MX362053B - Procedimiento para la preparacion de un poliester o copoliester heteroaromatico de elevado peso molecular. - Google Patents
Procedimiento para la preparacion de un poliester o copoliester heteroaromatico de elevado peso molecular.Info
- Publication number
- MX362053B MX362053B MX2014009844A MX2014009844A MX362053B MX 362053 B MX362053 B MX 362053B MX 2014009844 A MX2014009844 A MX 2014009844A MX 2014009844 A MX2014009844 A MX 2014009844A MX 362053 B MX362053 B MX 362053B
- Authority
- MX
- Mexico
- Prior art keywords
- copolyester
- preparing
- molecular weight
- high molecular
- diester
- Prior art date
Links
- 125000001072 heteroaryl group Chemical group 0.000 title abstract 4
- 229920001634 Copolyester Polymers 0.000 title abstract 2
- 229920000728 polyester Polymers 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 150000005690 diesters Chemical class 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 150000008065 acid anhydrides Chemical class 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 238000010924 continuous production Methods 0.000 abstract 1
- 230000032050 esterification Effects 0.000 abstract 1
- 238000005886 esterification reaction Methods 0.000 abstract 1
- 239000012456 homogeneous solution Substances 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 229920002601 oligoester Polymers 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
- C08G63/685—Polyesters containing atoms other than carbon, hydrogen and oxygen containing nitrogen
- C08G63/6854—Polyesters containing atoms other than carbon, hydrogen and oxygen containing nitrogen derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/6856—Dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
- C08G63/688—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur
- C08G63/6884—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/6886—Dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/80—Solid-state polycondensation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/91—Polymers modified by chemical after-treatment
- C08G63/914—Polymers modified by chemical after-treatment derived from polycarboxylic acids and polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2230/00—Compositions for preparing biodegradable polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
La invención se refiere a un procedimiento continuo para la preparación de un poliéster o co-poliéster heteroaromático, de elevado peso molecular, en el que a) al menos un ácido dicarboxílico heteroaromático o el diéster o un anhídrido de ácido del mismo, un ácido dicarboxílico heteroaromático con 2 - 12 átomos de C y al menos un alcohol con 2 a 12 átomos de carbono y al menos dos funcionalidades hidroxilo se elaboran mediante mezcladura para formar una pasta, o mediante mezcladura a temperatura elevada para formar una disolución homogénea, b) la pasta o disolución obtenida en la etapa a) se hace reaccionar para formar un producto de la esterificación que contiene al menos un diéster y/o al menos un oligoéster, y c) el producto de reacción obtenido de la etapa b) se policondensa o co-policondensa a presión reducida con respecto a las condiciones normales, llevándose a cabo la etapa c) de policondensación o co-policondensación en dos etapas.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102012003417A DE102012003417A1 (de) | 2012-02-17 | 2012-02-17 | Verfahren zur Herstellung eines hochmolekularen, heteroaromatischen Polyesters oder Copolyesters |
| PCT/EP2013/053065 WO2013120989A2 (de) | 2012-02-17 | 2013-02-15 | Verfahren zur herstellung eines hochmolekularen, heteroaromatischen polyesters oder copolyesters |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2014009844A MX2014009844A (es) | 2015-04-13 |
| MX362053B true MX362053B (es) | 2019-01-07 |
Family
ID=47749808
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2014009844A MX362053B (es) | 2012-02-17 | 2013-02-15 | Procedimiento para la preparacion de un poliester o copoliester heteroaromatico de elevado peso molecular. |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US9714320B2 (es) |
| EP (1) | EP2814864B1 (es) |
| KR (1) | KR102085389B1 (es) |
| CN (1) | CN104136485A (es) |
| DE (1) | DE102012003417A1 (es) |
| MX (1) | MX362053B (es) |
| RU (1) | RU2014132207A (es) |
| WO (1) | WO2013120989A2 (es) |
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| CA3061795C (en) | 2011-10-24 | 2022-09-13 | Furanix Technologies B.V. | A process for preparing a polymer product having a 2,5-furandicarboxylate moiety within the polymer backbone to be used in bottle, film or fibre applications |
| SG11201510340UA (en) | 2013-06-20 | 2016-01-28 | Furanix Technologies Bv | Process for the preparation of a fiber, a fiber and a yarn made from such a fiber |
| JP6749908B2 (ja) | 2014-08-25 | 2020-09-02 | フラニックス・テクノロジーズ・ベーフェー | ポリ(エチレン−2,5−フランジカルボキシレート)を含む配向フィルムの製造方法 |
-
2012
- 2012-02-17 DE DE102012003417A patent/DE102012003417A1/de not_active Withdrawn
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2013
- 2013-02-15 CN CN201380009860.5A patent/CN104136485A/zh active Pending
- 2013-02-15 MX MX2014009844A patent/MX362053B/es active IP Right Grant
- 2013-02-15 WO PCT/EP2013/053065 patent/WO2013120989A2/de not_active Ceased
- 2013-02-15 KR KR1020147025661A patent/KR102085389B1/ko active Active
- 2013-02-15 RU RU2014132207A patent/RU2014132207A/ru not_active Application Discontinuation
- 2013-02-15 EP EP13705973.9A patent/EP2814864B1/de not_active Revoked
-
2014
- 2014-08-15 US US14/460,939 patent/US9714320B2/en active Active
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2017
- 2017-04-17 US US15/489,317 patent/US20170218118A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| WO2013120989A3 (de) | 2013-10-10 |
| US20170218118A1 (en) | 2017-08-03 |
| WO2013120989A2 (de) | 2013-08-22 |
| MX2014009844A (es) | 2015-04-13 |
| KR20140138163A (ko) | 2014-12-03 |
| CN104136485A (zh) | 2014-11-05 |
| DE102012003417A1 (de) | 2013-08-22 |
| US20140357808A1 (en) | 2014-12-04 |
| EP2814864B1 (de) | 2020-09-16 |
| RU2014132207A (ru) | 2016-04-10 |
| US9714320B2 (en) | 2017-07-25 |
| KR102085389B1 (ko) | 2020-03-05 |
| EP2814864A2 (de) | 2014-12-24 |
| WO2013120989A9 (de) | 2014-04-10 |
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