MX346341B - Reactor catalítico de membrana con bombeo electroquímico de hidrógeno u oxígeno y sus aplicaciones. - Google Patents
Reactor catalítico de membrana con bombeo electroquímico de hidrógeno u oxígeno y sus aplicaciones.Info
- Publication number
- MX346341B MX346341B MX2012005263A MX2012005263A MX346341B MX 346341 B MX346341 B MX 346341B MX 2012005263 A MX2012005263 A MX 2012005263A MX 2012005263 A MX2012005263 A MX 2012005263A MX 346341 B MX346341 B MX 346341B
- Authority
- MX
- Mexico
- Prior art keywords
- hydrogen
- reactor
- electrochemical pumping
- catalytic membrane
- applications
- Prior art date
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2475—Membrane reactors
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/02—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of hydrogen atoms by amino groups
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/92—Metals of platinum group
- H01M4/921—Alloys or mixtures with metallic elements
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/94—Non-porous diffusion electrodes, e.g. palladium membranes, ion exchange membranes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
- H01M8/0681—Reactant purification by the use of electrochemical cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/08—Fuel cells with aqueous electrolytes
- H01M8/086—Phosphoric acid fuel cells [PAFC]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M2008/1293—Fuel cells with solid oxide electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2250/00—Fuel cells for particular applications; Specific features of fuel cell system
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/002—Shape, form of a fuel cell
- H01M8/004—Cylindrical, tubular or wound
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/103—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having nitrogen, e.g. sulfonated polybenzimidazoles [S-PBI], polybenzimidazoles with phosphoric acid, sulfonated polyamides [S-PA] or sulfonated polyphosphazenes [S-PPh]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Sustainable Energy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
La presente invención se refiere a un nuevo tipo de reactor químico, descrito como reactor catalítico de membrana con bombeo electroquímico de hidrógeno u oxígeno. Este nuevo tipo de reactor es particularmente adecuado para incrementar la selectividad y la velocidad de conversión de reacciones de deshidrogenación, hidrogenación, desoxidación y oxidación y a saber en la reacción de aminación directa de hidrocarburos. Este reactor puede ser usado para la producción de varios compuestos químicos, tales como la aminación directa de hidrocarburos y en particular para la síntesis de anilina a partir de benceno. En esta aplicación, en donde el hidrógeno es removido por bombeo electroquímico del hidrógeno formado o por bombeo de oxígeno así, conforme el hidrógeno se forma, se oxida. Este nuevo reactor presenta conversión de benceno a anilina superior del 40.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PT104812A PT104812A (pt) | 2009-11-06 | 2009-11-06 | Reactor catal?tico de membrana com bombagem electroqu?mica de hidrog?nio ou de oxig?nio e suas aplica??es |
PCT/IB2010/055045 WO2011055343A2 (pt) | 2009-11-06 | 2010-11-05 | Reactor catalítico de membrana com bombagem electroquímica de hidrogénio ou de oxigénio e suas aplicações |
Publications (2)
Publication Number | Publication Date |
---|---|
MX2012005263A MX2012005263A (es) | 2012-09-07 |
MX346341B true MX346341B (es) | 2017-03-14 |
Family
ID=43759121
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2012005263A MX346341B (es) | 2009-11-06 | 2010-11-05 | Reactor catalítico de membrana con bombeo electroquímico de hidrógeno u oxígeno y sus aplicaciones. |
Country Status (15)
Country | Link |
---|---|
US (1) | US9498765B2 (es) |
EP (1) | EP2497570A2 (es) |
JP (1) | JP5852575B2 (es) |
KR (1) | KR20120105461A (es) |
CN (1) | CN102762292B (es) |
AP (1) | AP3617A (es) |
AU (1) | AU2010316633B2 (es) |
BR (1) | BR112012010764A2 (es) |
CA (1) | CA2779953A1 (es) |
EA (1) | EA024313B1 (es) |
MA (1) | MA33728B1 (es) |
MX (1) | MX346341B (es) |
PT (1) | PT104812A (es) |
WO (1) | WO2011055343A2 (es) |
ZA (1) | ZA201204096B (es) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2012046889A1 (ko) * | 2010-10-05 | 2012-04-12 | 연세대학교 산학협력단 | 연료전지용 복합체 전해질 막, 이의 제조방법 및 이를 포함하는 연료전지 |
PT106860A (pt) | 2013-03-28 | 2014-09-29 | Cuf Químicos Ind S A | Conjunto elétrodos/eletrólito, reator e método para a aminação direta de hidrocarbonetos |
CN105552411B (zh) * | 2015-12-09 | 2017-09-22 | 佛山索弗克氢能源有限公司 | 氨气在sofc电池中的应用及其应用装置 |
US11136678B2 (en) | 2016-08-11 | 2021-10-05 | Massachusetts Institute Of Technology | Electrochemical oxidation of aliphatic and aromatic compounds |
CN114807983B (zh) * | 2021-01-18 | 2024-06-04 | 武汉理工大学 | 一种用于实现不饱和烯炔烃选择性催化加氢的电化学系统 |
Family Cites Families (26)
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US3919155A (en) | 1970-12-18 | 1975-11-11 | Du Pont | Synthesis of aromatic amines by reaction of aromatic compounds with ammonia |
US3929889A (en) | 1971-02-16 | 1975-12-30 | Du Pont | Synthesis of aromatic amines by reaction of aromatic compounds with ammonia |
US4031106A (en) | 1973-12-19 | 1977-06-21 | E. I. Du Pont De Nemours And Company | Synthesis of aromatic amines by reaction of aromatic compounds with ammonia |
US4001260A (en) | 1973-12-19 | 1977-01-04 | E. I. Du Pont De Nemours And Company | Synthesis of aromatic amines by reaction of aromatic compounds with ammonia |
US4933054A (en) * | 1987-03-13 | 1990-06-12 | The Standard Oil Company | Electrocatalytic oxidative dehydrogenation of saturated hydrocarbons to unsaturated hydrocarbons |
CA2017243C (en) * | 1989-05-25 | 2003-09-30 | Terry J. Mazanec | Novel solid multi-component membranes, electrochemical reactor and use of membranes and reactor for oxidation reactions |
DE4235125C2 (de) * | 1992-10-17 | 1994-09-29 | Zsw | Verfahren zur Herstellung von Synthesegas und Vorrichtung zum Durchführen des Verfahrens |
US6355093B1 (en) * | 1993-12-08 | 2002-03-12 | Eltron Research, Inc | Two component-three dimensional catalysis |
US5525436A (en) * | 1994-11-01 | 1996-06-11 | Case Western Reserve University | Proton conducting polymers used as membranes |
US7416803B2 (en) * | 1999-01-22 | 2008-08-26 | California Institute Of Technology | Solid acid electrolytes for electrochemical devices |
JP2003168446A (ja) * | 2001-11-29 | 2003-06-13 | Toyota Motor Corp | 燃料電池及びその製造方法 |
CN100396646C (zh) * | 2002-07-26 | 2008-06-25 | 中国科学院大连化学物理研究所 | 一种金属磷酸锆无机材料及其制备方法和应用 |
WO2005035444A2 (en) * | 2003-10-10 | 2005-04-21 | Ohio University | Electro-catalysts for the oxidation of ammonia in alkaline media |
DE102004062253A1 (de) | 2004-12-23 | 2006-07-06 | Basf Ag | Direktaminierung von Kohlenwasserstoffen |
WO2006138611A2 (en) * | 2005-06-16 | 2006-12-28 | Trustees Of Boston University | Waste to hydrogen conversion process and related apparatus |
DE102005041140A1 (de) * | 2005-08-30 | 2007-03-01 | Basf Ag | Direktaminierung von Kohlenwasserstoffen |
US8133637B2 (en) * | 2005-10-06 | 2012-03-13 | Headwaters Technology Innovation, Llc | Fuel cells and fuel cell catalysts incorporating a nanoring support |
US20080280190A1 (en) * | 2005-10-20 | 2008-11-13 | Robert Brian Dopp | Electrochemical catalysts |
CN101389592B (zh) | 2006-02-24 | 2012-10-10 | 巴斯夫欧洲公司 | 烃类的直接胺化 |
JP2008004312A (ja) * | 2006-06-20 | 2008-01-10 | Kuraray Co Ltd | イオン伝導性バインダー、膜−電極接合体及び燃料電池 |
CN101101887A (zh) * | 2006-07-06 | 2008-01-09 | 通用电气公司 | 抗腐蚀的晶片处理设备及其制造方法 |
JP5430079B2 (ja) * | 2007-06-12 | 2014-02-26 | キヤノン株式会社 | 膜電極接合体の製造方法 |
KR101753922B1 (ko) * | 2009-07-10 | 2017-07-04 | 바스프 에스이 | 수소의 전기화학적 분리 및 수소의 물로의 전기화학적 반응을 포함하는, 탄화수소의 아미노탄화수소로의 직접 아미노화 방법 |
JP5536207B2 (ja) * | 2009-07-10 | 2014-07-02 | ビーエーエスエフ ソシエタス・ヨーロピア | 水素を電気化学的に除去しながら炭化水素をアミノ炭化水素に直接アミノ化する方法 |
CA2767793C (en) * | 2009-07-17 | 2017-12-05 | Danmarks Tekniske Universitet | Platinum and palladium alloys suitable as fuel cell electrodes |
US8361288B2 (en) * | 2009-08-27 | 2013-01-29 | Sun Catalytix Corporation | Compositions, electrodes, methods, and systems for water electrolysis and other electrochemical techniques |
-
2009
- 2009-11-06 PT PT104812A patent/PT104812A/pt unknown
-
2010
- 2010-11-05 EP EP10803630A patent/EP2497570A2/en not_active Withdrawn
- 2010-11-05 EA EA201290284A patent/EA024313B1/ru not_active IP Right Cessation
- 2010-11-05 US US13/508,542 patent/US9498765B2/en not_active Expired - Fee Related
- 2010-11-05 WO PCT/IB2010/055045 patent/WO2011055343A2/pt active Application Filing
- 2010-11-05 BR BR112012010764-0A patent/BR112012010764A2/pt not_active IP Right Cessation
- 2010-11-05 AP AP2012006290A patent/AP3617A/xx active
- 2010-11-05 KR KR1020127014403A patent/KR20120105461A/ko not_active Application Discontinuation
- 2010-11-05 AU AU2010316633A patent/AU2010316633B2/en not_active Ceased
- 2010-11-05 CN CN201080057841.6A patent/CN102762292B/zh not_active Expired - Fee Related
- 2010-11-05 MX MX2012005263A patent/MX346341B/es active IP Right Grant
- 2010-11-05 JP JP2012537478A patent/JP5852575B2/ja not_active Expired - Fee Related
- 2010-11-05 CA CA2779953A patent/CA2779953A1/en not_active Abandoned
-
2012
- 2012-05-07 MA MA34839A patent/MA33728B1/fr unknown
- 2012-06-05 ZA ZA2012/04096A patent/ZA201204096B/en unknown
Also Published As
Publication number | Publication date |
---|---|
ZA201204096B (en) | 2013-08-28 |
EA201290284A1 (ru) | 2012-10-30 |
CN102762292B (zh) | 2015-09-30 |
AU2010316633A1 (en) | 2012-06-14 |
MA33728B1 (fr) | 2012-11-01 |
WO2011055343A3 (pt) | 2011-06-30 |
AP2012006290A0 (en) | 2012-06-30 |
KR20120105461A (ko) | 2012-09-25 |
PT104812A (pt) | 2011-05-06 |
CA2779953A1 (en) | 2011-05-12 |
AU2010316633B2 (en) | 2016-04-14 |
BR112012010764A2 (pt) | 2018-03-06 |
AP3617A (en) | 2016-02-29 |
US9498765B2 (en) | 2016-11-22 |
JP2013514873A (ja) | 2013-05-02 |
US20120273366A1 (en) | 2012-11-01 |
CN102762292A (zh) | 2012-10-31 |
EP2497570A2 (en) | 2012-09-12 |
WO2011055343A2 (pt) | 2011-05-12 |
EA024313B1 (ru) | 2016-09-30 |
MX2012005263A (es) | 2012-09-07 |
JP5852575B2 (ja) | 2016-02-03 |
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