MX2014005243A - Proceso para producir 2,3,3,3-tetrafluoropropeno. - Google Patents
Proceso para producir 2,3,3,3-tetrafluoropropeno.Info
- Publication number
- MX2014005243A MX2014005243A MX2014005243A MX2014005243A MX2014005243A MX 2014005243 A MX2014005243 A MX 2014005243A MX 2014005243 A MX2014005243 A MX 2014005243A MX 2014005243 A MX2014005243 A MX 2014005243A MX 2014005243 A MX2014005243 A MX 2014005243A
- Authority
- MX
- Mexico
- Prior art keywords
- oligomerization
- polymerization
- reagents
- present
- tetrafluoropropene
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- FXRLMCRCYDHQFW-UHFFFAOYSA-N 2,3,3,3-tetrafluoropropene Chemical compound FC(=C)C(F)(F)F FXRLMCRCYDHQFW-UHFFFAOYSA-N 0.000 title 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract 3
- 238000006384 oligomerization reaction Methods 0.000 abstract 2
- 238000006116 polymerization reaction Methods 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 230000009849 deactivation Effects 0.000 abstract 1
- 238000003682 fluorination reaction Methods 0.000 abstract 1
- 230000008016 vaporization Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
- C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/26—Chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/32—Manganese, technetium or rhenium
- B01J23/34—Manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/745—Iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/75—Cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/08—Halides
- B01J27/10—Chlorides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/08—Halides
- B01J27/12—Fluorides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/138—Halogens; Compounds thereof with alkaline earth metals, magnesium, beryllium, zinc, cadmium or mercury
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/07—Preparation of halogenated hydrocarbons by addition of hydrogen halides
- C07C17/087—Preparation of halogenated hydrocarbons by addition of hydrogen halides to unsaturated halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
- C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
- C07C17/206—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being HX
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/38—Separation; Purification; Stabilisation; Use of additives
- C07C17/42—Use of additives, e.g. for stabilisation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
La presente invención se refiere, en parte, al descubrimiento de que, durante la fluoración de ciertos reactivos de partida de fluoroolefina, la oligomerización/polimerización de tales reactivos reduce el proceso de conversión y lleva a una desactivación incrementada del catalizador. La presente invención también ilustra que la vaporización de tales reactivos de partida en la presencia de una o más co-alimentaciones orgánicas, reduce tal oligomerización/polimerización y mejora la estabilidad catalítica.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161555732P | 2011-11-04 | 2011-11-04 | |
| PCT/US2012/063331 WO2013067356A1 (en) | 2011-11-04 | 2012-11-02 | Process for producing 2,3,3,3-tetrafluoropropene |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2014005243A true MX2014005243A (es) | 2015-03-05 |
| MX359832B MX359832B (es) | 2018-10-12 |
Family
ID=48192826
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2014005243A MX359832B (es) | 2011-11-04 | 2012-11-02 | Proceso para producir 2,3,3,3-tetrafluoropropeno. |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US10131597B2 (es) |
| EP (1) | EP2773606B1 (es) |
| JP (2) | JP6518869B2 (es) |
| KR (1) | KR102052141B1 (es) |
| CN (2) | CN110343030B (es) |
| AR (1) | AR088659A1 (es) |
| ES (1) | ES2752461T3 (es) |
| IN (1) | IN2014DN03381A (es) |
| MX (1) | MX359832B (es) |
| TW (1) | TW201332939A (es) |
| WO (1) | WO2013067356A1 (es) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9670117B2 (en) | 2007-01-03 | 2017-06-06 | Honeywell International Inc. | Process for producing 2,3,3,3-tetrafluoropropene |
| US20170253545A1 (en) | 2007-01-03 | 2017-09-07 | Honeywell International Inc. | Process for producing 2,3,3,3-tetrafluoropropene |
| CN104169245B (zh) * | 2011-11-04 | 2016-09-21 | 塞尔马·贝克特什维克 | 用于制造2,3,3,3-四氟丙烯的方法 |
| US8889930B2 (en) | 2013-01-22 | 2014-11-18 | Axiall Ohio, Inc. | Process for producing chlorinated hydrocarbons |
| US9289758B2 (en) | 2013-01-22 | 2016-03-22 | Axiall Ohio, Inc. | Processes for producing chlorinated hydrocarbons and methods for recovering polyvalent antimony catalysts therefrom |
| JP6098608B2 (ja) * | 2014-10-07 | 2017-03-22 | ダイキン工業株式会社 | フッ素基を含有するハロオレフィン化合物の製造方法及び組成物 |
| CN107635955A (zh) | 2015-05-21 | 2018-01-26 | 科慕埃弗西有限公司 | 通过SbF5进行的1233xf至244bb的氢氟化 |
| GB2540421C (en) | 2015-07-17 | 2018-11-14 | Mexichem Fluor Sa De Cv | Process for preparing 245cb from 243db |
| GB2540427B (en) | 2015-07-17 | 2017-07-19 | Mexichem Fluor Sa De Cv | Process for the preparation of 2,3,3,3-tetrafluoropropene (1234yf) |
| FR3047240B1 (fr) * | 2016-01-28 | 2019-09-27 | Arkema France | Procede de fabrication du 2-chloro-3,3,3-trifluoropropene |
| US9950974B2 (en) * | 2016-08-31 | 2018-04-24 | Honeywell International Inc. | Azeotropic or azeotrope-like compositions of 1,3,3-trichloro-3-fluoro-1-ene (HCFO-1231zd) and hydrogen fluoride (HF) |
| WO2018231764A1 (en) * | 2017-06-12 | 2018-12-20 | Honeywell International Inc. | Method to produce hfo-1234yf from tcp by suppressing the bubble/dew point |
| CN108610233B (zh) * | 2018-06-14 | 2021-07-16 | 衢州环新氟材料有限公司 | 一种3,3,3-三氟丙烯的制备方法 |
| CN112125777B (zh) * | 2020-08-27 | 2022-06-03 | 浙江衢化氟化学有限公司 | 一种联产氢氟烃的方法 |
| CN116041138B (zh) * | 2022-08-19 | 2025-03-04 | 江西中欣埃克盛新材料有限公司 | 一种R134a与二氯甲烷为原料联产R244bb和R1234yf的方法 |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2931840A (en) | 1958-11-25 | 1960-04-05 | Du Pont | Process for preparing 2, 3, 3, 3-tetrafluoropropene |
| US3823195A (en) * | 1971-12-27 | 1974-07-09 | Monsanto Co | Preparation of 1,1,2,3-tetrachloropropene from 1,2,3-trichloropropane |
| JPH01207250A (ja) | 1988-02-12 | 1989-08-21 | Daikin Ind Ltd | 含フツ素オレフインの製造方法 |
| US5162594A (en) | 1990-10-11 | 1992-11-10 | E. I. Du Pont De Nemours And Company | Process for production of polyfluoroolefins |
| US5155082A (en) | 1991-04-12 | 1992-10-13 | Allied-Signal Inc. | Catalyst for the manufacture of chlorofluorocarbons, hydrochlorofluorocarbons and hydrofluorocarbons |
| JP2001507674A (ja) * | 1996-11-01 | 2001-06-12 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | ヘキサフルオロエタンの製造 |
| US8058486B2 (en) | 2004-04-29 | 2011-11-15 | Honeywell International Inc. | Integrated process to produce 2,3,3,3-tetrafluoropropene |
| US8067649B2 (en) * | 2004-04-29 | 2011-11-29 | Honeywell International Inc. | Method for producing fluorinated organic compounds |
| US8084653B2 (en) | 2004-04-29 | 2011-12-27 | Honeywell International, Inc. | Method for producing fluorinated organic compounds |
| SI3336074T1 (sl) * | 2006-01-03 | 2025-09-30 | Honeywell International Inc. | Postopek za proizvodnjo fluoriranih organskih spojin |
| US8664455B2 (en) * | 2008-08-08 | 2014-03-04 | Honeywell International Inc. | Process to manufacture 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb) |
| US7795480B2 (en) * | 2007-07-25 | 2010-09-14 | Honeywell International Inc. | Method for producing 2-chloro-3,3,3,-trifluoropropene (HCFC-1233xf) |
| CN101597209A (zh) * | 2008-03-20 | 2009-12-09 | 霍尼韦尔国际公司 | 用于制备2,3,3,3-四氟丙烯的一体式方法 |
| US8168837B2 (en) * | 2008-05-15 | 2012-05-01 | Honeywell International Inc. | Process for separating hydrogen fluoride from organic feedstocks |
| CN102076643B (zh) * | 2008-06-26 | 2014-08-06 | 阿科玛股份有限公司 | 1230xa至1234yf的催化气相氟化 |
| US8624067B2 (en) * | 2009-04-23 | 2014-01-07 | Daikin Industries, Ltd. | Process for preparing 2-chloro-3,3,3-trifluoropropene |
| JP5459320B2 (ja) | 2009-05-13 | 2014-04-02 | ダイキン工業株式会社 | 塩素含有フルオロカーボン化合物の製造方法 |
| US8618340B2 (en) * | 2009-11-03 | 2013-12-31 | Honeywell International Inc. | Integrated process for fluoro-olefin production |
| CA3016991C (en) * | 2009-12-22 | 2020-10-27 | E. I. Du Pont De Nemours And Company | Compositions comprising 2,3,3,3-tetrafluoropropene, 1,1,2,3-tetrachloropropene, 2-chloro-3,3,3-trifluoropropene, or 2-chloro-1,1,1,2-tetrafluoropropane |
| US20110245548A1 (en) | 2010-03-31 | 2011-10-06 | Honeywell International Inc. | Catalyst life improvement in the vapor phase fluorination of chlorocarbons |
| CN102001911B (zh) * | 2010-09-20 | 2013-09-25 | 西安近代化学研究所 | 2,3,3,3-四氟丙烯的制备方法 |
| WO2012051327A2 (en) | 2010-10-12 | 2012-04-19 | Cornell University | Method of dual-adapter recombination for efficient concatenation of multiple dna fragments in shuffled or specified arrangements |
-
2012
- 2012-11-02 EP EP12846743.8A patent/EP2773606B1/en active Active
- 2012-11-02 WO PCT/US2012/063331 patent/WO2013067356A1/en not_active Ceased
- 2012-11-02 IN IN3381DEN2014 patent/IN2014DN03381A/en unknown
- 2012-11-02 CN CN201910193997.XA patent/CN110343030B/zh active Active
- 2012-11-02 CN CN201280065398.6A patent/CN104284874A/zh active Pending
- 2012-11-02 ES ES12846743T patent/ES2752461T3/es active Active
- 2012-11-02 MX MX2014005243A patent/MX359832B/es active IP Right Grant
- 2012-11-02 US US14/355,894 patent/US10131597B2/en active Active
- 2012-11-02 KR KR1020147011931A patent/KR102052141B1/ko active Active
- 2012-11-02 JP JP2014540138A patent/JP6518869B2/ja active Active
- 2012-11-05 TW TW101141081A patent/TW201332939A/zh unknown
- 2012-11-05 AR ARP120104153A patent/AR088659A1/es not_active Application Discontinuation
-
2017
- 2017-12-04 JP JP2017232509A patent/JP2018058882A/ja active Pending
-
2018
- 2018-11-20 US US16/196,746 patent/US20190084906A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| EP2773606A1 (en) | 2014-09-10 |
| CN104284874A (zh) | 2015-01-14 |
| EP2773606A4 (en) | 2015-06-17 |
| JP2014532721A (ja) | 2014-12-08 |
| KR20140097149A (ko) | 2014-08-06 |
| KR102052141B1 (ko) | 2019-12-04 |
| US20140256996A1 (en) | 2014-09-11 |
| IN2014DN03381A (es) | 2015-06-26 |
| ES2752461T3 (es) | 2020-04-06 |
| US10131597B2 (en) | 2018-11-20 |
| AR088659A1 (es) | 2014-06-25 |
| CN110343030B (zh) | 2023-03-17 |
| WO2013067356A1 (en) | 2013-05-10 |
| EP2773606B1 (en) | 2019-08-07 |
| US20190084906A1 (en) | 2019-03-21 |
| JP6518869B2 (ja) | 2019-05-29 |
| CN110343030A (zh) | 2019-10-18 |
| TW201332939A (zh) | 2013-08-16 |
| JP2018058882A (ja) | 2018-04-12 |
| MX359832B (es) | 2018-10-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| MX359832B (es) | Proceso para producir 2,3,3,3-tetrafluoropropeno. | |
| MX341276B (es) | Procedimiento para la fabricacion de 2,3,3,3-tetrafluoropropeno mediante fluoracion en fase gaseosa de pentacloropropano. | |
| MX347872B (es) | Proceso para la preparacion de 2,3,3,3-tetrafluoropropeno. | |
| MX349999B (es) | Proceso para la fabricacion de hidrofluoroolefinas. | |
| SA518400053B1 (ar) | عملية مُحسنة لإنتاج حمض أكريليك | |
| IN2014DN03382A (es) | ||
| MX2023009585A (es) | Isomerizacion catalitica de z-1,1,1,4,4,4-hexafluoro-2- buteno a e-1,1,1,4,4,4-hexafluoro-2-buteno. | |
| BR112012030016B8 (pt) | processo para preparar etileno a partir de metano e método para preparar um produto a jusante de etileno | |
| IN2014DN05988A (es) | ||
| MX2011007401A (es) | Isomerizacion de 1, 1, 3, 3-tetrafluoropropeno. | |
| PH12015500512A1 (en) | Propylene via metathesis with low or no ethylene | |
| BR112017009754A2 (pt) | processo para produção de hexanotriol a partir de 5-hidroximetfilfurfural | |
| EA201791431A1 (ru) | Способ перехода между несовместимыми катализаторами | |
| MX2009005433A (es) | Proceso para producir alquenos de oxigenados utilizando catalizadores de heteropoliacidos soportados. | |
| MX377940B (es) | Metodo para producir mentonas a partir de isopulegol en la fase gaseosa. | |
| MX2015003077A (es) | Metodo para preparar mentona a partir de isopulegol. | |
| EP2963065A4 (en) | METHOD FOR PRODUCING A SOLID CATALYST COMPONENT FOR OLEFIN POLYMERSION, A CATALYST FOR THE POLYMERIZATION OF OLEFINES, AND POLYMERIZED OLEFINE PRODUCTION METHOD | |
| EA201691268A1 (ru) | Каталитическая система для полимеризации олефинов | |
| MX363998B (es) | Formacion de catalizador de ziegler-natta usando componentes no mezclados. | |
| BR112018074904A2 (pt) | processo contínuo e de alta seletividade para converter, em etileno glicol, aldo-hexose em um alimento que contém carboidrato que produz aldo-hexose, e, composições produtoras aquosas | |
| MX389335B (es) | Procedimiento de produccion de e-1-cloro-3,3,3-trifluoropropeno a partir de 1,1,3,3-tetracloropropeno. | |
| MX350643B (es) | Procedimiento para la produccion de acetato de vinilo. | |
| MX389521B (es) | Proceso. | |
| AR088209A1 (es) | Proceso para producir 2,3,3,3-tetrafluoropropeno | |
| EA201270172A1 (ru) | Цинеол |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant or registration |