MX341767B - Fluoracion catalitica en fase gas. - Google Patents
Fluoracion catalitica en fase gas.Info
- Publication number
- MX341767B MX341767B MX2013008409A MX2013008409A MX341767B MX 341767 B MX341767 B MX 341767B MX 2013008409 A MX2013008409 A MX 2013008409A MX 2013008409 A MX2013008409 A MX 2013008409A MX 341767 B MX341767 B MX 341767B
- Authority
- MX
- Mexico
- Prior art keywords
- gas phase
- catalytic gas
- phase fluorination
- fluorination
- stages
- Prior art date
Links
- 238000003682 fluorination reaction Methods 0.000 title abstract 4
- 230000003197 catalytic effect Effects 0.000 title 1
- 239000003054 catalyst Substances 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 239000007789 gas Substances 0.000 abstract 2
- 230000008929 regeneration Effects 0.000 abstract 2
- 238000011069 regeneration method Methods 0.000 abstract 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 abstract 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
- C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
- C07C17/206—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being HX
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/26—Chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/86—Chromium
- B01J23/866—Nickel and chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/92—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/94—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/132—Halogens; Compounds thereof with chromium, molybdenum, tungsten or polonium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/12—Oxidising
- B01J37/14—Oxidising with gases containing free oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/22—Halogenating
- B01J37/26—Fluorinating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
- B01J38/12—Treating with free oxygen-containing gas
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C21/00—Acyclic unsaturated compounds containing halogen atoms
- C07C21/02—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
- C07C21/18—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds containing fluorine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/125—Halogens; Compounds thereof with scandium, yttrium, aluminium, gallium, indium or thallium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
La invención se refiere a un proceso de fluoración, que comprende alternativamente etapas de reacción y etapas de regeneración, donde las etapas de reacción comprenden hacer reaccionar un compuesto dorado con fluoruro de hidrogeno en fase gas en presencia de un catalizador de fluoración para producir un compuesto fluorado, y las etapas de regeneración comprenden poner en contacto el catalizador de fluoración con un flujo de gas que contiene agente oxidante.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/IB2011/000316 WO2012098422A1 (en) | 2011-01-21 | 2011-01-21 | Catalytic gas phase fluorination |
Publications (2)
Publication Number | Publication Date |
---|---|
MX2013008409A MX2013008409A (es) | 2013-10-17 |
MX341767B true MX341767B (es) | 2016-09-01 |
Family
ID=44201982
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2013008409A MX341767B (es) | 2011-01-21 | 2011-01-21 | Fluoracion catalitica en fase gas. |
Country Status (9)
Country | Link |
---|---|
US (3) | US9302961B2 (es) |
EP (2) | EP3257832B2 (es) |
JP (1) | JP6165061B2 (es) |
CN (1) | CN103313960B (es) |
ES (2) | ES2740848T3 (es) |
MX (1) | MX341767B (es) |
PL (1) | PL2665693T3 (es) |
RU (2) | RU2571415C2 (es) |
WO (1) | WO2012098422A1 (es) |
Families Citing this family (23)
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ES2625204T3 (es) * | 2012-01-25 | 2017-07-18 | Daikin Industries, Ltd. | Procedimiento para producir una olefina que contiene flúor |
CN103880590B (zh) * | 2012-12-19 | 2016-10-05 | 中化蓝天集团有限公司 | 一种制备1,3,3,3-四氟丙烯的工艺 |
CN104918700B (zh) | 2013-01-29 | 2021-05-25 | 阿科玛股份有限公司 | 氟化催化剂的活化和再生 |
FR3023286B1 (fr) * | 2014-07-02 | 2018-02-16 | Arkema France | Procede de fabrication de tetrafluoropropene |
FR3027304B1 (fr) | 2014-10-16 | 2018-02-23 | Arkema France | Compositions a base de 1,1,1,3,3-pentachloropropane |
FR3027303B1 (fr) | 2014-10-16 | 2016-10-07 | Arkema France | Compositions a base de 1,1,1,2,3-pentachloropropane |
US10950140B2 (en) | 2017-06-22 | 2021-03-16 | Visyn Inc. | Video practice systems and methods |
JP6176262B2 (ja) * | 2015-01-13 | 2017-08-09 | ダイキン工業株式会社 | 含フッ素オレフィンの製造方法 |
CN107635955A (zh) | 2015-05-21 | 2018-01-26 | 科慕埃弗西有限公司 | 通过SbF5进行的1233xf至244bb的氢氟化 |
GB2540421C (en) | 2015-07-17 | 2018-11-14 | Mexichem Fluor Sa De Cv | Process for preparing 245cb from 243db |
GB2540427B (en) | 2015-07-17 | 2017-07-19 | Mexichem Fluor Sa De Cv | Process for the preparation of 2,3,3,3-tetrafluoropropene (1234yf) |
CN104987278B (zh) * | 2015-07-20 | 2016-09-28 | 山东联创互联网传媒股份有限公司 | 2,3,3,3-四氟丙烯的合成方法 |
FR3045029A1 (fr) | 2015-12-14 | 2017-06-16 | Arkema France | Fluoration catalytique en phase gazeuse avec des catalyseurs a base de chrome |
EP3412645B1 (en) * | 2016-02-03 | 2021-03-24 | Daikin Industries, Ltd. | Method for producing tetrafluoropropene |
FR3049599B1 (fr) * | 2016-04-04 | 2018-03-16 | Arkema France | Procede de preparation de l'hexafluorobutadiene. |
JP2017193511A (ja) * | 2016-04-21 | 2017-10-26 | ダイキン工業株式会社 | ハイドロクロロフルオロカーボン及び/又はハイドロフルオロカーボンの製造方法 |
FR3051469B1 (fr) | 2016-05-19 | 2018-05-11 | Arkema France | Procede de fabrication de tetrafluoropropene. |
FR3051468B1 (fr) | 2016-05-19 | 2019-07-26 | Arkema France | Procede de fabrication de tetrafluoropropene. |
FR3066926B1 (fr) * | 2017-06-06 | 2020-05-22 | Arkema France | Procede de modification de la distribution en fluor dans un compose hydrocarbure. |
FR3078699B1 (fr) | 2018-03-07 | 2020-02-21 | Arkema France | Procede de production du 2,3,3,3-tetrafluoropropene |
FR3078700B1 (fr) | 2018-03-07 | 2020-07-10 | Arkema France | Procede de production du 2,3,3,3-tetrafluoropropene |
FR3078698B1 (fr) | 2018-03-07 | 2020-02-21 | Arkema France | Procede de production du 2-chloro-3,3,3-trifluoropropene |
CN115803308A (zh) * | 2020-07-15 | 2023-03-14 | Agc株式会社 | 1-氯-2,3,3-三氟丙烯的制造方法 |
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GB805503A (en) * | 1956-03-15 | 1958-12-10 | Dow Chemical Co | Improved fluorination catalyst and process |
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DE2702360A1 (de) * | 1977-01-21 | 1978-08-03 | Hoechst Ag | Verfahren zur reaktivierung von fluorierungskatalysatoren |
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IT1252658B (it) * | 1991-12-23 | 1995-06-20 | Ausimont Spa | Procedimento per la depurazione dell'1,1,1-trifluoro-2-fluoroetano |
JP2996598B2 (ja) * | 1993-09-07 | 2000-01-11 | 昭和電工株式会社 | クロム系フッ素化触媒、その製法及びフッ素化方法 |
FR2713633B1 (fr) | 1993-12-09 | 1996-01-19 | Atochem Elf Sa | Fluoration en phase gazeuse au moyen de catalyseurs cristallisés. |
DE4419534C1 (de) * | 1994-06-03 | 1995-10-19 | Hoechst Ag | Verfahren zur Regenerierung eines chrom- und magnesiumhaltigen Fluorierungskatalysators |
JPH0977701A (ja) * | 1995-09-13 | 1997-03-25 | Asahi Chem Ind Co Ltd | ジクロロヘキサフルオロブテンの製造方法 |
IT1282960B1 (it) * | 1996-05-06 | 1998-04-02 | Ausimont Spa | Processo per la rigenerazione di un catalizzatore a base di composti cromo trivalente |
FR2757085B1 (fr) * | 1996-12-13 | 1999-01-22 | Atochem Elf Sa | Catalyseurs massiques a base de chrome et de nickel pour la fluoration en phase gazeuse d'hydrocarbures halogenes |
DE69909860T2 (de) | 1998-02-26 | 2004-05-27 | Central Glass Co., Ltd., Ube | Verfahren zur Herstellung von fluorierten Propanen |
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DE10163170A1 (de) * | 2001-12-21 | 2003-07-03 | Solvay Fluor & Derivate | Katalysator-Regenerierung mit elementarem Halogen |
DE60330789D1 (de) | 2002-08-22 | 2010-02-11 | Du Pont | Nickelsubstituierte und gemischt nickel- und cobaltsubstituierte chromoxidzusammensetzungen, deren herstellung und deren verwendung als katalysatoren und katalysatorvorläufer |
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US7722781B2 (en) * | 2006-06-27 | 2010-05-25 | E.I. Du Pont De Nemours And Company | Tetrafluoropropene production processes |
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CN103483140B (zh) | 2006-10-31 | 2015-09-09 | 纳幕尔杜邦公司 | 氟丙烷、卤代丙烯以及2-氯-3,3,3-三氟-1-丙烯与hf的共沸组合物和1,1,1,2,2-五氟丙烷与hf的共沸组合物的制备方法 |
JP5337799B2 (ja) * | 2007-06-27 | 2013-11-06 | アーケマ・インコーポレイテッド | ヒドロフルオロオレフィンの製造方法 |
US7795480B2 (en) * | 2007-07-25 | 2010-09-14 | Honeywell International Inc. | Method for producing 2-chloro-3,3,3,-trifluoropropene (HCFC-1233xf) |
FR2929271B1 (fr) | 2008-03-28 | 2010-04-16 | Arkema France | Procede pour la preparation du 1,2,3,3,3-pentafluoropropene- 1 |
GB0806419D0 (en) | 2008-04-09 | 2008-05-14 | Ineos Fluor Holdings Ltd | Process |
WO2009158321A1 (en) | 2008-06-26 | 2009-12-30 | Arkema Inc. | Catalytic gas phase fluorination of 1230xa to 1234yf |
KR101637584B1 (ko) * | 2009-04-21 | 2016-07-07 | 엘지전자 주식회사 | 무선 통신 시스템상에서 서비스의 품질(QoS)을 보장하는 방법 |
CN102405203B (zh) | 2009-04-23 | 2015-04-08 | 大金工业株式会社 | 制备2,3,3,3-四氟丙烯的方法 |
PL2516367T3 (pl) | 2009-12-23 | 2016-08-31 | Arkema France | Katalityczne fluorowanie w fazie gazowej 243db do 1234yf |
CN103180275B (zh) | 2010-10-22 | 2016-02-10 | 阿克马法国公司 | 2,3,3,3-四氟丙烯的制备方法 |
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2011
- 2011-01-21 ES ES17179561T patent/ES2740848T3/es active Active
- 2011-01-21 MX MX2013008409A patent/MX341767B/es active IP Right Grant
- 2011-01-21 EP EP17179561.0A patent/EP3257832B2/en active Active
- 2011-01-21 RU RU2013138746/04A patent/RU2571415C2/ru not_active IP Right Cessation
- 2011-01-21 CN CN201180065464.5A patent/CN103313960B/zh active Active
- 2011-01-21 EP EP11712666.4A patent/EP2665693B1/en active Active
- 2011-01-21 WO PCT/IB2011/000316 patent/WO2012098422A1/en active Application Filing
- 2011-01-21 US US13/980,672 patent/US9302961B2/en active Active
- 2011-01-21 PL PL11712666T patent/PL2665693T3/pl unknown
- 2011-01-21 JP JP2013549900A patent/JP6165061B2/ja active Active
- 2011-01-21 ES ES11712666.4T patent/ES2637249T3/es active Active
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2015
- 2015-11-03 RU RU2015147298A patent/RU2654694C2/ru not_active IP Right Cessation
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2016
- 2016-02-29 US US15/055,738 patent/US9758449B2/en active Active
-
2017
- 2017-07-10 US US15/644,973 patent/US9969663B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
ES2740848T5 (es) | 2022-12-29 |
US9302961B2 (en) | 2016-04-05 |
RU2013138746A (ru) | 2015-02-27 |
WO2012098422A1 (en) | 2012-07-26 |
US9969663B2 (en) | 2018-05-15 |
MX2013008409A (es) | 2013-10-17 |
US20160176789A1 (en) | 2016-06-23 |
EP2665693A1 (en) | 2013-11-27 |
RU2015147298A (ru) | 2017-05-10 |
ES2740848T3 (es) | 2020-02-06 |
US20170313638A1 (en) | 2017-11-02 |
WO2012098422A8 (en) | 2013-07-25 |
US9758449B2 (en) | 2017-09-12 |
CN103313960B (zh) | 2016-06-08 |
RU2571415C2 (ru) | 2015-12-20 |
RU2654694C2 (ru) | 2018-05-22 |
JP2014511351A (ja) | 2014-05-15 |
US20140012051A1 (en) | 2014-01-09 |
EP3257832B1 (en) | 2019-07-10 |
EP2665693B1 (en) | 2017-07-19 |
EP3257832A1 (en) | 2017-12-20 |
CN103313960A (zh) | 2013-09-18 |
EP3257832B2 (en) | 2022-10-19 |
JP6165061B2 (ja) | 2017-07-19 |
PL2665693T3 (pl) | 2017-10-31 |
ES2637249T3 (es) | 2017-10-11 |
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