AR015238A1 - PROCESS FOR THE PREPARATION OF ESTERICALLY IMPROVED AMINIC ETERS, COMPOSITIONS, COMPOUNDS AND USE OF SUCH COMPOUNDS AS STABILIZERS OR FLAME RETAINERS, AND PROCESS TO STABILIZE AN ORGANIC MATERIAL - Google Patents

PROCESS FOR THE PREPARATION OF ESTERICALLY IMPROVED AMINIC ETERS, COMPOSITIONS, COMPOUNDS AND USE OF SUCH COMPOUNDS AS STABILIZERS OR FLAME RETAINERS, AND PROCESS TO STABILIZE AN ORGANIC MATERIAL

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Publication number
AR015238A1
AR015238A1 ARP990100722A ARP990100722A AR015238A1 AR 015238 A1 AR015238 A1 AR 015238A1 AR P990100722 A ARP990100722 A AR P990100722A AR P990100722 A ARP990100722 A AR P990100722A AR 015238 A1 AR015238 A1 AR 015238A1
Authority
AR
Argentina
Prior art keywords
compounds
formula
stabilizers
organic
organic material
Prior art date
Application number
ARP990100722A
Other languages
Spanish (es)
Original Assignee
Ciba Sc Holding Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from IT98MI000366A external-priority patent/ITMI980366A1/en
Application filed by Ciba Sc Holding Ag filed Critical Ciba Sc Holding Ag
Publication of AR015238A1 publication Critical patent/AR015238A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D211/36—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D211/56—Nitrogen atoms
    • C07D211/58—Nitrogen atoms attached in position 4
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
    • C07D211/94—Oxygen atom, e.g. piperidine N-oxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
    • C07D251/40—Nitrogen atoms
    • C07D251/54—Three nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0066—Flame-proofing or flame-retarding additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
    • C08K5/3432—Six-membered rings
    • C08K5/3435—Piperidines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477—Six-membered rings
    • C08K5/3492—Triazines
    • C08K5/34926—Triazines also containing heterocyclic groups other than triazine groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
    • C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
    • C09K15/30—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing heterocyclic ring with at least one nitrogen atom as ring member

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Hydrogenated Pyridines (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

Proceso para la preparacion de éteres estéricamente impedidos de la formula I donde; R1, R2, R3 y R4 independientemente uno del otro, son alquilo C1-8, ohidroxialquilo C1-5, o R1 y R2 junto con el átomo de carbono al cual los mismos están unidos soncicloalquilo C5-12, o R3 y R4 junto con el átomo de carbono alcual los mismos están unidos son cicloalquilo; C5-12; R5, R6, R7, R8 y R9, independientemente uno del otro, son H, alquilo C1-8, alquenilo C2-8, arilo C5-12,haloalquilo C1-4, un grupo dador de electrones, o arilo C6-12, que es sustituido por un residuo seleccionado de alquilo C1-4, alcoxi C1-4, halogeno; y R7 y R8juntos pueden también formar un enlace químico; y R es un grupo orgánico de union que contiene 2-500 átomos de carbono y junto con los átomos a los cuales estádirectamente conectado y el átomo de nitrogeno, forma una estructura anular cíclica de 5, 6 o 7 miembros; que se caracteriza porque un compuesto de la formulaII donde todos los residuos R y R1-R9 son segun se define para la formula I, es oxidado. El compuesto de la formula I puede hidrogenarse y/o halogenarse pormétodos convencionales. Los compuestos de la formula I y los correspondientes compuestos hidrogenados y/o halogenados son apropiados como estabilizadores paramaterial orgánico contra la degradacion de la luz, el oxígeno y/o el calor o el color amarillento; algunos también son activos como agentes retardantes dellama. Composiciones, compuestos, uso de dichos compuestos como estabilizadores para material orgánico contra la degradacion a causa de la luz, el oxígeno,o elcalor, proceso para estabilizar un material orgánico contra la degradacion de la luz, el oxígeno y/o el calor por aplicacion de un estabilizador o laincorporacion de un estabilizador en dicho material, y uso de dichos compuestos como agentes retardantes de llama para un polímero orgánico.Process for the preparation of sterically hindered ethers of formula I where; R1, R2, R3 and R4 independently of each other, are C1-8 alkyl, C1-5 oxyxyalkyl, or R1 and R2 together with the carbon atom to which they are attached are C5-12 cycloalkyl, or R3 and R4 together with the carbon atom they are attached are cycloalkyl; C5-12; R5, R6, R7, R8 and R9, independently of one another, are H, C1-8 alkyl, C2-8 alkenyl, C5-12 aryl, C1-4 haloalkyl, an electron donor group, or C6-12 aryl, which is substituted by a residue selected from C1-4 alkyl, C1-4 alkoxy, halogen; and R7 and R8 together can also form a chemical bond; and R is an organic union group containing 2-500 carbon atoms and together with the atoms to which it is directly connected and the nitrogen atom, it forms a cyclic ring structure of 5, 6 or 7 members; characterized in that a compound of formula II where all residues R and R1-R9 are as defined for formula I, is oxidized. The compound of the formula I can be hydrogenated and / or halogenated by conventional methods. The compounds of the formula I and the corresponding hydrogenated and / or halogenated compounds are suitable as organic paramaterial stabilizers against the degradation of light, oxygen and / or heat or yellowish color; Some are also active as flame retardants. Compositions, compounds, use of said compounds as stabilizers for organic material against degradation due to light, oxygen, or heat, process for stabilizing an organic material against degradation of light, oxygen and / or heat by application of a stabilizer or incorporation of a stabilizer in said material, and use of said compounds as flame retardant agents for an organic polymer.

ARP990100722A 1998-02-25 1999-02-23 PROCESS FOR THE PREPARATION OF ESTERICALLY IMPROVED AMINIC ETERS, COMPOSITIONS, COMPOUNDS AND USE OF SUCH COMPOUNDS AS STABILIZERS OR FLAME RETAINERS, AND PROCESS TO STABILIZE AN ORGANIC MATERIAL AR015238A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT98MI000366A ITMI980366A1 (en) 1998-02-25 1998-02-25 PREPARATION OF STERICALLY PREVENTED AMINE ETHERS
US10471898A 1998-06-25 1998-06-25

Publications (1)

Publication Number Publication Date
AR015238A1 true AR015238A1 (en) 2001-04-18

Family

ID=26331570

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP990100722A AR015238A1 (en) 1998-02-25 1999-02-23 PROCESS FOR THE PREPARATION OF ESTERICALLY IMPROVED AMINIC ETERS, COMPOSITIONS, COMPOUNDS AND USE OF SUCH COMPOUNDS AS STABILIZERS OR FLAME RETAINERS, AND PROCESS TO STABILIZE AN ORGANIC MATERIAL

Country Status (17)

Country Link
JP (2) JP4798815B2 (en)
KR (1) KR100561146B1 (en)
CN (2) CN1202085C (en)
AR (1) AR015238A1 (en)
BE (1) BE1014990A5 (en)
BR (1) BR9900807B1 (en)
CA (2) CA2262435C (en)
CZ (1) CZ302752B6 (en)
DE (2) DE19907945B4 (en)
ES (1) ES2159462B1 (en)
FR (1) FR2777004B1 (en)
GB (1) GB2334717B (en)
ID (1) ID23225A (en)
MY (1) MY123467A (en)
NL (1) NL1011394C2 (en)
RU (1) RU2224758C2 (en)
SG (1) SG74700A1 (en)

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SG82601A1 (en) 1998-03-09 2001-08-21 Ciba Sc Holding Ag 1-alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators
JP2004083913A (en) * 2000-04-06 2004-03-18 Mitsubishi Rayon Co Ltd Flame retardant polypropylene film
JP3540759B2 (en) * 2000-04-06 2004-07-07 三菱レイヨン株式会社 Flame retardant polypropylene fiber and method for producing the same
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EP1038912A3 (en) * 2000-06-22 2000-12-27 Ciba SC Holding AG High molecular weight hindered hydrocarbyloxyamine stabilizers
TWI273115B (en) * 2000-12-12 2007-02-11 Ciba Sc Holding Ag Improved weatherability of flame retardant polyolefin
TW200407307A (en) * 2001-11-26 2004-05-16 Ciba Sc Holding Ag Process for the synthesis of amine ethers from secondary amino oxides
EP1513893B1 (en) * 2002-04-17 2009-01-07 Ciba Holding Inc. Flame retardant polymer compositions containing hydroxylamine esters
JP4167522B2 (en) * 2002-05-31 2008-10-15 サンテーラ株式会社 Olefin resin composition and laminated film comprising the same
ES2367796T3 (en) * 2004-08-31 2011-11-08 Basf Se STABILIZATION OF ORGANIC MATERIALS.
PL1807395T3 (en) 2004-11-02 2016-06-30 Basf Se Process for the synthesis of n-alkoxyamines
CN101541787B (en) * 2006-11-23 2015-02-04 西巴控股有限公司 Process for the preparation of tertiary N-allyl sterically hindered amines
JP5595279B2 (en) * 2007-12-21 2014-09-24 ビーエーエスエフ ソシエタス・ヨーロピア Plastic film or packaging film for agriculture, or use of nanostructured UV absorbers for the film
CN102482454B (en) * 2009-08-18 2014-03-05 巴斯夫欧洲公司 Photovoltaic module with stabilized polymeric encapsulant
US8895647B2 (en) * 2009-09-10 2014-11-25 Basf Se Sterically hindered amine stabilizer
JP5992422B2 (en) * 2010-10-20 2016-09-14 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ Steric hindered amine light stabilizers by mixed functionalization
EP2514800B2 (en) 2011-04-21 2018-03-07 Merck Patent GmbH Compounds and liquid crystalline medium
EP3526288B1 (en) 2016-10-14 2021-08-04 Basf Se Stabilizer composition
WO2018177846A1 (en) * 2017-03-28 2018-10-04 Basf Se Light stabilizer mixture
CN109503554B (en) * 2018-12-13 2020-10-30 天津利安隆新材料股份有限公司 Preparation method of polymerization type hindered amine light stabilizer HA-88
CN113544126A (en) * 2019-03-08 2021-10-22 巴斯夫欧洲公司 Hindered amine stabilizer mixtures
CN112126060B (en) * 2019-06-25 2022-05-31 北京天罡助剂有限责任公司 Polymeric high-molecular steric hindrance amine and preparation method thereof
CN113354813B (en) * 2021-06-02 2023-07-04 宿迁联盛科技股份有限公司 Preparation method of low-alkalinity hindered amine light stabilizer NOR371
WO2023194065A1 (en) 2022-04-04 2023-10-12 Zedda Innovation Consulting Process for the preparation of sterically hindered nitroxyl ethers

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Also Published As

Publication number Publication date
JPH11315067A (en) 1999-11-16
CZ302752B6 (en) 2011-10-19
FR2777004B1 (en) 2005-12-30
ES2159462A1 (en) 2001-10-01
NL1011394A1 (en) 1999-08-26
RU2224758C2 (en) 2004-02-27
GB2334717B (en) 2000-04-26
CN1235159A (en) 1999-11-17
CN1552758A (en) 2004-12-08
CA2262435C (en) 2009-12-22
KR19990072904A (en) 1999-09-27
JP2011006443A (en) 2011-01-13
CA2643170A1 (en) 1999-08-25
CA2262435A1 (en) 1999-08-25
ID23225A (en) 2000-03-30
BR9900807A (en) 2000-03-28
BE1014990A5 (en) 2004-08-03
NL1011394C2 (en) 1999-10-26
BR9900807B1 (en) 2013-06-11
DE19907945B4 (en) 2013-06-06
ES2159462B1 (en) 2002-05-01
MY123467A (en) 2006-05-31
CN100384826C (en) 2008-04-30
GB9903463D0 (en) 1999-04-07
KR100561146B1 (en) 2006-03-15
SG74700A1 (en) 2000-08-22
CA2643170C (en) 2013-04-16
DE19907945A1 (en) 1999-08-26
JP4798815B2 (en) 2011-10-19
GB2334717A (en) 1999-09-01
FR2777004A1 (en) 1999-10-08
DE19964603B4 (en) 2013-02-28
CN1202085C (en) 2005-05-18

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