MXPA03000505A - Proceso para producir tereftalato de politrimetileno. - Google Patents

Proceso para producir tereftalato de politrimetileno.

Info

Publication number
MXPA03000505A
MXPA03000505A MXPA03000505A MXPA03000505A MXPA03000505A MX PA03000505 A MXPA03000505 A MX PA03000505A MX PA03000505 A MXPA03000505 A MX PA03000505A MX PA03000505 A MXPA03000505 A MX PA03000505A MX PA03000505 A MXPA03000505 A MX PA03000505A
Authority
MX
Mexico
Prior art keywords
polytrimethylene terephthalate
cyclic dimer
product
precondensation
polymerization
Prior art date
Application number
MXPA03000505A
Other languages
English (en)
Inventor
Donald Ross Kelsey
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research filed Critical Shell Int Research
Publication of MXPA03000505A publication Critical patent/MXPA03000505A/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78Preparation processes
    • C08G63/82Preparation processes characterised by the catalyst used
    • C08G63/83Alkali metals, alkaline earth metals, beryllium, magnesium, copper, silver, gold, zinc, cadmium, mercury, manganese, or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16Dicarboxylic acids and dihydroxy compounds
    • C08G63/18Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181Acids containing aromatic rings
    • C08G63/183Terephthalic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78Preparation processes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

La presente invencion describe un proceso para la polimerizacion de tereftalato de politrimetileno por esterificacion de acido tereftalico o tereftalato de dimetilo con 1,3-propan diol, precondensacion del producto de esterificacion para producir un producto de precondensacion, y policondensacion del producto de precondensacion para producir tereftalato de politrimetileno y, como un subproducto, el dimero ciclico de acido tereftalico o tereftalato de dimetilo y 1,3-propan diol, que comprende: (a) recuperar el dimero ciclico de la polimerizacion, (b) hacer reaccionar de 0.5 a 2 5 por ciento en peso del dimero ciclico en 1,3-propan diol en presencia de 0.1 a 10 por ciento en peso del dimero ciclico de un catalizador basico durante cinco minutos a 24 horas de 50 a 210¦C, (c) neutralizar opcionalmente el catalizador basico en el producto de reaccion de (b), y (d) recircular el producto de reaccion en el proceso de polimerizacion.
MXPA03000505A 2000-07-20 2001-07-17 Proceso para producir tereftalato de politrimetileno. MXPA03000505A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US21977900P 2000-07-20 2000-07-20
PCT/EP2001/008281 WO2002008310A2 (en) 2000-07-20 2001-07-17 Process for producing polytrimethylene terephthalate

Publications (1)

Publication Number Publication Date
MXPA03000505A true MXPA03000505A (es) 2004-04-05

Family

ID=22820747

Family Applications (1)

Application Number Title Priority Date Filing Date
MXPA03000505A MXPA03000505A (es) 2000-07-20 2001-07-17 Proceso para producir tereftalato de politrimetileno.

Country Status (14)

Country Link
US (1) US6576774B2 (es)
EP (1) EP1301554B1 (es)
JP (1) JP2004504456A (es)
KR (1) KR100733642B1 (es)
CN (1) CN1211413C (es)
AT (1) ATE263200T1 (es)
AU (1) AU2001281990A1 (es)
CA (1) CA2418231C (es)
DE (1) DE60102588T2 (es)
ES (1) ES2214438T3 (es)
MX (1) MXPA03000505A (es)
MY (1) MY126884A (es)
TW (1) TW575597B (es)
WO (1) WO2002008310A2 (es)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6906164B2 (en) * 2000-12-07 2005-06-14 Eastman Chemical Company Polyester process using a pipe reactor
EP1378533A1 (en) * 2002-07-04 2004-01-07 General Electric Company Crystalline polyester resins and processes for their preparation
US6841505B2 (en) 2002-07-26 2005-01-11 E..I. Du Pont De Nemours And Company Titanium-zirconium catalyst compositions and use thereof
TWI255821B (en) * 2003-01-22 2006-06-01 Asahi Kasei Chemicals Corp Polytrimethylene terephthalate resin and method for production thereof
US7027689B2 (en) 2003-01-24 2006-04-11 Lucent Technologies Inc. Optical routers based on surface plasmons
US7196159B2 (en) 2004-10-04 2007-03-27 Shell Oil Company Process for producing polytrimethylene terephthalate
US7649109B2 (en) * 2006-12-07 2010-01-19 Eastman Chemical Company Polyester production system employing recirculation of hot alcohol to esterification zone
US7943094B2 (en) 2006-12-07 2011-05-17 Grupo Petrotemex, S.A. De C.V. Polyester production system employing horizontally elongated esterification vessel
US20080139780A1 (en) * 2006-12-07 2008-06-12 Debruin Bruce Roger Polyester production system employing short residence time esterification
US7863477B2 (en) * 2007-03-08 2011-01-04 Eastman Chemical Company Polyester production system employing hot paste to esterification zone
US7829653B2 (en) 2007-07-12 2010-11-09 Eastman Chemical Company Horizontal trayed reactor
US7872090B2 (en) 2007-07-12 2011-01-18 Eastman Chemical Company Reactor system with optimized heating and phase separation
US7868130B2 (en) 2007-07-12 2011-01-11 Eastman Chemical Company Multi-level tubular reactor with vertically spaced segments
US7868129B2 (en) 2007-07-12 2011-01-11 Eastman Chemical Company Sloped tubular reactor with spaced sequential trays
US7858730B2 (en) * 2007-07-12 2010-12-28 Eastman Chemical Company Multi-level tubular reactor with dual headers
US7847053B2 (en) 2007-07-12 2010-12-07 Eastman Chemical Company Multi-level tubular reactor with oppositely extending segments
US7842777B2 (en) 2007-07-12 2010-11-30 Eastman Chemical Company Sloped tubular reactor with divided flow
US7872089B2 (en) 2007-07-12 2011-01-18 Eastman Chemical Company Multi-level tubular reactor with internal tray
JP2008266660A (ja) * 2008-08-11 2008-11-06 Asahi Kasei Chemicals Corp ポリトリメチレンテレフタレート樹脂及びその製造方法
US20140005352A1 (en) * 2012-06-29 2014-01-02 Invista North America S.A R.L. Gas scrubber and related processes
CN107955141B (zh) * 2016-10-18 2020-07-07 中国石油化工股份有限公司 聚对苯二甲酸丙二醇酯组合物的制备方法
KR20220041177A (ko) * 2019-07-29 2022-03-31 이스트만 케미칼 컴파니 열분해 및 가메탄올분해로부터의 재활용된 단량체를 갖는 폴리에스테르의 제조 방법

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56116721A (en) 1980-02-20 1981-09-12 Nippon Ester Co Ltd Depolymerization of polyester
JPH05230199A (ja) 1991-12-26 1993-09-07 Toray Ind Inc 芳香族ポリエステルの製造方法
US5620665A (en) 1994-06-21 1997-04-15 Miyaso Chemical Co. Method of recycling unsaturated polyester resin waste and recycling apparatus
US5527973A (en) 1994-12-16 1996-06-18 Kelsey; Donald R. Purification of 1,3-propanediol
US5459229A (en) 1995-02-27 1995-10-17 Shell Oil Company By product stream purification in the preparation of 1,3-propanediol-based polyesters
DE19531990A1 (de) 1995-08-30 1997-05-15 Polymer Eng Gmbh Verfahren zur kontinuierlichen Herstellung von Polyamid 6 unter Verwendung von Rücklactam
DE19608614A1 (de) * 1996-03-06 1997-09-11 Basf Ag Verfahren zur Aufarbeitung von Dihydroxyverbindungen enthaltenden Rückständen
JPH10101784A (ja) 1996-09-30 1998-04-21 Nippon Ester Co Ltd スクラップ利用ポリエステルの製造法
JPH10147636A (ja) * 1996-11-19 1998-06-02 Mitsui Chem Inc ポリエステルの製造方法
DE19705249A1 (de) 1997-02-12 1998-08-13 Zimmer Ag Verfahren zur Herstellung von Polypropylenterphthalat
US6423814B1 (en) 1997-09-03 2002-07-23 Asahi Kasei Kabushiki Kaisha Polyester resin composition
US6297330B1 (en) 1998-08-28 2001-10-02 E. I. Du Pont De Nemours And Company Polymerizations based on cyclic oligomer
JP3749388B2 (ja) * 1998-11-30 2006-02-22 三菱化学株式会社 ポリプロピレンテレフタレートの製造方法
US6245879B1 (en) 1999-01-29 2001-06-12 Shell Oil Company Purification of 1,3-propanediol in carbonyl-containing stream

Also Published As

Publication number Publication date
WO2002008310A2 (en) 2002-01-31
US20020032302A1 (en) 2002-03-14
WO2002008310A3 (en) 2002-08-15
CA2418231A1 (en) 2002-01-31
DE60102588T2 (de) 2004-12-30
KR20030063337A (ko) 2003-07-28
CA2418231C (en) 2010-02-23
EP1301554B1 (en) 2004-03-31
AU2001281990A1 (en) 2002-02-05
JP2004504456A (ja) 2004-02-12
ES2214438T3 (es) 2004-09-16
ATE263200T1 (de) 2004-04-15
EP1301554A2 (en) 2003-04-16
CN1443210A (zh) 2003-09-17
MY126884A (en) 2006-10-31
CN1211413C (zh) 2005-07-20
US6576774B2 (en) 2003-06-10
DE60102588D1 (de) 2004-05-06
KR100733642B1 (ko) 2007-06-28
TW575597B (en) 2004-02-11

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