MX2011010379A - Proceso de hidroformilacion con un ligando de biosfosfito doblemente de extremo abierto. - Google Patents
Proceso de hidroformilacion con un ligando de biosfosfito doblemente de extremo abierto.Info
- Publication number
- MX2011010379A MX2011010379A MX2011010379A MX2011010379A MX2011010379A MX 2011010379 A MX2011010379 A MX 2011010379A MX 2011010379 A MX2011010379 A MX 2011010379A MX 2011010379 A MX2011010379 A MX 2011010379A MX 2011010379 A MX2011010379 A MX 2011010379A
- Authority
- MX
- Mexico
- Prior art keywords
- ligand
- organopoliphosphite
- hydroformylation
- transition metal
- organomonophosphine
- Prior art date
Links
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- 238000000034 method Methods 0.000 title claims abstract description 78
- 238000007037 hydroformylation reaction Methods 0.000 title claims abstract description 62
- 238000006243 chemical reaction Methods 0.000 claims abstract description 49
- 239000003054 catalyst Substances 0.000 claims abstract description 41
- 239000000203 mixture Substances 0.000 claims abstract description 27
- 229910052723 transition metal Inorganic materials 0.000 claims abstract description 27
- 150000003624 transition metals Chemical class 0.000 claims abstract description 27
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- 239000001257 hydrogen Substances 0.000 claims abstract description 25
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 23
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- 229910002091 carbon monoxide Inorganic materials 0.000 claims abstract description 21
- 150000001875 compounds Chemical class 0.000 claims abstract description 19
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- KJBRZWADVLEUIE-UHFFFAOYSA-N propyl oct-7-enoate Chemical compound CCCOC(=O)CCCCCC=C KJBRZWADVLEUIE-UHFFFAOYSA-N 0.000 description 1
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- 229910052708 sodium Inorganic materials 0.000 description 1
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- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 125000003107 substituted aryl group Chemical group 0.000 description 1
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- LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- BJIOGJUNALELMI-UHFFFAOYSA-N trans-isoeugenol Natural products COC1=CC(C=CC)=CC=C1O BJIOGJUNALELMI-UHFFFAOYSA-N 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- 125000002221 trityl group Chemical group [H]C1=C([H])C([H])=C([H])C([H])=C1C([*])(C1=C(C(=C(C(=C1[H])[H])[H])[H])[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
- C07C45/505—Asymmetric hydroformylation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
- C07C45/294—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups with hydrogen peroxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
- C07C45/298—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups with manganese derivatives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US16503909P | 2009-03-31 | 2009-03-31 | |
| PCT/US2009/067416 WO2010117391A1 (en) | 2009-03-31 | 2009-12-10 | Hydroformylation process with a doubly open-ended bisphosphite ligand |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2011010379A true MX2011010379A (es) | 2011-10-17 |
Family
ID=42537699
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2011010379A MX2011010379A (es) | 2009-03-31 | 2009-12-10 | Proceso de hidroformilacion con un ligando de biosfosfito doblemente de extremo abierto. |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US8513469B2 (cg-RX-API-DMAC10.html) |
| EP (1) | EP2414314B1 (cg-RX-API-DMAC10.html) |
| JP (1) | JP5603407B2 (cg-RX-API-DMAC10.html) |
| KR (1) | KR101706797B1 (cg-RX-API-DMAC10.html) |
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| US8741173B2 (en) | 2010-10-05 | 2014-06-03 | Dow Technology Investments Llc | Hydroformylation process |
| DE102013020323B3 (de) | 2013-12-05 | 2015-01-08 | Oxea Gmbh | Verfahren zur Herstellung von isomeren Hexansäuren aus den bei der Herstellung von Pentanalen anfallenden Nebenströmen |
| DE102013020322B4 (de) | 2013-12-05 | 2019-04-18 | Oxea Gmbh | Verfahren zur Gewinnung von 2-Methylbutanal aus den bei der Herstellung von Gemischen isomerer a,ß-ungesättigter Decenale anfallenden Nebenströmen |
| DE102013020320B4 (de) | 2013-12-05 | 2019-04-04 | Oxea Gmbh | Verfahren zur Herstellung von 2-Methylbuttersäure mit einem vermindertem Gehalt an 3-Methylbuttersäure aus den bei der Herstellung von Pentansäuren anfallenden Nebenströmen |
| CN105363493A (zh) * | 2015-12-15 | 2016-03-02 | 上海华谊（集团）公司 | 提高烯烃氢甲酰化催化剂存储稳定性的方法 |
| CN105413747A (zh) * | 2015-12-15 | 2016-03-23 | 上海华谊（集团）公司 | 含单膦配体的络合催化剂 |
| CN105498841A (zh) * | 2015-12-15 | 2016-04-20 | 上海华谊（集团）公司 | 含双膦配体的络合催化剂 |
| EP3318569B1 (de) | 2016-11-08 | 2019-07-17 | Evonik Degussa GmbH | Bisphosphite mit 2,4-tert.-butylphenyl-einheiten und deren verwendung als liganden in der hydroformylierung |
| SE1730036A1 (en) * | 2017-02-09 | 2018-08-10 | Perstorp Ab | Carbonylation process and ligand composition |
| EP3645606B1 (en) | 2017-06-26 | 2024-06-26 | Dow Silicones Corporation | Method for hydrosilylation of aliphatically unsaturated alkoxysilanes and hydrogen terminated organosiloxane oligomers to prepare alkoxysilyl terminated polymers useful for functionalizing polyorganosiloxanes using a rhodium catalyst |
| US11492448B2 (en) | 2017-06-26 | 2022-11-08 | Dow Silicones Corporation | Method for hydrosilylation of aliphatically unsaturated alkoxysilanes and hydrogen terminated organosiloxane oligomers to prepare alkoxysilyl terminated polymers useful for functionalizing polyorganosiloxanes using a cobalt catalyst |
| CN110770281B (zh) | 2017-06-26 | 2022-02-22 | 美国陶氏有机硅公司 | 制备烷氧基甲硅烷基封端的聚合物的方法 |
| MY207749A (en) * | 2018-05-30 | 2025-03-16 | Dow Technology Investments Llc | Catalyst composition comprising the combination of a monophopsphine, a tetraphosphine ligand and a hydroformylation process using it |
| EP3801899A1 (en) * | 2018-05-30 | 2021-04-14 | Dow Technology Investments LLC | Methods for slowing deactivation of a catalyst and/or slowing tetraphosphine ligand usage in hydroformylation processes |
| CN111138493A (zh) * | 2020-01-13 | 2020-05-12 | 上海华谊（集团）公司 | 一种合成双亚磷酸酯的方法 |
| GB202213997D0 (en) | 2022-09-26 | 2022-11-09 | Johnson Matthey Davy Technologies Ltd | Parallel zone hydroformylation reaction |
| CN115999643B (zh) * | 2023-01-09 | 2024-07-19 | 中国海洋石油集团有限公司 | 一种油溶性纳米催化剂及其制备方法和用途 |
| GB202303617D0 (en) | 2023-03-13 | 2023-04-26 | Johnson Matthey Davy Technologies Ltd | Method and apparatus for producing aldehyde |
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Also Published As
| Publication number | Publication date |
|---|---|
| CN102365258A (zh) | 2012-02-29 |
| CA2756936A1 (en) | 2010-10-14 |
| RU2011143929A (ru) | 2013-05-10 |
| RU2541537C2 (ru) | 2015-02-20 |
| PL2414314T3 (pl) | 2018-02-28 |
| TWI504586B (zh) | 2015-10-21 |
| TW201035033A (en) | 2010-10-01 |
| WO2010117391A1 (en) | 2010-10-14 |
| US8513469B2 (en) | 2013-08-20 |
| KR20110134930A (ko) | 2011-12-15 |
| EP2414314B1 (en) | 2017-09-13 |
| EP2414314A1 (en) | 2012-02-08 |
| JP5603407B2 (ja) | 2014-10-08 |
| KR101706797B1 (ko) | 2017-02-15 |
| JP2012522048A (ja) | 2012-09-20 |
| US20120029242A1 (en) | 2012-02-02 |
| MY158433A (en) | 2016-10-14 |
| CN102365258B (zh) | 2014-09-10 |
| ZA201107180B (en) | 2012-12-27 |
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