• 229910052801 chlorine Inorganic materials 0.000 description 6
• 239000003431 cross linking reagent Substances 0.000 description 6
• 150000001993 dienes Chemical class 0.000 description 6
• 229920001971 elastomer Polymers 0.000 description 6
• 238000005227 gel permeation chromatography Methods 0.000 description 6
• 239000012948 isocyanate Substances 0.000 description 6
• 239000007788 liquid Substances 0.000 description 6
• AFCCDDWKHLHPDF-UHFFFAOYSA-M metam-sodium Chemical compound [Na+].CNC([S-])=S AFCCDDWKHLHPDF-UHFFFAOYSA-M 0.000 description 6
• 239000000178 monomer Substances 0.000 description 6
• 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 6
• GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 6
• 229920000058 polyacrylate Polymers 0.000 description 6
• 239000005056 polyisocyanate Substances 0.000 description 6
• 229920001228 polyisocyanate Polymers 0.000 description 6
• 229920000098 polyolefin Polymers 0.000 description 6
• 150000003839 salts Chemical class 0.000 description 6
• 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 5
• 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 5
• 229920000178 Acrylic resin Polymers 0.000 description 5
• 239000004593 Epoxy Substances 0.000 description 5
• ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical group OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 5
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