BR112013032165B8 - catalisadores - Google Patents

catalisadores Download PDF

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Publication number
BR112013032165B8
BR112013032165B8 BR112013032165A BR112013032165A BR112013032165B8 BR 112013032165 B8 BR112013032165 B8 BR 112013032165B8 BR 112013032165 A BR112013032165 A BR 112013032165A BR 112013032165 A BR112013032165 A BR 112013032165A BR 112013032165 B8 BR112013032165 B8 BR 112013032165B8
Authority
BR
Brazil
Prior art keywords
catalyst precursor
cobalt compound
cobalt
catalyst
subsequent
Prior art date
Application number
BR112013032165A
Other languages
English (en)
Other versions
BR112013032165A2 (pt
BR112013032165B1 (pt
Inventor
Van Rensburg Hendrik
Original Assignee
Sasol Tech Pty Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sasol Tech Pty Ltd filed Critical Sasol Tech Pty Ltd
Publication of BR112013032165A2 publication Critical patent/BR112013032165A2/pt
Publication of BR112013032165B1 publication Critical patent/BR112013032165B1/pt
Publication of BR112013032165B8 publication Critical patent/BR112013032165B8/pt

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913Cobalt and noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • B01J23/75Cobalt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0205Impregnation in several steps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/024Multiple impregnation or coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • B01J37/082Decomposition and pyrolysis
    • B01J37/088Decomposition of a metal salt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/12Oxidising
    • B01J37/14Oxidising with gases containing free oxygen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16Reducing
    • B01J37/18Reducing with gases containing free hydrogen
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425Catalysts; their physical properties
    • C07C1/043Catalysts; their physical properties characterised by the composition
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12Silica and alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0213Preparation of the impregnating solution
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

catalisadores um processo para preparar um catalisador contendo cobalto para síntese de hidrocarboneto inclui calcinar um precursor de catalisador inicial compreendendo um suporte de catalisador suportando um composto de cobalto, pelo tratamento térmico do precursor de catalisador inicial sob condições não-redutoras para decompor o composto de cobalto e/ou levar o composto de cobalto a reagir com oxigênio, para se obter assim um precursor de catalisador inicial calcinado. um composto de cobalto é introduzido no e/ou dentro do precursor de catalisador inicial calcinado de modo que o precursor de catalisador inicial calcinado suporte esse composto de cobalto, obtendo-se assim um precursor de catalisador subsequente. o precursor de catalisador subsequente é diretamente submetido a condições de redução para ativar o precursor de catalisador subsequente, para se obter assim um catalisador contendo cobalto para síntese de hidrocarboneto.
BR112013032165A 2011-09-21 2012-08-31 catalisadores BR112013032165B8 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ZA201106909 2011-09-21
PCT/IB2012/054493 WO2013041997A1 (en) 2011-09-21 2012-08-31 Process for preparing a cobalt - containing fischer tropsch catalyst

Publications (3)

Publication Number Publication Date
BR112013032165A2 BR112013032165A2 (pt) 2016-12-13
BR112013032165B1 BR112013032165B1 (pt) 2019-09-03
BR112013032165B8 true BR112013032165B8 (pt) 2019-11-05

Family

ID=47018331

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112013032165A BR112013032165B8 (pt) 2011-09-21 2012-08-31 catalisadores

Country Status (14)

Country Link
US (1) US9248435B2 (pt)
EP (1) EP2758170B1 (pt)
JP (1) JP5961694B2 (pt)
CN (1) CN103635256B (pt)
AP (1) AP2013007293A0 (pt)
AR (1) AR087975A1 (pt)
AU (1) AU2012311175B2 (pt)
BR (1) BR112013032165B8 (pt)
CA (1) CA2838233C (pt)
MY (1) MY164214A (pt)
PE (1) PE20140735A1 (pt)
RU (1) RU2602803C2 (pt)
WO (1) WO2013041997A1 (pt)
ZA (1) ZA201309045B (pt)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9248435B2 (en) 2011-09-21 2016-02-02 Sasol Technology (Proprietary) Limited Process for preparing a cobalt-containing fischer tropsch catalyst
EA036728B1 (ru) * 2014-12-19 2020-12-14 Бп П.Л.К. Способ получения содержащего кобальт катализатора на подложке для синтеза фишера-тропша
EP3393659B1 (en) 2015-12-21 2022-02-09 Shell Internationale Research Maatschappij B.V. Method for preparing a hydrogenation catalyst
WO2018029548A1 (en) * 2016-08-11 2018-02-15 Sasol South Africa (Pty) Limited A cobalt-containing catalyst composition

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4413064A (en) * 1981-10-13 1983-11-01 Gulf Research & Development Company Fluid bed catalyst for synthesis gas conversion and utilization thereof for preparation of diesel fuel
DE3839580C1 (pt) 1988-11-24 1990-07-05 Condea Chemie Gmbh, 2212 Brunsbuettel, De
DZ2013A1 (fr) 1995-04-07 2002-10-23 Sastech Ltd Catalyseurs.
EP1119411B1 (en) 1998-10-05 2003-06-25 Sasol Technology (Proprietary) Limited Impregnation process for catalysts
US7071239B2 (en) * 2002-10-16 2006-07-04 Conocophillips Company Fischer-Tropsch processes and catalysts using stabilized supports
US7012104B2 (en) * 2002-10-16 2006-03-14 Conocophillips Company Fischer-Tropsch processes and catalysts made from a material comprising boehmite
AU2004228845B2 (en) * 2003-04-07 2009-07-09 Nippon Steel Corporation Catalyst for producing hydrocarbon from synthesis gas and method for producing catalyst
US7524787B2 (en) 2005-01-11 2009-04-28 Sasol Technology (Proprietary Limited) Producing supported cobalt catalysts for the Fisher-Tropsch synthesis
EP1853382B1 (en) * 2005-01-11 2014-11-19 Sasol Technology (Proprietary) Limited Producing supported cobalt catalysts for the fischer-tropsch synthesis
EP1947073A1 (de) 2007-01-22 2008-07-23 Phillip Mertens Zubreitungsform mit verzögerter Freisetzungsrate für wasserlösliche und/oder wasserunlösliche Stoffe
US20100160464A1 (en) * 2008-12-24 2010-06-24 Chevron U.S.A. Inc. Zeolite Supported Cobalt Hybrid Fischer-Tropsch Catalyst
UA106739C2 (uk) 2009-02-26 2014-10-10 Сесол Текнолоджі (Пропрайєтері) Лімітед Спосіб одержання каталізаторів фішера-тропша та їх застосування
US7943674B1 (en) * 2009-11-20 2011-05-17 Chevron U.S.A. Inc. Zeolite supported cobalt hybrid fischer-tropsch catalyst
US9248435B2 (en) 2011-09-21 2016-02-02 Sasol Technology (Proprietary) Limited Process for preparing a cobalt-containing fischer tropsch catalyst

Also Published As

Publication number Publication date
NZ618839A (en) 2015-10-30
CN103635256B (zh) 2016-08-17
JP2014527908A (ja) 2014-10-23
ZA201309045B (en) 2014-08-27
AR087975A1 (es) 2014-04-30
EP2758170B1 (en) 2015-10-07
AU2012311175B2 (en) 2016-09-01
PE20140735A1 (es) 2014-06-30
US9248435B2 (en) 2016-02-02
EP2758170A1 (en) 2014-07-30
JP5961694B2 (ja) 2016-08-02
CA2838233C (en) 2019-08-06
BR112013032165A2 (pt) 2016-12-13
AP2013007293A0 (en) 2013-12-31
CA2838233A1 (en) 2013-03-28
AU2012311175A1 (en) 2014-01-09
BR112013032165B1 (pt) 2019-09-03
US20140155501A1 (en) 2014-06-05
WO2013041997A1 (en) 2013-03-28
RU2602803C2 (ru) 2016-11-20
MY164214A (en) 2017-11-30
CN103635256A (zh) 2014-03-12
RU2013154968A (ru) 2015-10-27

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Legal Events

Date Code Title Description
B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B06T Formal requirements before examination [chapter 6.20 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 21/08/2012, OBSERVADAS AS CONDICOES LEGAIS. (CO) 20 (VINTE) ANOS CONTADOS A PARTIR DE 21/08/2012, OBSERVADAS AS CONDICOES LEGAIS

B16C Correction of notification of the grant [chapter 16.3 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 31/08/2012, OBSERVADAS AS CONDICOES LEGAIS. (CO) REFERENTE A PUBLICACAO NA RPI 2539 DE 03.09.2019, QUANTO A DATA DO DEPOSITO