MX3477E - Procedimiento catalitico mejorado para la polimerizacion y copolimerizacion de olefinas - Google Patents

Procedimiento catalitico mejorado para la polimerizacion y copolimerizacion de olefinas

Info

Publication number
MX3477E
MX3477E MX000163U MX16376U MX3477E MX 3477 E MX3477 E MX 3477E MX 000163 U MX000163 U MX 000163U MX 16376 U MX16376 U MX 16376U MX 3477 E MX3477 E MX 3477E
Authority
MX
Mexico
Prior art keywords
compounds
metal
compound
polymerization
titanium
Prior art date
Application number
MX000163U
Other languages
English (en)
Inventor
Eugene Barger
Charles Bienfait
Original Assignee
Solvay
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Solvay filed Critical Solvay
Publication of MX3477E publication Critical patent/MX3477E/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

La presente invención se refiere a procedimiento catalítico mejorado para la polimerización y copolimerización de olefinas de insaturación terminal cuya molécula contiene de 2 a 6 átomos de carbono, cuyo procedimiento se efectúa a una presión comprendida entre la presión atmósferica y 100 kg/cm2 y a una temperatura comprendida entre 20 a 200°C., de preferencia en presencia de un diluyente inerte, en cuyo procedimiento la polimerización se efectúa en presencia de un sistema catalítico que comprende un compuesto organometálico de un metal de los grupos Ia, IIa, IIb, IIIb y IVb de la tabla periódica y un complejo catalítico sólido formado por al menos un compuesto (M) de magnesio elegido entre los compuestos oxigenados orgánicos y los compuestos alogenados de éste metal: al menos un compuesto (T) de titanio elegido entre los compuestos oxigenados orgánicos y los compuestos halogenados de éste metal: al menos un compuesto (Z) de zirconio elegidos entre los compuesatos oxigenados orgánicos y los compuestos alogenados de éste metal, y al menos un alogenuro de aluminio (A), caracterizados por emplear los compuestos (M), (T), (Z), y (A) en cantidades tales que se cumple la relación: (ver gaceta) donde Mg, Zr, Ti y X representan las cantidades, expresadas en equivalentes-gramo, de magnesio, zirconio, titanio y halógeno empleados, y el complejo catalítico sólido sea utiliza a razón de 0.001 a 2.5 miliátomos-gramo de titanio y de zirconio por dm3 de diluyente o de volúmen de reactivo.
MX000163U 1975-04-14 1976-04-09 Procedimiento catalitico mejorado para la polimerizacion y copolimerizacion de olefinas MX3477E (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
LU72278A LU72278A1 (es) 1975-04-14 1975-04-14

Publications (1)

Publication Number Publication Date
MX3477E true MX3477E (es) 1980-12-11

Family

ID=19727905

Family Applications (1)

Application Number Title Priority Date Filing Date
MX000163U MX3477E (es) 1975-04-14 1976-04-09 Procedimiento catalitico mejorado para la polimerizacion y copolimerizacion de olefinas

Country Status (27)

Country Link
US (1) US4109071A (es)
JP (2) JPS51138785A (es)
AR (1) AR207281A1 (es)
AT (1) AT347677B (es)
BE (1) BE840378A (es)
BR (1) BR7602156A (es)
CA (1) CA1080208A (es)
CH (1) CH617212A5 (es)
DD (1) DD126387A5 (es)
DE (1) DE2615390C3 (es)
DK (1) DK149864C (es)
ES (1) ES446816A1 (es)
FI (1) FI61494C (es)
FR (1) FR2307824A1 (es)
GB (1) GB1490509A (es)
GR (1) GR58454B (es)
IN (1) IN143034B (es)
IT (1) IT1059283B (es)
LU (1) LU72278A1 (es)
MX (1) MX3477E (es)
NL (1) NL164569C (es)
NO (1) NO146991C (es)
PT (1) PT64985B (es)
SE (1) SE430253B (es)
SU (1) SU795488A3 (es)
TR (1) TR19292A (es)
ZA (1) ZA762076B (es)

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* Cited by examiner, † Cited by third party
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LU77489A1 (es) * 1977-06-06 1979-01-19
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US4258167A (en) * 1978-02-13 1981-03-24 Nissan Chemical Industries, Ltd. Process for producing powdery isotactic polyolefin
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US4210559A (en) * 1978-10-30 1980-07-01 Standard Oil Company (Indiana) Catalyst for the preparation of polyalpha-olefins having broad molecular weight distributions
JPS5919567B2 (ja) * 1978-11-27 1984-05-07 昭和電工株式会社 改善されたエチレン系重合体の製造方法
US4233182A (en) * 1978-12-26 1980-11-11 Standard Oil Company (Indiana) High activity catalyst for the polymerization of alpha-olefins
WO1980001485A1 (en) * 1979-01-18 1980-07-24 Mitsubishi Chem Ind Process for producing olefin polymer
US4363746A (en) 1979-05-29 1982-12-14 Phillips Petroleum Company Composition of matter and method of preparing same, catalyst, method of producing the catalyst and polymerization process employing the catalyst
JPS55160002A (en) * 1979-06-01 1980-12-12 Chisso Corp Production of olefin polymer
US4366298A (en) * 1979-07-05 1982-12-28 Wacker-Chemie Gmbh Process and heavy metal catalyst for the polymerization of α-olefins, particularly polyethylene
JPS6024805B2 (ja) * 1979-09-05 1985-06-14 日石三菱株式会社 共重合体の製法
US4269733A (en) * 1979-09-28 1981-05-26 The Dow Chemical Company Ultra high efficiency catalyst for polymerizing olefins
US4363902A (en) * 1980-03-17 1982-12-14 Wacker-Chemie Gmbh Process and heavy metal catalyst for the polymerization of α-olefins, particularly polyethylene
US4384087A (en) * 1980-03-24 1983-05-17 Phillips Petroleum Company Composition of matter and method of preparing same, catalyst, method of producing the catalyst and polymerization process employing the catalyst
JPS5712007A (en) * 1980-06-27 1982-01-21 Idemitsu Kosan Co Ltd Production of polyethylene
EP0043473B1 (en) * 1980-06-25 1985-08-07 Idemitsu Kosan Company Limited Process for the production of polyethylene
DE3025760A1 (de) * 1980-07-08 1982-02-04 Wacker-Chemie GmbH, 8000 München Verfahren zur polymersation von (alpha) -olefinen
US4326988A (en) * 1980-08-12 1982-04-27 Phillips Petroleum Company Catalyst, method of producing the catalyst, and polymerization process employing the catalyst
US4325837A (en) * 1980-08-12 1982-04-20 Phillips Petroleum Company Catalyst, method of producing the catalyst, and polymerization process employing the catalyst
US4310648A (en) * 1980-10-20 1982-01-12 The Dow Chemical Company Polymerization of olefins in the presence of a catalyst containing titanium and zirconium
US4356111A (en) * 1980-10-20 1982-10-26 The Dow Chemical Company High efficiency catalyst containing titanium and zirconium for polymerizing olefins
US4399053A (en) * 1980-12-24 1983-08-16 The Dow Chemical Company High efficiency catalyst containing titanium, zirconium and zinc for polymerizing olefins
US4394291A (en) * 1981-03-04 1983-07-19 Phillips Petroleum Company Polyolefin polymerization process and catalyst
US4525554A (en) * 1981-03-04 1985-06-25 Mitsubishi Chemical Industries Ltd. Process for polymerizing olefin
US4396747A (en) * 1981-05-22 1983-08-02 Phillips Petroleum Company Zirconium-titanium catalyzed olefin polymerization
US4472523A (en) * 1981-05-22 1984-09-18 Phillips Petroleum Company Zirconium-titanium catalyzed olefin polymerization
US4376065A (en) * 1981-06-01 1983-03-08 The Dow Chemical Company Organo zirconium-chromium compound, catalyst prepared therefrom and polymerization of olefins therewith
US4361685A (en) * 1981-06-01 1982-11-30 The Dow Chemical Company Polymerization of olefins in the presence of catalyst prepared from organo zirconium-chromium mixtures
US4518751A (en) * 1981-06-05 1985-05-21 Idemitsu Kosan Company Limited Process for the production of polyethylene
US4381253A (en) * 1981-10-22 1983-04-26 The Dow Chemical Company Ultra high efficiency catalyst for polymerizing olefins
US4409126A (en) * 1981-10-22 1983-10-11 The Dow Chemical Company Ultra high efficiency catalyst for polymerizing olefins
US4380508A (en) * 1981-10-22 1983-04-19 The Dow Chemical Company Ultra high efficiency catalyst for polymerizing olefins
US4379760A (en) * 1981-11-12 1983-04-12 The Dow Chemical Company High efficiency catalyst for polymerizing olefins
EP0083671A1 (en) * 1982-01-07 1983-07-20 The Dow Chemical Company High efficiency catalyst containing titanium and zirconium and process for polymerizing olefins
US4497906A (en) * 1982-02-16 1985-02-05 Sumitomo Chemical Company, Limited Solid catalyst component for olefin polymerization
US4550094A (en) * 1982-02-16 1985-10-29 Sumitomo Chemical Company, Limited Solid catalyst component for olefin polymerization
US4675368A (en) * 1982-10-04 1987-06-23 Solvay & Cie. Process for inhibiting crust formation in reactors during alpha-olefin prepolymerization modification of Ziegler catalyst
US4587727A (en) * 1983-07-05 1986-05-13 International Business Machines Corporation System for generating circuit boards using electroeroded sheet layers
JPS6042404A (ja) * 1983-08-16 1985-03-06 Sumitomo Chem Co Ltd オレフインの重合方法
IT1212779B (it) * 1983-10-14 1989-11-30 Enichimica Secondaria Procedimento per la polimerizzazione di etilene e per la copolimerizzazione di etilene con alfa-olefine e catalizzatore relativo.
US4496661A (en) * 1983-10-24 1985-01-29 The Dow Chemical Company High efficiency catalyst for polymerizing olefins
US4618660A (en) * 1984-06-29 1986-10-21 Exxon Research & Engineering Co. Polymerization catalyst
US4939217A (en) * 1987-04-03 1990-07-03 Phillips Petroleum Company Process for producing polyolefins and polyolefin catalysts
US5064797A (en) * 1987-04-03 1991-11-12 Phillips Petroleum Company Process for producing polyolefins and polyolefin catalysts
JPH0725827B2 (ja) * 1987-06-02 1995-03-22 出光石油化学株式会社 エチレン重合体の製造方法
EP0522424B1 (en) * 1991-07-03 1996-12-18 Tosoh Corporation Method for producing a polyolefin
US5332707A (en) * 1992-07-31 1994-07-26 Amoco Corporation Olefin polymerization and copolymerization catalyst
US5374597A (en) * 1993-02-12 1994-12-20 Quantum Chemical Corporation Vanadium based olefin polymerization catalyst
US5399540A (en) * 1993-02-12 1995-03-21 Quantum Chemical Corporation ZR/V multi-site olefin polymerization catalyst
US5405817A (en) * 1993-02-12 1995-04-11 Quantum Chemical Corporation V/TI multi-site olefin polymerization catalyst
BE1009308A3 (fr) * 1995-04-28 1997-02-04 Solvay Polymere d'ethylene et procedes pour son obtention.
EP1232161B1 (en) 1999-06-30 2007-11-28 Union Carbide Chemicals & Plastics Technology Corporation Mixed metal alkoxide complexes and polymerization catalysts made therefrom
KR20020019476A (ko) * 1999-06-30 2002-03-12 조셉 에스. 바이크 마그네슘-지르코늄 알콕사이드 착물 및 이로부터 제조된중합 촉매
US20090048402A1 (en) * 2007-08-17 2009-02-19 Lynch Michael W Preparing multimodal polyethylene having controlled long chain branching distribution
US8809220B2 (en) * 2010-04-13 2014-08-19 Union Carbide Chemicals & Plastics Technology Llc Method of making Ziegler-Natta type catalysts

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL213149A (es) * 1955-12-22
FR2093306A6 (fr) 1970-06-09 1972-01-28 Solvay Catalyseurs et procede perfectionnes pour la polymerisation et la copolymerisation des olefines
US3678025A (en) * 1970-05-22 1972-07-18 Dow Chemical Co Preparation of linear alpha olefin polymers having broad molecular weight distributions
DE2128760A1 (de) * 1970-06-12 1971-12-16 Shell Int Research Verfahren zur Polymerisation von Olefinen
BE791676A (fr) * 1971-12-08 1973-05-21 Solvay Procédé pour la polymérisation des oléfines
LU65587A1 (es) 1972-06-22 1973-12-27
IT1020055B (it) * 1973-09-08 1977-12-20 Solvay Polimerizzazione a bassa pressio ne di olefine
JPS5146387A (en) * 1974-10-18 1976-04-20 Yozo Kondo Horiorefuinno seizohoho
US3939137A (en) * 1974-11-22 1976-02-17 Phillips Petroleum Company Silane adjuvant for chromium oxide catalyst

Also Published As

Publication number Publication date
JPS5529597A (en) 1980-03-01
GR58454B (en) 1977-10-10
PT64985B (fr) 1977-09-07
US4109071A (en) 1978-08-22
DD126387A5 (es) 1977-07-13
IT1059283B (it) 1982-05-31
DK149864B (da) 1986-10-13
SU795488A3 (ru) 1981-01-07
FI61494C (fi) 1982-08-10
CA1080208A (fr) 1980-06-24
SE7604279L (sv) 1976-10-15
DE2615390A1 (de) 1976-10-21
ATA265676A (de) 1978-05-15
FR2307824A1 (fr) 1976-11-12
IN143034B (es) 1977-09-24
JPS51138785A (en) 1976-11-30
GB1490509A (en) 1977-11-02
NL7603907A (nl) 1976-10-18
AU1287276A (en) 1977-10-20
NO761239L (es) 1976-10-15
NL164569B (nl) 1980-08-15
ZA762076B (en) 1977-04-27
FI61494B (fi) 1982-04-30
LU72278A1 (es) 1977-02-03
JPS5846204B2 (ja) 1983-10-14
AR207281A1 (es) 1976-09-22
DE2615390B2 (de) 1980-11-06
PT64985A (fr) 1976-05-01
CH617212A5 (es) 1980-05-14
BR7602156A (pt) 1976-10-05
SE430253B (sv) 1983-10-31
DE2615390C3 (de) 1981-10-08
DK168976A (da) 1976-10-15
ES446816A1 (es) 1978-02-01
DK149864C (da) 1987-06-29
BE840378A (fr) 1976-10-05
AT347677B (de) 1979-01-10
TR19292A (tr) 1978-11-21
JPS558083B2 (es) 1980-03-01
NO146991B (no) 1982-10-04
NO146991C (no) 1983-01-12
FI761019A (es) 1976-10-15
NL164569C (nl) 1981-01-15
FR2307824B1 (es) 1979-04-20

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