WO2011055343A3 - Reactor catalítico de membrana com bombagem electroquímica de hidrogénio ou de oxigénio e suas aplicações - Google Patents

Reactor catalítico de membrana com bombagem electroquímica de hidrogénio ou de oxigénio e suas aplicações Download PDF

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Publication number
WO2011055343A3
WO2011055343A3 PCT/IB2010/055045 IB2010055045W WO2011055343A3 WO 2011055343 A3 WO2011055343 A3 WO 2011055343A3 IB 2010055045 W IB2010055045 W IB 2010055045W WO 2011055343 A3 WO2011055343 A3 WO 2011055343A3
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WO
WIPO (PCT)
Prior art keywords
hydrogen
reactor
electrochemical pumping
catalytic membrane
applications
Prior art date
Application number
PCT/IB2010/055045
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English (en)
French (fr)
Other versions
WO2011055343A2 (pt
Inventor
Adélio Miguel MAGALHÃES MENDES
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Cuf - Químicos Industriais S.A.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to JP2012537478A priority Critical patent/JP5852575B2/ja
Priority to CA2779953A priority patent/CA2779953A1/en
Priority to EA201290284A priority patent/EA024313B1/ru
Priority to US13/508,542 priority patent/US9498765B2/en
Priority to MX2012005263A priority patent/MX346341B/es
Priority to AU2010316633A priority patent/AU2010316633B2/en
Priority to AP2012006290A priority patent/AP3617A/xx
Priority to CN201080057841.6A priority patent/CN102762292B/zh
Application filed by Cuf - Químicos Industriais S.A. filed Critical Cuf - Químicos Industriais S.A.
Priority to EP10803630A priority patent/EP2497570A2/en
Priority to BR112012010764-0A priority patent/BR112012010764A2/pt
Publication of WO2011055343A2 publication Critical patent/WO2011055343A2/pt
Publication of WO2011055343A3 publication Critical patent/WO2011055343A3/pt
Priority to MA34839A priority patent/MA33728B1/fr
Priority to ZA2012/04096A priority patent/ZA201204096B/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2475—Membrane reactors
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/02—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of hydrogen atoms by amino groups
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/92—Metals of platinum group
    • H01M4/921—Alloys or mixtures with metallic elements
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/94—Non-porous diffusion electrodes, e.g. palladium membranes, ion exchange membranes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • H01M8/0681—Reactant purification by the use of electrochemical cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/08—Fuel cells with aqueous electrolytes
    • H01M8/086—Phosphoric acid fuel cells [PAFC]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M2008/1293—Fuel cells with solid oxide electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2250/00—Fuel cells for particular applications; Specific features of fuel cell system
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/002—Shape, form of a fuel cell
    • H01M8/004—Cylindrical, tubular or wound
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/103—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having nitrogen, e.g. sulfonated polybenzimidazoles [S-PBI], polybenzimidazoles with phosphoric acid, sulfonated polyamides [S-PA] or sulfonated polyphosphazenes [S-PPh]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

A presente invenção diz respeito a um novo tipo de reactor químico, descrito como reactor catalítico de membrana com bombagem electroquímica de hidrogénio ou de oxigénio. Este novo tipo de reactor é especialmente apropriado para aumentar a selectividade e conversão em reacções de desidrogenação, hidrogenação, desoxidação e oxidação nomeadamente na reacção de aminação directa de hidrocarbonetos. Este reactor poderá ser utilizado para a produção de diversos compostos químicos, como por exemplo, para aminação directa de hidrocarbonetos, em particular para síntese de anilina a partir de benzeno. Nesta aplicação, onde se efectuou a remoção do hidrogénio com bombagem electroquímica de hidrogénio ou a bombagem de oxigénio para oxidação do hidrogénio formado, resulta numa conversão do benzeno em anilina, superior a 40 %.
PCT/IB2010/055045 2009-11-06 2010-11-05 Reactor catalítico de membrana com bombagem electroquímica de hidrogénio ou de oxigénio e suas aplicações WO2011055343A2 (pt)

Priority Applications (12)

Application Number Priority Date Filing Date Title
AP2012006290A AP3617A (en) 2009-11-06 2010-11-05 A hydrogen or oxygen electrochemical pumping catalytic membrane reactor and its applications
EA201290284A EA024313B1 (ru) 2009-11-06 2010-11-05 Каталитический мембранный реактор с электрохимической перекачкой водорода или кислорода и его использование
US13/508,542 US9498765B2 (en) 2009-11-06 2010-11-05 Hydrogen or oxygen electrochemical pumping catalytic membrane reactor and its applications
MX2012005263A MX346341B (es) 2009-11-06 2010-11-05 Reactor catalítico de membrana con bombeo electroquímico de hidrógeno u oxígeno y sus aplicaciones.
AU2010316633A AU2010316633B2 (en) 2009-11-06 2010-11-05 A hydrogen or oxygen electrochemical pumping catalytic membrane reactor and its applications
JP2012537478A JP5852575B2 (ja) 2009-11-06 2010-11-05 水素又は酸素の電気化学的ポンピング触媒膜リアクタ及びその利用
CN201080057841.6A CN102762292B (zh) 2009-11-06 2010-11-05 氢或氧电化学抽吸催化膜反应器及其用途
CA2779953A CA2779953A1 (en) 2009-11-06 2010-11-05 A hydrogen or oxygen electrochemical pumping catalytic membrane reactor and its applications
EP10803630A EP2497570A2 (en) 2009-11-06 2010-11-05 A hydrogen or oxygen electrochemical pumping catalytic membrane reactor and its applications
BR112012010764-0A BR112012010764A2 (pt) 2009-11-06 2010-11-05 reator catalítico de membrana com bombagem eletroquímica de hidrogênio ou de oxigênio e suas aplicações
MA34839A MA33728B1 (fr) 2009-11-06 2012-05-07 Réacteur catalytique à membrane avec pompage éléctrochimique d'hydrogène ou d'oxygène et ses applications
ZA2012/04096A ZA201204096B (en) 2009-11-06 2012-06-05 A hydrogen or oxygen electrochemical pumping catalytic membrane reactor and its applications

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
PT104812A PT104812A (pt) 2009-11-06 2009-11-06 Reactor catal?tico de membrana com bombagem electroqu?mica de hidrog?nio ou de oxig?nio e suas aplica??es
PT104812 2009-11-06

Publications (2)

Publication Number Publication Date
WO2011055343A2 WO2011055343A2 (pt) 2011-05-12
WO2011055343A3 true WO2011055343A3 (pt) 2011-06-30

Family

ID=43759121

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2010/055045 WO2011055343A2 (pt) 2009-11-06 2010-11-05 Reactor catalítico de membrana com bombagem electroquímica de hidrogénio ou de oxigénio e suas aplicações

Country Status (15)

Country Link
US (1) US9498765B2 (pt)
EP (1) EP2497570A2 (pt)
JP (1) JP5852575B2 (pt)
KR (1) KR20120105461A (pt)
CN (1) CN102762292B (pt)
AP (1) AP3617A (pt)
AU (1) AU2010316633B2 (pt)
BR (1) BR112012010764A2 (pt)
CA (1) CA2779953A1 (pt)
EA (1) EA024313B1 (pt)
MA (1) MA33728B1 (pt)
MX (1) MX346341B (pt)
PT (1) PT104812A (pt)
WO (1) WO2011055343A2 (pt)
ZA (1) ZA201204096B (pt)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2626938A4 (en) * 2010-10-05 2016-11-16 Univ Yonsei Iacf COMPLEX ELECTROLYTIC MEMBRANE FOR FUEL CELL, PROCESS FOR PRODUCING THE SAME, AND FUEL CELL COMPRISING SAME
PT106860A (pt) * 2013-03-28 2014-09-29 Cuf Químicos Ind S A Conjunto elétrodos/eletrólito, reator e método para a aminação direta de hidrocarbonetos
CN105552411B (zh) * 2015-12-09 2017-09-22 佛山索弗克氢能源有限公司 氨气在sofc电池中的应用及其应用装置
WO2018031893A1 (en) * 2016-08-11 2018-02-15 Massachusetts Institute Of Technology Electrochemical oxidation of aliphatic and aromatic compounds

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GB2203446A (en) * 1987-03-13 1988-10-19 Standard Oil Co Ohio Electrocatalytic oxidative dehydrogenation of saturated hydrocarbons to unsaturated hydrocarbons
DE4235125A1 (de) * 1992-10-17 1994-04-21 Zsw Verfahren zur Herstellung von Synthesegas und Vorrichtung zum Durchführen des Verfahrens
US20070082255A1 (en) * 2005-10-06 2007-04-12 Gongquan Sun Fuel cells and fuel cell catalysts incorporating a nanoring support
US20090075149A1 (en) * 1999-01-22 2009-03-19 Haile Sossina M Solid acid electrolytes for electrochemical devices
US20090203941A1 (en) * 2005-08-30 2009-08-13 Basf Se Direct hydrocarbon amination

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Publication number Priority date Publication date Assignee Title
GB2203446A (en) * 1987-03-13 1988-10-19 Standard Oil Co Ohio Electrocatalytic oxidative dehydrogenation of saturated hydrocarbons to unsaturated hydrocarbons
DE4235125A1 (de) * 1992-10-17 1994-04-21 Zsw Verfahren zur Herstellung von Synthesegas und Vorrichtung zum Durchführen des Verfahrens
US20090075149A1 (en) * 1999-01-22 2009-03-19 Haile Sossina M Solid acid electrolytes for electrochemical devices
US20090203941A1 (en) * 2005-08-30 2009-08-13 Basf Se Direct hydrocarbon amination
US20070082255A1 (en) * 2005-10-06 2007-04-12 Gongquan Sun Fuel cells and fuel cell catalysts incorporating a nanoring support

Also Published As

Publication number Publication date
CN102762292A (zh) 2012-10-31
EA024313B1 (ru) 2016-09-30
AP3617A (en) 2016-02-29
US20120273366A1 (en) 2012-11-01
CN102762292B (zh) 2015-09-30
CA2779953A1 (en) 2011-05-12
AP2012006290A0 (en) 2012-06-30
ZA201204096B (en) 2013-08-28
EA201290284A1 (ru) 2012-10-30
PT104812A (pt) 2011-05-06
MX346341B (es) 2017-03-14
MX2012005263A (es) 2012-09-07
AU2010316633B2 (en) 2016-04-14
KR20120105461A (ko) 2012-09-25
WO2011055343A2 (pt) 2011-05-12
JP2013514873A (ja) 2013-05-02
US9498765B2 (en) 2016-11-22
BR112012010764A2 (pt) 2018-03-06
EP2497570A2 (en) 2012-09-12
AU2010316633A1 (en) 2012-06-14
JP5852575B2 (ja) 2016-02-03
MA33728B1 (fr) 2012-11-01

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