KR840000461A - 카르복실산 및 에스테르의 제조방법 - Google Patents
카르복실산 및 에스테르의 제조방법 Download PDFInfo
- Publication number
- KR840000461A KR840000461A KR1019820002507A KR820002507A KR840000461A KR 840000461 A KR840000461 A KR 840000461A KR 1019820002507 A KR1019820002507 A KR 1019820002507A KR 820002507 A KR820002507 A KR 820002507A KR 840000461 A KR840000461 A KR 840000461A
- Authority
- KR
- South Korea
- Prior art keywords
- carbon monoxide
- organic compound
- range
- organic compounds
- group
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims 8
- 150000002148 esters Chemical class 0.000 title claims 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 title 1
- 150000002894 organic compounds Chemical class 0.000 claims 17
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 12
- 229910002091 carbon monoxide Inorganic materials 0.000 claims 12
- 150000008064 anhydrides Chemical class 0.000 claims 5
- 150000001450 anions Chemical class 0.000 claims 4
- 150000001336 alkenes Chemical class 0.000 claims 3
- 125000004432 carbon atom Chemical group C* 0.000 claims 3
- 239000007791 liquid phase Substances 0.000 claims 3
- 239000012808 vapor phase Substances 0.000 claims 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims 2
- WVRPFQGZHKZCEB-UHFFFAOYSA-N Isopropyl 2-methylpropanoate Chemical compound CC(C)OC(=O)C(C)C WVRPFQGZHKZCEB-UHFFFAOYSA-N 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- IAQRGUVFOMOMEM-UHFFFAOYSA-N but-2-ene Chemical compound CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 claims 2
- WDAXFOBOLVPGLV-UHFFFAOYSA-N ethyl isobutyrate Chemical compound CCOC(=O)C(C)C WDAXFOBOLVPGLV-UHFFFAOYSA-N 0.000 claims 2
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 claims 2
- 229940024423 isopropyl isobutyrate Drugs 0.000 claims 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 2
- 239000011541 reaction mixture Substances 0.000 claims 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- IJMWOMHMDSDKGK-UHFFFAOYSA-N Isopropyl propionate Chemical compound CCC(=O)OC(C)C IJMWOMHMDSDKGK-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 claims 1
- -1 ethylene, propylene, isobutene Chemical class 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/58—Preparation of carboxylic acid halides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/14—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
- C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (8)
- 일산화탄소, 무수불화수소산 및 일산화탄소를 부가시킬 수 있는 유기화합물을 액상에서 반응시켜서 아실리움 음이온 생성물을 제조하는 동시에 한편으로는 일산화탄소, 유기화합물 및 무수 살화수소산이 아실리움 음이온 생성물을 생성시키는 속도와 실제로 같은 속도로 액체 반응 혼합물 상의 증기상에 일산화탄소와유기화합물을 공급하고, 상기 혼합물의 증기상 중의 일산화탄소가 초임계 액상이고, 유기화합물이 용해되는 온도와 압력 범위 내에서 액체상에 있는 증기상을 유지시키고, 상기 유기화합물은 (a) 일반식(여기서, R는 20개 까지의 탄소원자를 가진 알킬기이고, R'는 2-20개의 탄소원자를 가진 알킬기임)로 표시되는 에스테르류와 (b) 일산화탄소를 부가 시킬 수 있는 적어도 한개 이상의 이중 결합을 갖고 20개 까지의 탄소원자수를 가진 올레핀류로 구성된군에서 선택된 것이며, 상기 온도는 40℃ 내지 90℃ 범위 내이고 압력은 109바(1,600psia) 내지 340바(5,000psia)이고, 상기 반응 혼합물중의 무수불화수소산 대 유기화합물의 최종 몰비는 무수 불화수소산 1-100몰 대 유기화합물 1몰 범위내이고, 일산화탄소 대 유기화합물의 몰비는 일산화탄소 1-25몰 대 유기화합물 1몰 범위 내로 공급하는 것은 특징으로 하는 일산화탄소, 무수산 및 일산화탄소를 부가시킬 수 있는 유기화합물로부터 아실리움 음이온 생성물의 제조방법.
- 상기 제1항 기재에 있어서, 유기화합물이 이소프로필 이소부티트산염, 에틸 이소부티트산염, 이소프로필 프로피온산염 및 에틸프로피온산염으로 구성되는 군에서 선택된 에스테르인 것이 특징인 방법.
- 상기 제1항 기재에 있어서, 유기화합물이 이소프로필 이소부티트산염의 에스테르인것이 특징인 방법.
- 상기 제1항 기재에 있어서, 유기 화합물이 에틸렌, 프로필렌, 이소부텐, 1-부텐, 2-부텐 및 1,3-부타디엔으로 구성된 군에서 선택된 올레핀인 것이 특징인 방법.
- 상기 제1항 기재에 있어서, 올래핀이 에틸렌과 프로필렌으로 구성되는 군에서 선택된 것이 특징인 방법.
- 상기 제1항 기재에 있어서, 올레핀이 프로필렌인 것이 특징인 방법.
- 상기 제1,2,3,4,5 또는 6항 중의 어느 한가지 항기재에 있어서, 온도가 40℃ 내지 70℃ 범위 내이고, 압력은 169바(2,500psia) 내지 197바(2,900psia) 범위내이며 무수 불화수소산 대 유기화합물의 최종몰비가 무수불화수소산 10-20몰 대 유기화합물 1몰 범위내이고 일산화탄소 대 유기 화합물의 몰비가 일산화탄소 15-25몰 대 유기화합물 1몰 범위 내인 것이 특징인 방법.
- 상기 제7항 기재에 있어서 아실리움 음이온 생성물을 반응혼합물로부터 분리시키는 것을 특징으로 하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US27876481A | 1981-06-29 | 1981-06-29 | |
| US278764 | 1981-06-29 | ||
| US278,764 | 1981-06-29 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR840000461A true KR840000461A (ko) | 1984-02-22 |
| KR850001914B1 KR850001914B1 (ko) | 1985-12-31 |
Family
ID=23066263
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR8202507A KR850001914B1 (ko) | 1981-06-29 | 1982-06-04 | 불화이소부티릴의 제조 방법 |
Country Status (12)
| Country | Link |
|---|---|
| JP (1) | JPS6024088B2 (ko) |
| KR (1) | KR850001914B1 (ko) |
| AT (1) | AT388160B (ko) |
| AU (1) | AU532639B2 (ko) |
| BE (1) | BE893419A (ko) |
| CA (1) | CA1173057A (ko) |
| CH (1) | CH660180A5 (ko) |
| DE (1) | DE3221172C2 (ko) |
| FR (1) | FR2508441B1 (ko) |
| GB (1) | GB2100729B (ko) |
| IT (1) | IT1195930B (ko) |
| NL (1) | NL187013C (ko) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NZ195559A (en) * | 1979-11-29 | 1984-03-16 | Ris Irrigation Syst | Butterfly sprinkler with dust protection for bearing |
| US4499029A (en) * | 1983-06-15 | 1985-02-12 | Ashland Oil, Inc. | Isobutyryl fluoride manufacture |
| DE3725428A1 (de) * | 1987-07-31 | 1989-02-09 | Basf Ag | Verfahren zur herstellung von carbonsaeurehalogeniden |
| FR2691965A1 (fr) * | 1992-06-04 | 1993-12-10 | Atochem Elf Sa | Procédé de fabrication de fluorure d'isobutyryle. |
| GB9917429D0 (en) * | 1999-07-23 | 1999-09-22 | Swan Thomas & Co Ltd | Carbonylation reactions |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE972291C (de) * | 1954-05-16 | 1959-07-02 | Studiengesellschaft Kohle Mbh | Verfahren zur Herstellung von Monocarbonsaeuren aus Olefinen, Kohlenoxyd und Wasser |
| DE973077C (de) * | 1954-07-30 | 1959-11-26 | Studiengesellschaft Kohle Mbh | Verfahren zur Herstellung von Carbonsaeuren aus Olefinen und Kohlenoxyd |
| DE1064941B (de) * | 1957-04-24 | 1959-09-10 | Studiengesellschaft Kohle Mbh | Verfahren zur Herstellung von Gemischen aus gesaettigten aliphatischen oder cycloaliphatischen Monocarbonsaeurealkylestern |
| US3065242A (en) * | 1960-02-23 | 1962-11-20 | Du Pont | Production of acyl halides, carboxylic acids and lactones |
| US3167585A (en) * | 1960-08-25 | 1965-01-26 | Gulf Research Development Co | Process for carboxylation of iso-olefins |
| GB942367A (en) * | 1961-04-29 | 1963-11-20 | Basf Ag | Continuous production of carboxylic acids from olefines, carbon monoxide and water |
| NL6816940A (ko) * | 1967-11-28 | 1969-05-30 | ||
| GB1232317A (ko) * | 1968-12-30 | 1971-05-19 | ||
| BE755997A (fr) * | 1969-09-11 | 1971-03-10 | Bp Chem Int Ltd | Production d'acides dicarboxyliques |
| DE2750719A1 (de) * | 1977-11-12 | 1979-05-17 | Roehm Gmbh | Verfahren zur herstellung von isobuttersaeure |
| US4224232A (en) * | 1978-12-21 | 1980-09-23 | Gulf Research & Development Company | Production of carboxylic acids from olefins and mixtures of olefins |
| DE3064472D1 (en) * | 1979-04-09 | 1983-09-08 | Chem Systems | Preparation of acids and esters |
-
1982
- 1982-06-03 AT AT0215082A patent/AT388160B/de not_active IP Right Cessation
- 1982-06-04 DE DE3221172A patent/DE3221172C2/de not_active Expired
- 1982-06-04 CA CA000404487A patent/CA1173057A/en not_active Expired
- 1982-06-04 JP JP57096065A patent/JPS6024088B2/ja not_active Expired
- 1982-06-04 CH CH3476/82A patent/CH660180A5/de not_active IP Right Cessation
- 1982-06-04 NL NLAANVRAGE8202268,A patent/NL187013C/xx not_active IP Right Cessation
- 1982-06-04 GB GB08216304A patent/GB2100729B/en not_active Expired
- 1982-06-04 AU AU84609/82A patent/AU532639B2/en not_active Ceased
- 1982-06-04 KR KR8202507A patent/KR850001914B1/ko active
- 1982-06-04 FR FR8209809A patent/FR2508441B1/fr not_active Expired
- 1982-06-04 IT IT21707/82A patent/IT1195930B/it active
- 1982-06-04 BE BE0/208271A patent/BE893419A/fr not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| JPS588036A (ja) | 1983-01-18 |
| GB2100729A (en) | 1983-01-06 |
| BE893419A (fr) | 1982-10-01 |
| GB2100729B (en) | 1985-10-30 |
| JPS6024088B2 (ja) | 1985-06-11 |
| NL187013B (nl) | 1990-12-03 |
| FR2508441B1 (fr) | 1987-04-30 |
| AU8460982A (en) | 1983-03-10 |
| AT388160B (de) | 1989-05-10 |
| CH660180A5 (de) | 1987-03-31 |
| AU532639B2 (en) | 1983-10-06 |
| DE3221172C2 (de) | 1984-08-02 |
| KR850001914B1 (ko) | 1985-12-31 |
| NL8202268A (nl) | 1983-01-17 |
| IT1195930B (it) | 1988-11-03 |
| NL187013C (nl) | 1991-05-01 |
| IT8221707A0 (it) | 1982-06-04 |
| CA1173057A (en) | 1984-08-21 |
| DE3221172A1 (de) | 1983-01-05 |
| FR2508441A1 (fr) | 1982-12-31 |
| ATA215082A (de) | 1988-10-15 |
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