MX337012B - Catalizadores masicos y soportados de sulfuro de rutenio no-promovido con alta actividad catalitica para reacciones de hidrotratamiento de hidrocarburos y su metodo de obtenccion. - Google Patents
Catalizadores masicos y soportados de sulfuro de rutenio no-promovido con alta actividad catalitica para reacciones de hidrotratamiento de hidrocarburos y su metodo de obtenccion.Info
- Publication number
- MX337012B MX337012B MX2011013529A MX2011013529A MX337012B MX 337012 B MX337012 B MX 337012B MX 2011013529 A MX2011013529 A MX 2011013529A MX 2011013529 A MX2011013529 A MX 2011013529A MX 337012 B MX337012 B MX 337012B
- Authority
- MX
- Mexico
- Prior art keywords
- unsupported
- catalyst
- catalytic activity
- high catalytic
- hydrotreatments
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 6
- 230000003197 catalytic effect Effects 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 title 1
- DUDJJJCZFBPZKW-UHFFFAOYSA-N [Ru]=S Chemical compound [Ru]=S DUDJJJCZFBPZKW-UHFFFAOYSA-N 0.000 title 1
- 229930195733 hydrocarbon Natural products 0.000 title 1
- 150000002430 hydrocarbons Chemical class 0.000 title 1
- 239000012327 Ruthenium complex Substances 0.000 abstract 2
- 239000002243 precursor Substances 0.000 abstract 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 abstract 1
- 238000001994 activation Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 238000010348 incorporation Methods 0.000 abstract 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 abstract 1
- 229910052707 ruthenium Inorganic materials 0.000 abstract 1
- 238000001308 synthesis method Methods 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/04—Sulfides
- B01J27/043—Sulfides with iron group metals or platinum group metals
- B01J27/045—Platinum group metals
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- B01J35/30—
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- B01J35/393—
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- B01J35/613—
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- B01J35/615—
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/031—Precipitation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
- B01J37/18—Reducing with gases containing free hydrogen
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/20—Sulfiding
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/42—Catalytic treatment
- C10G3/44—Catalytic treatment characterised by the catalyst used
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/16—Pore diameter
- C01P2006/17—Pore diameter distribution
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
Abstract
La presente invención describe un método de síntesis de catalizadores base rutenio (RuS2) másicos y soportados a partir de un precursor complejo de rutenio, el cual es descompuesto y activado mediante un proceso de simple activación; estos pasos proporcionan un catalizador con muy alta actividad catalítica, además se describe la incorporación de precursor complejo de rutenio a un soporte mediante métodos de impregnación incipiente y húmeda; las actividades catalíticas logradas en esta invención son del orden de 100 veces el catalizador de sulfuro de molibdeno sin soporte y sin promotor, 14 veces el catalizador industrial soportado y 5 veces la actividad del catalizador comercial másico hoy en día.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
MX2011013529A MX337012B (es) | 2011-12-14 | 2011-12-14 | Catalizadores masicos y soportados de sulfuro de rutenio no-promovido con alta actividad catalitica para reacciones de hidrotratamiento de hidrocarburos y su metodo de obtenccion. |
US13/444,411 US8987165B2 (en) | 2011-12-14 | 2012-04-11 | Unsupported and supported non-promoted ruthenium sulfide catalyst with high catalytic activity for hydrocarbon hydrotreatments and its method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
MX2011013529A MX337012B (es) | 2011-12-14 | 2011-12-14 | Catalizadores masicos y soportados de sulfuro de rutenio no-promovido con alta actividad catalitica para reacciones de hidrotratamiento de hidrocarburos y su metodo de obtenccion. |
Publications (2)
Publication Number | Publication Date |
---|---|
MX2011013529A MX2011013529A (es) | 2013-06-17 |
MX337012B true MX337012B (es) | 2015-12-15 |
Family
ID=48609048
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2011013529A MX337012B (es) | 2011-12-14 | 2011-12-14 | Catalizadores masicos y soportados de sulfuro de rutenio no-promovido con alta actividad catalitica para reacciones de hidrotratamiento de hidrocarburos y su metodo de obtenccion. |
Country Status (2)
Country | Link |
---|---|
US (1) | US8987165B2 (es) |
MX (1) | MX337012B (es) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111939940B (zh) * | 2020-07-03 | 2023-05-16 | 南方科技大学 | 钌基催化剂及其制备方法和应用 |
CN113398951B (zh) * | 2021-06-16 | 2022-10-28 | 中国科学技术大学 | 金属间化合物催化剂及采用双金属络合物制备金属间化合物催化剂的方法 |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3055840A (en) * | 1958-01-13 | 1962-09-25 | Engelhard Ind Inc | Ruthenium-containing catalysts and methods of making said catalysts and increasing their activity |
JPS5316686A (en) * | 1976-07-07 | 1978-02-15 | Ricoh Watch | Method of quantitative analysis of metallic ruthenium |
US4279737A (en) * | 1978-02-23 | 1981-07-21 | Exxon Research & Engineering Co. | Hydrodesulfurization over catalysts comprising chalcogenides of group VIII prepared by low temperature precipitation from nonaqueous solution |
US4288422A (en) * | 1979-02-23 | 1981-09-08 | Exxon Research & Engineering Co. | Method of preparing chalcogenides of group VIII by low temperature precipitation from monaqueous solution, the products produced by said method and their use as catalysts |
FR2678179B1 (fr) * | 1991-06-26 | 1995-01-13 | Elf Antar France | Catalyseur d'hydroraffinage renfermant des sulfures de ruthenium et d'au moins un autre metal sur un support d'oxydes refractaires et procede d'hydroraffinage mettant en óoeuvre ledit catalyseur. |
DE69613587T2 (de) | 1995-10-13 | 2002-04-25 | K U Leuven Res & Dev Leuven | Chiraler fester katalysator, seine erzeugung und seine verwendung zur hesrtellung von praktischen enantiomerenreinen produkten |
US6299760B1 (en) | 1999-08-12 | 2001-10-09 | Exxon Research And Engineering Company | Nickel molybodtungstate hydrotreating catalysts (law444) |
JP3943015B2 (ja) | 2000-08-10 | 2007-07-11 | トラスティーズ オブ ボストン カレッジ | リサイクル可能メタセシス触媒 |
US6426437B1 (en) | 2000-12-13 | 2002-07-30 | Arco Chemical Technology, L.P. | Hydroformylation process |
US7879753B2 (en) * | 2003-05-27 | 2011-02-01 | Industrie De Nora S.P.A. | Catalyst for oxygen reduction |
US7812251B2 (en) | 2003-10-17 | 2010-10-12 | Sharp Kabushiki Kaisha | Photosensitizing transition metal complex and its use for photovoltaic cell |
US6967185B2 (en) * | 2004-01-28 | 2005-11-22 | De Nora Elettrodi S.P.A. | Synthesis of noble metal, sulphide catalysts in a sulfide ion-free aqueous environment |
US7754899B2 (en) | 2004-07-02 | 2010-07-13 | Japan Science And Technology Agency | Method for producing optically active aziridine compounds and amine compounds as well as complexes and their intermediates used in this method |
BRPI0601787B1 (pt) | 2006-05-17 | 2016-06-07 | Petroleo Brasileiro Sa | processo de hidrodessulfurização seletiva de nafta |
US7772445B2 (en) | 2007-07-06 | 2010-08-10 | Kanata Chemical Technologies Inc. | Ruthenium catalysts for catalytic hydrogenation |
CN101544904B (zh) | 2008-03-28 | 2012-11-14 | 中国科学院大连化学物理研究所 | 一种复合金属氧化物催化剂及制备和应用 |
JP5191972B2 (ja) | 2008-10-30 | 2013-05-08 | 高砂香料工業株式会社 | ルテニウム錯体の製造方法 |
EP2196260A1 (en) | 2008-12-02 | 2010-06-16 | Research Institute of Petroleum Industry (RIPI) | Hydrodesulphurization nanocatalyst, its use and a process for its production |
JP5276043B2 (ja) | 2009-05-19 | 2013-08-28 | 高砂香料工業株式会社 | 含ケイ素置換基で置換された芳香環を配位子とするルテニウム錯体及びその製造方法 |
US7893290B1 (en) | 2010-04-13 | 2011-02-22 | W.C. Heraeus Gmbh | Process for the preparation of bis(pentadienyl)-complexes of iron group metals |
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2011
- 2011-12-14 MX MX2011013529A patent/MX337012B/es active IP Right Grant
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2012
- 2012-04-11 US US13/444,411 patent/US8987165B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
MX2011013529A (es) | 2013-06-17 |
US20130153468A1 (en) | 2013-06-20 |
US8987165B2 (en) | 2015-03-24 |
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