MX168277B - Metodo para la produccion de esteres de acido carboxilico insaturado - Google Patents
Metodo para la produccion de esteres de acido carboxilico insaturadoInfo
- Publication number
- MX168277B MX168277B MX007275A MX727587A MX168277B MX 168277 B MX168277 B MX 168277B MX 007275 A MX007275 A MX 007275A MX 727587 A MX727587 A MX 727587A MX 168277 B MX168277 B MX 168277B
- Authority
- MX
- Mexico
- Prior art keywords
- production
- acid esters
- carboxyl acid
- unsaturated carboxyl
- reaction solution
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
- C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
- C07C69/54—Acrylic acid esters; Methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
La presente invención se refiere a un método para la produción de un éster correspondiente mediante la racción de ácido acrílico ó ácido de metacrílico con un alcohol alifático de 1 a 12 átomos de carbono en presencia de una resina de intercambio de cationes fuertemente ácida, como catalizador, método que se caracreriza porque se mantiene la solución de reacción en estado de ebullición y mantiene el catalizador suspendido y disperso en la solución de la reacción con un agitador manipulado con una fuerza motriz en escala de 0.005 a 2 kV por m3 de la solución de la reacción.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61159674A JPS6317844A (ja) | 1986-07-09 | 1986-07-09 | 不飽和カルボン酸エステルの製造方法 |
Publications (1)
Publication Number | Publication Date |
---|---|
MX168277B true MX168277B (es) | 1993-05-14 |
Family
ID=15698854
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX007275A MX168277B (es) | 1986-07-09 | 1987-07-09 | Metodo para la produccion de esteres de acido carboxilico insaturado |
Country Status (12)
Country | Link |
---|---|
US (1) | US4833267A (es) |
EP (1) | EP0273060B1 (es) |
JP (1) | JPS6317844A (es) |
KR (1) | KR910008371B1 (es) |
CN (1) | CN1024190C (es) |
BR (1) | BR8707412A (es) |
CA (1) | CA1290767C (es) |
CS (1) | CS272223B2 (es) |
DE (1) | DE3773872D1 (es) |
HU (1) | HU204024B (es) |
MX (1) | MX168277B (es) |
WO (1) | WO1988000180A1 (es) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2884639B2 (ja) * | 1989-11-28 | 1999-04-19 | 三菱瓦斯化学株式会社 | 不飽和カルボン酸エステルの製造法 |
EP0594008B1 (en) * | 1992-10-22 | 1997-08-13 | Sumitomo Chemical Company, Limited | Process for producing methyl methacrylate |
FR2721313B1 (fr) * | 1994-06-17 | 1996-07-19 | Atochem Elf Sa | Procédé de fabrication d'acrylates d'alkyle par estérification directe. |
US6605738B1 (en) | 1996-05-29 | 2003-08-12 | Union Carbide Chemicals & Plastics Technology Corporation | Processes for refining butyl acrylate |
US6015435A (en) * | 1996-10-24 | 2000-01-18 | International Vision, Inc. | Self-centering phakic intraocular lens |
US5877345A (en) | 1997-02-07 | 1999-03-02 | Rohm And Haas Company | Process for producing butyl acrylate |
FR2810316B1 (fr) * | 2000-06-19 | 2002-07-26 | Atofina | Preparation d'esters carboxyliques catalysee par un acide sulfonique |
JP4205841B2 (ja) | 2000-07-31 | 2009-01-07 | 株式会社日本触媒 | 不均一触媒を用いた反応方法およびその反応装置 |
FR2818639B1 (fr) * | 2000-12-26 | 2003-02-07 | Atofina | Procede perfectionne de fabrication d'esters carboxyliques insatures |
DE602004028591D1 (de) * | 2003-02-28 | 2010-09-23 | Arkema Inc | Verfahren zur durchführung von gleichgewichtsbegrenzten reaktionen |
US20040192957A1 (en) * | 2003-03-31 | 2004-09-30 | Wickens Danita Inez | Method of recovering 2-ethylhexyl alcohol from a mixture comprising 2-ethylhexyl acrylate |
CN100445261C (zh) * | 2005-05-24 | 2008-12-24 | 上海华谊丙烯酸有限公司 | 一种(甲基)丙烯酸环己酯的合成方法 |
CN101041621B (zh) * | 2006-11-24 | 2010-12-01 | 中国石油集团工程设计有限责任公司东北分公司 | 制备(甲基)丙烯酸丁酯的方法 |
CN101735051B (zh) * | 2009-12-10 | 2014-03-19 | 青岛琅琊台集团股份有限公司 | 一种制备衣康酸二异辛酯的方法 |
BR112015023718B1 (pt) | 2013-03-15 | 2020-10-13 | 3M Innovative Properties Company | método para produzir acrilato de 2-octila e método de fabricação de um adesivo |
JP2019172665A (ja) | 2018-03-28 | 2019-10-10 | 三菱ケミカル株式会社 | 不飽和カルボン酸エステルの製造方法 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE590370A (es) * | 1959-04-29 | 1900-01-01 | ||
US3470238A (en) * | 1964-11-06 | 1969-09-30 | Mitsubishi Petrochemical Co | Process for recovering acrylic and methacrylic ester |
DE2226829A1 (de) * | 1972-06-02 | 1973-12-20 | Knapsack Ag | Verfahren zur herstellung von acrylsaeureestern |
JPS5239620B2 (es) * | 1973-05-14 | 1977-10-06 | ||
JPS5912102B2 (ja) * | 1976-11-04 | 1984-03-21 | 日本化薬株式会社 | アクリル酸エステルの製造方法 |
JPS55122740A (en) * | 1979-03-16 | 1980-09-20 | Nippon Kayaku Co Ltd | Preparation of acrylate or methacrylate |
JPS5967244A (ja) * | 1982-09-27 | 1984-04-16 | Nippon Kayaku Co Ltd | アクリル酸エチルの製造法 |
US4733004A (en) * | 1986-06-23 | 1988-03-22 | Ashland Oil, Inc. | Continuous esterification of methacrylic acid and product recovery |
-
1986
- 1986-07-09 JP JP61159674A patent/JPS6317844A/ja active Pending
-
1987
- 1987-07-07 BR BR8707412A patent/BR8707412A/pt not_active Application Discontinuation
- 1987-07-07 CA CA000541491A patent/CA1290767C/en not_active Expired - Fee Related
- 1987-07-07 WO PCT/JP1987/000482 patent/WO1988000180A1/ja active IP Right Grant
- 1987-07-07 HU HU873812A patent/HU204024B/hu not_active IP Right Cessation
- 1987-07-07 KR KR1019880700262A patent/KR910008371B1/ko not_active IP Right Cessation
- 1987-07-07 EP EP87904331A patent/EP0273060B1/en not_active Expired - Lifetime
- 1987-07-07 DE DE8787904331T patent/DE3773872D1/de not_active Expired - Lifetime
- 1987-07-07 US US07/193,523 patent/US4833267A/en not_active Expired - Lifetime
- 1987-07-09 CS CS875239A patent/CS272223B2/cs unknown
- 1987-07-09 CN CN87105726A patent/CN1024190C/zh not_active Expired - Lifetime
- 1987-07-09 MX MX007275A patent/MX168277B/es unknown
Also Published As
Publication number | Publication date |
---|---|
CS272223B2 (en) | 1991-01-15 |
BR8707412A (pt) | 1988-11-01 |
CN87105726A (zh) | 1988-07-06 |
US4833267A (en) | 1989-05-23 |
HU204024B (en) | 1991-11-28 |
HUT48863A (en) | 1989-07-28 |
KR910008371B1 (ko) | 1991-10-12 |
CS523987A2 (en) | 1990-04-11 |
WO1988000180A1 (en) | 1988-01-14 |
EP0273060A4 (en) | 1988-11-09 |
DE3773872D1 (de) | 1991-11-21 |
JPS6317844A (ja) | 1988-01-25 |
EP0273060B1 (en) | 1991-10-16 |
CN1024190C (zh) | 1994-04-13 |
CA1290767C (en) | 1991-10-15 |
KR880701702A (ko) | 1988-11-04 |
EP0273060A1 (en) | 1988-07-06 |
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