KR950031013A - 치과용 충전 조성물 및 방법 - Google Patents

치과용 충전 조성물 및 방법 Download PDF

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KR950031013A
KR950031013A KR1019950006385A KR19950006385A KR950031013A KR 950031013 A KR950031013 A KR 950031013A KR 1019950006385 A KR1019950006385 A KR 1019950006385A KR 19950006385 A KR19950006385 A KR 19950006385A KR 950031013 A KR950031013 A KR 950031013A
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composition
substituted
monomer
filler
alkyl
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KR1019950006385A
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에. 클레 요아힘
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게르하르트 슈미트
덴츠플라이 게엠베하
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Publication of KR950031013A publication Critical patent/KR950031013A/ko

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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00Preparations for dentistry
    • A61K6/50Preparations specially adapted for dental root treatment
    • A61K6/54Filling; Sealing

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  • Health & Medical Sciences (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Epidemiology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Dental Preparations (AREA)
  • Dental Tools And Instruments Or Auxiliary Dental Instruments (AREA)
  • Cosmetics (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Epoxy Resins (AREA)

Abstract

본 발명은 치과용 충전조성물 및 그 방법에 관한 것으로, 본 발명에 따른 치근관봉합 치과용 충전조성물은 액상의 중합가능한 유기단량체 및 필러를 포함한다. 중합가능한 유기단량체는 디엑포사이드 단량체 및 1급 모노아민 및/또는 2급 아민 단량체를 포함한다. 필러는 조성물이 40 내지 85중량%를 차지하며, 적어도 3㎜/㎜A1의 방사선투과성을 제공한다. 치관 봉합방법은 치관을 봉할 치하중의 치관에 본 발명의 치근관 봉합 치과용 충전조성물을 제공하는 것이다.

Description

치과용 충전 조성물 및 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (24)

  1. 에폭사이드 단량체가 디에폭사이드이고 단량체를 함유하는 아민이 1급 모노아민 및/또는 2급 디아민인, 중합가능한 에폭사이드 잔기 및 아민 잔기를 포함하는 액체 중합가능한 유기 단량체 및 조성물의 40 내지 85중량%를 차지하여도 적어도 3㎜/㎜A1의 방사선투과성을 제공하는 필러를 포함함을 특징으로 하는 치근관 봉합치과용 충전조성물.
  2. 제1항에 있어서, 상기 단량체가 중합되어 치근관을 봉하는데 사용하는 열가소성 선형 중합체를 형성하는 조성물.
  3. 제1항에 있어서, 상기 중합가능한 에폭사이드 단량체가 비스페놀-A의 디글리시딜 에테르, 비스페놀-F의 디글리시딜 에테르, 부탄디올 디글리시딜 에테르 또는 △3-테트라히드로프탈산 에스테르인 조성물.
  4. 제1항에 있어서, 상기 모노아민이 벤질아민, 아다만탄아민, α-펜에틸아민 또는 에탄올아민이고; 디아민이 N,N'-디벤질에틸렌디아민, N,N'-디벤질-3.6-디옥사옥디아민-1.8, N,N'-디벤질-5-옥사노난디아민-1.9, N,N'-디벤질-(2,2,4)/(2,4,4)-트리메틸렉사 메틸렌디아민인 조성물.
  5. 제1항에 있어서, TKDRL 필러가 La2O3, ZrO2, BiPO4, BaWO4, SrF2, Bi2O3및/또는 중합체 입자인 조성물.
  6. 제1항에 있어서, 상기 조성물이 함께 혼합되어 중합화를 개시하는데 적용되는 2-성분으로부터 형성되는 조성물.
  7. 제1항에 있어서, 디에폭사이드, 모노아민 및/또는 디아민이 적용되어 CHCl3및/또는 C2H5OH 중에 가용성인 복합물을 형성하는 조성물.
  8. 제1항에 있어서, 상기 필러가 적어도 3㎜/㎜Al의 방사선투과성을 제공하는 조성물.
  9. 제1항에 있어서, 상기 필러가 적어도 5㎜/㎜Al의 방사선투과성을 제공하는 조성물.
  10. 제1항에 있어서, 상기 조성물이 37℃에서 0.5 내지 40시간 내에 고정되도록 되어 있는 조성물.
  11. 제1항에 있어서, 상기 조성물이 0.5 내지 3시간내에 고정되도록 되어 있는 조성물.
  12. 제1항에 있어서, 상기 조성물이 5000CP 미만의 점도를 가지는 조성물.
  13. 제1항에 있어서, 상기 아민 단량체와 에폭사이드 단량체가 중합되어 다음 일반식(Ⅰ), (Ⅱ) 및 (Ⅲ)중 적어도 하나의 범주내의 중합체를 형성하는 조성물.
    상기식에서, R은 디에폭사이드로부터 형성된 잔기이고; R1은 탄소수 2 내지 12의 치환된 알킬, 시클로알킬, 치환된시클로알킬, 탄소수 6 내지 20의 아릴, 치환된 아릴, 아릴알킬, 또는 치환된 아릴알킬이며; R2는 2기능성 알킬, 탄소수2 내지 12의 치환된 알킬, 시클리알킬, 치환된 시클로알킬, 탄소수 6 내지 20의 아릴, 치환된 아릴, 아릴 알킬, 또는 치환된 아릴알킬이고; n, m, x 및 y는 1 내지 1,000사이의 정수이며, 치환되는 경우, R1및 R2는 서로 독립적으로 알콕시, 할로겐, 니트레이트, 아실 또는 카르복시 알킬 잔기중 하나 이상으로 치환됨.
  14. 에폭사이드 단량체가 디에폭사이드이고, 아민단량체가 1급 노모아민 및/또는 2급 디아민인 액체중합가능한 유기 단량체 및 조성물의 40 내지 85중량%를 차지하며, 적어도 3㎜/㎜Al의 방사선 투과성을 제공하는 필러를 포함하는 치근관 봉합 치과용 조성물을 치관을 봉할 치아중 치관에 제공함을 특징으로 하는 치관 봉합 방법.
  15. 제14항에 있어서, 중합가능한 에폭사이드 단량체가 비스페놀-A의 디글리시딜 에테르, 비스페놀-F의 디글리시딜 에테르, 부탄디올 디글리시딜 에테르 또는 △3-테트라히드로프탈산 디글리시딜 에스테르인 방법.
  16. 제14항에 있어서, 상기 모노아민이 벤질아민, 아다만탄아민, α-펜에틸아민 또는 에탄올이만이고; 디아민이 N,N'-디벤질에틸렌디아민, N,N'-3,6-디옥사옥탄디아민,-1.8, N,N'-디벤질-5-옥사노난디아민-1.8, N,N'-디벤질-(2,2,4)/(2,4,4)-트리메틸헥사 메틸렌디아민인 방법.
  17. 제14항에 있어서, 상기 필러가 La2O3, ZrO2, BiPO4, BaWO4, SrF2, Bi2O3및/또는 중합체 입자인 방법.
  18. 제14항에 있어서, 상기 조성물이 함께 혼합되어 중합반응을 개시하는데 적용되는 2-성분으로부터 형성되는 조성물인 방법.
  19. 제14항에 있어서, 상기 필러가 적어도 3㎜/㎜Al의 방사선투과성을 제공하는 방법.
  20. 제14항에 있어서, 상기 조성물이 0.5 내지 3시간내에 고정되는 방법.
  21. 제14항에 있어서, 상기 조성물이 점도가 20,000CP 미만의 점도를 가지고 1㎜직경도관의 니들을 통해 치근으로 통과되는 방법.
  22. 제21항에 있어서, 상기 조성물의 3%미만의 체적 수출률로 중합되고, 상아질에 대해 실질적인 접착성을 갖는 방법.
  23. 제14항에 있어서, 상기 조성물의 점도가 5,000CP 미만인 방법.
  24. 제14항에 있어서, 아민 단량체와 에폭사이드 단량체가 중합되어 다음 일반식(Ⅰ), (Ⅱ) 및 (Ⅲ)중 적어도 하나의 범주내의 중합체를 형성하는 방법.
    상기식에서, R은 디에폭사이드로부터 형성된 잔기이고; R1은 탄소수 2 내지 12의 치환된 알킬, 시클로알킬, 치환된 시클로알킬, 탄소수 6 내지 20의 알릴, 치환된 아릴, 아릴알킬, 또는 치환된 아릴알킬이며; R2는 2기능성 알킬, 탄소수 2 내지 12의 치환된 알킬, 시클로알킬, 치환된 시클로알킬, 탄소수 6 내지 20의 아릴, 치환된 아릴, 아릴 알킬, 또는 치환된 아릴아킬이고; n, m, x 및 y는 1 내지 1,000 이며, 치환되는 경우, R1및 R2는 서로 독립적으로 알콕시, 할로겐, 니트레이트, 아실 또는 카르복시 알킬 잔기중 하나 이상으로 치환된다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950006385A 1994-03-25 1995-03-24 치과용 충전 조성물 및 방법 KR950031013A (ko)

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US08/217,998 US5624976A (en) 1994-03-25 1994-03-25 Dental filling composition and method
US08/217998 1994-03-25

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KR950031013A true KR950031013A (ko) 1995-12-18

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US (1) US5624976A (ko)
EP (1) EP0673637B1 (ko)
JP (1) JPH083014A (ko)
KR (1) KR950031013A (ko)
CN (1) CN1112413A (ko)
AT (1) ATE194766T1 (ko)
AU (1) AU699521B2 (ko)
CA (1) CA2144584C (ko)
DE (1) DE69518030T2 (ko)
ES (1) ES2149288T3 (ko)
FI (1) FI951408A (ko)
ZA (1) ZA952422B (ko)

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EP0673637A1 (en) 1995-09-27
AU699521B2 (en) 1998-12-03
DE69518030D1 (de) 2000-08-24
EP0673637B1 (en) 2000-07-19
US5624976A (en) 1997-04-29
CA2144584A1 (en) 1995-09-26
CN1112413A (zh) 1995-11-29
FI951408A0 (fi) 1995-03-24
FI951408A (fi) 1995-09-26
ATE194766T1 (de) 2000-08-15
ZA952422B (en) 1996-01-11
AU1483895A (en) 1995-10-05
JPH083014A (ja) 1996-01-09
DE69518030T2 (de) 2000-12-21
ES2149288T3 (es) 2000-11-01
CA2144584C (en) 2002-08-27

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