MX9204062A - Componente solido de catalizador para la (co) polimerizacion de etileno y procedimiento para la (co)polimerizacion de etileno empleando dicho catalizador. - Google Patents
Componente solido de catalizador para la (co) polimerizacion de etileno y procedimiento para la (co)polimerizacion de etileno empleando dicho catalizador.Info
- Publication number
- MX9204062A MX9204062A MX9204062A MX9204062A MX9204062A MX 9204062 A MX9204062 A MX 9204062A MX 9204062 A MX9204062 A MX 9204062A MX 9204062 A MX9204062 A MX 9204062A MX 9204062 A MX9204062 A MX 9204062A
- Authority
- MX
- Mexico
- Prior art keywords
- polymerization
- ethylene
- magnesium
- catalyst component
- procedure
- Prior art date
Links
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title abstract 3
- 239000005977 Ethylene Substances 0.000 title abstract 3
- 238000006116 polymerization reaction Methods 0.000 title abstract 3
- 239000011949 solid catalyst Substances 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 5
- 239000011777 magnesium Substances 0.000 abstract 3
- 229910052749 magnesium Inorganic materials 0.000 abstract 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 abstract 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 2
- 239000000377 silicon dioxide Substances 0.000 abstract 2
- 229910052719 titanium Inorganic materials 0.000 abstract 2
- 239000010936 titanium Substances 0.000 abstract 2
- KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- 230000003213 activating effect Effects 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical compound CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 abstract 1
- -1 magnesium alkyl chloride Chemical class 0.000 abstract 1
- 229910001629 magnesium chloride Inorganic materials 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
Abstract
La presente invención se refiere a un componente sólido de catalizador para la (CO) polimerización del etileno, el cual está compuesto de un soporte de sílice y de una parte catalíticamente activa que contiene titanio, magnesio, cloro y grupos alcoxi, y que se obtienen por: i) activar un soporte de sílice mediante el contacto con una solución de dialquilo de magnesio, o alquil cloruro de magnesio, en un solvente líquido, de un hidrocarburo alifático; ii) impregnar el sílice activado con una solución, en un éster líquido, alifático o aromático, de tetracloruro y tetraalcóxido de titanio en cantidades equimoleculares o casi equimoleculares, y cloruro de magnesio; y iii) tratar el sólido obtenido en el paso (ii) con una cantidad proporcionada de alquil sesquicloruro de aluminio.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI911938A IT1251465B (it) | 1991-07-12 | 1991-07-12 | Catalizzatore supportato per la (co)polimerizzazione dell'etilene. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX9204062A true MX9204062A (es) | 1993-07-01 |
Family
ID=11360341
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX9204062A MX9204062A (es) | 1991-07-12 | 1992-07-10 | Componente solido de catalizador para la (co) polimerizacion de etileno y procedimiento para la (co)polimerizacion de etileno empleando dicho catalizador. |
Country Status (22)
| Country | Link |
|---|---|
| US (1) | US5298474A (es) |
| EP (1) | EP0522651B1 (es) |
| JP (1) | JPH05214024A (es) |
| KR (1) | KR950001278B1 (es) |
| CN (1) | CN1072683C (es) |
| AT (1) | ATE116340T1 (es) |
| AU (1) | AU651470B2 (es) |
| BR (1) | BR9202665A (es) |
| CA (1) | CA2073644A1 (es) |
| DE (1) | DE69201023T2 (es) |
| DK (1) | DK0522651T3 (es) |
| DZ (1) | DZ1597A1 (es) |
| EG (1) | EG20437A (es) |
| ES (1) | ES2066551T3 (es) |
| FI (1) | FI104083B (es) |
| IT (1) | IT1251465B (es) |
| MX (1) | MX9204062A (es) |
| NO (1) | NO179331C (es) |
| RU (1) | RU2073689C1 (es) |
| SA (1) | SA92130197B1 (es) |
| TN (1) | TNSN92058A1 (es) |
| ZA (1) | ZA925140B (es) |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FI91968C (fi) * | 1989-11-28 | 1994-09-12 | Borealis Polymers Oy | -olefiinien polymerointiin tarkoitettu prokatalyyttikompositio, sen valmistus ja käyttö |
| FI89500C (fi) * | 1991-12-31 | 1993-10-11 | Neste Oy | Prokatalytkomposition foer homo- och sampolymerisering av alfa-olefiner, dess framstaellning och anvaendning |
| US6015779A (en) | 1996-03-19 | 2000-01-18 | Energy & Environmental International, L.C. | Methods for forming amorphous ultra-high molecular weight polyalphaolefin drag reducing agents |
| ZA974798B (en) | 1996-05-31 | 1998-11-30 | Sastech Pty Ltd | Termpolymerization |
| CZ34998A3 (cs) * | 1997-02-17 | 1999-08-11 | Pcd Polymere Gesellschaft M. B. H. | Způsob přípravy pevného nosiče pro katalyzátory polymerace olefinů |
| US6815011B2 (en) | 2000-11-27 | 2004-11-09 | Energy & Environmental International, L.C. | Alpha olefin monomer partitioning agents for drag reducing agents and methods of forming drag reducing agents using alpha olefin monomer partitioning agents |
| KR20010016528A (ko) * | 2000-12-18 | 2001-03-05 | 이봉규 | Ｇｉｓ 기반의 도로 기상 정보 제공 방법 및 시스템 |
| AU2002243529A1 (en) | 2001-01-16 | 2002-07-30 | Energy And Environmental International, L.C. | Methods for forming amorphous ultra-high molecular weight polyolefins for use as drag reducing agents |
| WO2002074818A1 (en) * | 2001-03-15 | 2002-09-26 | Basell Poliolefine Italia S.P.A. | Process for the (co)polymerization of ethylene |
| DE10122111B4 (de) * | 2001-05-08 | 2007-03-01 | Ticona Gmbh | Verfahren zur Herstellung von Olefinpolymeren, sowie ausgewählte Katalysatoren |
| US7012046B2 (en) * | 2001-06-08 | 2006-03-14 | Eaton Gerald B | Drag reducing agent slurries having alfol alcohols and processes for forming drag reducing agent slurries having alfol alcohols |
| KR20030066163A (ko) * | 2002-02-04 | 2003-08-09 | 전우현 | 영상과 환경정보가 함께 전달되는 구성 전달 체계 |
| AU2002315589A1 (en) * | 2002-06-19 | 2004-01-06 | Braskem S.A. | Solid catalyst component for polymerization and copolymerization of ethylene, and, process for obtaining the same |
| US9352308B2 (en) | 2002-06-19 | 2016-05-31 | Braskem S.A. | Solid catalyst component for polymerization and copolymerization of ethylene and process for obtaining the same |
| CN100417670C (zh) * | 2006-03-07 | 2008-09-10 | 中国石油化工股份有限公司 | 一种烯烃聚合催化剂及其制备方法和应用 |
| JP5302888B2 (ja) * | 2006-08-31 | 2013-10-02 | エスケー ケミカルズ カンパニー リミテッド | 薬物含有高分子微小球の製造方法及びその方法により製造された薬物含有高分子微小球 |
| CN102344506A (zh) * | 2010-07-30 | 2012-02-08 | 中国石油化工股份有限公司 | 用于乙烯聚合的催化剂组分及其催化剂 |
| CN102344507A (zh) * | 2010-07-30 | 2012-02-08 | 中国石油化工股份有限公司 | 一种用于乙烯聚合反应的催化剂组分及其催化剂 |
| EP2607388B1 (en) | 2010-08-19 | 2015-08-12 | China Petroleum & Chemical Corporation | Catalytic composition for polymerization of olefin and preparation method thereof |
| CN102372803B (zh) * | 2010-08-19 | 2013-03-27 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分及其制备方法 |
| CN102372802B (zh) * | 2010-08-19 | 2013-03-27 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂组分及其制备方法 |
| CN102372799B (zh) * | 2010-08-19 | 2013-03-27 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂组分及其制备方法 |
| CN102372800B (zh) * | 2010-08-19 | 2013-03-27 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂组分及其制备方法 |
| CN102372801B (zh) * | 2010-08-19 | 2013-05-01 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂组分及其制备方法 |
| CN102372798B (zh) * | 2010-08-19 | 2013-03-27 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分及其制备方法 |
| CN102453132B (zh) * | 2010-10-19 | 2013-03-27 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂组分及制备方法 |
| CN102453126B (zh) * | 2010-10-19 | 2013-03-27 | 中国石油化工股份有限公司 | 烯烃聚合的催化剂组份、制备方法及应用 |
| WO2012069157A1 (en) * | 2010-11-26 | 2012-05-31 | Saudi Basic Industries Corporation (Sabic) | Process for making a solid catalyst component for ethylene polymerization and copolymerization |
| BR102016009378B1 (pt) * | 2016-04-27 | 2021-04-20 | Braskem S.A. | Catalisador heterogêneo de múltiplos sítios, e, processos de preparação do catalisador heterogêneo de múltiplos sítios e de obtenção de poliolefin |
| KR20220008669A (ko) * | 2020-07-14 | 2022-01-21 | 주식회사 엘지화학 | 프로필렌의 암모산화용 촉매, 이의 제조 방법, 이를 이용한 프로필렌의 암모산화 방법 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA920299A (en) * | 1968-08-01 | 1973-01-30 | Mitsui Petrochemical Industries | Process for the polymerization and/or copolymerization of olefins with use of ziegler-type catalytsts supported on carrier |
| IT1136627B (it) * | 1981-05-21 | 1986-09-03 | Euteco Impianti Spa | Catalizzatore supportato per la polimerizzazione di etilene |
| US4532312A (en) * | 1982-12-15 | 1985-07-30 | Phillips Petroleum Company | Polyolefin polymerization process and catalyst |
| NL8700322A (nl) * | 1987-02-11 | 1988-09-01 | Stamicarbon | Katalysatorsysteem voor (co)polymerisatie van etheen in solutie. |
| US5126302A (en) * | 1990-04-30 | 1992-06-30 | Quantum Chemical Corporation | Olefin polymerization catalyst and methods |
| IT1248981B (it) * | 1990-06-22 | 1995-02-11 | Enichem Anic Spa | Procedimento per la preparazione di un componente solido di catalizzatore per la (co)polimerizzazione dell'etilene |
| IT1252041B (it) * | 1990-10-11 | 1995-05-29 | Enimont Anic Srl | Componente solido di catalizzatore per la (co)polimerizzazione dell'etilene |
-
1991
- 1991-07-12 IT ITMI911938A patent/IT1251465B/it active IP Right Grant
-
1992
- 1992-07-07 AU AU19482/92A patent/AU651470B2/en not_active Ceased
- 1992-07-07 DK DK92202060.7T patent/DK0522651T3/da active
- 1992-07-07 DE DE69201023T patent/DE69201023T2/de not_active Expired - Fee Related
- 1992-07-07 EP EP92202060A patent/EP0522651B1/en not_active Expired - Lifetime
- 1992-07-07 AT AT92202060T patent/ATE116340T1/de not_active IP Right Cessation
- 1992-07-07 ES ES92202060T patent/ES2066551T3/es not_active Expired - Lifetime
- 1992-07-08 FI FI923154A patent/FI104083B/fi active
- 1992-07-08 DZ DZ920087A patent/DZ1597A1/fr active
- 1992-07-09 ZA ZA925140A patent/ZA925140B/xx unknown
- 1992-07-09 NO NO922712A patent/NO179331C/no not_active IP Right Cessation
- 1992-07-10 CA CA002073644A patent/CA2073644A1/en not_active Abandoned
- 1992-07-10 TN TNTNSN92058A patent/TNSN92058A1/fr unknown
- 1992-07-10 RU SU925052225A patent/RU2073689C1/ru not_active IP Right Cessation
- 1992-07-10 MX MX9204062A patent/MX9204062A/es not_active IP Right Cessation
- 1992-07-10 US US07/911,419 patent/US5298474A/en not_active Expired - Lifetime
- 1992-07-11 CN CN92105683A patent/CN1072683C/zh not_active Expired - Fee Related
- 1992-07-11 EG EG38392A patent/EG20437A/xx active
- 1992-07-11 KR KR1019920012377A patent/KR950001278B1/ko not_active IP Right Cessation
- 1992-07-13 BR BR929202665A patent/BR9202665A/pt not_active IP Right Cessation
- 1992-07-13 JP JP4185407A patent/JPH05214024A/ja active Pending
- 1992-10-26 SA SA92130197A patent/SA92130197B1/ar unknown
Also Published As
| Publication number | Publication date |
|---|---|
| KR930002384A (ko) | 1993-02-23 |
| ZA925140B (en) | 1993-04-28 |
| FI104083B1 (fi) | 1999-11-15 |
| SA92130197B1 (ar) | 2004-06-23 |
| ATE116340T1 (de) | 1995-01-15 |
| KR950001278B1 (ko) | 1995-02-15 |
| JPH05214024A (ja) | 1993-08-24 |
| TNSN92058A1 (fr) | 1993-06-08 |
| BR9202665A (pt) | 1993-03-23 |
| NO179331B (no) | 1996-06-10 |
| EP0522651A3 (en) | 1993-03-03 |
| FI923154A0 (fi) | 1992-07-08 |
| ITMI911938A1 (it) | 1993-01-12 |
| NO922712D0 (no) | 1992-07-09 |
| DE69201023T2 (de) | 1995-06-22 |
| NO922712L (no) | 1993-01-13 |
| US5298474A (en) | 1994-03-29 |
| AU651470B2 (en) | 1994-07-21 |
| IT1251465B (it) | 1995-05-15 |
| DK0522651T3 (da) | 1995-04-24 |
| ES2066551T3 (es) | 1995-03-01 |
| RU2073689C1 (ru) | 1997-02-20 |
| EP0522651A2 (en) | 1993-01-13 |
| EP0522651B1 (en) | 1994-12-28 |
| FI104083B (fi) | 1999-11-15 |
| AU1948292A (en) | 1993-01-14 |
| CN1069031A (zh) | 1993-02-17 |
| NO179331C (no) | 1996-09-18 |
| ITMI911938A0 (it) | 1991-07-12 |
| DE69201023D1 (de) | 1995-02-09 |
| DZ1597A1 (fr) | 2002-02-17 |
| FI923154A (fi) | 1993-01-13 |
| CN1072683C (zh) | 2001-10-10 |
| EG20437A (en) | 1999-04-29 |
| CA2073644A1 (en) | 1993-01-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant or registration | ||
| MM | Annulment or lapse due to non-payment of fees |