MX337012B - Catalizadores masicos y soportados de sulfuro de rutenio no-promovido con alta actividad catalitica para reacciones de hidrotratamiento de hidrocarburos y su metodo de obtenccion. - Google Patents

Catalizadores masicos y soportados de sulfuro de rutenio no-promovido con alta actividad catalitica para reacciones de hidrotratamiento de hidrocarburos y su metodo de obtenccion.

Info

Publication number
MX337012B
MX337012B MX2011013529A MX2011013529A MX337012B MX 337012 B MX337012 B MX 337012B MX 2011013529 A MX2011013529 A MX 2011013529A MX 2011013529 A MX2011013529 A MX 2011013529A MX 337012 B MX337012 B MX 337012B
Authority
MX
Mexico
Prior art keywords
catalytic activity
high catalytic
mastical
hydrotracting
rutenium
Prior art date
Application number
MX2011013529A
Other languages
English (en)
Other versions
MX2011013529A (es
Inventor
Lorena Alvarez Contreras
Carlos Elias Ornelas Gutierrez
Jose Rurik Farias Mancilla
Original Assignee
Ct Investig Materiales Avanzados Sc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ct Investig Materiales Avanzados Sc filed Critical Ct Investig Materiales Avanzados Sc
Priority to MX2011013529A priority Critical patent/MX337012B/es
Priority to US13/444,411 priority patent/US8987165B2/en
Publication of MX2011013529A publication Critical patent/MX2011013529A/es
Publication of MX337012B publication Critical patent/MX337012B/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B01J27/043—Sulfides with iron group metals or platinum group metals
    • B01J27/045—Platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B01J35/77—Compounds characterised by their crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/16—Pore diameter
    • C01P2006/17—Pore diameter distribution
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Nanotechnology (AREA)
  • Inorganic Chemistry (AREA)
  • Thermal Sciences (AREA)
  • Composite Materials (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

La presente invención describe un método de síntesis de catalizadores base rutenio (RuS2) másicos y soportados a partir de un precursor complejo de rutenio, el cual es descompuesto y activado mediante un proceso de simple activación; estos pasos proporcionan un catalizador con muy alta actividad catalítica, además se describe la incorporación de precursor complejo de rutenio a un soporte mediante métodos de impregnación incipiente y húmeda; las actividades catalíticas logradas en esta invención son del orden de 100 veces el catalizador de sulfuro de molibdeno sin soporte y sin promotor, 14 veces el catalizador industrial soportado y 5 veces la actividad del catalizador comercial másico hoy en día.
MX2011013529A 2011-12-14 2011-12-14 Catalizadores masicos y soportados de sulfuro de rutenio no-promovido con alta actividad catalitica para reacciones de hidrotratamiento de hidrocarburos y su metodo de obtenccion. MX337012B (es)

Priority Applications (2)

Application Number Priority Date Filing Date Title
MX2011013529A MX337012B (es) 2011-12-14 2011-12-14 Catalizadores masicos y soportados de sulfuro de rutenio no-promovido con alta actividad catalitica para reacciones de hidrotratamiento de hidrocarburos y su metodo de obtenccion.
US13/444,411 US8987165B2 (en) 2011-12-14 2012-04-11 Unsupported and supported non-promoted ruthenium sulfide catalyst with high catalytic activity for hydrocarbon hydrotreatments and its method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
MX2011013529A MX337012B (es) 2011-12-14 2011-12-14 Catalizadores masicos y soportados de sulfuro de rutenio no-promovido con alta actividad catalitica para reacciones de hidrotratamiento de hidrocarburos y su metodo de obtenccion.

Publications (2)

Publication Number Publication Date
MX2011013529A MX2011013529A (es) 2013-06-17
MX337012B true MX337012B (es) 2015-12-15

Family

ID=48609048

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2011013529A MX337012B (es) 2011-12-14 2011-12-14 Catalizadores masicos y soportados de sulfuro de rutenio no-promovido con alta actividad catalitica para reacciones de hidrotratamiento de hidrocarburos y su metodo de obtenccion.

Country Status (2)

Country Link
US (1) US8987165B2 (es)
MX (1) MX337012B (es)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111939940B (zh) * 2020-07-03 2023-05-16 南方科技大学 钌基催化剂及其制备方法和应用
CN113398951B (zh) * 2021-06-16 2022-10-28 中国科学技术大学 金属间化合物催化剂及采用双金属络合物制备金属间化合物催化剂的方法

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3055840A (en) * 1958-01-13 1962-09-25 Engelhard Ind Inc Ruthenium-containing catalysts and methods of making said catalysts and increasing their activity
JPS5316686A (en) * 1976-07-07 1978-02-15 Ricoh Watch Method of quantitative analysis of metallic ruthenium
US4279737A (en) * 1978-02-23 1981-07-21 Exxon Research & Engineering Co. Hydrodesulfurization over catalysts comprising chalcogenides of group VIII prepared by low temperature precipitation from nonaqueous solution
US4288422A (en) * 1979-02-23 1981-09-08 Exxon Research & Engineering Co. Method of preparing chalcogenides of group VIII by low temperature precipitation from monaqueous solution, the products produced by said method and their use as catalysts
FR2678179B1 (fr) * 1991-06-26 1995-01-13 Elf Antar France Catalyseur d'hydroraffinage renfermant des sulfures de ruthenium et d'au moins un autre metal sur un support d'oxydes refractaires et procede d'hydroraffinage mettant en óoeuvre ledit catalyseur.
JPH11514290A (ja) 1995-10-13 1999-12-07 カー．ウ．ロイフェン レサーチ エン デフェロプメント 実質的に鏡像異性体として純粋な生成物を得るためのキラルな固形触媒、その製法及びその利用
US6299760B1 (en) 1999-08-12 2001-10-09 Exxon Research And Engineering Company Nickel molybodtungstate hydrotreating catalysts (law444)
AU2001284773B2 (en) 2000-08-10 2004-08-05 Trustees Of Boston College Recyclable metathesis catalysts
US6426437B1 (en) 2000-12-13 2002-07-30 Arco Chemical Technology, L.P. Hydroformylation process
US7879753B2 (en) * 2003-05-27 2011-02-01 Industrie De Nora S.P.A. Catalyst for oxygen reduction
US7812251B2 (en) 2003-10-17 2010-10-12 Sharp Kabushiki Kaisha Photosensitizing transition metal complex and its use for photovoltaic cell
US6967185B2 (en) * 2004-01-28 2005-11-22 De Nora Elettrodi S.P.A. Synthesis of noble metal, sulphide catalysts in a sulfide ion-free aqueous environment
JP4564010B2 (ja) 2004-07-02 2010-10-20 独立行政法人科学技術振興機構 光学活性なアジリジン化合物及びアミン化合物の製造方法、並びに該方法に用いる錯体及びその中間体
BRPI0601787B1 (pt) 2006-05-17 2016-06-07 Petroleo Brasileiro Sa processo de hidrodessulfurização seletiva de nafta
US7772445B2 (en) 2007-07-06 2010-08-10 Kanata Chemical Technologies Inc. Ruthenium catalysts for catalytic hydrogenation
CN101544904B (zh) 2008-03-28 2012-11-14 中国科学院大连化学物理研究所 一种复合金属氧化物催化剂及制备和应用
JP5191972B2 (ja) 2008-10-30 2013-05-08 高砂香料工業株式会社 ルテニウム錯体の製造方法
EP2196260A1 (en) 2008-12-02 2010-06-16 Research Institute of Petroleum Industry (RIPI) Hydrodesulphurization nanocatalyst, its use and a process for its production
JP5276043B2 (ja) 2009-05-19 2013-08-28 高砂香料工業株式会社 含ケイ素置換基で置換された芳香環を配位子とするルテニウム錯体及びその製造方法
US7893290B1 (en) 2010-04-13 2011-02-22 W.C. Heraeus Gmbh Process for the preparation of bis(pentadienyl)-complexes of iron group metals

Also Published As

Publication number Publication date
US20130153468A1 (en) 2013-06-20
MX2011013529A (es) 2013-06-17
US8987165B2 (en) 2015-03-24

Similar Documents

Publication Publication Date Title
EA201400487A1 (ru) Способы получения и формирования нанесенных активных металлических катализаторов и предшественников
ES2579854T3 (es) Un método para la producción de hidrocarburos aumentando la longitud de la cadena de hidrocarburo
WO2011097127A3 (en) Acid washed silica supported catalysts and their use in olefin metathesis
BR112013020271A2 (pt) método para preparar um catalisador, catalisador, e, processo para realizar uma reação de reforma a vapor
AR085850A1 (es) Produccion de etanol a partir del acido acetico utilizando un catalizador de carburo de molibdeno
MX345655B (es) Metodo para producir un alcano que contiene fluor.
GB2513745A (en) Process intensification in the catalytic synthesis of supported catalysts with hierarchic pore structure
EA201491067A1 (ru) Катализаторы из нанопроволоки и способы их применения и получения
CO6141475A2 (es) Procedimiento para la produccion en fase condensada a partir de uno o mas reactantes en fase gaseosa
MY161641A (en) Catalytic processes and systems for base oil production from light feedstock
EA201101340A1 (ru) Катализатор никель/оксид лантана для получения синтез-газа
MX366574B (es) Nanocatalizador de cobalto para sintesis de fischer-tropsch, basado en confinacion de material poroso, y metodo para su preparacion.
MX2015012182A (es) Proceso para la conversión de compuestos aromáticos metoxilados en compuestos aromáticos simples.
CA2900730C (fr) Procede pour le demarrage d'unites d'hydrotraitement ou d'hydroconversion
BR112018006782A2 (pt) processo para produção de um catalisador, e, uso de um catalisador
AR089980A1 (es) Produccion de caprolactama a partir de acido adipico
MX373623B (es) Catalizadores de rutenio-fenol para reacciones de hidrogenación por trasferencia.
MX337012B (es) Catalizadores masicos y soportados de sulfuro de rutenio no-promovido con alta actividad catalitica para reacciones de hidrotratamiento de hidrocarburos y su metodo de obtenccion.
WO2014058865A3 (en) Metal-supported catalyst structures and processes for manufacturing the same
IN2013CH01255A (es)
MY171009A (en) Isomerization of light alpha-olefins to light internal olefins
CO2017008412A2 (es) Proceso para la purificación de ácido monocloroacético
MX348939B (es) Un catalizador metalico reducido protegido.
PL421462A1 (pl) Sposób wytwarzania cyklicznych związków w reakcji metatezy olefin oraz zastosowanie katalizatorów rutenowych do wytwarzania cyklicznych olefin w reakcjach metatezy olefin
MX376857B (es) Catalizador para la sintesis de metilmercaptano y procedimiento de produccion de metilmercaptano a partir de gas de sintesis y de sulfuro de hidrogeno.

Legal Events

Date Code Title Description
FG Grant or registration