MY123467A - Preparation of sterically hindered amine ethers - Google Patents
Preparation of sterically hindered amine ethersInfo
- Publication number
- MY123467A MY123467A MYPI99000420A MYPI9900420A MY123467A MY 123467 A MY123467 A MY 123467A MY PI99000420 A MYPI99000420 A MY PI99000420A MY PI9900420 A MYPI9900420 A MY PI9900420A MY 123467 A MY123467 A MY 123467A
- Authority
- MY
- Malaysia
- Prior art keywords
- formula
- compound
- preparation
- c12aryl
- c8alkyl
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
- C07D211/36—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D211/56—Nitrogen atoms
- C07D211/58—Nitrogen atoms attached in position 4
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
- C07D211/94—Oxygen atom, e.g. piperidine N-oxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
- C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
- C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
- C07D251/40—Nitrogen atoms
- C07D251/54—Three nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0066—Flame-proofing or flame-retarding additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34926—Triazines also containing heterocyclic groups other than triazine groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
- C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
- C09K15/30—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing heterocyclic ring with at least one nitrogen atom as ring member
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Hydrogenated Pyridines (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Plural Heterocyclic Compounds (AREA)
Abstract
A NEW PROCESS IS DESCRIBED TO THE PREPARATION OF A COMPOUND OF THE FORMULA IFORMULA 1 WHEREIN R₁, R₂, R₃, AND R₄ INDEPENDENTLY OF EACH OTHER, ARE C₁-C8ALKYL OR C₁-C5HYDROXYALKYL, OR R₁ AND R₂ TOGETHER WITH THE CARBON ATOM THEY ARE ATTACHED TO ARE C5-C12CYCLOALKYL, OR R₃ AND R₄ TOGETHER WITH THE CARBON ATOM THEY ARE ATTACHED TO ARE C5-C12CYCLOALKYL; R5, R6, R7, R8, AND R9, INDEPENDENTLY OF EACH OTHER, ARE H, C₁-C8ALKYL, C2-ALKENYL, C5-C12ARYL, C₁-C₄HALOALKYL, AN ELECTRON WITHDRAWING GROUP, OR C6-C12ARYL WHICH IS SUBSTITUTED BY A RESIDUE SELECTED FROM C1-C₄ALKYL, A₁-C₄ALKOXY, HALOGEN; AND R7 AND R8 TOGETHER MAY ALSO FROM A CHEMICAL BOND; AND R IS AN ORGANIC LINKING GROUP CONTAINING 2-500 CARBON ATOMS AND FORMING, TOGETHER WITH THE CARBON ATOMS IT IS DIRECTLY CONNECTED TO AND THE NITROGEN ATOM, A SUBSTITUTED, 5-, 6 OR 7-MEMBERED CYCLIC RING STRUCTURE; CHARACTERIZED IN THAT A COMPOUND OF THE FORMULA II FORMULA IIIS OXIDIZED. THE COMPOUND OF THE FORMULA I CAN BE HYDROGENATED AND/OR HALOGENATED BY CONVENTIONAL METHODS. COMPOUNDS OF THE FORMULA I AND THE CORRESPONDING HYDROGENATED AND/OR HALOGENATED COMPOUNDS ARE WELL SUITABLE AS STABILIZERS FOR ORGANIC MATERIAL AGAINST DEGRADATION BY LIGHT, OXYGEN AND/OR HEAT OR YELLOWING; SOME ARE ALSO ACTIVE AS FLAME RETARDANTS.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT98MI000366A ITMI980366A1 (en) | 1998-02-25 | 1998-02-25 | PREPARATION OF STERICALLY PREVENTED AMINE ETHERS |
US10471898A | 1998-06-25 | 1998-06-25 |
Publications (1)
Publication Number | Publication Date |
---|---|
MY123467A true MY123467A (en) | 2006-05-31 |
Family
ID=26331570
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MYPI99000420A MY123467A (en) | 1998-02-25 | 1999-02-08 | Preparation of sterically hindered amine ethers |
Country Status (17)
Country | Link |
---|---|
JP (2) | JP4798815B2 (en) |
KR (1) | KR100561146B1 (en) |
CN (2) | CN1202085C (en) |
AR (1) | AR015238A1 (en) |
BE (1) | BE1014990A5 (en) |
BR (1) | BR9900807B1 (en) |
CA (2) | CA2262435C (en) |
CZ (1) | CZ302752B6 (en) |
DE (2) | DE19907945B4 (en) |
ES (1) | ES2159462B1 (en) |
FR (1) | FR2777004B1 (en) |
GB (1) | GB2334717B (en) |
ID (1) | ID23225A (en) |
MY (1) | MY123467A (en) |
NL (1) | NL1011394C2 (en) |
RU (1) | RU2224758C2 (en) |
SG (1) | SG74700A1 (en) |
Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SG82601A1 (en) | 1998-03-09 | 2001-08-21 | Ciba Sc Holding Ag | 1-alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators |
JP2004083913A (en) * | 2000-04-06 | 2004-03-18 | Mitsubishi Rayon Co Ltd | Flame retardant polypropylene film |
JP3540759B2 (en) * | 2000-04-06 | 2004-07-07 | 三菱レイヨン株式会社 | Flame retardant polypropylene fiber and method for producing the same |
TW572896B (en) * | 2000-05-26 | 2004-01-21 | Ciba Sc Holding Ag | Process for the synthesis of amine ethers from secondary amino oxides |
EP1038912A3 (en) * | 2000-06-22 | 2000-12-27 | Ciba SC Holding AG | High molecular weight hindered hydrocarbyloxyamine stabilizers |
TWI273115B (en) * | 2000-12-12 | 2007-02-11 | Ciba Sc Holding Ag | Improved weatherability of flame retardant polyolefin |
TW200407307A (en) * | 2001-11-26 | 2004-05-16 | Ciba Sc Holding Ag | Process for the synthesis of amine ethers from secondary amino oxides |
EP1513893B1 (en) * | 2002-04-17 | 2009-01-07 | Ciba Holding Inc. | Flame retardant polymer compositions containing hydroxylamine esters |
JP4167522B2 (en) * | 2002-05-31 | 2008-10-15 | サンテーラ株式会社 | Olefin resin composition and laminated film comprising the same |
ES2367796T3 (en) * | 2004-08-31 | 2011-11-08 | Basf Se | STABILIZATION OF ORGANIC MATERIALS. |
PL1807395T3 (en) | 2004-11-02 | 2016-06-30 | Basf Se | Process for the synthesis of n-alkoxyamines |
CN101541787B (en) * | 2006-11-23 | 2015-02-04 | 西巴控股有限公司 | Process for the preparation of tertiary N-allyl sterically hindered amines |
JP5595279B2 (en) * | 2007-12-21 | 2014-09-24 | ビーエーエスエフ ソシエタス・ヨーロピア | Plastic film or packaging film for agriculture, or use of nanostructured UV absorbers for the film |
CN102482454B (en) * | 2009-08-18 | 2014-03-05 | 巴斯夫欧洲公司 | Photovoltaic module with stabilized polymeric encapsulant |
US8895647B2 (en) * | 2009-09-10 | 2014-11-25 | Basf Se | Sterically hindered amine stabilizer |
JP5992422B2 (en) * | 2010-10-20 | 2016-09-14 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | Steric hindered amine light stabilizers by mixed functionalization |
EP2514800B2 (en) | 2011-04-21 | 2018-03-07 | Merck Patent GmbH | Compounds and liquid crystalline medium |
EP3526288B1 (en) | 2016-10-14 | 2021-08-04 | Basf Se | Stabilizer composition |
WO2018177846A1 (en) * | 2017-03-28 | 2018-10-04 | Basf Se | Light stabilizer mixture |
CN109503554B (en) * | 2018-12-13 | 2020-10-30 | 天津利安隆新材料股份有限公司 | Preparation method of polymerization type hindered amine light stabilizer HA-88 |
CN113544126A (en) * | 2019-03-08 | 2021-10-22 | 巴斯夫欧洲公司 | Hindered amine stabilizer mixtures |
CN112126060B (en) * | 2019-06-25 | 2022-05-31 | 北京天罡助剂有限责任公司 | Polymeric high-molecular steric hindrance amine and preparation method thereof |
CN113354813B (en) * | 2021-06-02 | 2023-07-04 | 宿迁联盛科技股份有限公司 | Preparation method of low-alkalinity hindered amine light stabilizer NOR371 |
WO2023194065A1 (en) | 2022-04-04 | 2023-10-12 | Zedda Innovation Consulting | Process for the preparation of sterically hindered nitroxyl ethers |
Family Cites Families (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1215462B (en) * | 1987-05-07 | 1990-02-14 | Ciba Geigy Spa | PIPERIDIN COMPOUNDS USABLE AS LIGHT, HEAT AND OXIDATION STABILIZERS FOR SYNTHETIC POLYMERS. |
US4824884A (en) * | 1987-08-12 | 1989-04-25 | Pennwalt Corporation | Cyclic anhydride derivatives of hydrazide functionalized hindered amine light stabilizers |
US5124378A (en) * | 1987-09-21 | 1992-06-23 | Ciba-Geigy Corporation | Stabilization of ambient cured coatings |
US5204473A (en) * | 1987-09-21 | 1993-04-20 | Ciba-Geigy Corporation | O-substituted N-hydroxy hindered amine stabilizers |
EP0309402B2 (en) * | 1987-09-21 | 2002-06-12 | Ciba Specialty Chemicals Holding Inc. | N-substituted hindered amine stabilizers |
US5004770A (en) * | 1988-10-19 | 1991-04-02 | Ciba-Geigy Corporation | Polymeric substrates stabilized with N-substituted hindered amines |
US4921962A (en) * | 1988-10-19 | 1990-05-01 | Ciba-Geigy Corporation | Process for preparing N-hydrocarbyloxy derivatives of sterically hindered amines |
US5096950A (en) * | 1988-10-19 | 1992-03-17 | Ciba-Geigy Corporation | Polyolefin compositions stabilized with NOR-substituted hindered amines |
US4978699A (en) * | 1988-10-24 | 1990-12-18 | Atochem North America, Inc. | Light stabilizing flame retardants |
BR8907375A (en) * | 1989-02-13 | 1991-04-30 | Atochem North America | COMPOUND, PROCESS FOR THE PREPARATION OF THE SAME, AND PROCESSES FOR THE STABILIZATION OF A COMPOSITION OF NATURAL OR SYNTHETIC POLYMER AND POLYPROPYLENE |
DE69012615T2 (en) * | 1989-03-21 | 1995-01-26 | Ciba Geigy Ag | Ethylenically unsaturated compounds containing 1-hydrocarbyloxy-2,2,6,6-tetramethylpiperidine parts and polymers, copolymers and stabilized compositions. |
DE69026747T2 (en) * | 1989-03-21 | 1996-11-14 | Ciba Geigy Ag | Non-migrating 1-hydrocarbyloxy-hindered amine compounds as polymer stabilizers |
EP0389428A3 (en) * | 1989-03-21 | 1991-10-09 | Ciba-Geigy Ag | N,n-bis(l-hydroxycarbyloxy-2,2,6,6-tetramethyl-piperidin-4-yl) amino triazines and stabilized compositions |
DE69012617T2 (en) * | 1989-03-21 | 1995-01-26 | Ciba Geigy Ag | Azo compounds with a sterically hindered amino group of low basicity. |
IT1246170B (en) * | 1990-07-24 | 1994-11-16 | Ciba Geigy Spa | POLYPROPYLENE STABILIZING COMPOSITION INCLUDING TRIAZINIC COMPOUNDS CONTAINING PIPERIDINIC GROUPS AND METALLIC COMPOUNDS |
US5216156A (en) * | 1992-05-05 | 1993-06-01 | Ciba-Geigy Corporation | Non-migrating 1-hydrocarbyloxy-2,2,6,6-tetramethylpiperidine 1,3,5-triazine derivatives |
IT1263993B (en) * | 1993-04-05 | 1996-09-06 | Ciba Geigy Spa | PIPERIDIN-TRIAZIN COMPOUNDS SUITABLE FOR USE AS STABILIZERS FOR ORGANIC MATERIALS |
TW270131B (en) * | 1993-07-13 | 1996-02-11 | Ciba Geigy | |
IT1264946B1 (en) * | 1993-07-16 | 1996-10-17 | Ciba Geigy Spa | DERIVATIVES OF 2,2,6,6-TETRAMETHYL-4-PIPERIDINOL USEFUL AS LIGHT AND OXIDATION STABILIZERS FOR ORGANIC MATERIALS. |
US5393812A (en) * | 1993-08-31 | 1995-02-28 | Hercules Incorporated | Flame retardant, light stable composition |
US5380828A (en) * | 1993-10-05 | 1995-01-10 | Ciba-Geigy Corporation | Azodicarboxylic acid derivatives containing hindered amine moieties as polymer stabilizers |
AU7216796A (en) * | 1995-10-12 | 1997-04-30 | Ciba-Geigy Ag | Thermally stable hindered amines as stabilizers |
US6046304A (en) * | 1995-12-04 | 2000-04-04 | Ciba Specialty Chemicals Corporation | Block oligomers containing 2,2,6,6-tetramethyl-4-piperidyl groups as stabilizers for organic materials |
EP0782994B1 (en) * | 1995-12-04 | 2003-02-05 | Ciba SC Holding AG | Block oligomers containing 2,2,6,6-tetramethyl-4-piperidyl groups as stabilizers for organic materials |
EP0792911A3 (en) * | 1996-02-27 | 1998-01-14 | Fmc Corporation | Flame resistant polyolefin compositions |
JPH09292682A (en) * | 1996-04-23 | 1997-11-11 | Fuji Photo Film Co Ltd | Silver halide color photographic sensitive material |
ATE327216T1 (en) * | 1997-02-03 | 2006-06-15 | Fuji Photo Film Co Ltd | COLOR PHOTOGRAPHIC MATERIAL CONTAINING SILVER HALIDE, PHENIDONE COMPOUNDS FOR THE PRODUCTION THEREOF AND METHOD FOR PRODUCING THESE PHENIDONE COMPOUNDS |
ITMI980366A1 (en) * | 1998-02-25 | 1999-08-25 | Ciba Spec Chem Spa | PREPARATION OF STERICALLY PREVENTED AMINE ETHERS |
-
1999
- 1999-02-06 SG SG1999000492A patent/SG74700A1/en unknown
- 1999-02-08 MY MYPI99000420A patent/MY123467A/en unknown
- 1999-02-17 GB GB9903463A patent/GB2334717B/en not_active Expired - Lifetime
- 1999-02-22 CZ CZ20080401A patent/CZ302752B6/en not_active IP Right Cessation
- 1999-02-23 CA CA002262435A patent/CA2262435C/en not_active Expired - Lifetime
- 1999-02-23 AR ARP990100722A patent/AR015238A1/en active IP Right Grant
- 1999-02-23 FR FR9902218A patent/FR2777004B1/en not_active Expired - Lifetime
- 1999-02-23 CA CA2643170A patent/CA2643170C/en not_active Expired - Lifetime
- 1999-02-24 DE DE19907945A patent/DE19907945B4/en not_active Expired - Lifetime
- 1999-02-24 RU RU99103614/04A patent/RU2224758C2/en active
- 1999-02-24 CN CNB991033833A patent/CN1202085C/en not_active Expired - Lifetime
- 1999-02-24 DE DE19964603A patent/DE19964603B4/en not_active Expired - Lifetime
- 1999-02-24 CN CNB2004100473618A patent/CN100384826C/en not_active Expired - Lifetime
- 1999-02-24 ES ES009900376A patent/ES2159462B1/en not_active Expired - Lifetime
- 1999-02-24 ID IDP990142D patent/ID23225A/en unknown
- 1999-02-24 KR KR1019990006156A patent/KR100561146B1/en not_active IP Right Cessation
- 1999-02-25 NL NL1011394A patent/NL1011394C2/en not_active IP Right Cessation
- 1999-02-25 JP JP04790499A patent/JP4798815B2/en not_active Expired - Lifetime
- 1999-02-25 BE BE9900127A patent/BE1014990A5/en not_active IP Right Cessation
- 1999-02-25 BR BRPI9900807-6B1A patent/BR9900807B1/en active IP Right Grant
-
2010
- 2010-08-17 JP JP2010182352A patent/JP2011006443A/en active Pending
Also Published As
Publication number | Publication date |
---|---|
JPH11315067A (en) | 1999-11-16 |
CZ302752B6 (en) | 2011-10-19 |
FR2777004B1 (en) | 2005-12-30 |
ES2159462A1 (en) | 2001-10-01 |
NL1011394A1 (en) | 1999-08-26 |
RU2224758C2 (en) | 2004-02-27 |
GB2334717B (en) | 2000-04-26 |
CN1235159A (en) | 1999-11-17 |
CN1552758A (en) | 2004-12-08 |
CA2262435C (en) | 2009-12-22 |
KR19990072904A (en) | 1999-09-27 |
JP2011006443A (en) | 2011-01-13 |
CA2643170A1 (en) | 1999-08-25 |
CA2262435A1 (en) | 1999-08-25 |
ID23225A (en) | 2000-03-30 |
BR9900807A (en) | 2000-03-28 |
BE1014990A5 (en) | 2004-08-03 |
AR015238A1 (en) | 2001-04-18 |
NL1011394C2 (en) | 1999-10-26 |
BR9900807B1 (en) | 2013-06-11 |
DE19907945B4 (en) | 2013-06-06 |
ES2159462B1 (en) | 2002-05-01 |
CN100384826C (en) | 2008-04-30 |
GB9903463D0 (en) | 1999-04-07 |
KR100561146B1 (en) | 2006-03-15 |
SG74700A1 (en) | 2000-08-22 |
CA2643170C (en) | 2013-04-16 |
DE19907945A1 (en) | 1999-08-26 |
JP4798815B2 (en) | 2011-10-19 |
GB2334717A (en) | 1999-09-01 |
FR2777004A1 (en) | 1999-10-08 |
DE19964603B4 (en) | 2013-02-28 |
CN1202085C (en) | 2005-05-18 |
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