AR080062A1 - Proceso para la metatesis de etileno y2-buteno y/o la isomerizacion de uniones dobles - Google Patents
Proceso para la metatesis de etileno y2-buteno y/o la isomerizacion de uniones doblesInfo
- Publication number
- AR080062A1 AR080062A1 ARP100102645A ARP100102645A AR080062A1 AR 080062 A1 AR080062 A1 AR 080062A1 AR P100102645 A ARP100102645 A AR P100102645A AR P100102645 A ARP100102645 A AR P100102645A AR 080062 A1 AR080062 A1 AR 080062A1
- Authority
- AR
- Argentina
- Prior art keywords
- isomerization
- ethylene
- methodsis
- butene
- olefins
- Prior art date
Links
- 238000006317 isomerization reaction Methods 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title abstract 2
- 239000005977 Ethylene Substances 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 abstract 4
- 150000001336 alkenes Chemical class 0.000 abstract 3
- 229910000272 alkali metal oxide Inorganic materials 0.000 abstract 1
- 230000009849 deactivation Effects 0.000 abstract 1
- 239000012530 fluid Substances 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/23—Rearrangement of carbon-to-carbon unsaturated bonds
- C07C5/25—Migration of carbon-to-carbon double bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/23—Rearrangement of carbon-to-carbon unsaturated bonds
- C07C5/25—Migration of carbon-to-carbon double bonds
- C07C5/2506—Catalytic processes
- C07C5/2512—Catalytic processes with metal oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/10—Magnesium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/14—Silica and magnesia
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/04—Mixing
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
- C07C11/08—Alkenes with four carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
- C07C4/08—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule
- C07C4/10—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from acyclic hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
- C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/20—Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- C07C2521/08—Silica
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/10—Magnesium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/16—Clays or other mineral silicates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
- C07C2523/04—Alkali metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/30—Tungsten
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Water Supply & Treatment (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
Un proceso para la isomerizacion de la doble union de olefinas. El proceso puede incluir poner en contacto una corriente de fluido que comprende olefinas con un lecho fijo que comprende un catalizador de isomerizacion de oxido de metal alcalino activado para convertir por lo menos una porcion de la olefina en su isomero. Los catalizadores de isomerizacion que se divulgan aquí pueden tener una desactivacion reducida de un ciclo a otro en comparacion con los catalizadores convencionales, manteniendo de esta manera una mayor actividad durante el ciclo de vida util completo del catalizador. Reivindicacion 20: El proceso de reivindicacion 17, caracterizado porque además comprende reciclar por lo menos una porcion de la fraccion de etileno al reactor de lecho fijo.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/506,615 US8586813B2 (en) | 2009-07-21 | 2009-07-21 | Catalyst for metathesis of ethylene and 2-butene and/or double bond isomerization |
Publications (1)
Publication Number | Publication Date |
---|---|
AR080062A1 true AR080062A1 (es) | 2012-03-14 |
Family
ID=43497901
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP100102645A AR080062A1 (es) | 2009-07-21 | 2010-07-20 | Proceso para la metatesis de etileno y2-buteno y/o la isomerizacion de uniones dobles |
Country Status (18)
Country | Link |
---|---|
US (2) | US8586813B2 (es) |
EP (1) | EP2456738B1 (es) |
JP (2) | JP5542908B2 (es) |
KR (3) | KR101492697B1 (es) |
CN (2) | CN102341358A (es) |
AR (1) | AR080062A1 (es) |
BR (1) | BRPI1014666B1 (es) |
CA (2) | CA2826975C (es) |
CL (1) | CL2015001033A1 (es) |
HU (1) | HUE032458T2 (es) |
MX (1) | MX2011008746A (es) |
MY (1) | MY158576A (es) |
PH (1) | PH12015500369A1 (es) |
PL (1) | PL2456738T3 (es) |
SG (2) | SG10201407666YA (es) |
TW (2) | TWI574942B (es) |
WO (1) | WO2011011173A2 (es) |
ZA (1) | ZA201106468B (es) |
Families Citing this family (57)
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US20120016172A1 (en) * | 2009-04-01 | 2012-01-19 | Mitsui Chemicals, Inc. | Method for manufacturing olefin |
US8343885B2 (en) * | 2010-12-21 | 2013-01-01 | Basf Corporation | Isomerization catalysts |
CN103492357A (zh) * | 2011-04-20 | 2014-01-01 | 考格尼斯知识产权管理有限责任公司 | 制备不饱和化合物的方法 |
US20130340327A1 (en) * | 2012-06-26 | 2013-12-26 | Basf Se | Process For Preparing Unsaturated Compounds |
CN103539618B (zh) * | 2012-07-12 | 2015-07-08 | 中国石油化工股份有限公司 | 己烯双键异构化的方法 |
US9695096B2 (en) | 2012-07-12 | 2017-07-04 | Lummus Technology Inc. | More energy efficient C5 hydrogenation process |
MX360442B (es) * | 2012-09-14 | 2018-10-31 | Lummus Technology Inc | Propileno via metatesis sin etileno o con bajo contenido de etileno. |
US10328417B2 (en) | 2012-10-06 | 2019-06-25 | Clariant Catalysts (Japan) K.K. | Catalyst mixture for olefin metathesis reactions, method of producing same, and method of producing propylene using same |
CN103772115B (zh) * | 2012-10-25 | 2015-08-12 | 中国石油化工股份有限公司 | 异丁烯生产四甲基乙烯的方法 |
US20140121429A1 (en) * | 2012-10-30 | 2014-05-01 | Lyondell Chemical Technology, L.P. | Propylene production process with heavies recycle |
WO2014077997A1 (en) | 2012-11-19 | 2014-05-22 | Lummus Technology Inc. | Process to produce linear pentenes and metathesis thereof |
US9688591B2 (en) | 2013-01-10 | 2017-06-27 | Equistar Chemicals, Lp | Ethylene separation process |
US20140235914A1 (en) * | 2013-02-19 | 2014-08-21 | Basf Corporation | Eggshell Catalyst Composites Containing Tungsten Oxide or Tungsten Oxide Hydrate |
CN104107688B (zh) * | 2013-04-16 | 2016-12-28 | 中国石油化工股份有限公司 | 片状金属氧化物催化剂及其制备方法 |
EP2829317A1 (en) * | 2013-07-23 | 2015-01-28 | Borealis AG | Improved catalyst bed configuration for olefin production |
WO2015032860A1 (de) * | 2013-09-05 | 2015-03-12 | Linde Aktiengesellschaft | Verfahren zur erzeugung von kohlenwasserstoffprodukten |
EP2862629A1 (en) * | 2013-10-15 | 2015-04-22 | Borealis AG | Catalyst and process for olefin metathesis reaction |
CN104549351B (zh) * | 2013-10-28 | 2017-10-27 | 中国石油化工股份有限公司 | 异构化催化剂 |
CN104549212B (zh) * | 2013-10-28 | 2017-03-15 | 中国石油化工股份有限公司 | 双键异构化催化剂 |
CN104549295B (zh) * | 2013-10-28 | 2017-09-15 | 中国石油化工股份有限公司 | 烯烃异构化催化剂 |
EP2873459A1 (en) | 2013-11-14 | 2015-05-20 | Borealis AG | Catalyst bed configuration for olefin conversion and process for obtaining olefins |
HUE054256T2 (hu) * | 2013-11-20 | 2021-08-30 | Lummus Technology Inc | Katalizátormérgeknek jól ellenálló, kettõs kötésû olefin-izomerizációs katalizátor |
EP2886189A1 (en) | 2013-12-20 | 2015-06-24 | Borealis AG | Process for olefin production by metathesis and reactor system therefor |
CN103804227B (zh) * | 2014-02-17 | 2016-02-10 | 重庆中平紫光科技发展有限公司 | 一种烯腈混合液直接异构化合成2-甲基-2-丁烯腈的方法 |
KR101979132B1 (ko) | 2015-01-29 | 2019-05-15 | 루머스 테크놀로지 엘엘씨 | 스팀 크래커 c5 공급물로부터 c5 올레핀류의 제조 |
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SG10201913486WA (en) | 2015-07-02 | 2020-02-27 | Saudi Arabian Oil Co | Systems and methods for producing propylene |
KR102178406B1 (ko) | 2015-07-02 | 2020-11-16 | 사우디 아라비안 오일 컴퍼니 | 프로필렌 제조용의 이중 촉매 시스템 |
US10005703B2 (en) | 2015-07-02 | 2018-06-26 | Saudi Arabian Oil Company | Propylene production using a mesoporous silica foam metathesis catalyst |
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US10010870B2 (en) * | 2015-11-12 | 2018-07-03 | Saudi Arabian Oil Company | Synthesis of catalytic materials for metathesis and isomerization reactions and other catalytic applications via well controlled aerosol processing |
KR102029612B1 (ko) | 2016-01-29 | 2019-10-07 | 라이온델 케미칼 테크놀로지, 엘.피. | 에틸렌 및 부텐으로부터 프로필렌을 생산하기 위한 촉매 및 방법 |
US10550048B2 (en) | 2017-01-20 | 2020-02-04 | Saudi Arabian Oil Company | Multiple-stage catalyst system for self-metathesis with controlled isomerization and cracking |
US10329225B2 (en) | 2017-01-20 | 2019-06-25 | Saudi Arabian Oil Company | Dual catalyst processes and systems for propylene production |
US10934231B2 (en) | 2017-01-20 | 2021-03-02 | Saudi Arabian Oil Company | Multiple-stage catalyst systems and processes for propene production |
US10407363B2 (en) | 2017-08-16 | 2019-09-10 | Saudi Arabian Oil Company | Steam-less process for converting butenes to 1,3-butadiene |
FR3084362A1 (fr) | 2018-07-25 | 2020-01-31 | IFP Energies Nouvelles | Procede de metathese des olefines utilisant un catalyseur contenant du silicium, du molybdene et un element alcalin |
FR3084361A1 (fr) | 2018-07-25 | 2020-01-31 | IFP Energies Nouvelles | Procede de metathese des olefines utilisant un catalyseur contenant du silicium, du molybdene et du soufre |
FR3084363B1 (fr) | 2018-07-25 | 2020-08-07 | Ifp Energies Now | Procede de metathese des olefines utilisant un catalyseur contenant du silicium, du molybdene et un element alcalin |
US11242299B2 (en) | 2018-10-10 | 2022-02-08 | Saudi Arabian Oil Company | Catalyst systems that include metal oxide co-catalysts for the production of propylene |
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CN110201713B (zh) * | 2019-06-17 | 2022-03-11 | 万华化学集团股份有限公司 | 一种催化剂及其制备方法和在烯烃异构反应中的应用 |
FR3103192A1 (fr) | 2019-11-15 | 2021-05-21 | IFP Energies Nouvelles | Procede de metathese des olefines utilisant un catalyseur a haute teneur en alcalin contenant du silicium, du molybdene |
CN110922291B (zh) * | 2019-11-22 | 2021-09-21 | 中国石油大学(北京) | 一种生物基乙醇和丁醇混合液生产丙烯的方法 |
US11311869B2 (en) * | 2019-12-03 | 2022-04-26 | Saudi Arabian Oil Company | Methods of producing isomerization catalysts |
US11517892B2 (en) | 2019-12-03 | 2022-12-06 | Saudi Arabian Oil Company | Methods of producing isomerization catalysts |
US11339332B2 (en) | 2020-01-29 | 2022-05-24 | Saudi Arabian Oil Company | Systems and processes integrating fluidized catalytic cracking with metathesis for producing olefins |
US11572516B2 (en) | 2020-03-26 | 2023-02-07 | Saudi Arabian Oil Company | Systems and processes integrating steam cracking with dual catalyst metathesis for producing olefins |
US11420915B2 (en) | 2020-06-11 | 2022-08-23 | Saudi Arabian Oil Company | Red mud as a catalyst for the isomerization of olefins |
US11427519B2 (en) | 2021-01-04 | 2022-08-30 | Saudi Arabian Oil Company | Acid modified red mud as a catalyst for olefin isomerization |
US11679378B2 (en) | 2021-02-25 | 2023-06-20 | Saudi Arabian Oil Company | Methods of producing isomerization catalysts |
US11319263B1 (en) | 2021-03-03 | 2022-05-03 | Saudi Arabian Oil Company | Methods for low temperature production of 1-butene |
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US6777582B2 (en) | 2002-03-07 | 2004-08-17 | Abb Lummus Global Inc. | Process for producing propylene and hexene from C4 olefin streams |
FI118516B (fi) * | 2003-03-14 | 2007-12-14 | Neste Oil Oyj | Menetelmä katalyytin valmistamiseksi |
US7214841B2 (en) * | 2003-07-15 | 2007-05-08 | Abb Lummus Global Inc. | Processing C4 olefin streams for the maximum production of propylene |
US7074976B2 (en) | 2003-08-19 | 2006-07-11 | Equistar Chemicals, Lp | Propylene production |
US7223895B2 (en) | 2003-11-18 | 2007-05-29 | Abb Lummus Global Inc. | Production of propylene from steam cracking of hydrocarbons, particularly ethane |
KR101159087B1 (ko) * | 2003-12-12 | 2012-06-25 | 미쓰비시 가가꾸 가부시키가이샤 | 프로필렌의 제조 방법 |
US8178737B2 (en) * | 2007-06-14 | 2012-05-15 | Lyondell Chemical Technology, L.P. | Propylene production |
KR20100075997A (ko) | 2007-10-15 | 2010-07-05 | 바스프 에스이 | 올레핀의 이성질화 방법 |
US8440874B2 (en) * | 2008-09-04 | 2013-05-14 | Lummus Technology Inc. | Olefin isomerization and metathesis catalyst |
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2009
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2010
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