MX339720B - Proceso de aspersion para oxidacion selectiva. - Google Patents

Proceso de aspersion para oxidacion selectiva.

Info

Publication number
MX339720B
MX339720B MX2011009929A MX2011009929A MX339720B MX 339720 B MX339720 B MX 339720B MX 2011009929 A MX2011009929 A MX 2011009929A MX 2011009929 A MX2011009929 A MX 2011009929A MX 339720 B MX339720 B MX 339720B
Authority
MX
Mexico
Prior art keywords
oxidizable
reactant
alkyl substituent
ring
reaction mixture
Prior art date
Application number
MX2011009929A
Other languages
English (en)
Other versions
MX2011009929A (es
Inventor
Subramaniam Bala
H Busch Daryle
Niu Fenghui
Original Assignee
Univ Kansas
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Kansas filed Critical Univ Kansas
Publication of MX2011009929A publication Critical patent/MX2011009929A/es
Publication of MX339720B publication Critical patent/MX339720B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J10/00—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor
    • B01J10/007—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor in the presence of catalytically active bodies, e.g. porous plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J4/00—Feed or outlet devices; Feed or outlet control devices
    • B01J4/001—Feed or outlet devices as such, e.g. feeding tubes
    • B01J4/002—Nozzle-type elements
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
    • C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00004—Scale aspects
    • B01J2219/00006—Large-scale industrial plants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00054—Controlling or regulating the heat exchange system
    • B01J2219/00056—Controlling or regulating the heat exchange system involving measured parameters
    • B01J2219/00058—Temperature measurement
    • B01J2219/00063—Temperature measurement of the reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00054—Controlling or regulating the heat exchange system
    • B01J2219/00056—Controlling or regulating the heat exchange system involving measured parameters
    • B01J2219/00065—Pressure measurement
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00162—Controlling or regulating processes controlling the pressure

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

El proceso de oxidación puede incluir: introducir pequeñas gotas de mezcla líquida de reacción que tiene un reactivo oxidable, un catalizador y un solvente en una zona de reacción que contiene oxígeno y gas diluyente; y oxidar el reactivo con el oxígeno a una temperatura de reacción adecuada y una presión de reacción adecuada para producir un producto oxidado. La mezcla líquida de reacción puede tener una materia prima aromática que tenga una sustituyente oxidable como el reactivo oxidable. El producto oxidado puede incluir un componente aromático que tenga al menos un ácido carboxílico. Por ejemplo, la materia prima aromática puede incluir un anillo de benceno que tenga al menos un sustituyente de alquilo oxidable, un hetero-anillo de furano que tenga al menos un sustituyente de alquilo oxidable, un poli-anillo de naftaleno que tenga al menos un sustituyente alquilo oxidable, derivados de los mismos y mezclas de los mismos.
MX2011009929A 2009-03-23 2010-03-23 Proceso de aspersion para oxidacion selectiva. MX339720B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US16240609P 2009-03-23 2009-03-23
PCT/US2010/028343 WO2010111288A2 (en) 2009-03-23 2010-03-23 Spray process for selective oxidation

Publications (2)

Publication Number Publication Date
MX2011009929A MX2011009929A (es) 2012-01-20
MX339720B true MX339720B (es) 2016-06-07

Family

ID=42781823

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2011009929A MX339720B (es) 2009-03-23 2010-03-23 Proceso de aspersion para oxidacion selectiva.

Country Status (11)

Country Link
US (1) US9238608B2 (es)
EP (1) EP2411357B1 (es)
JP (1) JP6141011B2 (es)
KR (1) KR101820969B1 (es)
CN (1) CN102405207A (es)
AU (1) AU2010230069B2 (es)
BR (1) BRPI1006228B1 (es)
CA (1) CA2756060C (es)
MX (1) MX339720B (es)
MY (1) MY165153A (es)
WO (1) WO2010111288A2 (es)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011106747A1 (en) * 2010-02-26 2011-09-01 Perkin Elmer Health Sciences, Inc. Jet assembly for use in detectors and other devices
BR112014004592A2 (pt) * 2011-08-31 2017-03-28 Univ Kansas processo para efetuar uma oxidação em um suprimento
EP2750789B1 (en) * 2011-08-31 2018-07-11 Archer Daniels Midland Co. Spray oxidation process for producing 2,5-furandicarboxylic acid from hydroxymethylfurfural
CN102731448B (zh) * 2012-06-27 2014-08-13 北京大学 一种2，5-呋喃二甲醛的制备方法
HUP1400180A2 (hu) 2014-03-31 2015-10-28 Cominnex Zrt Lüktetõ hangfrekvenciás mezofluidikai reaktor
CN105565276B (zh) * 2014-11-03 2017-10-27 中国石油化工股份有限公司 一种双氧水生产的高效氧化方法
DE102015206843A1 (de) * 2015-04-16 2016-10-20 Hte Gmbh The High Throughput Experimentation Company Vorrichtung und Verfahren zum Versprühen von Flüssigkeiten und der Erzeugung von Feinstnebel
EP3325461B1 (en) 2015-07-24 2020-03-11 DuPont Industrial Biosciences USA, LLC Processes for preparing 2,5-furandicarboxylic acid and esters thereof
US20180111109A1 (en) 2016-10-24 2018-04-26 Michael W. Rogers Method, apparatus, and computer-readable media for vortex arc reactor
CN112047822A (zh) * 2020-07-27 2020-12-08 南京延长反应技术研究院有限公司 一种氧化卤代甲苯制备卤代苯甲醛的反应系统及方法
CN112142577B (zh) * 2020-09-23 2022-04-29 浙江工业大学 一种无金属催化氧化系统、氧气氧化方法以及应用于苯甲酸衍生物的生产方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5328902B2 (es) * 1973-09-14 1978-08-17
JPS61236746A (ja) * 1985-04-09 1986-10-22 パウル・ボンゼルス 液状有機物質の酸化法
US5270019A (en) * 1988-10-07 1993-12-14 Olin Corporation Hypochlorous acid reactor
US5221800A (en) * 1989-09-05 1993-06-22 Amoco Corporation One step air oxidation of cyclohexane to produce adipic acid
US5087741A (en) 1990-11-29 1992-02-11 Eastman Kodak Company Continuous production of aromatic carboxylic acids
TW226359B (es) * 1991-08-22 1994-07-11 Hoechst Ag
US5502245A (en) * 1995-06-07 1996-03-26 Twenty-First Century Research Corporation Methods of making intermediate oxidation products by controlling transient conversion in an atomized liquid
US5883292A (en) 1996-01-17 1999-03-16 Twenty-First Century Research Corporation Reaction control by regulating internal condensation inside a reactor
BR9609096A (pt) * 1995-06-07 1999-08-10 Twenty First Century Res Corp Métodos e aparelhos para a obtenção de produtos de oxidação intermediários mediante o controle de conversões e temperaturas em um líquido atomizado
US7198201B2 (en) 2002-09-09 2007-04-03 Bete Fog Nozzle, Inc. Swirl nozzle and method of making same

Also Published As

Publication number Publication date
KR20120001777A (ko) 2012-01-04
CA2756060A1 (en) 2010-09-30
EP2411357A2 (en) 2012-02-01
JP6141011B2 (ja) 2017-06-07
WO2010111288A3 (en) 2011-01-13
KR101820969B1 (ko) 2018-01-22
EP2411357A4 (en) 2014-04-02
CN102405207A (zh) 2012-04-04
US9238608B2 (en) 2016-01-19
WO2010111288A2 (en) 2010-09-30
CA2756060C (en) 2017-12-12
MY165153A (en) 2018-02-28
EP2411357B1 (en) 2018-04-25
US20120022287A1 (en) 2012-01-26
BRPI1006228B1 (pt) 2021-01-26
MX2011009929A (es) 2012-01-20
AU2010230069A1 (en) 2011-10-13
BRPI1006228A2 (pt) 2020-04-28
JP2012521985A (ja) 2012-09-20
AU2010230069B2 (en) 2015-02-12

Similar Documents

Publication Publication Date Title
MY165153A (en) Spray process for selective oxidation
Ni et al. Deep eutectic solvent (DES) as both solvent and catalyst for oxidation of furfural to maleic acid and fumaric acid
Guo et al. Effective catalysis of simple metalloporphyrins for cyclohexane oxidation with air in the absence of additives and solvents
WO2007133976A3 (en) Process for the production of aromatic carboxylic acids in water
Marsh et al. Chemoselective sulfide oxidation mediated by bridged flavinium organocatalysts
WO2013033081A3 (en) Process for producing both biobased succinic acid and 2,5-furandicarboxylic acid
Choudhary et al. Supported copper oxide as a highly active/selective catalyst for the epoxidation of styrene by TBHP to styrene oxide
Lan et al. Remarkable differences between benzaldehyde and isobutyraldehyde as coreductant in the performance toward the iron (III) porphyrins-catalyzed aerobic Baeyer–Villiger oxidation of cyclohexanone, kinetic and mechanistic features
CN102115353B (zh) 一种芳烃选择性氧化的方法
Bunge et al. Enantioselective epoxidation of 2-substituted 1, 4-naphthoquinones using gem-dihydroperoxides
Jinwei et al. Aerobic oxidation of ethylbenzene Co-catalyzed by N-hydroxyphthalimide and oxobis (8-quinolinolato) vanadium (IV) complexes
Bhaumik et al. Oxidation of alcohols by TBHP in the presence of sub-stoichiometric amounts of MnO 2
Guo et al. First industrial-scale biomimetic oxidation of hydrocarbon with air over metalloporphyrins as cytochrome P-450 monooxygenase model and its mechanistic studies
CN104557640A (zh) 一种分子氧催化氧化制备2-硝基-4-甲砜基苯甲酸的方法
WO2009128608A3 (en) Oxidation reactor for manufacturing of crude terephthalic acid
WO2011055343A3 (pt) Reactor catalítico de membrana com bombagem electroquímica de hidrogénio ou de oxigénio e suas aplicações
CN104151133B (zh) 一种甲苯选择性氧化制备苯甲醛的方法
Shirini et al. 1, 3-Dibromo-5, 5-dimethylhydantoin (DBH)/kaolin: an efficient reagent system for the synthesis of 14-aryl-14H-dibenzo [a, j] xanthenes under solvent-free conditions
ITMI20080461A1 (it) Processo per la produzione di idroperossidi di alchilbenzeni in condizioni blande ed in presenza di nuovi sistemi catalitici
Jiang et al. Aerobic liquid-phase oxidation of p-xylene over metalloporphyrins
CN101830869A (zh) 利用空气氧化制备比卡鲁胺的环氧化物中间体新工艺
WO2007042114A1 (en) Process for the oxidation of organic substrates by means of singlet oxygen at high reaction temperatures
TH121469B (th) "กระบวนการสเปรย์สำหรับออกซิเดชั่นแบบเลือกเฉพาะ"
CN104292090A (zh) 一种催化氧化环己烷的方法
Xing et al. Silica/A153–SO3H: An efficient catalyst for the Baeyer–Villiger oxidation of cyclic ketones with hydrogen peroxide

Legal Events

Date Code Title Description
FG Grant or registration