MX2013007351A - Proceso de metatesis de olefinas y catalizador que contiene enlaces tungsteno-fluor. - Google Patents

Proceso de metatesis de olefinas y catalizador que contiene enlaces tungsteno-fluor.

Info

Publication number
MX2013007351A
MX2013007351A MX2013007351A MX2013007351A MX2013007351A MX 2013007351 A MX2013007351 A MX 2013007351A MX 2013007351 A MX2013007351 A MX 2013007351A MX 2013007351 A MX2013007351 A MX 2013007351A MX 2013007351 A MX2013007351 A MX 2013007351A
Authority
MX
Mexico
Prior art keywords
catalyst containing
containing tungsten
olefin metathesis
metathesis process
fluorine bonds
Prior art date
Application number
MX2013007351A
Other languages
English (en)
Inventor
Christopher P Nicholas
Mostafa Taoufik
Eetienne Mazoyer
Jean-Marie Basset
Original Assignee
Uop Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/156,918 external-priority patent/US20120316374A1/en
Priority claimed from US13/156,860 external-priority patent/US8935891B2/en
Application filed by Uop Llc filed Critical Uop Llc
Publication of MX2013007351A publication Critical patent/MX2013007351A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122—Metal aryl or alkyl compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B01J37/035—Precipitation on carriers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/66—Tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Se ha desarrollado un proceso y catalizador para la metátesis de olefinas en general, y específicamente para la producción de propileno a partir de etileno y bitileno. El catalizador comprende un compuesto de tungsteno metálico, que contiene cuando menos un enlace tungsteno-flúor, dispersado o injertado sobre o en un soporte. Un ejemplo específico del catalizador es el compuesto WOF (CH2CMe3)3 injertado sobre un soporte de sílice.
MX2013007351A 2010-12-29 2011-12-20 Proceso de metatesis de olefinas y catalizador que contiene enlaces tungsteno-fluor. MX2013007351A (es)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201061427893P 2010-12-29 2010-12-29
US201061427884P 2010-12-29 2010-12-29
US13/156,918 US20120316374A1 (en) 2011-06-09 2011-06-09 Olefin metathesis process using a catalyst containing tungsten fluorine bonds
US13/156,860 US8935891B2 (en) 2011-06-09 2011-06-09 Olefin metathesis catalyst containing tungsten fluorine bonds
PCT/US2011/066065 WO2012092014A2 (en) 2010-12-29 2011-12-20 Olefin metathesis process and catalyst containing tungsten fluorine bonds

Publications (1)

Publication Number Publication Date
MX2013007351A true MX2013007351A (es) 2013-08-01

Family

ID=46383808

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2013007351A MX2013007351A (es) 2010-12-29 2011-12-20 Proceso de metatesis de olefinas y catalizador que contiene enlaces tungsteno-fluor.

Country Status (8)

Country Link
EP (1) EP2658648A4 (es)
JP (1) JP5662587B2 (es)
CN (1) CN103269791B (es)
CA (1) CA2822796C (es)
MX (1) MX2013007351A (es)
SG (1) SG191375A1 (es)
TW (1) TWI458551B (es)
WO (1) WO2012092014A2 (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB201506684D0 (en) * 2015-04-20 2015-06-03 Isis Innovation Tungsten catalysts
EP3565799B1 (en) 2017-01-05 2020-10-07 SABIC Global Technologies B.V. Conversion of waste plastic to propylene and cumene
CN110139846B (zh) 2017-01-05 2022-07-01 沙特基础全球技术有限公司 废塑料向丙烯和枯烯的转化
KR102296488B1 (ko) 2020-04-06 2021-09-01 한국생산기술연구원 로봇 그리퍼 모듈

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3923920A (en) * 1971-03-29 1975-12-02 Phillips Petroleum Co Olefin disproportionation catalyst and process for using same
JPS58164545A (ja) * 1982-01-13 1983-09-29 ビ−ピ−・ケミカルズ・リミテツド 官能基のあるオレフインの不均化法
FR2547513B1 (fr) * 1983-06-15 1986-03-21 Elf Aquitaine Catalyseur perfectionne pour la metathese d'olefines
DE3460103D1 (en) * 1983-06-15 1986-05-28 Elf Aquitaine Catalyst for olefin methathesis
FR2577216B1 (fr) * 1985-02-12 1987-09-11 Elf Aquitaine Perfectionnement a la metathese d'olefines avec un catalyseur a base d'un complexe de tungstene
FI86298C (fi) * 1990-12-05 1992-08-10 Neste Oy Metatesprocess foer olefiner och katalysator foer tillaempning av denna.
US5639900A (en) * 1993-12-29 1997-06-17 Metton America, Inc. Thermally activated olefin metathesis catalyst precursor
BE1008339A3 (nl) 1994-05-03 1996-04-02 Dsm Nv Heterogene metathesekatalysator.
US5914433A (en) 1997-07-22 1999-06-22 Uop Lll Process for producing polymer grade olefins
US20050124839A1 (en) * 2001-06-13 2005-06-09 Gartside Robert J. Catalyst and process for the metathesis of ethylene and butene to produce propylene
US6867341B1 (en) 2002-09-17 2005-03-15 Uop Llc Catalytic naphtha cracking catalyst and process
US7074976B2 (en) * 2003-08-19 2006-07-11 Equistar Chemicals, Lp Propylene production
US7268265B1 (en) 2004-06-30 2007-09-11 Uop Llc Apparatus and process for light olefin recovery
BRPI0618557A2 (pt) * 2005-11-14 2011-09-06 Mitsui Chemicals Inc método para produzir e método para produzir continuamente propileno contendo carbono derivado de biomassa, propileno de alta pureza, polìmero ou copolìmero de propileno e artigo
US7459593B1 (en) * 2005-11-18 2008-12-02 Uop Llc Metathesis unit pretreatment process with formation of octene
DK2121546T3 (en) * 2006-10-13 2018-03-12 Elevance Renewable Sciences Process for preparing omega-dicarboxylic acid olefin derivative by metathesis
US7586018B2 (en) 2006-12-21 2009-09-08 Uop Llc Oxygenate conversion to olefins with dimerization and metathesis

Also Published As

Publication number Publication date
CN103269791A (zh) 2013-08-28
WO2012092014A3 (en) 2013-01-17
WO2012092014A2 (en) 2012-07-05
EP2658648A2 (en) 2013-11-06
TW201233441A (en) 2012-08-16
TWI458551B (zh) 2014-11-01
CN103269791B (zh) 2015-09-30
CA2822796A1 (en) 2012-07-05
JP2014511256A (ja) 2014-05-15
EP2658648A4 (en) 2015-03-25
JP5662587B2 (ja) 2015-02-04
CA2822796C (en) 2016-05-31
SG191375A1 (en) 2013-08-30

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