LV11014B - Composition for wood impregnating to provide fire-resistance - Google Patents
Composition for wood impregnating to provide fire-resistance Download PDFInfo
- Publication number
- LV11014B LV11014B LVP-93-965A LV930965A LV11014B LV 11014 B LV11014 B LV 11014B LV 930965 A LV930965 A LV 930965A LV 11014 B LV11014 B LV 11014B
- Authority
- LV
- Latvia
- Prior art keywords
- composition
- compound
- hjih
- wood
- triazine
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/06—Organic materials
- C09K21/12—Organic materials containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/02—Polyureas
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Fireproofing Substances (AREA)
- Saccharide Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Description
LV 11014 COCTAB flJIH OBPAEOTKJf flPEEECJfflH OT ΠΡΜ2ΑΗΜΗ EH ΟΓΗΕΟΤΟΜΟΟΤΜ ίίοΟόρθΤβΗΗΘ OTHOCMTCH K /ļepēB006pa60TKe H MOiKcT ūbi'Tb HCrTOJIb3GBaHO IlpM OOpaāūTKe flpeBeCMHbl flJIH npHflaHMH βίί ΟΓΗΘΟ-ΤΟΗ-KOCTH.
PisBedeH cocTaB .zļjih oSpaGoTKM ^peBecMHbi ajih npHflaHMH ePi GrHēCTūHKOCTH, BKJIKMaiOlHHit /i / Tē TpaKHCH06 ΟΟββΗΗΘΗΗβ φΟΟφΟΗΗΗ /ΤΟΦ/, MoqeBHHy π tpnetaHoji&mhh /1/.
OjļnciKO} JļaHHbm CGCTaB ΗΜΘ6Τ ΗΘΤίΟΟΤαΤΟΗΗ^ tO CTaOHJIfcHOCTb.
Ilejib HSoGpeTeHHH - noBhiineHHe CTaGMJībHocTM cocTaBa.
HsoāpeTeHne ποηοηηθτοη ejieflyjomMMM npMMepaMM. ĪIponHTO^Hbie pacTBopbi nojiyyaiOT nyTeM cMeuiHBaHMH κομποηθη-tob zļsyx ynaK.0B0K} npnneM, nepBan ynaKOBKa co^epjiiHT cojib ΤΟΦ h ocHOBaHKe, a BTopaa ynaKOBKa coflep/KHT / i i / coeflHHeHHe TpMa3MHa w MoqeBHHy.
PacTBopbi oGbPiHo flejiaBT cpasy m nepes πρημ6ηθημθμ h 3aT6M npeflno^TMTeJiBHo coxpaHHior npM OKpyjKaioin,eft hjih Gojiee ηηθκοϊϊ τθμ- 0 c nepaType, HanpHMep, 0-30 Chb <iacTHOCTH, 0-20 C, ηθμ ημλθ TeMnepaTypa ΧρβΗβΗΗΗ Η ΠρΗΜβΗβΗΗΗ, ΤΘΜ Bbinie CTaČHJLbHOCTb COC-TaBa. 15-90%, HanpHMep,
PaCTBOpbl OČbIMHO ΗΜΘΙΟΤ ΟδΐΙ^βθ COfleptfaHHH TBepflbIX BemeCTB B 30-75% η b qacTHocTH, 40-70% h flauta 40-60%. ΚοΗΘμΗΗ?! paCTBOp npeflnu^TMTe.nrHO ΠΡΜΓΟΤΟΒΛΗιΟΊ' B φορΜΘ KOHUeHT- paTci flO ΤΘΧ πορ, ΠΟKa OH Ηβ δγ,Π^Τ HeīIOCpenCTBeHHO γοτοβ κ πρπ-
MrsnrH/Ihl TfJIH ίίΓιΟΠΗ7ΒίΒβΗΗλ Z5p6BcCWHbi. ΚΟΓΗα ΟΚ ΟδοίΗΗΟ peiouaBJIH' 6TCH BOflOH. COflēpmaH/ΙΘ TBēpJļbiX BcIUēCTB B ΠρΟΠΗΤυΗΗΟΜ pSCTBOpē oObinno cocTSBJiHeT 1-60%, HanpHMep, 2-30%, b nacTHOCTH, 2-15% hjih 5-10% .
HepeBHHHbift HocOTejiB, κοτοροΜγ· floJDKHa ābiTB npHflaHa cnocoS-HOCTb MeSJieHHO BOSrOpaTbCH, M0JK6T 6bITb OTpy6jieK VIJI Η ΟΠΗΛΘΗ B B/ifle SpeBeH hjih GTpoeBoro Jieca, b nacTHOCTH, MHrKatf npeBecHHa, TaKan KaK cocHa, ramapnc, KpacHbiīī κβηρ hjih nnxTa, hjih TBepnan ApeBecHHa, TaKan KaK ny6, HanpHMep, b BHjļe ctojiGhkob, noineneK, HOCOK, 6pycbeB hjih spaHKH, hjih MoaceT npefiCTaBJiHTb οοδοίϊ H3fle-jihh H3 flepeBa, npOHSBeneHHhie H3 hhx co 3HaHHTejibhro# nacTbio hh-TaKTHOft BOJioKHHCTO/ί cTpyKTypbt HcxoflHOH apeBeeHHbi, a TaKJKe b BHfle j«ecTKHX hjih nojiyjKecTKHx hocok H3 nacTHii, nojiyHeHHHx npeCC0BaHH6M /H BOSMOiKHO C ΠΟΚΌΜΤΗΟΜ CMOJIOf·!/, Τ3ΚΗΧ K3K (|®.Ηβ-pa, ΑρβΕβΟΗΟ-ΟΤργΜΒ^ΗβΗ nJttHTa, ΤΒΘΡΛΒΙΗ KapTOH H KyCKH flOCOK, ho He 6yMara hjih KapTOH. Πρπ ηθο6χο£ημοοτη H3nejiHH hs nepeBa ΜΟΓΥΤ ČHTb OāpaCOTaHU paCTBOpaMH COrJiaCHO Η3θ6ρβΤβΗΗΚ) flO npeccoBaHHH. JepeBHHHbrii HocHTejib μο/κθτ ημθτβ TOJinņiHy b 0,05-10 cm, HanpHMep, 0,2-10 cm, ho npeanoHTHTejibHO 0,2-2 cm. ITpHMeHeHHe na npeBecHHy /BKJHonan H3flejiHH, npoHSBepeHKbie H3 Hee/ M0JK6T OCymeCTBJIHTbCH H6CKOJIbKHMH nyTHMH. PaCTBOpbl COr~ JiacHO H3o5peT6HHK) MoryT 6biTb HaHeceHH nyreM norpy;«eHHH hjih ok-pauiHBaHHH upeBecHHbi /hjih npoH3BeaeHHoro H3 Hee HsneJiHH/, koto-pan nojuka noflBeprHjrrbca očpaāoTKe b pacTBope no TaKoro cpona, noKa He nocTHraeTcn nocTaTOHHoe norjiomeHHe. OflHaKO, npennonTH- - 3 - LV 11014 tejILHO C nOMOIUbKD ΤΘΧΗΟ-ΠΟΓΗΜ BaKyyMHO# ΠρΟΠΗΤΚΗ H/HJBT ΓφΟΠΜΤΚΗ nofl flaBJieHHeM, npeflHa3Ha^eHH0# ajijī oāecne^ieHHa τοΓΟ,^τοόω paCTBOpbl 6bIJIM IIOJIHOCTBiO ΠΟΓϋΟΙΠ,ΘΗΗ B ΗΟΟΗΤΘΛΘ. TaKHM 00pa30M, IīeJ1JUOJET03HbCA HOCHTeJIB ΜΟ»£Τ ČblTB ΒΒββθΗ B KOHTaKT C BOflHbIM pacTBopoM, ^aBJieHHe ποβηπβθτοη Bbirne aTMoetJepHoro, ripu θτομ Ma-TepHan eme HaxoflMTca b KOHTaKTe c KOMno3Hiļneft, m aaBJieHHe BOBBpamaeTca κ aTMoc(ļ)epHOMy, npw stom BeJiPmuHa flaBJieHHH h Bpe-mh j Ha κοτοροβ coxpaHaeTca flaBJieHne, hbjihiotch αοοτ3τοηηημμ ajih Toro,^To6bi nojiyqHTL· ηθο6χοαημοθ BnuThiBaHHe. ΠρββποΗΤΗΤθΛΒΗο SpeBecHHa noflBepraeTCH βο3αθΛοτβηιο saBJieHHH Hnace aTMoetJjepHoro HJM nOCJie BBefleHMH B KOHTaKT C BOflHHM pacTBopoM MJW B θ6θΗΧ cjiyvaHX. HanpuMep, HocHTejiB μομβτ 6ητβ πομθπιρη b KaMepy, aaB-jieHne b KaMepe οηημθηο, aoāaBJiHeTCH προπμτο’Ίηη# pacTBop, o6bw-ho npH KOMHaTHoft TeMnepaType, ajih ποκρηγμη ηοοητθλη, fiasjieHHe noBbffiiaeTca flo aaBJieHHfl, npeBbiuiaioiuero 3τμοοΦθρηοθ, nojmepxHBa-eTCH b TaKOM COCTOHHMK H aaTēM CHHJKaeTCH RO βΤΜΟΟφβρΗΟΓΟ H pacTBop cjiHBaeTCH hs KaMepbi, 3a ^θμ μο/κθτ cjieaoBaTb KpaTKHft nepnofl ποηημβηηογο aaBJieHHH.. B KaqecTBe BapnaHTa, Ha^ajīBHoe ΟΗΗΜΘΗΗΘ flaBJieHHH M03K8T Ηθ ΠΡΚΜΘΗΗΤΒΟΗ.
KoHiieHTpaunH /ii/ coefiHHeHHe TpHa3HKa, οοθαηηθηηθ Τ0Φ h MoqeBHHbi b BOflHOH cHCTeMe, pa3Mep flaBJieHHft, ερβΜΗ Bbij[ep«KH ripu noflflepjKHBaHHH Bbmie h HHJice aTMoc<JiepHoro h npnpofla αρθβθοηογο MaTepnajia bjihhjot Ha BiruTbiBaHHe b MaTepnaji. TaK, yBejiHqeHMe KOHUeHTpaUHH HJIH flaBJieHHH BbnDe aTMOClJepHOrO, ΒρβΜΗ BblflepJKKH npw flaBJieHHHX Bbfine 3ΤΜΟθφθρΗΟΓΟ ΠΡΗΒΟΛΗΤ K yBeJDWeHHHJ BITHTblBa-HHH aKTHBHHX ΚΟΜΠΟΗΘΗΤΟΒ B MaTepHajI. CMeHa HOCHTeJIH Ha TaKOtf, KOTOpbIH ΗΜβΘΤ II0Bblin6HHyK) CnOCOCHOCTB ΠΟΓΛΟΠίβΗΜΗ, IīpMBOflHT K - 4 - ΤΒΘΛΗΊΘΗϋΠ ΒΠΗΤΜΒΘΗΗΗ, KSK 3T0 0ΗΒΒΘΤ ΠρΗ OČpaČOTKe MaTepHaJia c MajībiM nonepe^HHM cenenneM. Βθλη^ηηη βπητκβ3ηηη b HocHTejib,
Bbipaw0HHbie b 3Ha^eHMHX Beca o6m,ero KOjmnecTBa TBepflbix BemecTB H3 pacTBopa, BnHTHBaeMoro b gahh Ky6mecmii Μβτρ HOCHTejiH, mo- i, ryr H3M6HHTI>Cfl OT 10 flO 2000 ΚΓ/Μ , B 3aBHCHM0CTH OT HOCHTeJIH η στ οτθπθημ Tpe6yeMoH οΓΗβοτοήκοοτπ. OčbmHo npoMejKyTKH βρθμθηη flaBJieHHH HHJ«e aTMoeOepHoro ot πητη MHHyT flo flByx nacoB, očbNHO 5-30 hjih 12-30 MMHyT, HcnoJib- l 3yioTCS c BaKyyMOM mxe 0,5 čapa /5000 κγ/μ /, HanpHMep, 0,05-0,4 čapa /500-4000 ΚΓ/ΐνΛ. JlaBJieHMH Bbirne aTMOciJepHoro ot 2 ito 20 Gap, HanpHMep, 5-15 čap /20000-200000, HanpHMep, ot 50000 flO 150000 ΚΓ/Μl/ flJIH ΠρΟΜβΙΚγΤΚΟΒ ΒρβΜΘΗΗ οτ 10 nacoB flO 5 MHHyT, HanpHMep, ot 5 ^acoe flo 10 hjih 20 MHHyr, HanpHMep, npHroflHbi npoMeiityTKH ot 2 nacoB ao 30 MHHyT, npn 3tom čojiee npoflOjniCHTejibHHe npoMe«yTKH BpeMeHH πρημθηηιοτοη πρκ nenoJibsoBa-HHH ČOJiee ΗΗ3ΚΗΧ flaBJieHHft H ČOJiee flJIHTeJIbHbie ηρΟΜβ^ΤΚΗ BpeMeHH TpečyioTCH ajih cjiačo norjioinaiomeft speBecHHU, ηθμ ajih apeBecH-hu c JiymneM norjiomeHHeM. flaBJieHHe ηηικθ aTMoeiJjepHoro η Hcnojib-ayeMue npoMejKyTKH βρθμθηη, ecjiH πρημθηηιοτοη nocjie jiaBJieHHft bh-rne aτMOcφepHOΓO, HaxoflHTca b npeaejiax, ycTaHOBJieHHbix μά πρκ-ΜΘΗΘΗΗΗ flO OČpačOTKH ΠΟΑ flaBJieHHeM BHnie 3ΤΜΟΟφβρΗΟΓΟ.
Koraa HOCHTeJIb, TO eCTb, flpeBeCHHa /HJIH npOH3BOflHbIH H3 Hee npoayKT/ προπητηβιοτ pacTBopoM corjtacHo H30čpeTeHHKi, hoch-TeJib očhMHO BbicyniHBaiOT flo τογο, ^točh coflepjftaHHe b ηθμ BJiarn BepHyjioci) πρπΜβρΗΟ κ TOMy Λίβ, mto h b HeočpačoTaHHOM HocHTejie, HanpHMep, 2-25% coflepwaHHH BJiarn. CyniKa uorni čhtb npoBefleHa HarpeBOM npn 50-100°C h 25-95%, HanpHMep, 25-75% hjih 50-95% - 5 - LV 11014 OTHOCHTeJIbHOH BJIcUKHOCTH, ΠρθΑΠΟΜΤΗΤβΛΒΗΟ flO ΠΟΟΤΟΗΗΚΟΓΟ Beca, ο χοτη eyuiKa πρνι 20-25 C, oOotho npn 20-60% OTHOCHTejibHoii bjis^-HOCTH MGJK8ī npHMeHHThCH, HanpHMep, B ΤΘ^ΘΚΗΗ 0,5~2 M6CHU6B. npefliiomiTaioT nporpaMMHpyeMyio cyniKy, Ha^MHaroiionocH npn 50-80°C 50-95% OTHocMTejibHoft BJiajKHOCTH. C uejiLK) Jiyqmero ycTa-HOBJieHHH COeflMHeHHH Τ0Φ H COeflHHeHHH Tpna3HHa H IIOBbimeHHH ctoūkocth κ BbnueJia^HBaHmo očpaāoTaHHoro aepeBa, BHcymeHHbrii ho-CHTeJLb Μ03ΚΘΤ 5faITb OTBepJKfleH, HanpHMep, C nOMOIIļblO aMMOHHH HJIH cneiiHajībHO njrreM HarpeBa. OTBep«fleHHe MOjueT npoBOflHTbcn nyreM īipOĪUiTbEBaHHH BOflHHM paCTBOpOM JKHflKOrO aMMOHHH, B tjaCTHOCTH, Korfla cocTaB ημθθτ pH 7-8, HanpHMep, npn Hcnojn>30BaHHH τθχηο-ΛΟΓΗΗ ΠΡΟΠΗΤΚΗ, OnHCaHHOft Bbnne, HO ΗΘΟδΧΟΑΗΜΟ OCTeperaTbCH TO-ro, hto6h BbimeJiaHHBaHHe nponHTHBaiomHx χημηκ3τοβ očpaTHO b aM-ΜΟΗΗΪΪ 6bIJIO ΒΒΘΑΘΗΟ flO MHHHMyMa, ΗΤΟ Μ03ΚΘΤ CHH3HTb OrHeCTOŽKOCTb HOCHTeJIH. TaKHM 0Čpa30M, npeflnOHTHTeJIbHO hoch-Tejib HaxoflHTCH b KOHTaKTe tojibko e flocTaToqHbiM ko jnmecτbom ΒΟΑΗΟΓΟ HJIH JfCHflKOrO aMMOHHH, ΚΟΤΟρΟΘ <5yfleT HM ΠΟΓΛΟΐαΘΗΟ. īlocjie hjih BMecTO peiKHMa cyniKH HOCHTejib μολϊθτ 6ητβ OTBepjīt-fleH B ΓΟΡΗ^ΘΜ COCTOHHHH ΒΜΘΟΤΟ ΟΤΒθρϋ®βΗΗΘΜ 3ΜΜΟΗΗΘΜ nyTeM HarpeBa ao 100-180°C, HanpHMep, ot 100 no 150°C b τθηθηηη ot 10 MHHyT flo 2 qacoB, HanpHMep, πρκ 100-180°C b TeneHHH 15-70 MHHyT. B TeHeHHH OTBepjIifleHHH HarpeBOM OTHOCHTejn>HaH BJIcUKHOCTb flOJDKHa coxpaHHTCH npn 50-95% c uejibio ynpaBJieHHH rpaflneHTOM BJIcUKHOCTH B flpeBeCHHe flJIH CBefleHHH flO MHHHMyMa HcnpaBJieHHH, hjih speBecHHa MoateT čtiTb noflBeprHyra peKOHfleHCHpoBaHHio nocjie cyniKH hjih OTBepjKEeHHH c nejibio cooGmeHHH en ηοχο,ιιηογο conepaca- HHH BJiaJKHOCTH. - 6 -
OTBepffifleHMe πρπ ποβηιιιθηηοϊϊ TeMnepaType npeflnoHTHTejibHo OCyin,eCTBJIHeTCH 663 KaKOft-JIHGo flOČaBKM aMMOHHH HJIH COJieft aMMOHHH HJIH flOČaBJieHHH yCKOpHTeJieH flJIH OTBep»aeHHH MejraMHH(|)OpMaJIb-flerHflHOŽ CMOJIH, Τ3ΚΗΧ KaK COJIH aMMOHHH HJIH COJIH ΤρβΤΗΗΗΟΓΟ aMHHa hjih cojih MeTajuiOB, flaroniHe pacTBopH khcjiot b βο,ώθ, Tanne KaK paCTBOpbl flBJOCBaJieHTHbK MeTaJLUOB C CHJIbHblMH KHCJIOTaMH, Han-ρΗΜβρ, HHTpaT UHHKa HJIH XJI0PHS MaTHHH. IIpeflnOHTHTeJIbHO CyinKy H otΒβpmjieηηθ πρπ ποβηιπθηηοΗ TeMnepaType ocymecTBJiHioT βμθοτθ πρπ o 50-100 C H 25-95% OTHOCHTeJIbHOH BJiattHOCTH, KaK OIIHCaHO ΒΗΠΙΘ, Β ocoāeHHOcTH πρπ yKa3aHH0M pejttHMe nporpaMMnpyeMoH cjtiikh. ĪIponHTaHHoe οτβθρλνιθηηοθ aepeBO ημθθτ GoJiee BhicoKjno or-HecToiiKocTb, ηθμ HeoGpaGoTaHHoe nepeBO h mojubt 6ητβ Oojiee cto$khm κ B03fleHCTBHH3 pa3JiaraioniHx apeBecHHy γρη6κοβ. Πο cpaB-ΗΘΗΗΚ) C ΗρβΒβΟΗΗΟίϊ, OāpaČOTaHHOft orH63aniHTHbIM 0OC$aTOM aMMOHHH, oGpaāoTaHHan corjiacHo Η3ο6ρθτθηηιο noflBepraeTCH ηεμηογο ΜβΗΒΠΙΗΜ ΠΟΤβρΗΜ aKTHBHOCTH 0ΓΗβ33ΙΕ(ΗΤΗ0Γ0 Cpe^CTBa IIpM npOfiOJI-ίΚΗΤβΠΒΗΟΜ BHHieJia^HBaHHH.
JfeoSpeTeHHe HJiJiiocTpHpyeTCH cJieflyioniHMH npHMepaMH.
TpHa3HHbi A,C η E GbuiH nojiyneHU οτ Φηρμη Bphthiii MHnacTpnaJi IlnacTHKC, Βηρμηηγθμ, Ahfjihh, KaK BemecTBa, 0003HaHeHHbie BT 336, 370 h 309. Tpna3HHbi B h J GhiJiH noJiyHeHbi οτ φκρΜΗ Ch-Sa-JI«ežflHiH, ^κοφορί, AHrjiHH, KaK npoflyKTH, o6o3HaHeHHbie hyofix CH h Cibaneen M/1000 GB, οοοτβθτοτβθηηο. ΒρβΜΗ OTBepjKfleHHH Ghjio onpefleJieHO πρπ 70° C če3 peryjwpo-BaHHH pH. IIpH 3T0M HCXOflHOe 3Η3ΗΘΗΗβ Iip03paHH0r0 paCTBOpa COC~ TaBJineT hjih Tpna3HH0B ABE, 4,8 hjih TpHaaHHa C h 5,6 ajih Tpna-3HHa - 7 - LV 11014
TaOjiHua 1 CBoftcTBa Tpna3HHa
TpHa3HH % pearH- ΒρβΜΗ cpeflHHe ^HCJIO ^HCJIO py?oiipix OTBepjK- κολη^θ- rpynn rpynn TBepflbK fleHHS, CTBa HOCH^ CH^OCH^ BemecTB MHH. rpynn B pacT- POCHj Bope Ha MOJie- «yjiy 80 50 35 108 5 okojio 3 okojio 2 100 264 95 290 6 OKOJIG 1,5 okojio 4S 90 23
A
B
C Ά
E Očmee ^hcjio οκομμθτηλβηηχ μ6τοκοημθτηλβηηχ rpynn ηβληθτοη IipOH3BO#Hbflvi OT ^MCJia ^pMaJIbflerHflHbDC 3Β6ΗΒΘΒ Ha MOJieKyJiy TpMa-3ΗΗ3, HCnOJIB3yeMyH3 flJIH nOJiyweHHSī COeflHKeHHH, Η OHO /H pa3pHB M6JKJ[y OKCH- Η ΜβΤΟΚΟΗΜΘΤΗΛΒΗΗΜΜ TpynnaMH/ Πρ0Η3ΒΟΛΗΤ0Η ΙφΗ flO~ nymeHHM, MTO ΗΘ MMeJIO MeCTO CaMOKOHfleHCHpOBaHHe. IIpHMep 1 h cpaBHMTeji&Hbifl πρΗΜβρ A. Πο oTHomeHHio κ Kaa(flOMy hs TpnasunoB A-E flBa pacTBopa 1 h 2 ābiJiH npMroTOBJieH bi pasaejiBHO. PacTBop 1 eoflep»aJi 28 uacTeft 80% βο,ζϊηογο pacTBopa xjiopwfla TeTpaKHCHoro οοθληηθηηη φοοφοΗΗΗ /Τ0Φ/, (KOTOpblft ΗΜΘβΤ ΜΘΟΤΟ pH IīpMMepHO ΗΗΛίβ 0), 20 ^acτeiί bo- - 8 - flbi h 12 ^acTeft TpnasTaHOJiaMUHa.
FacTBop 2 co^epjītaji 31,5 ^acTeft BOflbi, 9 yacTeft μο^θβμηη h 11,5 ^acTeft Tpna3MHa. PacTBopbi 1 m 2 6buw CMemaHbi «jih nojiy^e-
Hm ΠρΟΠΜΤΟ^ΗΗΧ paCTBOpOB C pH 6,8 , KOTOpbie COXpaHHJIHCh npH o 25 C, Η ΒΡΘΜΗ, Β3ΗΤΟΘ flJIS ΗΗΧ flJIH ΤΟΓΟ, <IT06b[ ΠΟΜΤΤΗΘΤΒ, pe~ rHCTpHpOBaJIOCb.
Pe3yjibTaTbi 6bim cJiefljTOiitne.
TaāJiHiia 2
CBOŽCTBa nponMTOMHbDC pacTBopoB ITpHMep TpnasHH ΒρβΜΗ B nOMyTHeHHfl flHHX flJIH: ocTyaeBaHHH 1 A 10 12 2 B 10 10-14 3 C 14 15-16 4 Ά 14 17 CpaBH. Δ E .7 8 B flonojiHeHHe κ Tpwa3HHy C, tojibko nepeMeinHBaHHe pacTBopoB 1 h 2 npuBejio κ HeMefljieHHOMy πομτγηθηηιο, vt'o rrpHBejio κ co3fla-hhjo npo3pa^Hofi JoiflKOCTH Hafl HeSojiBUMM KOJitmecTBOM Gejioro ocafl-Ka. ĪIpo3payHafl «HflKOCTB 3aTew oeTaBajiacb npo3pa^HOH ao Ha^ajia nocTOHHHotf mjtthocth crrycTH 14 flHeft. IIpMMepbi 5-9.
PacTBopbi, KaK h b npHMepe 1, ho c πθρθμθηηημη KOJiimeeTBa-mh TpHSTaHOJiaMHHa, 6wjih npuroTOBJieHbi h čhijia onpe^ejieHa hx cTa- - 9 - LV 11014 GHJIbHOCTb. B 3THX CJiy^aHX paCTBOpH He XpaHHJIMCb npM nOCTOHHHOH TeMnepaType, a coflepatajiHeb βμθοτθ b jiaOopaTopHH npn oKpy*aiom,eft TeMnepaType. Jļasi KaagļOM προπητο^ηοΛ κηακοοτμ, pH MSMepHJicH h BpeMH wejiaTMHH3auHH onpeflejiHJiocb.
Pe3yjn>TaTH Gburn cjie^romuMH.
TaGjmua 3
CTaāHJībHocTL· nponHTogHbK paCTBOPOB ΠρΗΜθρ ^acTeft TpH3Ta-HOJiaMHHa PH ΒρβΜΗ JKBJiaTHHH3aiļHH, 5 15 7 13 6 11,5 6,7-6,8 11 7 9 6,6 7-10 8 6 6,4 7-10 9 3 5,7 5 ΠρΗΜθρΗ 10-12
PacTBopH, KaK b npHMepe 8, ho c pasjnreHHMH KOJBroecTBaMH ΜΟ^ΘΒΗΗΗ GhIJIH ΠΟβΓΟΤΟΒΛΘΗΗ H HX CTaČHJIbHOCTb OIipefleJIHJiaCb npH OKpyjKaioiiiefl TeMnepaType, ksk b npHMepe 8.
Pe3yjibTaTbi Ghum cjieflyioinHMH.
TaOjiHua 4
CTaGHJIbHOCTb ΠΡΟΠΗΤΟ^ΗΗΧ paCTBOPOB ΠρΗΜθρ qacTeft pH rejieoGpasoBaHHe 10 - 10 12 5,6 10 11 9 5,6 10 12 6 5,5 14 ΠρΗΜβρΗ 13-17
BbUiM npHroTOBJieHH pacTBopbi, KaK b npHMepe 8, ho c nepe-MeHHbflviH KOjnmecTBaMM Tpna3HHa A, h hx pH h CTa6njii)H0CTi) onpe-ZtejiHJiacb npn oKpyacafomeft TeMnepaType, KaK b npHMepe 8. Pe3yjn>TaTbi όωϋΗ ejieflyjoiuHMH.
TaāJiHi^a 5
CTaāHJIBHOCTb ΠΡΟΠΗΤΟΗΗΜΧ paCTBOPOB IIpHMep nacTen TpHa3HHa A PH reJieo6pa30BaHHe, AHeii 13 15 5,9 8 14 11,5 5,6 8 15 9 5,8 8 16 6 5,9 9 17 3 5,9 9 ĪTpHMep 18
BbiJio πρΗΓοτοΒϋβΗΟ h eoxpaHHjioeb πρκ pa3JiHHH0ū TeMnepaType 5 0TflejibHbix paeTBopoB, KaK b npHMepe 1, c nejibio onpeaejieHHH hx CTaČHJIbHOCTH ΠρΗ pa3JIHWHHX yCJIOBHHX.
Pe3yjibTaTbi 6mjih cjie^yioinwMH. - 11 - LV 11014
TeMnepaTypa °C BpeMH atejuaTMHHaaiļHH, flHefi 40 1.5 25 12 oKpyj«aiomafl KOMHaTHaa 14 • oKpy}ftaioniaH yjiMMHan (JieTOM) 21-25 15 40-42 IIpHMep 19-22
Bhjio npuroTOBJieHo τρκ nponKTO^Hfaix pacTBopa eie, KaK b
npHMepe 1, a 3aT6M ohh Gbijin pa3čaBJieKH ηθκοτορημμ KOJMMecTBaMH BOflti, KOTopbie cocTaBJiHJiH οοοτβθτοτβθηηο oflHa TpeTb, paBHoe ko- λη^θοτβο TpoftHoft KOJMMecTBO Beea προπητομηογο pacTBopa, mtoGh IIOJiyMHTi) paCTBOpbl 20,21 H 22 COOTBeTCTBeHHO.
Bee MeTbīpe pacTBopa /προπητομηηη pacTBop 1 h pacTBopbi 20- 22/ C OTHOCHTeJH>HHMH ΚΟΗΙίθΗΤρβΙίΗΗΜΗ 4: 3: 2:1, KOTOpbie nojiyMeHhi,
GbIJIM OTfleJIbHO ΓφΗΜΘΚΘΗΗ flJIH ΙφΟΠΗΤΚΗ flpeBeCHHbi H GbIJia ΟΠρββθ-
JieHa ΟΓΗθοτοήκοοτb αρθβθοηηη. ITpoiieee Ghji cjie^jTonjHM. 100% flpaHKH KJIMH00dpa3H0fl φΟρΜΗ M3 Hflpa flpeBeCHHH' pa3MepOM 40*10*30 b cpeflHeM 0,5 cm h coflepjfiaHMe BJiar» 7% 6ηλη ποαβθργη^τη τθχηο- ΛΟΓΗΗ ΠΟΛΗΟή ΠρΟΠΗΤΚΗ B Κ3Μβρβ ΠγΤβΜ BaKyyMHpOBaHHH flpaHKH ΙφΗ 2 0,2 Gap /2000 κγ/μ /, (το ecTL, paBpeateHne 0,8 Gap) Ha 15 mh-
HyT, flpaHKM GbIJIM nOKpblTbi paCTBOpOM, 3a ΜΘΜ CJieflOBaJI 1 Mac nofl
AaBJieHHeM b 12 Gap /120000 κγ/μ / cjihb jkhskocth qepe3 npaHKy, L· paspejKeHMe #jih apaHKH Ha 15 MWHyT npH 0,2 Gapa /2000 κγ/μ /, a 12 - 3aTeM yflajieHwe khakocth hs flpaHKH. ftpaHKa 3aTeM SbiJia BbicynieHa Ha B03syxe npn 20-25°C η npH 30-40% OTHocHTejibHoft BJiajttHOCTH b ΤΘ4ΘΗΗΗ 1 MeCHUa, ΠΟΟΛβ 3ΤΟΓΟ ΒρβΜβΗΗ COflepJKaHHe B ΗθΡί BJiam B03BpaTMJI0Cb npMMBpHO K 7%. B SaBHCHMOCTH OT pa3MepOB flpaHKH H hx yBejnmeHHH no Becy, yaepjitaHHe χμμμκ3τοβ H3 pacTBopoB 6ηλο noflc^HTaHo flJiH KastuO/i apaHKH. JIpaKKa GbiJia ί&κχβ HcnbrraHa Ha noBepxHocTHyio orHecroftKocTb corjiacHO Hcnbrramiio pacnpocTpaHeHHH no ποΒθρχΗοοτΗ Majioro MaciiiTaāa, B5 476, ^acTb 7 /1971r. / Pe3yjibTaTb! Sbuih cjie,qyiomKMM.
Tafijmija 6 CBoftcTBa oāpaSoTaHHOii gpeBecHHbi ΠρΗΜβρ ΠΡΟΠΗΤΟ^ΗΗΖ pacTBop cpeflnee norjiomeHHe $ XHMHKaTOB, ΚΓ/Μ KJiacc HcnbrraHHH BS 476,wacTb 7 19 1 186 1 20 20 148 1 21 21 102 1 22 22 64 1-2 ΠρΗΜβρ 23 īlpouecc no npHMepy 22 noBTopajicn c 3aMeHož τθχηολογηη βοαηοΛ nponuTKH b KaMepe npocTbiM boahhm norpy«eHneM spaHKH b προπΗΤΟ^ΗΜή pacTBop 22 Ha 1,5 ^aca. Πογλοπι,θηηθ χημηκβτοβ coc-TaBHJio 17 κγ/μ3, h orHecToftKocTL 6biJia 3 Kjiacca. ΠρΜΜβρ 24 ITponecc no npnMepy 19 CbiJi noBTopeH c 38μθηοΛ τβχηολογηη - 13 - LV 11014 BOflHOtf ΠΡΟΠΗΤΚΗ B KHMepe ΠΟΚρΗΤΗβΜ KHCTbiO C paCTBOpOM flpaHKH flO HaebimeHHH. ĪIorjIOmeHHe ΧΗΜΗΚ3Τ0Β COCTaBHJIO npHMepHO 50 ΚΓ/Μ m orHecTožKocTi) GbiJia 2 KJiacca. ΠρρίΜβρ 25 ΠροπΗΤο^Ηωϋ pacTBop, KaK b npHMepe 20, 6hji npnroTOBJieH h pa36aBJieH Bo^oft β οοοτηοιπθηηη 16 nacTeft pacTBopa M3 npHMepa 1 Ha 65 nacTefl BOflbi. Ilpouecc npHMepa 19 6ηλ ποβτορθη c θτημ pa3-ČaBJieHHHM paCTBOpOM H C nporpaMMHpyeMbIM peJKHMOM CymKH, npn KO-τοροΜ nponHTaHHyio spaHKy noflBepraiOT HarpeBy, HanaTOMy npH 62° C c GTHocHTeJiLHož BJiaiKHoeTBio 70% η 3aKaH^HBaiomeMycH npH 75°C h 30% oTHOCHTejibHofi BJiaJītHoeTH b TeneHHe 7 flHeft. CyniKa Tara®, KaK nojiaraioT, npHBejia κ HeKOTopoMy cxBaTbmaHHio οοθαηηθηηη Τ0Φ. CpeflHee πογλοιπ,θηηθ XHMHKaTOB cocTaBHJio 40 kt/m5, h oCpaSoTaH-ηηθ Τ0Φ flpaHKH Shjih KJiaccmJanņipoBaHH no Kjiaccy 2 npn McnbrraHHH njiaMeHeM B5 476, ^acTb 7 /1971r. / h no KJiaccy C npn HcnbrraHHH njiaMeHeM, noflo6HOMy CTaHflapTH3HpoBaHHOMy HcnbīTaHHio Ha Bocnjia-μθηθηηθ CIIIA, ASTM 108/54. Πο cpaBHeHHRD c HeoāpaSoTaHHoft flpaHKoft, oGpaSoTaHHaa spaH-Ka HMeeT cymecTBeHHO TaKyio m nponHOCTb Ha Η3ΓΗ0, yflapHyw npo^HOCTb h TBepflocTb. UpaHKa, oGpačoTaHHaH npoflaBaeMbiM ογηθ-3amHTHHM epe^CTBOM Β BHfle (J)OC(i)aTa aMMOHHS nOCJie BbimeJianHBaHHH BOfloft β annapaTe CoKcxjieTa b TeneHHe 20 nacoB ημθθτ 75% noTepb β cosepjftaHHH φοοφορβ /no cpaBHeHHKD c 16% coflepjKaHHH φοοφορ3, OTMenemn^ "pM EumesrrcaoainioĀ ^paHKe, oCpaāoTaHHož Τ0Φ/.
TaKMM 06pa.30M, Η3θ6ρβΤΘΗΗΘ nOSBOJInēT nOBblCHTb CTaOHJIb-HocTb cocTaBa. (56): IlaTeHT BejiHKoGpHTaHHH N 761195, kji. 2/5/R, 1956. LV 11014 ΦΟΡΜΥΠΑ M30BPETEHH51 1. CocTaB ηna o6pa6oTKH flpesecnHbi οπα npnflaHMf! θμ ογηθοτομκοοτμ, BK/iKDMafOLUnii l\l TeipaKucHoe οοθαμηθημθ φοοφΟΗΜΑ, MOHeBMHy n TpnaTanoHaMUH, oTnunaio^niicii τθμ, hto c penbīo noBbiiueHUfl ciaāunbHocTH cociaBa, oh flononHmenbHO coflep>KHT /ii/ οοθαμηθημθ Tpna3HHa β βμαθ nacTMHHO anKunupoBaHHoro μθτμποπμθπβμμηθ, MMetomero ot 3,5 ao 6 γμαροκομμθτιλποβηχ rpynn Ha aapo Tpna3HHa μ βρθμα οτβθρ^καθημα ηθ μθηθθ 50 MHHyT npM TeMnepaiype 70°C, npn stom cocTaB coAep>KHT 28 Mac. nacTeii 80% βοαηογο pacTBopa TeTpaKMCHoro οοθαμηθημθ φοοφΟΗΜΑ, 3-15 Mac. ηθοτθμ τρΜ33ΜΗ3, 6-12 nacTeM MoneBMHbi m 3-15 Mac. nacTeM TpMSTaHonaMMHa, a pH 50% βοαηογο pacTBopa cociasa cocTaBnaeT 5,8 - 6,2. 2. CocTaB απα očpaCoTKM ApeeecMHbi απη npMAaHMfl Θίί ογηθοτομκοοτμ no π. 1, OTHMHaiOmMMCil ΤΘΜ, HTO Β Κ34Θ0ΤΒΘ ΤΘΤρβΚΜΟΗΟΓΟ ΟΟΘΑΜΗΘΗΜΑ φΟΘφΟΗΜΑ MCnOnb3yfOT MHAOrMApOKCMMeTMflbHblM XT10pMCTblM φΟΟφΟΗΜΜ ΠρΜ cneAyK)iueM οοοτηοοιθημμ κομποηθητοβ, Mac. ηθοτθμ: TMApOKCMMeTMnbHbiM xnopMCTbiM φοοφοΗΜΜ - 22, TpMSTaHonaMMH - 9-15, /ϋ/ οοθαμηθημθ Tpna3MHa - 6-12. 3. CocTaB απη očpaāoTKM αρ©βθομημ no n.n. 1 μπμ 2, omuHaiomniicfl ΤΘΜ, MTO ΟΟΘΑΜΗΘΗΜΘ ΤρΜ33ΜΗ3 MCnOnb3y*OT CO ΒρβΜΘΗΘΜ ΟΤΒΘρΧφθΗΜΑ 40-140 MMHyT, npeMyLuecTBeHHO 40-75 MMHyT. LV 11014 ΡΕΦΕΡΑΤ
CocTaBbi απα npnflaHUfl αρθβθοι/ιηθ ογηθοτομκοοτμ, HanpuMep, β βμαθ βοαηνχ pacTBopoB, coflepjKamne TeipaKucHoe οοθαμηθημθ φοοφοΗΜΑ, μθτμποπμθπβμμη c ΗΘ ΜΘΗΘΘ, ΗΘΜ 3,5 anKUnMpOBaHHblMU Ι/lflH HeanKUnupOBaHHblMU ri/iApoKcnMeTnnHbiMn rpynnaMM Ha flApo Tpna3UHa, πoπyφyHκ^noHaπbHoe a30THoe οοθαμηθημθ c no KpatiHei/i ΜθρΘ 2 rpynnaMi/i, Hanpi/iMep, MoneBi/ma, μ οοηοβ3ηι/ιθ, HanpuMep, TpnsTaHonaMMH.
Claims (3)
- LV 11014 IZGUDROJUMA FORMULA SASTĀVS KOKSNES APSTRĀDEI TĀS UGUNSIZTURĪBAS NODROŠINĀŠANAI 1. Sastāvs koksnes apstrādei tās ugunsizturības nodrošināšanai, kurš satur (i) fosfonija ceturtējo savienojumu, urinvielu un trietanolamīnu, atšķiriras ar to, ka, lai paaugstinātu sastāva stabilitāti, tas papildus satur (ii) triazina savienojumu daļēji alkilētā metilolmelamīna veidā, kurš satur no 3,5 līdz 6 hidroksilgrupām uz vienu triazina kodolu un sacietēšanas laiks ir ne mazāks par 50 min. pie 70°C temperatūras, pie kam sastāvs satur 28 masas daļas fosfonija ceturtējā savienojuma 80% ūdens šķīdumu, 3-15 masas daļas triazina, 6-12 masas daļas urīnvielas un 3-15 masas daļas trietanolamīna, bet 50%-tīga ūdens šķīduma pH ir 5,8-6,2.
- 2. Sastāvs koksnes apstrādei tās ugunsizturības nodrošināšanai pēc 1. punkta, kas atšķiras ar to, ka par ceturtējo fosfonija savienojumu izmanto indohidroksi-metilhlorīda fosfoniju ar komponentu masas daļām: fosfonija hidroksimetilhlorīds -22, trietanolamīns - 9-15, urīnviela 6-12, (ii) triazina savienojums - 6-12.
- 3. Sastāvs koksnes apstrādei pēc 1. vai 2. punkta, kas atšķiras ar to, ka triazina savienojumu izmanto ar cietināšanas laiku 40-140 min., ieteicamāk - 40-75 min.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB878702055A GB8702055D0 (en) | 1987-01-30 | 1987-01-30 | Wood treatment process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| LV11014A LV11014A (lv) | 1996-02-20 |
| LV11014B true LV11014B (en) | 1996-06-20 |
Family
ID=10611458
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| LVP-93-965A LV11014B (en) | 1987-01-30 | 1993-06-30 | Composition for wood impregnating to provide fire-resistance |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US5094890A (lv) |
| EP (1) | EP0278641B1 (lv) |
| JP (1) | JP2577029B2 (lv) |
| CN (1) | CN1016672B (lv) |
| AT (1) | ATE75650T1 (lv) |
| AU (1) | AU610117B2 (lv) |
| CA (1) | CA1298942C (lv) |
| DE (1) | DE3870645D1 (lv) |
| ES (1) | ES2037206T3 (lv) |
| FI (1) | FI94037C (lv) |
| GB (2) | GB8702055D0 (lv) |
| GR (1) | GR3005091T3 (lv) |
| LT (1) | LT3756B (lv) |
| LV (1) | LV11014B (lv) |
| NO (1) | NO172107C (lv) |
| RU (1) | RU1829995C (lv) |
| UA (1) | UA18869A (lv) |
| YU (1) | YU45486B (lv) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5389309A (en) * | 1990-12-21 | 1995-02-14 | Lopez; Richard A. | Composition and method for making fire-retardant materials |
| DE4112652A1 (de) * | 1991-04-18 | 1992-10-22 | Wolman Gmbh Dr | Holzschutzmittel |
| ZA928476B (en) * | 1991-11-27 | 1993-05-06 | Fmc Corp Uk Ltd | Composition for protecting timber from fungal growth. |
| ATE158338T1 (de) * | 1994-06-24 | 1997-10-15 | Wolman Gmbh Dr | Intumeszierendes imprägniermittel |
| US6811731B2 (en) * | 2000-10-23 | 2004-11-02 | Chemical Specialties, Inc. | Methods of incorporating phosphate/borate fire retardant formulations into wood based composite products |
| FR2876797B1 (fr) * | 2004-10-20 | 2007-01-12 | Jean Luc Sandoz | Procede pour determiner l'etat d'un support en bois |
| DE102007005527A1 (de) * | 2007-02-03 | 2008-08-07 | Alzchem Trostberg Gmbh | Verfahren zur Behandlung von Holzteilen |
| CN101121277B (zh) * | 2007-07-27 | 2010-04-07 | 瓮福（集团）有限责任公司 | 一种氮-磷高效膨胀型木材阻燃剂及其制备方法 |
| DE102007041988A1 (de) | 2007-09-05 | 2009-03-12 | Forschungszentrum Karlsruhe Gmbh | Flammhemmende Additive |
| RU2499387C2 (ru) | 2009-07-27 | 2013-11-27 | Дау Глоубл Текнолоджиз Ллк | Синергетическая противомикробная композиция |
| RU2523522C2 (ru) | 2009-09-25 | 2014-07-20 | Дау Глоубл Текнолоджиз Ллк | Синергетическая противомикробная композиция |
| EP2681998B9 (en) | 2009-10-20 | 2015-06-17 | Dow Global Technologies LLC | Synergistic antimicrobial composition |
| US8613941B1 (en) | 2012-01-05 | 2013-12-24 | Dow Global Technologies Llc | Synergistic antimicrobial composition |
| CN108115785A (zh) * | 2017-12-19 | 2018-06-05 | 重庆羽铠门业有限公司 | 一种木材加工过程中的污染处理装置 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB761195A (en) * | 1953-09-03 | 1956-11-14 | Albright & Wilson | Flame-proofing of wood |
| CH1110170A4 (lv) * | 1970-07-22 | 1972-02-15 | ||
| GB1336063A (en) * | 1971-02-23 | 1973-11-07 | Union Carbide Corp | Flame retardant composition |
| BE788586A (fr) * | 1971-09-10 | 1973-03-08 | Ciba Geigy | Procede d'obtention de produits de condensation contenant du phosphore,les produits obtenus et leur utilisation comme agent ignifuges |
| US3994971A (en) * | 1971-09-10 | 1976-11-30 | Ciba-Geigy Corporation | Phosphorus-containing condensation products |
| BE788595A (fr) * | 1972-01-14 | 1973-03-08 | Ciba Geigy | Procede de preparation de produits de condensation contenant duphosphore, les produits ainsi obtenus et leur utilisation comme ignifuges |
| US4154890A (en) * | 1972-04-17 | 1979-05-15 | Hooker Chemicals & Plastics Corp. | Process for imparting flame retardant property to cellulosic containing materials |
| CH561323A (lv) * | 1972-12-15 | 1975-04-30 | ||
| JPS5218800A (en) * | 1975-08-05 | 1977-02-12 | Toyobo Co Ltd | Process for preparing condensation products containing phosphorus |
| US4092108A (en) * | 1976-02-03 | 1978-05-30 | The United States Of America As Represented By The Secretary Of Agriculture | Compositions and process for imparting durable flame resistance to cellulosic textiles |
| US4095945A (en) * | 1976-07-23 | 1978-06-20 | Toyo Boseki Kabushiki Kaisha | Process for treating textile articles |
| US4585703A (en) * | 1982-11-15 | 1986-04-29 | Dainippon Ink & Chemicals, Inc. | Method of treating woody material and treated woody material |
| JPH0432247Y2 (lv) * | 1985-03-23 | 1992-08-03 | ||
| US4741971A (en) * | 1986-05-23 | 1988-05-03 | The Dow Chemical Company | Method for imparting flame resistance to wood surfaces |
-
1987
- 1987-01-30 GB GB878702055A patent/GB8702055D0/en active Pending
-
1988
- 1988-01-29 JP JP63017507A patent/JP2577029B2/ja not_active Expired - Lifetime
- 1988-01-29 ES ES198888300768T patent/ES2037206T3/es not_active Expired - Lifetime
- 1988-01-29 DE DE8888300768T patent/DE3870645D1/de not_active Expired - Fee Related
- 1988-01-29 YU YU176/88A patent/YU45486B/xx unknown
- 1988-01-29 CA CA000557695A patent/CA1298942C/en not_active Expired - Lifetime
- 1988-01-29 EP EP88300768A patent/EP0278641B1/en not_active Expired - Lifetime
- 1988-01-29 RU SU884355395A patent/RU1829995C/ru active
- 1988-01-29 NO NO880402A patent/NO172107C/no unknown
- 1988-01-29 AT AT88300768T patent/ATE75650T1/de not_active IP Right Cessation
- 1988-01-29 GB GB8802009A patent/GB2200363B/en not_active Expired - Lifetime
- 1988-01-29 UA UA4355395A patent/UA18869A/uk unknown
- 1988-01-29 AU AU10994/88A patent/AU610117B2/en not_active Ceased
- 1988-01-29 CN CN88100463A patent/CN1016672B/zh not_active Expired
- 1988-01-29 FI FI880416A patent/FI94037C/fi not_active IP Right Cessation
-
1990
- 1990-08-01 US US07/561,280 patent/US5094890A/en not_active Expired - Fee Related
-
1992
- 1992-07-01 GR GR920401436T patent/GR3005091T3/el unknown
-
1993
- 1993-06-30 LV LVP-93-965A patent/LV11014B/lv unknown
-
1994
- 1994-01-28 LT LTIP1817A patent/LT3756B/lt not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| FI880416A (fi) | 1988-07-31 |
| NO172107B (no) | 1993-03-01 |
| YU45486B (en) | 1992-05-28 |
| LT3756B (en) | 1996-03-25 |
| RU1829995C (ru) | 1993-07-23 |
| GB8702055D0 (en) | 1987-03-04 |
| NO172107C (no) | 1993-06-09 |
| GB8802009D0 (en) | 1988-02-24 |
| EP0278641A1 (en) | 1988-08-17 |
| GB2200363B (en) | 1991-02-20 |
| FI94037C (fi) | 1995-07-10 |
| GB2200363A (en) | 1988-08-03 |
| NO880402D0 (no) | 1988-01-29 |
| US5094890A (en) | 1992-03-10 |
| JPS63193802A (ja) | 1988-08-11 |
| GR3005091T3 (lv) | 1993-05-24 |
| EP0278641B1 (en) | 1992-05-06 |
| JP2577029B2 (ja) | 1997-01-29 |
| NO880402L (no) | 1988-08-01 |
| LTIP1817A (en) | 1995-08-25 |
| UA18869A (uk) | 1997-12-25 |
| CA1298942C (en) | 1992-04-21 |
| CN1016672B (zh) | 1992-05-20 |
| AU1099488A (en) | 1988-08-04 |
| LV11014A (lv) | 1996-02-20 |
| FI880416A0 (fi) | 1988-01-29 |
| ES2037206T3 (es) | 1993-06-16 |
| FI94037B (fi) | 1995-03-31 |
| ATE75650T1 (de) | 1992-05-15 |
| AU610117B2 (en) | 1991-05-16 |
| YU17688A (en) | 1989-10-31 |
| DE3870645D1 (de) | 1992-06-11 |
| CN88100463A (zh) | 1988-09-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| LV11014B (en) | Composition for wood impregnating to provide fire-resistance | |
| AU1791292A (en) | Composition, method and kit for potentiating antitumor activity and for curing tumor | |
| DE69432409D1 (de) | Verwendung der NDV zur Herstellung eines Medikaments zur Krebsbehandlung | |
| DK1124541T3 (da) | Anvendelse af vandopløselige eller vanddispergerbare polyetherholdige podepolymerisater som overtræksmidler, bindemidler og/eller filmdannende hjælpestoffer til farmaceutiske indgivelsesformer | |
| NO20061318L (no) | 6-[-(substituerte) fenyl] Triazolopyrimidiner somanticancer midler | |
| IL137964A0 (en) | Antitumor agents | |
| ES2135441T3 (es) | Procedimiento para la preparacion de derivados de indolo-pirrolocarbazol. | |
| MX9304801A (es) | 2-toindoles (selenoidoles) disulfuros (seleniduros) relacinados, los cuales inhiben a las proteinas tirosina cinasas y los cuales tienen propiedades anti-tumorales. | |
| TW269686B (lv) | ||
| AU1312392A (en) | New compounds, named the "leustroducins", their preparation and their therapeutic uses | |
| RU94028278A (ru) | Производные пиридо-[5,4-d]пиримидина и их соли | |
| US4277466A (en) | Complexes of DNA and esters derived from daunorubicine, their preparation and use | |
| AU3515193A (en) | Antimicrobial carbapenem derivatives, their preparation and their therapeutic use | |
| CA2124793A1 (en) | Use of creatine phosphate or phosphoenolpyruvic acid for the treatment of tumours | |
| KR900013470A (ko) | 자기 기록매체 | |
| PT98069A (pt) | Processo para a preparacao de uma poliolefina | |
| KR910021358A (ko) | 비스페놀 a의 제조방법 | |
| KR20210037594A (ko) | 항균성이 우수한 lpm 가구 및 이의 제조방법 | |
| AU3900693A (en) | Quinuclidine derivatives as squalene synthase inhibitors | |
| GB0301975D0 (en) | Treating slurries | |
| Fleming et al. | Protracted results of dose-intensive therapy using cyclophosphamide, carmustine, and continuous infusion etoposide with autologous stem cell support in patients with relapse or refractory Hodgkin's disease: a phase II study from the North American Marrow Transplant Group | |
| GB1350970A (en) | Phosphorus containing triazine derivatives processes for their pr'duction and their use | |
| CA2111974A1 (en) | Carbapenem derivatives | |
| WO2002079271A3 (en) | Acid macromonomers and their method of preparation | |
| AU2003231926A1 (en) | NOVEL PROCESS FOR STEREOSELECTIVE REDUCTION OF ss-KETOESTERS |