MX2011008746A - Catalizador para metatesis de etileno y 2-buteno y/o isomerizacion de doble enlace. - Google Patents
Catalizador para metatesis de etileno y 2-buteno y/o isomerizacion de doble enlace.Info
- Publication number
- MX2011008746A MX2011008746A MX2011008746A MX2011008746A MX2011008746A MX 2011008746 A MX2011008746 A MX 2011008746A MX 2011008746 A MX2011008746 A MX 2011008746A MX 2011008746 A MX2011008746 A MX 2011008746A MX 2011008746 A MX2011008746 A MX 2011008746A
- Authority
- MX
- Mexico
- Prior art keywords
- catalyst
- isomerization
- cycle
- olefins
- disclosed
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 11
- 238000006317 isomerization reaction Methods 0.000 title abstract 7
- IAQRGUVFOMOMEM-UHFFFAOYSA-N but-2-ene Chemical compound CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 title 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title 1
- 239000005977 Ethylene Substances 0.000 title 1
- XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 title 1
- 238000005649 metathesis reaction Methods 0.000 title 1
- 150000001336 alkenes Chemical class 0.000 abstract 6
- 238000000034 method Methods 0.000 abstract 4
- 229910001038 basic metal oxide Inorganic materials 0.000 abstract 2
- 230000009849 deactivation Effects 0.000 abstract 2
- 230000000694 effects Effects 0.000 abstract 2
- 239000012530 fluid Substances 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 150000002739 metals Chemical class 0.000 abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 230000008021 deposition Effects 0.000 abstract 1
- 239000002808 molecular sieve Substances 0.000 abstract 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/23—Rearrangement of carbon-to-carbon unsaturated bonds
- C07C5/25—Migration of carbon-to-carbon double bonds
- C07C5/2506—Catalytic processes
- C07C5/2512—Catalytic processes with metal oxides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/23—Rearrangement of carbon-to-carbon unsaturated bonds
- C07C5/25—Migration of carbon-to-carbon double bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/10—Magnesium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/14—Silica and magnesia
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/04—Mixing
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
- C07C11/08—Alkenes with four carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
- C07C4/08—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule
- C07C4/10—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from acyclic hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
- C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/20—Use of additives, e.g. for stabilisation
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- C07C2521/08—Silica
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/10—Magnesium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/16—Clays or other mineral silicates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
- C07C2523/04—Alkali metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/30—Tungsten
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Water Supply & Treatment (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
Se describe un proceso para la isomerización de doble enlace de olefinas. El proceso puede incluir poner en contacto el flujo de líquidos que comprende olefinas, con un lecho fijo que comprende un catalizador de isomerización de óxido de metal alcalino activado para convertir al menos una porción de la olefina a su isómero. Los catalizadores de isomerización descritos aquí pueden tener un ciclo reducido para ciclizar la desactivación en comparación con los catalizadores convencionales, manteniendo así una actividad más elevada con respecto al ciclo de vida completo del catalizador.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/506,615 US8586813B2 (en) | 2009-07-21 | 2009-07-21 | Catalyst for metathesis of ethylene and 2-butene and/or double bond isomerization |
PCT/US2010/040528 WO2011011173A2 (en) | 2009-07-21 | 2010-06-30 | Catalyst for metathesis of ethylene and 2-butene and/or double bond isomerization |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2011008746A true MX2011008746A (es) | 2011-09-06 |
Family
ID=43497901
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2011008746A MX2011008746A (es) | 2009-07-21 | 2010-06-30 | Catalizador para metatesis de etileno y 2-buteno y/o isomerizacion de doble enlace. |
Country Status (18)
Country | Link |
---|---|
US (2) | US8586813B2 (es) |
EP (1) | EP2456738B1 (es) |
JP (2) | JP5542908B2 (es) |
KR (3) | KR101643062B1 (es) |
CN (2) | CN105541541A (es) |
AR (1) | AR080062A1 (es) |
BR (1) | BRPI1014666B1 (es) |
CA (2) | CA2748877C (es) |
CL (1) | CL2015001033A1 (es) |
HU (1) | HUE032458T2 (es) |
MX (1) | MX2011008746A (es) |
MY (1) | MY158576A (es) |
PH (1) | PH12015500369B1 (es) |
PL (1) | PL2456738T3 (es) |
SG (2) | SG10201407666YA (es) |
TW (2) | TWI537244B (es) |
WO (1) | WO2011011173A2 (es) |
ZA (1) | ZA201106468B (es) |
Families Citing this family (58)
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US20120016172A1 (en) * | 2009-04-01 | 2012-01-19 | Mitsui Chemicals, Inc. | Method for manufacturing olefin |
US8343885B2 (en) * | 2010-12-21 | 2013-01-01 | Basf Corporation | Isomerization catalysts |
KR20140029452A (ko) * | 2011-04-20 | 2014-03-10 | 코그니스 아이피 매니지먼트 게엠베하 | 불포화 화합물의 제조 방법 |
US20130340327A1 (en) * | 2012-06-26 | 2013-12-26 | Basf Se | Process For Preparing Unsaturated Compounds |
CN103539618B (zh) * | 2012-07-12 | 2015-07-08 | 中国石油化工股份有限公司 | 己烯双键异构化的方法 |
US9695096B2 (en) | 2012-07-12 | 2017-07-04 | Lummus Technology Inc. | More energy efficient C5 hydrogenation process |
EP2895445B1 (en) * | 2012-09-14 | 2017-03-01 | Lummus Technology Inc. | Propylene via metathesis with low or no ethylene |
EP2905073A4 (en) * | 2012-10-06 | 2016-08-03 | Clariant Catalysts Japan Kk | A CATALYST MIXTURE FOR OLEFINMETATHY REACTIONS, METHOD FOR THE PRODUCTION THEREOF AND METHOD FOR PRODUCING PROPYLENE THEREWITH |
CN103772115B (zh) * | 2012-10-25 | 2015-08-12 | 中国石油化工股份有限公司 | 异丁烯生产四甲基乙烯的方法 |
US20140121429A1 (en) * | 2012-10-30 | 2014-05-01 | Lyondell Chemical Technology, L.P. | Propylene production process with heavies recycle |
WO2014077997A1 (en) | 2012-11-19 | 2014-05-22 | Lummus Technology Inc. | Process to produce linear pentenes and metathesis thereof |
US9688591B2 (en) * | 2013-01-10 | 2017-06-27 | Equistar Chemicals, Lp | Ethylene separation process |
US20140235914A1 (en) * | 2013-02-19 | 2014-08-21 | Basf Corporation | Eggshell Catalyst Composites Containing Tungsten Oxide or Tungsten Oxide Hydrate |
CN104107688B (zh) * | 2013-04-16 | 2016-12-28 | 中国石油化工股份有限公司 | 片状金属氧化物催化剂及其制备方法 |
EP2829317A1 (en) * | 2013-07-23 | 2015-01-28 | Borealis AG | Improved catalyst bed configuration for olefin production |
EP3041917B1 (de) * | 2013-09-05 | 2017-10-25 | Linde Aktiengesellschaft | Verfahren zur erzeugung von kohlenwasserstoffprodukten |
EP2862629A1 (en) | 2013-10-15 | 2015-04-22 | Borealis AG | Catalyst and process for olefin metathesis reaction |
CN104549351B (zh) * | 2013-10-28 | 2017-10-27 | 中国石油化工股份有限公司 | 异构化催化剂 |
CN104549295B (zh) * | 2013-10-28 | 2017-09-15 | 中国石油化工股份有限公司 | 烯烃异构化催化剂 |
CN104549212B (zh) * | 2013-10-28 | 2017-03-15 | 中国石油化工股份有限公司 | 双键异构化催化剂 |
EP2873459A1 (en) | 2013-11-14 | 2015-05-20 | Borealis AG | Catalyst bed configuration for olefin conversion and process for obtaining olefins |
EP3071538B1 (en) * | 2013-11-20 | 2021-02-17 | Lummus Technology LLC | Olefin double bond isomerization catalyst with high poison resistance |
EP2886189A1 (en) | 2013-12-20 | 2015-06-24 | Borealis AG | Process for olefin production by metathesis and reactor system therefor |
CN103804227B (zh) * | 2014-02-17 | 2016-02-10 | 重庆中平紫光科技发展有限公司 | 一种烯腈混合液直接异构化合成2-甲基-2-丁烯腈的方法 |
CN107646028B (zh) | 2015-01-29 | 2021-07-16 | 鲁姆斯科技公司 | 由蒸汽裂化器c5进料制备c5烯烃 |
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CN107921425B (zh) | 2015-07-02 | 2021-11-30 | 沙特阿拉伯石油公司 | 使用介孔二氧化硅泡沫复分解催化剂生产丙烯 |
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KR102178406B1 (ko) | 2015-07-02 | 2020-11-16 | 사우디 아라비안 오일 컴퍼니 | 프로필렌 제조용의 이중 촉매 시스템 |
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US10329225B2 (en) | 2017-01-20 | 2019-06-25 | Saudi Arabian Oil Company | Dual catalyst processes and systems for propylene production |
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US10934231B2 (en) | 2017-01-20 | 2021-03-02 | Saudi Arabian Oil Company | Multiple-stage catalyst systems and processes for propene production |
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US11339332B2 (en) | 2020-01-29 | 2022-05-24 | Saudi Arabian Oil Company | Systems and processes integrating fluidized catalytic cracking with metathesis for producing olefins |
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DE10013253A1 (de) * | 2000-03-17 | 2001-09-20 | Basf Ag | Verfahren zur flexiblen Herstellung von Propen und Hexen |
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FI118516B (fi) * | 2003-03-14 | 2007-12-14 | Neste Oil Oyj | Menetelmä katalyytin valmistamiseksi |
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KR101159087B1 (ko) * | 2003-12-12 | 2012-06-25 | 미쓰비시 가가꾸 가부시키가이샤 | 프로필렌의 제조 방법 |
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JP2011500628A (ja) * | 2007-10-15 | 2011-01-06 | ビーエーエスエフ ソシエタス・ヨーロピア | オレフィンの異性化方法 |
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