NL1006487C2 - Fenol-vrije stabilisatie van polyalkeenvezels. - Google Patents

Info

Publication number

NL1006487C2

NL1006487C2 NL1006487A NL1006487A NL1006487C2 NL 1006487 C2 NL1006487 C2 NL 1006487C2 NL 1006487 A NL1006487 A NL 1006487A NL 1006487 A NL1006487 A NL 1006487A NL 1006487 C2 NL1006487 C2 NL 1006487C2

Authority

NL

Netherlands

Prior art keywords

alkyl

hydrogen

substituted

group

formula

Prior art date

1996-07-05

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• 239000000835 fiber Substances 0.000 title claims description 69
• 229920000098 polyolefin Polymers 0.000 title claims description 43
• 230000006641 stabilisation Effects 0.000 title description 21
• 238000011105 stabilization Methods 0.000 title description 21
• -1 C 1 -C 4 alkylamino Chemical group 0.000 claims description 370
• 150000001875 compounds Chemical class 0.000 claims description 165
• 125000000217 alkyl group Chemical group 0.000 claims description 154
• 229910052739 hydrogen Inorganic materials 0.000 claims description 118
• 239000001257 hydrogen Substances 0.000 claims description 109
• 239000000203 mixture Substances 0.000 claims description 99
• 150000002431 hydrogen Chemical class 0.000 claims description 65
• 229910052760 oxygen Inorganic materials 0.000 claims description 54
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 53
• 125000004432 carbon atom Chemical group C* 0.000 claims description 53
• 239000001301 oxygen Substances 0.000 claims description 53
• 239000003381 stabilizer Substances 0.000 claims description 53
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 47
• NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 46
• 229910052717 sulfur Inorganic materials 0.000 claims description 46
• 239000011593 sulfur Substances 0.000 claims description 46
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 41
• 125000002947 alkylene group Chemical group 0.000 claims description 28
• 125000003545 alkoxy group Chemical group 0.000 claims description 27
• 125000001589 carboacyl group Chemical group 0.000 claims description 25
• 150000001412 amines Chemical class 0.000 claims description 23
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 23
• 230000015556 catabolic process Effects 0.000 claims description 19
• 125000001544 thienyl group Chemical group 0.000 claims description 18
• NPDLYUOYAGBHFB-WDSKDSINSA-N Asn-Arg Chemical compound NC(=O)C[C@H](N)C(=O)N[C@H](C(O)=O)CCCN=C(N)N NPDLYUOYAGBHFB-WDSKDSINSA-N 0.000 claims description 16
• 125000003884 phenylalkyl group Chemical group 0.000 claims description 16
• 239000000654 additive Substances 0.000 claims description 15
• 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 claims description 15
• 125000000753 cycloalkyl group Chemical group 0.000 claims description 15
• WPWHSFAFEBZWBB-UHFFFAOYSA-N 1-butyl radical Chemical compound [CH2]CCC WPWHSFAFEBZWBB-UHFFFAOYSA-N 0.000 claims description 14
• 238000006731 degradation reaction Methods 0.000 claims description 14
• 238000000034 method Methods 0.000 claims description 14
• 229910052736 halogen Inorganic materials 0.000 claims description 13
• 150000002367 halogens Chemical class 0.000 claims description 13
• 125000004423 acyloxy group Chemical group 0.000 claims description 12
• 125000004414 alkyl thio group Chemical group 0.000 claims description 12
• 125000001231 benzoyloxy group Chemical group C(C1=CC=CC=C1)(=O)O* 0.000 claims description 12
• 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 12
• XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical class OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 claims description 12
• 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 12
• ACZGCWSMSTYWDQ-UHFFFAOYSA-N 3h-1-benzofuran-2-one Chemical class C1=CC=C2OC(=O)CC2=C1 ACZGCWSMSTYWDQ-UHFFFAOYSA-N 0.000 claims description 11
• 125000005605 benzo group Chemical group 0.000 claims description 11
• 229910052751 metal Inorganic materials 0.000 claims description 11
• 230000001590 oxidative effect Effects 0.000 claims description 11
• HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 10
• 125000003342 alkenyl group Chemical group 0.000 claims description 10
• 239000002184 metal Substances 0.000 claims description 10
• 229910052799 carbon Inorganic materials 0.000 claims description 9
• 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 9
• ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 8
• 125000004450 alkenylene group Chemical group 0.000 claims description 8
• 239000000460 chlorine Substances 0.000 claims description 8
• 229910052801 chlorine Inorganic materials 0.000 claims description 8
• 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 8
• AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 claims description 8
• 230000000087 stabilizing effect Effects 0.000 claims description 8
• 125000005236 alkanoylamino group Chemical group 0.000 claims description 7
• ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 7
• 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 7
• 125000001624 naphthyl group Chemical group 0.000 claims description 7
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
• 125000002993 cycloalkylene group Chemical group 0.000 claims description 6
• 125000004987 dibenzofuryl group Chemical group C1(=CC=CC=2OC3=C(C21)C=CC=C3)* 0.000 claims description 6
• 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 claims description 6
• 125000003302 alkenyloxy group Chemical group 0.000 claims description 5
• 125000000000 cycloalkoxy group Chemical group 0.000 claims description 5
• 125000006254 cycloalkyl carbonyl group Chemical group 0.000 claims description 5
• 125000002883 imidazolyl group Chemical group 0.000 claims description 5
• 125000004957 naphthylene group Chemical group 0.000 claims description 5
• 125000005561 phenanthryl group Chemical group 0.000 claims description 5
• 125000002071 phenylalkoxy group Chemical group 0.000 claims description 5
• 229910052698 phosphorus Inorganic materials 0.000 claims description 5
• 125000000168 pyrrolyl group Chemical group 0.000 claims description 5
• ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 4
• 125000001118 alkylidene group Chemical group 0.000 claims description 4
• 125000005428 anthryl group Chemical group [H]C1=C([H])C([H])=C2C([H])=C3C(*)=C([H])C([H])=C([H])C3=C([H])C2=C1[H] 0.000 claims description 4
• 239000004305 biphenyl Substances 0.000 claims description 4
• 125000000609 carbazolyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3NC12)* 0.000 claims description 4
• 229910002091 carbon monoxide Inorganic materials 0.000 claims description 4
• 125000005201 cycloalkylcarbonyloxy group Chemical group 0.000 claims description 4
• 125000001041 indolyl group Chemical group 0.000 claims description 4
• 125000000904 isoindolyl group Chemical group C=1(NC=C2C=CC=CC12)* 0.000 claims description 4
• 125000005956 isoquinolyl group Chemical group 0.000 claims description 4
• 125000000842 isoxazolyl group Chemical group 0.000 claims description 4
• 125000001484 phenothiazinyl group Chemical group C1(=CC=CC=2SC3=CC=CC=C3NC12)* 0.000 claims description 4
• 125000005954 phenoxathiinyl group Chemical group 0.000 claims description 4
• 125000003226 pyrazolyl group Chemical group 0.000 claims description 4
• 125000001834 xanthenyl group Chemical group C1=CC=CC=2OC3=CC=CC=C3C(C12)* 0.000 claims description 4
• 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 3
• 235000010290 biphenyl Nutrition 0.000 claims description 3
• 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
• 150000001768 cations Chemical class 0.000 claims description 3
• 125000000259 cinnolinyl group Chemical group N1=NC(=CC2=CC=CC=C12)* 0.000 claims description 3
• FNIATMYXUPOJRW-UHFFFAOYSA-N cyclohexylidene Chemical group [C]1CCCCC1 FNIATMYXUPOJRW-UHFFFAOYSA-N 0.000 claims description 3
• 125000003838 furazanyl group Chemical group 0.000 claims description 3
• 125000003453 indazolyl group Chemical group N1N=C(C2=C1C=CC=C2)* 0.000 claims description 3
• 125000003406 indolizinyl group Chemical group C=1(C=CN2C=CC=CC12)* 0.000 claims description 3
• 229910052740 iodine Inorganic materials 0.000 claims description 3
• 125000001786 isothiazolyl group Chemical group 0.000 claims description 3
• 125000004430 oxygen atom Chemical group O* 0.000 claims description 3
• 125000001644 phenoxazinyl group Chemical group C1(=CC=CC=2OC3=CC=CC=C3NC12)* 0.000 claims description 3
• 125000000951 phenoxy group Chemical class [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 3
• 125000001042 pteridinyl group Chemical group N1=C(N=CC2=NC=CN=C12)* 0.000 claims description 3
• 125000003373 pyrazinyl group Chemical group 0.000 claims description 3
• 125000002098 pyridazinyl group Chemical group 0.000 claims description 3
• WGKLOLBTFWFKOD-UHFFFAOYSA-N tris(2-nonylphenyl) phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(OC=1C(=CC=CC=1)CCCCCCCCC)OC1=CC=CC=C1CCCCCCCCC WGKLOLBTFWFKOD-UHFFFAOYSA-N 0.000 claims description 3
• 101100483630 Arabidopsis thaliana UCH3 gene Proteins 0.000 claims description 2
• 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
• 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 2
• UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims description 2
• 125000004437 phosphorous atom Chemical group 0.000 claims description 2
• 125000004592 phthalazinyl group Chemical group C1(=NN=CC2=CC=CC=C12)* 0.000 claims description 2
• 125000002294 quinazolinyl group Chemical group N1=C(N=CC2=CC=CC=C12)* 0.000 claims description 2
• 125000005493 quinolyl group Chemical group 0.000 claims description 2
• 125000001567 quinoxalinyl group Chemical group N1=C(C=NC2=CC=CC=C12)* 0.000 claims description 2
• 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 claims 10
• 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims 1
• 125000003031 C5-C7 cycloalkylene group Chemical group 0.000 claims 1
• 102100038916 Caspase-5 Human genes 0.000 claims 1
• 101100112336 Homo sapiens CASP5 gene Proteins 0.000 claims 1
• 101000913968 Ipomoea purpurea Chalcone synthase C Proteins 0.000 claims 1
• 101100273286 Mus musculus Casp4 gene Proteins 0.000 claims 1
• ILPYHDWANUBJNJ-UHFFFAOYSA-N P(OC1(C(C=CC=C1)C(C)(C)C)C(C)(C)C)(OC1(C(C=CC=C1)C(C)(C)C)C(C)(C)C)OC1(C(C=CC=C1)C(C)(C)C)C(C)(C)C Chemical compound P(OC1(C(C=CC=C1)C(C)(C)C)C(C)(C)C)(OC1(C(C=CC=C1)C(C)(C)C)C(C)(C)C)OC1(C(C=CC=C1)C(C)(C)C)C(C)(C)C ILPYHDWANUBJNJ-UHFFFAOYSA-N 0.000 claims 1
• 101000907988 Petunia hybrida Chalcone-flavanone isomerase C Proteins 0.000 claims 1
• 125000005037 alkyl phenyl group Chemical group 0.000 claims 1
• 229920005556 chlorobutyl Polymers 0.000 claims 1
• 229940125773 compound 10 Drugs 0.000 claims 1
• INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 claims 1
• ZLVXBBHTMQJRSX-VMGNSXQWSA-N jdtic Chemical compound C1([C@]2(C)CCN(C[C@@H]2C)C[C@H](C(C)C)NC(=O)[C@@H]2NCC3=CC(O)=CC=C3C2)=CC=CC(O)=C1 ZLVXBBHTMQJRSX-VMGNSXQWSA-N 0.000 claims 1
• 125000004593 naphthyridinyl group Chemical group N1=C(C=CC2=CC=CN=C12)* 0.000 claims 1
• 125000000714 pyrimidinyl group Chemical group 0.000 claims 1
• 239000011368 organic material Substances 0.000 description 29
• 229910052757 nitrogen Inorganic materials 0.000 description 27
• 238000002845 discoloration Methods 0.000 description 23
• 229920001577 copolymer Polymers 0.000 description 21
• 239000000155 melt Substances 0.000 description 18
• 238000012545 processing Methods 0.000 description 18
• 239000004743 Polypropylene Substances 0.000 description 17
• 229920000642 polymer Polymers 0.000 description 15
• 229920001155 polypropylene Polymers 0.000 description 15
• 238000009987 spinning Methods 0.000 description 15
• 239000002253 acid Substances 0.000 description 14
• 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 14
• 239000003795 chemical substances by application Substances 0.000 description 14
• 125000004356 hydroxy functional group Chemical group O* 0.000 description 14
• 125000001424 substituent group Chemical group 0.000 description 13
• 125000001931 aliphatic group Chemical group 0.000 description 12
• 125000003118 aryl group Chemical group 0.000 description 12
• MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 description 10
• ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical group OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 10
• JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 10
• 239000000314 lubricant Substances 0.000 description 9
• VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 8
• 239000005977 Ethylene Substances 0.000 description 8
• QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 8
• 239000012964 benzotriazole Substances 0.000 description 8
• DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 8
• 229920001684 low density polyethylene Polymers 0.000 description 8
• 239000004702 low-density polyethylene Substances 0.000 description 8
• 238000000465 moulding Methods 0.000 description 8
• 238000012360 testing method Methods 0.000 description 8
• RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-Tetramethylpiperidine Substances CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 7
• OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 7
• 239000004698 Polyethylene Substances 0.000 description 7
• 125000003282 alkyl amino group Chemical group 0.000 description 7
• 125000000732 arylene group Chemical group 0.000 description 7
• 239000003054 catalyst Substances 0.000 description 7
• 150000002148 esters Chemical class 0.000 description 7
• 239000010408 film Substances 0.000 description 7
• 229920000573 polyethylene Polymers 0.000 description 7
• 239000000126 substance Substances 0.000 description 7
• 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 7
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
• 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 6
• KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
• HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
• 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 6
• 125000003710 aryl alkyl group Chemical group 0.000 description 6
• 125000004956 cyclohexylene group Chemical group 0.000 description 6
• 229920001903 high density polyethylene Polymers 0.000 description 6
• 239000004700 high-density polyethylene Substances 0.000 description 6
• 125000002768 hydroxyalkyl group Chemical group 0.000 description 6
• 239000007788 liquid Substances 0.000 description 6
• 239000000843 powder Substances 0.000 description 6
• 235000002639 sodium chloride Nutrition 0.000 description 6
• 239000000243 solution Substances 0.000 description 6
• 229910052724 xenon Inorganic materials 0.000 description 6
• FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 6
• RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
• 229910052784 alkaline earth metal Inorganic materials 0.000 description 5
• 125000006193 alkinyl group Chemical group 0.000 description 5
• 239000003963 antioxidant agent Substances 0.000 description 5
• 235000006708 antioxidants Nutrition 0.000 description 5
• CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 5
• 235000013539 calcium stearate Nutrition 0.000 description 5
• 239000008116 calcium stearate Substances 0.000 description 5
• 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 5
• 239000008187 granular material Substances 0.000 description 5
• 238000010438 heat treatment Methods 0.000 description 5
• 239000002530 phenolic antioxidant Substances 0.000 description 5
• 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 5
• 125000004974 2-butenyl group Chemical group C(C=CC)* 0.000 description 4
• 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 4
• 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 4
• VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
• 239000004952 Polyamide Substances 0.000 description 4
• 230000032683 aging Effects 0.000 description 4
• 125000004063 butyryl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
• 150000001732 carboxylic acid derivatives Chemical class 0.000 description 4
• 150000001993 dienes Chemical class 0.000 description 4
• DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 4
• 239000000945 filler Substances 0.000 description 4
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• 239000011777 magnesium Substances 0.000 description 4
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• 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
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• 150000002815 nickel Chemical class 0.000 description 4
• 125000002801 octanoyl group Chemical group C(CCCCCCC)(=O)* 0.000 description 4
• 229920002647 polyamide Polymers 0.000 description 4
• 125000001501 propionyl group Chemical group O=C([*])C([H])([H])C([H])([H])[H] 0.000 description 4
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• 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 description 4
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• OISVCGZHLKNMSJ-UHFFFAOYSA-N 2,6-dimethylpyridine Chemical compound CC1=CC=CC(C)=N1 OISVCGZHLKNMSJ-UHFFFAOYSA-N 0.000 description 3
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• 125000006024 2-pentenyl group Chemical group 0.000 description 3
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• RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 3
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• AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 3
• OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
• 241001104043 Syringa Species 0.000 description 3
• 235000004338 Syringa vulgaris Nutrition 0.000 description 3
• YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
• 239000007983 Tris buffer Substances 0.000 description 3
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