GB1336063A - Flame retardant composition - Google Patents
Flame retardant compositionInfo
- Publication number
- GB1336063A GB1336063A GB525671A GB1336063DA GB1336063A GB 1336063 A GB1336063 A GB 1336063A GB 525671 A GB525671 A GB 525671A GB 1336063D A GB1336063D A GB 1336063DA GB 1336063 A GB1336063 A GB 1336063A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polyphosphate
- resin
- mixture
- reaction
- trimethylolmelamine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 6
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract 2
- 239000003063 flame retardant Substances 0.000 title abstract 2
- 229920005989 resin Polymers 0.000 abstract 6
- 239000011347 resin Substances 0.000 abstract 6
- 229920000388 Polyphosphate Polymers 0.000 abstract 4
- 239000001205 polyphosphate Substances 0.000 abstract 4
- 235000011176 polyphosphates Nutrition 0.000 abstract 4
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 abstract 2
- USDJGQLNFPZEON-UHFFFAOYSA-N [[4,6-bis(hydroxymethylamino)-1,3,5-triazin-2-yl]amino]methanol Chemical compound OCNC1=NC(NCO)=NC(NCO)=N1 USDJGQLNFPZEON-UHFFFAOYSA-N 0.000 abstract 2
- 229920003180 amino resin Polymers 0.000 abstract 2
- 235000013877 carbamide Nutrition 0.000 abstract 2
- 239000007795 chemical reaction product Substances 0.000 abstract 2
- -1 cyclic ureas Chemical class 0.000 abstract 2
- 239000004744 fabric Substances 0.000 abstract 2
- ZEYUSQVGRCPBPG-UHFFFAOYSA-N 4,5-dihydroxy-1,3-bis(hydroxymethyl)imidazolidin-2-one Chemical compound OCN1C(O)C(O)N(CO)C1=O ZEYUSQVGRCPBPG-UHFFFAOYSA-N 0.000 abstract 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 abstract 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- 229920000877 Melamine resin Chemical class 0.000 abstract 1
- 239000004698 Polyethylene Substances 0.000 abstract 1
- IXYWGDAONWUVER-UHFFFAOYSA-N [(4,6-diamino-1,3,5-triazin-2-yl)amino]methanol;urea Chemical compound NC(N)=O.NC1=NC(N)=NC(NCO)=N1 IXYWGDAONWUVER-UHFFFAOYSA-N 0.000 abstract 1
- YDHWWBZFRZWVHO-UHFFFAOYSA-N [hydroxy(phosphonooxy)phosphoryl] phosphono hydrogen phosphate Chemical compound OP(O)(=O)OP(O)(=O)OP(O)(=O)OP(O)(O)=O YDHWWBZFRZWVHO-UHFFFAOYSA-N 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- WBJBEMDHFMUSAY-UHFFFAOYSA-N dibutyl phosphono phosphate Chemical compound CCCCOP(=O)(OP(O)(O)=O)OCCCC WBJBEMDHFMUSAY-UHFFFAOYSA-N 0.000 abstract 1
- BGXRJLLPQWKPIH-UHFFFAOYSA-N dimethoxymethylurea Chemical compound COC(OC)NC(N)=O BGXRJLLPQWKPIH-UHFFFAOYSA-N 0.000 abstract 1
- WVJOGYWFVNTSAU-UHFFFAOYSA-N dimethylol ethylene urea Chemical compound OCN1CCN(CO)C1=O WVJOGYWFVNTSAU-UHFFFAOYSA-N 0.000 abstract 1
- 150000002170 ethers Chemical class 0.000 abstract 1
- 150000002191 fatty alcohols Chemical class 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 abstract 1
- 238000011065 in-situ storage Methods 0.000 abstract 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical class NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 abstract 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Natural products OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 1
- 150000002924 oxiranes Chemical group 0.000 abstract 1
- 229920000573 polyethylene Polymers 0.000 abstract 1
- 229920000137 polyphosphoric acid Polymers 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 150000003672 ureas Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/423—Amino-aldehyde resins
- D06M15/43—Amino-aldehyde resins modified by phosphorus compounds
- D06M15/433—Amino-aldehyde resins modified by phosphorus compounds by phosphoric acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
- C07F9/093—Polyol derivatives esterified at least twice by phosphoric acid groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
- C08G79/02—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Textile Engineering (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
1336063 Phosphate-modified aminoplast resins; textile-treating compositions UNION CARBIDE CORP 23 Feb 1971 5256/71 Heading C3R [Also in Divisions C2 and D1] A flame retardant composition comprises the reaction product of a hydroxyalkyl polyphosphate of the formula wherein R is the divalent residue of a vicinal epoxide, Z<SP>1</SP> is a C 1-5 alkoxy group or Z, Z is a group HO(RO) m - or and m is at least one, with an aminoplast durable press resin. The polyphosphate may be obtained by reaction of an alkylene oxide with a polyphosphoric acid. Suitable resins include N- methylol derivatives of ureas, amides, carbamates, cyclic ureas, and melamine, and ethers thereof. The reaction product is preferably formed in situ on a fibrous substrate by heating the reactants to 70-200‹, these having been applied in aqueous solution which may also contain a curing agent for the resin. In examples the polyphosphates used are obtained by reaction of about 14 moles of propylene oxide, ethylene oxide, or epichlorhydrin, or a mixture of these, with tetraphosphoric acid, or of propylene oxide with dibutyl pyrophosphoric acid: the resins used are a methylol melamine-urea mixture, trimethylolmelamine, dimethoxymethylurea, dimethyloldihydroxyethyleneurea, and a mixture of dimethylolethyleneurea and trimethylolmelamine; the polyphosphate and resin are dissolved in water with Zn(NO 3 ) 2 catalyst, and optionally a polyethylene softener and/or an ethoxylated fatty alcohol surfactant, and applied to cellulosic fabrics: the fabrics are dried at 140‹ C. and cured at about 170‹ C.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB525671 | 1971-02-23 | ||
| DE19712109846 DE2109846A1 (en) | 1971-02-23 | 1971-03-02 | Flame retardants |
| FR7108925A FR2129084A5 (en) | 1971-02-23 | 1971-03-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1336063A true GB1336063A (en) | 1973-11-07 |
Family
ID=27183241
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB525671A Expired GB1336063A (en) | 1971-02-23 | 1971-02-23 | Flame retardant composition |
Country Status (3)
| Country | Link |
|---|---|
| DE (1) | DE2109846A1 (en) |
| FR (1) | FR2129084A5 (en) |
| GB (1) | GB1336063A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4376802A (en) | 1980-01-24 | 1983-03-15 | Allied Corporation | Finish composition for polyester yarn |
| EP0278641A1 (en) * | 1987-01-30 | 1988-08-17 | Albright & Wilson Limited | Wood treatment composition and process |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2253662A1 (en) * | 1972-11-02 | 1974-05-22 | Hoechst Ag | FLAME RESISTANT EQUIPMENT OF FIBER MATERIAL BASED ON PHOSPHORIC ACID ESTERS |
| CN114517407B (en) * | 2022-02-25 | 2023-08-29 | 江苏恒力化纤股份有限公司 | Cyclic borate flame retardant and preparation method of flame-retardant polyester fiber product thereof |
-
1971
- 1971-02-23 GB GB525671A patent/GB1336063A/en not_active Expired
- 1971-03-02 DE DE19712109846 patent/DE2109846A1/en active Pending
- 1971-03-15 FR FR7108925A patent/FR2129084A5/fr not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4376802A (en) | 1980-01-24 | 1983-03-15 | Allied Corporation | Finish composition for polyester yarn |
| EP0278641A1 (en) * | 1987-01-30 | 1988-08-17 | Albright & Wilson Limited | Wood treatment composition and process |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2109846A1 (en) | 1972-09-14 |
| FR2129084A5 (en) | 1972-10-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |