GB903014A - Improvements in or relating to the production of polymers - Google Patents

Improvements in or relating to the production of polymers

Info

Publication number
GB903014A
GB903014A GB19215/60A GB1921560A GB903014A GB 903014 A GB903014 A GB 903014A GB 19215/60 A GB19215/60 A GB 19215/60A GB 1921560 A GB1921560 A GB 1921560A GB 903014 A GB903014 A GB 903014A
Authority
GB
United Kingdom
Prior art keywords
complexes
molecular weight
mixture
product
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB19215/60A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP PLC
Original Assignee
BP PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to NL265079D priority Critical patent/NL265079A/xx
Priority to BE604447D priority patent/BE604447A/xx
Priority to BE604446D priority patent/BE604446A/xx
Application filed by BP PLC filed Critical BP PLC
Priority to GB19215/60A priority patent/GB903014A/en
Priority to US95802A priority patent/US3325559A/en
Priority to FR862004A priority patent/FR1290549A/en
Priority to FR863380A priority patent/FR1293286A/en
Publication of GB903014A publication Critical patent/GB903014A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20—Carbon compounds
    • B01J27/22—Carbides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/107—Alkenes with six carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/107—Alkenes with six carbon atoms
    • C07C11/113—Methylpentenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/10—Catalytic processes with metal oxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/24—Catalytic processes with metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/30—Catalytic processes with hydrides or organic compounds containing metal-to-carbon bond; Metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/2206—Catalytic processes not covered by C07C5/23 - C07C5/31
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F295/00—Macromolecular compounds obtained by polymerisation using successively different catalyst types without deactivating the intermediate polymer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/10—Chlorides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/18—Carbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/20—Carbon compounds
    • C07C2527/22—Carbides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/14—Monomers containing five or more carbon atoms

Abstract

High molecular weight polypropylene is made by (1) polymerizing propylene in contact with a lamellar complex containing or consisting of, an alkali metal and carbon to give a liquid low-molecular weight product and, (2) polymerizing this product, or a C6 fraction, or a dimer, or a mixture of dimers separated from this product in the presence of a catalyst comprising an aluminium alkyl compound. The complex is preferably selected from complexes of the formula KC8, KC16, KC24, KC36, KC48, and KC60, although other complexes which contain lithium, sodium, e.g. NaC64, rubidium, or caesium, may be used as well as mixtures of complexes, and also a mixture of the lamellar complex and an alkali metal supported on carbon. In (1) the polymerization is generally effected in the temperature range of 50 DEG to 200 DEG C., and at a pressure of 50 to 4,000 lbs./sq. inch gauge. The C6 fraction is preferably 4-methylpentene-1 which is obtained by employing a reaction temperature between 100 DEG -160 DEG C., and a polymerization contact time of relatively short duration. The propylene is purified before use. The reaction may be effected batchwise or continuously, and the catalyst employed as a fixed bed, fluidized bed, or a slurry in a solvent, or suspended in one or more of the liquid reaction products. The catalyst in stage (2) is preferably a mixture of titanium tetrachloride and aluminium triethyl. The high molecular weight polypropylene recovered from (2) is a crystalline powder of melting point in excess of 220 DEG C. Specification 810,023 is referred to.
GB19215/60A 1960-03-23 1960-05-31 Improvements in or relating to the production of polymers Expired GB903014A (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
NL265079D NL265079A (en) 1960-05-31
BE604447D BE604447A (en) 1960-05-31
BE604446D BE604446A (en) 1960-05-31
GB19215/60A GB903014A (en) 1960-05-31 1960-05-31 Improvements in or relating to the production of polymers
US95802A US3325559A (en) 1960-03-23 1961-03-15 Production of 4-methylpentene-1
FR862004A FR1290549A (en) 1960-05-31 1961-05-16 Process for the production of polymers and products obtained
FR863380A FR1293286A (en) 1960-05-31 1961-05-30 Manufacturing process of hydrocarbons and products obtained

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB19215/60A GB903014A (en) 1960-05-31 1960-05-31 Improvements in or relating to the production of polymers

Publications (1)

Publication Number Publication Date
GB903014A true GB903014A (en) 1962-08-09

Family

ID=10125645

Family Applications (1)

Application Number Title Priority Date Filing Date
GB19215/60A Expired GB903014A (en) 1960-03-23 1960-05-31 Improvements in or relating to the production of polymers

Country Status (3)

Country Link
BE (2) BE604447A (en)
GB (1) GB903014A (en)
NL (1) NL265079A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0283958A2 (en) * 1987-03-19 1988-09-28 Idemitsu Kosan Company Limited Olefin polymer and process for production thereof
JP2547208B2 (en) 1987-03-19 1996-10-23 出光興産株式会社 Olefin-based polymer and method for producing the same
JP2554071B2 (en) 1987-03-19 1996-11-13 出光興産株式会社 Olefin-based copolymer and method for producing the same
JP2561277B2 (en) 1987-06-10 1996-12-04 出光興産株式会社 Branched α-olefin copolymer and method for producing the same

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0283958A2 (en) * 1987-03-19 1988-09-28 Idemitsu Kosan Company Limited Olefin polymer and process for production thereof
EP0283958A3 (en) * 1987-03-19 1991-05-08 Idemitsu Kosan Company Limited Olefin polymer and process for production thereof
JP2547208B2 (en) 1987-03-19 1996-10-23 出光興産株式会社 Olefin-based polymer and method for producing the same
JP2554071B2 (en) 1987-03-19 1996-11-13 出光興産株式会社 Olefin-based copolymer and method for producing the same
JP2561277B2 (en) 1987-06-10 1996-12-04 出光興産株式会社 Branched α-olefin copolymer and method for producing the same

Also Published As

Publication number Publication date
BE604447A (en) 1900-01-01
NL265079A (en) 1900-01-01
BE604446A (en) 1900-01-01

Similar Documents

Publication Publication Date Title
ES397560A1 (en) Process for the polymerization of alkenes
GB903014A (en) Improvements in or relating to the production of polymers
GB822926A (en) Catalysts for the polymerisation of olefins and process for preparing same
GB1291552A (en) Olefin polymerization
GB930433A (en) Preparation of olefins
GB961960A (en) Novel derivatives of trimellitic anhydride
AU2257588A (en) Phenothiazine dimers and oligomers, process for preparing and use in reactor scale prevention
ES415100A1 (en) Catalyst for the polymerization of olefins based upon magnesium and transition metal
ES448943A1 (en) Transition metal compound
US2615915A (en) Halogenoalkanenitriles
GB1006879A (en) Polymerisation process
GB779111A (en) Improvements in the production of polyethylene
US2930782A (en) Preparation of resins
US2346048A (en) Method of producing dialkoxy stilbenes
GB812515A (en) Improvements in or relating to the polymerisation of ethylene
GB867139A (en) Improvements in the production of polyolefins
GB1019149A (en) Improvements in or relating to the manufacture of 1,2,3,4-tetrachlorobutane
GB1245071A (en) Improved process for the manufacture of 5-alkenyl-2-norbornenes
GB821107A (en) Improvements in and relating to the polymerisation of olefins
JPS5611909A (en) Solid catalyst component for polymerization of olefin
GB1019131A (en) Improvements in or relating to the manufacture of 1,2,3,4-tetrachlorobutane
GB1437899A (en) Preparation of chlorine-substituted aromatic carboxylic acid chlorides
GB935984A (en) Improvements in the production of solid propylene polymers
GB1050944A (en)
US3256264A (en) Catalyst for the polymerization of monoolefins consisting of powdered aluminum, the halide of a metal of groups iva, va, via of the periodic table, and the product of a reaction mass containing benzene, aici, and a halogen acid