MX2016013269A - Proceso para la produccion de alquenoles y uso de los mismos para la produccion de 1,3-butadieno. - Google Patents

Proceso para la produccion de alquenoles y uso de los mismos para la produccion de 1,3-butadieno.

Info

Publication number
MX2016013269A
MX2016013269A MX2016013269A MX2016013269A MX2016013269A MX 2016013269 A MX2016013269 A MX 2016013269A MX 2016013269 A MX2016013269 A MX 2016013269A MX 2016013269 A MX2016013269 A MX 2016013269A MX 2016013269 A MX2016013269 A MX 2016013269A
Authority
MX
Mexico
Prior art keywords
production
alkenols
butadiene
same
butanediol
Prior art date
Application number
MX2016013269A
Other languages
English (en)
Other versions
MX390442B (es
Inventor
Raffaele Cesana
Ramello Stefano
Spano' Guido
Original Assignee
Versalis Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Versalis Spa filed Critical Versalis Spa
Publication of MX2016013269A publication Critical patent/MX2016013269A/es
Publication of MX390442B publication Critical patent/MX390442B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0036—Grinding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Proceso para la producción de alquenoles que comprende la deshidratación de al menos un diol en la presencia de al menos un catalizador basado en óxido de cerio, en donde el catalizador basado en óxido de cerio se obtiene mediante precipitación, en la presencia de al menos una base, de al menos un compuesto que tiene cerio. De manera preferente, el diol puede ser un butanodiol, de manera más preferente 1,3-butanodiol, de manera aún más preferente bio-10 1,3-butanodiol derivado de procesos biosintéticos. Estos alquenoles se pueden usar de manera ventajosa para la producción de 1,3-butadieno, en particular de bio-1,3- butadieno.
MX2016013269A 2014-05-16 2015-05-15 Proceso para la produccion de alquenoles y uso de los mismos para la produccion de 1,3-butadieno. MX390442B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITMI20140897 2014-05-16
PCT/IB2015/053592 WO2015173780A1 (en) 2014-05-16 2015-05-15 Process for the production of alkenols and use thereof for the production of 1,3-butadiene

Publications (2)

Publication Number Publication Date
MX2016013269A true MX2016013269A (es) 2017-02-22
MX390442B MX390442B (es) 2025-03-20

Family

ID=51220686

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2016013269A MX390442B (es) 2014-05-16 2015-05-15 Proceso para la produccion de alquenoles y uso de los mismos para la produccion de 1,3-butadieno.

Country Status (13)

Country Link
US (1) US9862664B2 (es)
EP (1) EP3142785B1 (es)
JP (1) JP6804300B2 (es)
CN (1) CN106414383B (es)
DK (1) DK3142785T3 (es)
ES (1) ES2924482T3 (es)
HU (1) HUE059279T2 (es)
MX (1) MX390442B (es)
PL (1) PL3142785T3 (es)
PT (1) PT3142785T (es)
RU (1) RU2695786C2 (es)
TW (1) TWI659946B (es)
WO (1) WO2015173780A1 (es)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112017013738B1 (pt) * 2015-02-23 2021-11-03 Versalis S.P.A. Processo para a produção de dienos
JP6456231B2 (ja) * 2015-04-27 2019-01-23 昭和電工株式会社 ジエン化合物の製造方法
JP6815594B2 (ja) * 2016-04-05 2021-01-20 国立大学法人千葉大学 ジエン化合物の製造方法
JP6684635B2 (ja) * 2016-04-06 2020-04-22 昭和電工株式会社 ジエン化合物の製造方法
JP6684641B2 (ja) * 2016-04-26 2020-04-22 昭和電工株式会社 共役ジエン化合物の製造方法及びアリル型不飽和アルコールの脱水触媒
JP6656074B2 (ja) * 2016-04-26 2020-03-04 昭和電工株式会社 アリル型不飽和アルコールの脱水による共役ジエン化合物の製造方法
WO2018040058A1 (en) * 2016-09-02 2018-03-08 Rhodia Operations Dehydration of diols
IT201600105178A1 (it) * 2016-10-19 2018-04-19 Versalis Spa Procedimento per la produzione di dieni
US10639621B2 (en) * 2018-03-05 2020-05-05 Qatar University Nanoporous cerium oxide with interconnected pores for catalysis and a cost-effective method of preparing thereof
ES2975943T3 (es) 2018-09-21 2024-07-18 Versalis Spa Proceso para purificar bio-1,3-butanodiol a partir de un caldo de fermentación
IT201900015069A1 (it) 2019-08-27 2021-02-27 Versalis Spa Catalizzatore comprendente coke e procedimento per la produzione di dieni.
CN110465298B (zh) * 2019-08-29 2022-01-28 湘潭大学 一种用于糖类发酵产物abe直接制备长碳链化合物的催化剂及其制备方法
IT201900025000A1 (it) 2019-12-20 2021-06-20 Versalis Spa Procedimento per la produzione di dieni.
CN113385212B (zh) * 2021-06-11 2022-12-27 上海巽田科技股份有限公司 用于制备烯醇的非金属掺杂的碳基催化剂及使用其制备烯醇的方法
CN115894171B (zh) * 2022-11-17 2024-04-16 凯瑞环保科技股份有限公司 一种醋酸仲丁酯加氢制备仲丁醇的方法

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1150671B (de) 1961-12-30 1963-06-27 Huels Chemische Werke Ag Verfahren zur Herstellung reiner Butenole
DE1908620A1 (de) 1969-02-21 1970-09-03 Basf Ag Verfahren zur Herstellung modifizierter Polyolefinwachse
FR2044085A5 (es) * 1969-05-08 1971-02-19 Raffinage Cie Francaise
SU396312A1 (ru) 1971-02-01 1973-08-29 Г. Д. Закумбаева, Закарина , Д. В. Сокольский Способ получения виниловых спиртов
US4400562A (en) 1981-07-02 1983-08-23 The United States Of America As Represented By The Secretary Of The Navy Alkenol synthesis
JPS63222135A (ja) 1987-03-11 1988-09-16 Nkk Corp 不飽和アルコ−ルの製造方法
US5406007A (en) 1994-07-15 1995-04-11 Eastman Chemical Company Process for the production of unsaturated alcohols
JPH08253435A (ja) * 1995-03-17 1996-10-01 Asahi Chem Ind Co Ltd 高純度１，３−シクロヘキサジエンの製造方法
FR2748740B1 (fr) 1996-05-15 1998-08-21 Rhone Poulenc Chimie Composition a base d'oxyde de cerium et d'oxyde de zirconium a haute surface specifique et a capacite elevee de stockage d'oxygene, procede de preparation et utilisation en catalyse
DE19646679A1 (de) 1996-11-12 1998-05-14 Basf Ag Katalysator und Verfahren zur Herstellung von 2-Buten-1-ol-Verbindungen
US7259280B1 (en) * 2006-03-22 2007-08-21 Lyondell Chemical Technology, L.P. Process for producing alkenyl alcohols
EP3318626B1 (en) 2009-04-30 2020-01-15 Genomatica, Inc. Organisms for the production of 1,3-butanediol
EP2495305A1 (en) * 2009-10-30 2012-09-05 Daicel Corporation Transgenic microorganism provided with the ability to produce 1,3-butanediol, and usage therefor
CN101759529B (zh) * 2010-01-19 2013-04-10 山西大学 一种由1,4-丁二醇合成3-丁烯-1-醇的方法
WO2012174439A2 (en) * 2011-06-17 2012-12-20 Invista Technologies S.A R.L. Methods of producing four carbon molecules
WO2012177619A2 (en) 2011-06-22 2012-12-27 Genomatica, Inc. Microorganisms for producing 1,3-butanediol and methods related thereto
JP6272757B2 (ja) 2011-08-19 2018-01-31 ジェノマティカ， インコーポレイテッド ２，４−ペンタジエノエート、ブタジエン、プロピレン、１，３−ブタンジオールおよび関連アルコールを生成するための微生物および方法
WO2013130481A1 (en) 2012-03-02 2013-09-06 Codexis, Inc. Recombinant host cells and processes for producing 1,3-butadiene through a crotonol intermediate
JP2014030376A (ja) * 2012-08-02 2014-02-20 Mitsubishi Chemicals Corp ブタジエンの製造方法
ITMI20132069A1 (it) 2013-12-11 2015-06-12 Versalis Spa Procedimento per la produzione di zuccheri da biomassa

Also Published As

Publication number Publication date
JP2017520511A (ja) 2017-07-27
ES2924482T3 (es) 2022-10-07
DK3142785T3 (da) 2022-08-01
BR112016026512A2 (pt) 2017-08-15
US9862664B2 (en) 2018-01-09
US20170057893A1 (en) 2017-03-02
JP6804300B2 (ja) 2020-12-23
CN106414383A (zh) 2017-02-15
PL3142785T3 (pl) 2022-08-22
TW201602068A (zh) 2016-01-16
WO2015173780A1 (en) 2015-11-19
RU2016140173A (ru) 2018-06-20
EP3142785B1 (en) 2022-06-29
MX390442B (es) 2025-03-20
RU2016140173A3 (es) 2018-09-21
EP3142785A1 (en) 2017-03-22
CN106414383B (zh) 2019-10-25
TWI659946B (zh) 2019-05-21
RU2695786C2 (ru) 2019-07-26
HUE059279T2 (hu) 2022-11-28
PT3142785T (pt) 2022-07-29

Similar Documents

Publication Publication Date Title
MX2016013269A (es) Proceso para la produccion de alquenoles y uso de los mismos para la produccion de 1,3-butadieno.
CL2019001365A1 (es) Polipéptido para la escisión hidrolítica de la zearalenona y/o derivados de la zearalenona, polinucleótido aislado de la misma y aditivo que contiene el polipéptido, uso y procedimiento de los mismos. (divisional solicitud 201600464)
BR112018007017A2 (pt) polipeptídeos
CL2018001790A1 (es) Procesos para preparar un inhibidor de jak1 y nuevas formas de este (divisional solicitud 201602748)
CO2018010877A2 (es) Ácido acrílico y métodos de producción del mismo
MX2020010841A (es) Composicion detergente.
MX392185B (es) Metodo de uso de una composicion que comprende un compuesto de amonio cuaternario, un polisacarido cationico y un polisacarido no ionico.
MX2016013557A (es) Produccion de 4-metil-tetrahidropiranos 2-sustituidos a partir de materiales de partida con contenido de 2-alquil-4,4-dimetil-1,3-di oxanos.
EA201690440A1 (ru) Способ эксплуатации установки, содержащей по меньшей мере один блок с вращающейся поверхностью
MX365157B (es) Peptidos y composiciones para el tratamiento de daños de las articulaciones.
MX2017016109A (es) Microorganismo recombinante para la produccion mejorada de productos quimicos finos.
CR20150495A (es) Procesos para la preparación de un agente inductor de la apoptosis
MX389370B (es) Microorganismo recombinante para la produccion mejorada de quimicos finos.
MY181068A (en) Recombinant microorganism for improved production of fine chemicals
MX377149B (es) Microorganismo recombinante para la produccion mejorada de productos quimicos finos.
TR201904150T4 (tr) Bir sıvı deterjan bileşimi.
MX384182B (es) Microorganismo recombinante para la produccion mejorada de quimicos finos.
MX376871B (es) Metodo para ciclizar biocataliticamente el geranillinalool y productos de ciclizacion obtenidos de este modo.
BR112016025024A2 (pt) ?processo para preparar compostos ceto, e, uso de farnesil acetona?
UA117779C2 (uk) Піразини як модулятори gpr6
CO2017000010A2 (es) Proceso para la preparacion de ácidos 3-hidroxipicolínicos
UY36217A (es) Compuestos piridona sustituídos, composiciones farmacéuticas y métodos de uso.
MX375977B (es) Proceso para preparar 3-metilciclopentadecano-1, 5-diol.
MX2016013586A (es) Tinturas reactivas fluorescentes, proceso para su produccion y su uso.
CL2017001383A1 (es) Proceso para la fabricación de anhídrido carboxílico