MY143732A - Chain growth reaction process - Google Patents
Chain growth reaction processInfo
- Publication number
- MY143732A MY143732A MYPI20022909A MYPI20022909A MY143732A MY 143732 A MY143732 A MY 143732A MY PI20022909 A MYPI20022909 A MY PI20022909A MY PI20022909 A MYPI20022909 A MY PI20022909A MY 143732 A MY143732 A MY 143732A
- Authority
- MY
- Malaysia
- Prior art keywords
- chain growth
- alpha
- alkyl chain
- group
- zinc
- Prior art date
Links
- 238000006243 chemical reaction Methods 0.000 title abstract 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 4
- 229910052725 zinc Inorganic materials 0.000 abstract 4
- 239000011701 zinc Substances 0.000 abstract 4
- 239000004711 α-olefin Substances 0.000 abstract 3
- -1 ALKOXIDE COMPOUNDS Chemical class 0.000 abstract 1
- 229910052768 actinide Inorganic materials 0.000 abstract 1
- 150000001255 actinides Chemical class 0.000 abstract 1
- 239000012190 activator Substances 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 150000004703 alkoxides Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006073 displacement reaction Methods 0.000 abstract 1
- 230000007062 hydrolysis Effects 0.000 abstract 1
- 238000006460 hydrolysis reaction Methods 0.000 abstract 1
- 229910052747 lanthanoid Inorganic materials 0.000 abstract 1
- 150000002602 lanthanoids Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 150000003138 primary alcohols Chemical class 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/30—Catalytic processes with hydrides or organic compounds containing metal-to-carbon bond; Metal hydrides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
- C07C1/325—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a metal atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
- C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
- C07C29/54—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only starting from compounds containing carbon-to-metal bonds and followed by conversion of the -O- metal to -OH groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/06—Zinc compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/941—Synthetic resins or natural rubbers -- part of the class 520 series having the transition metal bonded directly to carbon
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/921,695 US7087686B2 (en) | 2001-08-06 | 2001-08-06 | Chain growth reaction process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MY143732A true MY143732A (en) | 2011-07-15 |
Family
ID=25445836
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MYPI20022909A MY143732A (en) | 2001-08-06 | 2002-08-02 | Chain growth reaction process |
Country Status (10)
| Country | Link |
|---|---|
| US (3) | US7087686B2 (https=) |
| EP (2) | EP2308815B1 (https=) |
| JP (1) | JP2004537584A (https=) |
| KR (1) | KR100895599B1 (https=) |
| CN (2) | CN101070261B (https=) |
| CA (1) | CA2456711C (https=) |
| EA (2) | EA011711B1 (https=) |
| ES (2) | ES2623164T3 (https=) |
| MY (1) | MY143732A (https=) |
| WO (1) | WO2003014046A1 (https=) |
Families Citing this family (91)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001053369A1 (en) * | 2000-01-21 | 2001-07-26 | Mitsui Chemicals, Inc. | Olefin block copolymers, production processes of the same and use thereof |
| US8426535B2 (en) * | 2001-08-06 | 2013-04-23 | Ineos Europe Limited | Chain growth reaction process |
| US7087686B2 (en) * | 2001-08-06 | 2006-08-08 | Bp Chemicals Limited | Chain growth reaction process |
| ATE412016T1 (de) * | 2001-09-14 | 2008-11-15 | Basell Polyolefine Gmbh | Verfahren zur polymerisation von olefinen |
| DE10145453A1 (de) * | 2001-09-14 | 2003-06-05 | Basell Polyolefine Gmbh | Monocyclopentadienylkomplexe mit einem kondensierten Heterocyclus |
| US7582716B2 (en) | 2004-03-17 | 2009-09-01 | Dow Global Technologies Inc. | Compositions of ethylene/α-olefin multi-block interpolymer for blown films with high hot tack |
| US8816006B2 (en) | 2004-03-17 | 2014-08-26 | Dow Global Technologies Llc | Compositions of ethylene/α-olefin multi-block interpolymer suitable for films |
| US7863379B2 (en) | 2004-03-17 | 2011-01-04 | Dow Global Technologies Inc. | Impact modification of thermoplastics with ethylene/alpha-olefin interpolymers |
| US7795321B2 (en) | 2004-03-17 | 2010-09-14 | Dow Global Technologies Inc. | Rheology modification of interpolymers of ethylene/α-olefins and articles made therefrom |
| US7504347B2 (en) | 2004-03-17 | 2009-03-17 | Dow Global Technologies Inc. | Fibers made from copolymers of propylene/α-olefins |
| US7714071B2 (en) | 2004-03-17 | 2010-05-11 | Dow Global Technologies Inc. | Polymer blends from interpolymers of ethylene/α-olefins and flexible molded articles made therefrom |
| US7622179B2 (en) | 2004-03-17 | 2009-11-24 | Dow Global Technologies Inc. | Three dimensional random looped structures made from interpolymers of ethylene/α-olefins and uses thereof |
| AU2005224259B2 (en) | 2004-03-17 | 2010-09-09 | Dow Global Technologies Inc. | Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation |
| US8273838B2 (en) | 2004-03-17 | 2012-09-25 | Dow Global Technologies Llc | Propylene/α-olefins block interpolymers |
| US7687442B2 (en) | 2004-03-17 | 2010-03-30 | Dow Global Technologies Inc. | Low molecular weight ethylene/α-olefin interpolymer as base lubricant oils |
| US7608668B2 (en) | 2004-03-17 | 2009-10-27 | Dow Global Technologies Inc. | Ethylene/α-olefins block interpolymers |
| US7557147B2 (en) | 2004-03-17 | 2009-07-07 | Dow Global Technologies Inc. | Soft foams made from interpolymers of ethylene/alpha-olefins |
| US7622529B2 (en) | 2004-03-17 | 2009-11-24 | Dow Global Technologies Inc. | Polymer blends from interpolymers of ethylene/alpha-olefin with improved compatibility |
| US7524911B2 (en) | 2004-03-17 | 2009-04-28 | Dow Global Technologies Inc. | Adhesive and marking compositions made from interpolymers of ethylene/α-olefins |
| US7579408B2 (en) | 2004-03-17 | 2009-08-25 | Dow Global Technologies Inc. | Thermoplastic vulcanizate comprising interpolymers of ethylene/α-olefins |
| US7741397B2 (en) | 2004-03-17 | 2010-06-22 | Dow Global Technologies, Inc. | Filled polymer compositions made from interpolymers of ethylene/α-olefins and uses thereof |
| US7803728B2 (en) | 2004-03-17 | 2010-09-28 | Dow Global Technologies Inc. | Fibers made from copolymers of ethylene/α-olefins |
| US7671131B2 (en) | 2004-03-17 | 2010-03-02 | Dow Global Technologies Inc. | Interpolymers of ethylene/α-olefins blends and profiles and gaskets made therefrom |
| US7897689B2 (en) | 2004-03-17 | 2011-03-01 | Dow Global Technologies Inc. | Functionalized ethylene/α-olefin interpolymer compositions |
| US7662881B2 (en) | 2004-03-17 | 2010-02-16 | Dow Global Technologies Inc. | Viscosity index improver for lubricant compositions |
| RU2375381C2 (ru) * | 2004-03-17 | 2009-12-10 | Дау Глобал Текнолоджиз Инк. | Состав катализатора, содержащий челночный агент, для формирования мульти-блок-сополимера высшего олефина |
| US7671106B2 (en) | 2004-03-17 | 2010-03-02 | Dow Global Technologies Inc. | Cap liners, closures and gaskets from multi-block polymers |
| US7514517B2 (en) | 2004-03-17 | 2009-04-07 | Dow Global Technologies Inc. | Anti-blocking compositions comprising interpolymers of ethylene/α-olefins |
| US7355089B2 (en) | 2004-03-17 | 2008-04-08 | Dow Global Technologies Inc. | Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates |
| US7666918B2 (en) | 2004-03-17 | 2010-02-23 | Dow Global Technologies, Inc. | Foams made from interpolymers of ethylene/α-olefins |
| KR100617990B1 (ko) * | 2004-07-30 | 2006-09-01 | 한국화학연구원 | 다핵으로 연결된 전이금속 화합물 및 이를 이용한 개환복분해 중합체의 제조방법 |
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| US7910658B2 (en) | 2005-03-17 | 2011-03-22 | Dow Global Technologies Llc | Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates |
| TWI388574B (zh) | 2005-03-17 | 2013-03-11 | Dow Global Technologies Llc | 由乙烯／α-烯烴之異種共聚物製成的黏著及標記組成物 |
| JP5227786B2 (ja) | 2005-03-17 | 2013-07-03 | ダウ グローバル テクノロジーズ エルエルシー | マルチブロックポリマーからのキャップライナー、クロージャーおよびガスケット |
| DE602006021557D1 (de) | 2005-03-17 | 2011-06-09 | Dow Global Technologies Inc | Zusammensetzungen aus einem ethylen/alpha-olefin-multiblock-interpolymer für elastische folien und laminate |
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| US7906587B2 (en) | 2005-09-16 | 2011-03-15 | Dow Global Technologies Llc | Polymer blends from interpolymer of ethylene/α olefin with improved compatibility |
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| EP2220128B2 (en) † | 2007-11-09 | 2021-03-10 | University of Maryland, College Park | Process for preparation of polyolefins via living coordinative chain transfer polymerization |
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| EP2665754A1 (en) | 2011-01-20 | 2013-11-27 | Ineos Commercial Services UK Limited | Activating supports |
| US20130131294A1 (en) * | 2011-11-21 | 2013-05-23 | John R. Hagadorn | Amidinate Catalyst Compounds, Process for Their Use and Polymers Produced Therefrom |
| US10385084B2 (en) * | 2014-01-08 | 2019-08-20 | The Governing Council Of The University Of Toronto | Iron(II) catalysts containing tridentate PNP ligands, their synthesis, and use thereof |
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| WO2019182720A1 (en) | 2018-03-19 | 2019-09-26 | Dow Silicones Corporation | Polyolefin-polydiorganosiioxane block copolymer and method for the synthesis thereof |
| WO2019182719A1 (en) | 2018-03-19 | 2019-09-26 | Dow Silicones Corporation | Polyorganosiloxane hot melt adhesive compositions containing polyolefin - polydiorganoosiloxane copolymers and methods for the preparation and use thereof |
| KR102693602B1 (ko) | 2018-03-19 | 2024-08-12 | 다우 실리콘즈 코포레이션 | 폴리올레핀 - 폴리디오르가노실록산 블록 공중합체 및 이의 합성을 위한 히드로실릴화 반응 방법 |
| KR102742384B1 (ko) | 2018-03-19 | 2024-12-16 | 다우 글로벌 테크놀로지스 엘엘씨 | 폴리올레핀 - 폴리디오르가노실록산 공중합체를 함유하는 핫멜트 접착제 조성물 및 그 제조 방법 및 그것의 용도 |
| WO2019210026A1 (en) | 2018-04-26 | 2019-10-31 | Exxonmobil Chemical Patents Inc. | Non-coordinating anion type activators containing cation having large alkyl groups |
| WO2020018159A1 (en) | 2018-07-17 | 2020-01-23 | Dow Silicones Corporation | Polysiloxane resin - polyolefin copolymer and methods for the preparation and use thereof |
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| US12202920B2 (en) | 2019-01-08 | 2025-01-21 | ExxonMobil Engineering & Technology Company | Olefin polymerization processes featuring in situ blending of an oil extension |
| US12202917B2 (en) | 2019-03-21 | 2025-01-21 | Exxonmobil Chemical Patents Inc. | Methods for improving gas phase polymerization |
| US12152095B2 (en) | 2019-03-21 | 2024-11-26 | Exxonmobil Chemical Patents Inc. | Methods for improving production in gas phase polymerization |
| US12466902B2 (en) | 2019-08-02 | 2025-11-11 | Exxonmobil Chemical Patents Inc. | Non-coordinating anion type activators for use with polyolefin polymerization catalysts |
| WO2021119089A1 (en) | 2019-12-11 | 2021-06-17 | Exxonmobil Chemical Patents Inc. | Processes for introduction of liquid activators in olefin polymerization reactions |
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-
2001
- 2001-08-06 US US09/921,695 patent/US7087686B2/en not_active Expired - Lifetime
-
2002
- 2002-07-05 KR KR1020047001907A patent/KR100895599B1/ko not_active Expired - Fee Related
- 2002-07-05 EP EP10179957.5A patent/EP2308815B1/en not_active Expired - Lifetime
- 2002-07-05 CN CN2007101264295A patent/CN101070261B/zh not_active Expired - Lifetime
- 2002-07-05 ES ES02745584.9T patent/ES2623164T3/es not_active Expired - Lifetime
- 2002-07-05 CN CNB028194128A patent/CN100457695C/zh not_active Expired - Lifetime
- 2002-07-05 EP EP02745584.9A patent/EP1414772B1/en not_active Expired - Lifetime
- 2002-07-05 WO PCT/GB2002/003096 patent/WO2003014046A1/en not_active Ceased
- 2002-07-05 EA EA200601455A patent/EA011711B1/ru not_active IP Right Cessation
- 2002-07-05 EA EA200400255A patent/EA007922B1/ru not_active IP Right Cessation
- 2002-07-05 CA CA2456711A patent/CA2456711C/en not_active Expired - Lifetime
- 2002-07-05 JP JP2003519002A patent/JP2004537584A/ja active Pending
- 2002-07-05 ES ES10179957T patent/ES2711251T3/es not_active Expired - Lifetime
- 2002-08-02 MY MYPI20022909A patent/MY143732A/en unknown
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2006
- 2006-06-28 US US11/476,206 patent/US7767771B2/en not_active Expired - Fee Related
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- 2007-01-31 US US11/700,111 patent/US7964681B2/en not_active Expired - Fee Related
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| CN100457695C (zh) | 2009-02-04 |
| ES2711251T3 (es) | 2019-04-30 |
| EP2308815A1 (en) | 2011-04-13 |
| JP2004537584A (ja) | 2004-12-16 |
| US20080200709A1 (en) | 2008-08-21 |
| EP2308815B1 (en) | 2018-11-14 |
| ES2623164T3 (es) | 2017-07-10 |
| US7087686B2 (en) | 2006-08-08 |
| KR100895599B1 (ko) | 2009-05-06 |
| CN101070261A (zh) | 2007-11-14 |
| EA200601455A1 (ru) | 2006-12-29 |
| CA2456711A1 (en) | 2003-02-20 |
| EP1414772B1 (en) | 2017-02-01 |
| US7964681B2 (en) | 2011-06-21 |
| CA2456711C (en) | 2013-01-08 |
| WO2003014046A1 (en) | 2003-02-20 |
| US7767771B2 (en) | 2010-08-03 |
| EP1414772A1 (en) | 2004-05-06 |
| EA011711B1 (ru) | 2009-04-28 |
| EA007922B1 (ru) | 2007-02-27 |
| EA200400255A1 (ru) | 2004-10-28 |
| US20070142656A1 (en) | 2007-06-21 |
| CN1561317A (zh) | 2005-01-05 |
| CN101070261B (zh) | 2012-11-14 |
| US20030078458A1 (en) | 2003-04-24 |
| KR20040032897A (ko) | 2004-04-17 |
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